KR930005592B1 - Method of forming black matrix on crt panel - Google Patents

Method of forming black matrix on crt panel Download PDF

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Publication number
KR930005592B1
KR930005592B1 KR1019910009337A KR910009337A KR930005592B1 KR 930005592 B1 KR930005592 B1 KR 930005592B1 KR 1019910009337 A KR1019910009337 A KR 1019910009337A KR 910009337 A KR910009337 A KR 910009337A KR 930005592 B1 KR930005592 B1 KR 930005592B1
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South Korea
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panel
black matrix
cathode ray
ray tube
exposure
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KR1019910009337A
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Korean (ko)
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KR930001270A (en
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김병주
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삼성전관 주식회사
김정배
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J9/00Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
    • H01J9/20Manufacture of screens on or from which an image or pattern is formed, picked up, converted or stored; Applying coatings to the vessel
    • H01J9/22Applying luminescent coatings
    • H01J9/227Applying luminescent coatings with luminescent material discontinuously arranged, e.g. in dots or lines
    • H01J9/2278Application of light absorbing material, e.g. between the luminescent areas
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J9/00Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
    • H01J9/20Manufacture of screens on or from which an image or pattern is formed, picked up, converted or stored; Applying coatings to the vessel

Abstract

The black matrix of a cathode ray tube (CRT) is formed by (a) covering a polyvinyl pyrrolidone-photosensitive liquor onto the inner surface of the panel for the CRT, and then drying it, (b) light-exposing it by the ultraviolet irradiation of 200-500 nm wave length for 2-5 sec., (c) bonding a mask onto the inner surface of the panel, and (d) light-exposing it, coating it with a colloidal graphite, and then etching it.

Description

음극선관 패널면의 블랙 매트릭스 형성방법Method of Forming Black Matrix on Cathode Ray Tube Panel

본 발명은 칼라 음극선관의 형광체패턴을 구획하는 블랙매트릭스를 패널 내측면에 형성하는 방법에 관한 것으로서, 보다 상세하게는 폴리비닐필로리돈계 감광제에 적합한 음극선관 패널면의 블랙 매트릭스 형성방법에 관한 것이다.The present invention relates to a method of forming a black matrix on a panel inner surface that partitions a phosphor pattern of a colored cathode ray tube, and more particularly, to a method of forming a black matrix of a cathode ray tube panel surface suitable for a polyvinylpyrrolidone-based photosensitive agent. .

블랙 매트릭스는 콜로이드상의 혹연을 패널 내측면에 도포하여 형성되는 것으로서, 그 공정은 다음과 같다.The black matrix is formed by applying a colloidal abyss to the inner surface of the panel, and the process is as follows.

음극선관용 패널의 내측면에 감광도료를 피착하고 그 위로 매트릭스 형성용 마스크를 밀착시킨 다음, 이 마스크를 개재하여 노광 현상, 콜로이드상 혹연도포, 그리고 에칭하고 현상하면 소망의 블랙 매트릭스를 얻을 수 있다.A photosensitive paint is deposited on the inner surface of the cathode ray tube panel, and a mask for forming a matrix is brought into close contact therewith, followed by exposure development, colloidal graphite coating, and etching through this mask to develop a desired black matrix. .

이와 같은 블랙 매트릭스 형성공정에서, 감광제로는 폴리 비닐 필로리돈이 사용되고 있다.In such a black matrix forming step, polyvinyl pilolidone is used as the photosensitizer.

이 경우에 형광체패턴을 형성하는 R, G, B 스트라이프별로 노광시간을 달리해야 하는 문제가 생긴다.In this case, a problem arises in that the exposure time is different for each of the R, G, and B stripes forming the phosphor pattern.

실예를 들면, G 스트라이프는 5.6초, B 스트라이프는 5.2초, R 스트라이프는 5초로 각각 노광해야만 소망하는 패턴별 스트라이프를 얻을 수 있다.For example, a G-stripe of 5.6 seconds, a B stripe of 5.2 seconds, and an R stripe of 5 seconds each require exposure to obtain a desired patterned stripe.

각 패턴별로 노광시간이 달라지게 되는 원인은 도포된 감광제에 내포된 수분, 산소와 같은 반응 방해원소가 노광이 거듭될 수록 줄어 들어 뒤에 노광할 수록 반응이 잘 이루어지기 때문에 처음 노광시 보다 나중 노광이 짧아지게 되는 것이다.The reason that the exposure time is different for each pattern is that the reaction disturbing elements such as moisture and oxygen contained in the applied photosensitive agent decrease as the exposure is repeated, and the reaction is better as the subsequent exposure is performed. It will be short.

그런데 각 패턴별 스트라이프의 노광시간 차이는 상이과 같이 마이크로초 단위로 되기 때문에 이를 관리하기가 어려운 단점이 있다.However, since the exposure time difference of each pattern stripe is in microsecond units as different, there is a disadvantage that it is difficult to manage.

본 발명은 상술한 블랙매트릭스 형성방법의 단점을 해결하기 위하여 각 스트라이프의 노광시간 차이가 거의 없는 새로운 블랙 매트릭스 형성방법을 제공함에 있다.The present invention provides a new method of forming a black matrix with little difference in exposure time of each stripe in order to solve the disadvantages of the method of forming a black matrix described above.

상기 목적은 구현하고자, 본 발명은 음극선관용 패널의 내측면에 감광도료를 도포 건조시킨 다음, 파장 200-500nm의 자외선을 전기한 음극선관용 패널 내측면 전체로 2-5초간 조사시켜서 예비 노광하고, 다음에 음극선광용 패널의 내측면에 마스크를 밀착시킨 다음, 이 마스크를 개재하여 노광 현상, 콜로이드상 흑연도표, 그리고 에칭 현상 순으로 행해짐을 특징으로 한다.To achieve the above object, the present invention is applied by drying the photosensitive paint on the inner surface of the cathode ray tube panel, and then pre-exposure by irradiating the entire inner surface of the cathode ray tube panel with ultraviolet rays of wavelength 200-500nm for 2-5 seconds, Next, the mask is brought into close contact with the inner surface of the cathode ray panel, followed by exposure development, colloidal graphite diagram, and etching development via the mask.

이와 같이 음극선관용 패널의 내측면에 감광액을 도포시킨 다음, 전체면을 예비노광하고 본 노광을 실시함에 따라 R, G, B 각 스트라이프의 노광시간을 일률적으로 관리하여도 각 스트라이프의 폭이 일정하게 형성된다.In this way, after the photosensitive liquid is applied to the inner surface of the cathode ray tube panel, the entire surface is pre-exposured and the main exposure is carried out, so that even if the exposure time of each of the R, G, and B stripes is uniformly managed, the width of each stripe is constant. Is formed.

이하 본 발명을 바람직한 실시예로서 상세히 설명한다.Hereinafter, the present invention will be described in detail as a preferred embodiment.

순수에 의해 내측면이 세정된 음극선관용 패널에 폴리 비닐 필로리돈계 감광액을 도포하고 건조시킨다.A polyvinyl pilolidone-based photosensitive liquid is applied to a cathode ray tube panel whose inner surface is washed with pure water and dried.

건조된 패널을 통상의 노광장치에 탑재하여 200-500nm의 자외선에 노출시켜 패널의 내측면 전체가 2-5초 바람직하게는 3초간 노광시켜 예비노광을 한다.The dried panel is mounted in a conventional exposure apparatus, and is exposed to ultraviolet rays of 200-500 nm, and the entire inner surface of the panel is exposed for 2-5 seconds, preferably 3 seconds, to be pre-exposured.

다음에 패널의 내측면 상으로 매트릭스 형성용 마스크를 개재지키고 본 노광을 실시한다.Next, this exposure is performed while interposing a mask for forming a matrix on the inner surface of the panel.

본 노광은 통상적인 방법에 따라 수은여기 자외선등을 광원으로 하는 것이며, 단지 R, G, B 스트라이프 각각의 노광식간은 10∼20초 바람직하게는 15초간 동일한 시간으로 노광한다.In this exposure, mercury-excited ultraviolet light is used as a light source according to a conventional method, and only the exposure time of each of the R, G, and B stripes is exposed for the same time for 10 to 20 seconds, preferably 15 seconds.

노광된 패널을 노광장치에서 내리고 현상한다. 현상과정에서 비노광부는 세정되어 패널의 내측면에는 단지 블랙 매트릭스로 되는 노광부만이 남게 된다.The exposed panel is lowered and developed in the exposure apparatus. In the development process, the non-exposed part is cleaned so that only the exposed part, which becomes a black matrix, remains on the inner surface of the panel.

현상과정을 거친 패널을 적외선으로 건조하고, 다시 그 위로 콜로이드상 흑연을 도포한다.The developed panel is dried by infrared rays, and then colloidal graphite is applied on it.

콜로이드상 흑연은 패널의 내측면 전체에 걸쳐 고르게 도포된다.Colloidal graphite is applied evenly over the inner side of the panel.

흑연이 도포된 패널은 다시 순수로 세정되어 에칭된 비노광부에 도포되어 있는 흑연이 씻겨 제거되게 하면, 소망의 블랙 매트릭스가 패널 내측면에 남게 된다.The graphite coated panel is washed again with pure water so that the graphite applied to the etched non-exposed part is washed away and the desired black matrix remains on the inner surface of the panel.

이상과 같이 행하는 본 발명의 방법은 감광액을 도포하고 건조시킨 다음에 전체를 동일한 조건으로 예비노광시켜서 감광과정에서 장애를 일으키는 물이나 산소 등을 제거함으로써 이들이 감광과정에서 문제를 일으키는 원인으로 되는 일이 없게 하고 있으므로 각각의 스트라이프 폭이 일정한 매트릭스패턴을 얻을 수 있고, 또 본 노광과정에서 노광시간을 스트라이프 별로 관리해야 할 필요도 없게 되어 한층 용이하게 실시할 수 있음과 아울러 이렇게 얻어진 매트릭스패턴은 음극선관의 화면 상 휘도를 균일하게 하는 품질적 향상을 제공하기도 한다.In the method of the present invention as described above, by applying and drying the photosensitive liquid and then pre-exposure the whole under the same conditions to remove the water or oxygen, which causes obstacles in the photosensitive process, they cause a problem in the photosensitive process. Since the matrix pattern has a uniform stripe width, a matrix pattern can be obtained, and the exposure time does not need to be managed for each stripe in the present exposure process, so that the matrix pattern can be more easily performed. It also provides a quality improvement that makes screen brightness uniform.

Claims (1)

음극선관용 패널의 내측면에 폴리 비닐 필로리돈계 감광액을 도포해서 블랙 매트릭스를 형성함에 있어서, 상기의 감광액을 패널 내측면에 도포건조시킨 다음, 파장 200-500nm의 자외선을 전기한 음극선관용 패널 내측면 전체로 2-5초간 조사시켜서 예비 노광하고, 다음에 음극선관용 패널의 내측면에 마스크를 밀착시킨 다음, 이 마스크를 개재하여 노광 현상, 콜로이드상 흑연도포, 그리고 에칭 현상 순으로 행해짐을 특징으로 하는 음극선관용 패널의 블랙 매트릭스 형성방법.In forming a black matrix by applying polyvinyl pilolidone-based photosensitive liquid to the inner surface of the cathode ray tube panel, the photosensitive liquid is applied to the inner side of the panel and dried, and then the inner surface of the cathode ray tube panel which is exposed to ultraviolet rays having a wavelength of 200 to 500 nm. After preliminary exposure by irradiating for 2-5 seconds, the mask is brought into close contact with the inner surface of the cathode ray tube panel, and then subjected to exposure development, colloidal graphite coating, and etching development through this mask. Method for forming black matrix of cathode ray tube panel.
KR1019910009337A 1991-06-05 1991-06-05 Method of forming black matrix on crt panel KR930005592B1 (en)

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KR930001270A KR930001270A (en) 1993-01-16
KR930005592B1 true KR930005592B1 (en) 1993-06-23

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