KR930001810B1 - Water purifying material - Google Patents

Water purifying material Download PDF

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KR930001810B1
KR930001810B1 KR1019860008319A KR860008319A KR930001810B1 KR 930001810 B1 KR930001810 B1 KR 930001810B1 KR 1019860008319 A KR1019860008319 A KR 1019860008319A KR 860008319 A KR860008319 A KR 860008319A KR 930001810 B1 KR930001810 B1 KR 930001810B1
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water
coral sand
coral
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chlorine
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KR880004838A (en
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노브오 소메야
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마린바이오 가부시끼가이샤
노브오 소메야
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment

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  • Hydrology & Water Resources (AREA)
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  • Water Supply & Treatment (AREA)
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Abstract

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Description

정수제Water purifier

본 발명은, 음료수등의 정수제에 관한 것이며, 특히 정수장의 물에 침지하여 둠으로써 제균효과를 발휘함과 동시에 물을 알칼리성으로 이행시키고, 또한 염소, 중금속 및 불순물이 흡착제거된 양질의 미네랄워터로 할 수가 있는 정수제(淨水製)에 관한 것이다.The present invention relates to water purifiers such as beverages, and in particular, by immersing in water of a water purification plant, it exhibits a bactericidal effect, transfers water to alkalinity, and is a high quality mineral water in which chlorine, heavy metals and impurities are adsorbed and removed. It relates to a water purification agent that can be made.

근년, 하천등의 수질오염이 진행됨에 따라서, 이것을 수도물로 이용하기 위해, 오탁물질의 제거, 멸균등을 목적으로 하여, 화학약품이 더욱더 다량으로 사용되게 되었다. 예컨대, 정수장에서는 원수가 오탁하는 것을 방지하기 위해, 여과제로서 황산반토등으로 유기물을 침전화하고, 살균제로는 염소가 사용되고 있으나, 이들 화학물질의 사용으로 원수가 산성화하고, 그로인하여 수도관등에 빨간 녹이 발생하여, 수도관이 부식된다는 문제가 발생하고 있다.In recent years, as water pollution in rivers and the like progresses, in order to use this as tap water, more and more chemicals have been used for the purpose of removing contaminants and sterilization. For example, in a water purification plant, organic matters are precipitated with alumina as a filter agent and chlorine is used as a disinfectant, and chlorine is used as a disinfectant. However, raw water is acidified due to the use of these chemicals, which results in redness in water pipes. There arises a problem that rust is generated and the water pipes are corroded.

이와같은 수도관의 부식을 방지하기 위해, 원수를 알칼리화시키도록 가성소오다, 소오다회, 탄산칼슘이 일반적으로 사용되고 있다. 그러나, 이들 가성소오다등은 자극성이 강하고, 피부 및 기타의 동물조직에 심한 작용을 하기 때문에, 손이 트는 등의 원인도 되어, 특히 정수장 부근의 주민일수록 그 피해에 괴로움을 당하고 있다.In order to prevent corrosion of such water pipes, caustic soda, soda ash, and calcium carbonate are generally used to alkalinize raw water. However, since these caustic soda and the like are highly irritating and have a severe action on skin and other animal tissues, they may cause hand breaks and the like, and especially the residents near the water purification plant suffer more damage.

본 발명의 목적은, 상기 종래예의 가성소오다, 소오다회등의 수도관 부식방지제와는 다른 안전하고 또한 여러가지 정수기능을 가지며 제균작용도 수반하는 천연의 정수제를 제공하는데 있다.SUMMARY OF THE INVENTION An object of the present invention is to provide a natural water purification agent which is safe and has various water purification functions and also has a bactericidal action different from water pipe corrosion inhibitors such as caustic soda and soda ash of the conventional example.

본 발명자는 상기 문제점을 해결하기 위해, 여러가지의 실험결과, 가성소오다등의 수도관 부식방지제에 대신하는 것으로, 조초(造礁) 산호의 생골격이나 화석군(化石群)에서 얻어지는 코랄샌드가, 물을 알칼리상으로 이행시켜, 맛있는 미네랄수로 할 수가 있고, 염소, 중금속 및 불순물을 흡착제거할 뿐만 아니라 더구나 코랄샌드가 갖는 그의 독자의 제균효과로부터 물을 제균시켜 종래의 화학 화합물의 정수제를 대신하는 정수제로서 사용할 수 있는 것을 발견하고, 본 발명을 완성하기에 이르렀다.MEANS TO SOLVE THE PROBLEM In order to solve the said problem, the present inventors substituted various water pipe corrosion inhibitors, such as caustic soda, and the coral sand obtained from the raw skeletal structure of fossil coral and fossil group, water, Can be converted into an alkaline phase to form a delicious mineral water, and not only adsorption and removal of chlorine, heavy metals and impurities, but also sterilizes water from its own bactericidal effect of Coral Sand to replace the conventional water purification agent of chemical compounds It discovered what can be used as a water purifier to make, and came to complete this invention.

본 발명에서 말하는 코랄샌드란, 조초산호의 생골격이나 화석군에서 얻어지는 코랄샌드이고, 표 1에 표시한 바와 같이, 탄산칼슘(CaCO3, 약 95%)을 주성분으로 해서 중요한 생체성분인 마그네슘, 스트론튬, 나트륨, 칼륨, 인, 염소를 위시해서 미량의 철, 동, 아연, 망간, 코발트, 크롬등을 함유하고 있다.Coral sand is referred to in the present invention, the coral sand obtained by the production skeleton or hwaseokgun of one trillion seconds coral, as shown in Table 1, and calcium carbonate as the main component (CaCO 3, about 95%) by significant biological component, magnesium, strontium Contains traces of iron, copper, zinc, manganese, cobalt and chromium, including sodium, potassium, phosphorus and chlorine.

[표 1 (코랄샌드의 성분표)]Table 1 (Composition table of coral sand)

Figure kpo00001
Figure kpo00001

이들의 원소는 강장동물인 조초산호의 생명활동에 의해 축적 풍화된 것이다.These elements accumulate and weathered by the life activities of the tonic coral.

따라서, 화학적처리에 의해 얻어지는 다른 정수제와는 달리, 생태학적 화학조직을 가지고 있어, 인체에 안전하고, 더구나 탄산칼슘을 주성분으로 하기 때문에 물을 알칼리화 하는 효과를 가지고, 예컨대 이것을 직접 시식하여도 인체에는 하등 해를 미치지 않는 것이다.Therefore, unlike other water purifiers obtained by chemical treatment, it has an ecological chemical structure and is safe for the human body. Moreover, since calcium carbonate is the main component, it has the effect of alkalizing water. There is no harm.

코랄샌드가 염소를 제거하는 과정을 설명하면, 코랄샌드는 탄산칼슘을 주성분으로 하기 때문에, 다음 식에 표시한 바와같이 원수를 염소살균하는 과정에서 유리되는 산(H3O+)를 중화하고, 칼슘이온(Ca2+), 염소이온(Cl-)과 중탄산이온(HCO3 -)으로 분해한다.When coral sand explains the process of removing chlorine, since coral sand is mainly composed of calcium carbonate, neutralizing acid (H 3 O + ) liberated in the process of chlorination of raw water, as shown in the following equation, Parts by calcium ions (Ca 2+), chloride (Cl - -) and bicarbonate ion (HCO 3).

Figure kpo00002
Figure kpo00002

(1) 내지 (4)까지의 각 반응식을 집약하면 (5)식에 표시하는 결과로 된다.When each reaction formula from (1) to (4) is aggregated, it is a result shown in Formula (5).

따라서 생석회 냄새가 있는 염소를 함유하는 물은, 코랄샌드에 의하여 탈취되고, 동시에 부생하는 중탄산 이온 때문에 원수의 pH는 알칼리성측으로 이행됨과 동시에 다량으로 칼슘이온을 함유하게 되고, 양질의 미네랄워터가 얻어진다.Therefore, the water containing chlorine with quicklime smell is deodorized by the coral sand, and at the same time, the pH of the raw water is shifted to the alkaline side due to the by-product bicarbonate ions, and contains a large amount of calcium ions, and high quality mineral water is obtained. .

또한 코랄샌드의 주성분인 탄산칼슘의 칼슘이 수중의 중금속이온과 치환되어 칼슘이온으로 되고 중금속은 난용성의 탄산염으로 되어 코랄샌드가 갖는 미세한 구멍에 의해 흡착제거된다.In addition, calcium of calcium carbonate, which is a major component of coral sand, is replaced with heavy metal ions in water to form calcium ions, and heavy metals become poorly soluble carbonates, which are adsorbed and removed by the fine pores of coral sand.

더욱이 가열에 의해 미세한 구멍이 발달하여 표면적이 크게 됨으로써 수중의 불순물을 흡착제거한다.In addition, fine pores develop by heating to increase the surface area, thereby adsorbing and removing impurities in the water.

또, 본 발명의 정수제의 대상인 코랄샌드는 그것 자체가 제균효과를 가지는 것이 실험결과 판명되었다.In addition, it was found that the coral sand, which is the object of the water purifying agent of the present invention, has an bactericidal effect by itself.

이 효과를 입증하기 위해, 지바껜 에이세이 단기 대학에 시험을 의뢰한 결과는 다음과 같았다.In order to prove this effect, the results of applying the test to Chibasei Asei Junior College were as follows.

우선 대장균을 플레이트한 것에, 본 발명의 대상인 코랄샌드를 부분적으로 뿌렸던바, 코랄샌드를 뿌린 부분만이 대장균 생육 저지 효과를 보였다.First, the E. coli plate was partially sprayed with Coral Sand, which is the subject of the present invention, and only the portion sprayed with Coral Sand showed an effect of inhibiting E. coli growth.

다음에 코랄샌드를 전면에 뿌렸던바 대장균 생육 저지 효과가 전면에 걸쳐 분명히 나타났다.Next, the coral sand was sprayed on the front, and the effect of preventing the growth of E. coli was evident throughout.

이와같이 실험한 결과, 지금까지 세균제로서는 전혀 생각하지 않았던 코랄샌드가 명료하게 대장균 생육 저지 효과를 가진다는 것을 판명하고 천연물의 제균제로서 사용될 수 있다는 것을 알았다.As a result of this experiment, it was found that coral sand, which was never thought of as a bacterial agent, clearly has an effect of inhibiting the growth of E. coli and can be used as a natural antibacterial agent.

또 코랄샌드에 은을 부착하여 더욱 제균효과를 높일 수는 있으나, 본 발명의 코랄샌드는 은을 부착하지 않아도 방부제로서의 효과를 충분히 발휘할 수 있는 것이다.In addition, by attaching silver to the coral sand can further increase the bactericidal effect, the coral sand of the present invention can fully exhibit the effect as a preservative without attaching silver.

이상과 같은, 본 발명의 대상인 코랄샌드는 정수장의 원수에 침지시켜 두어도 좋으나, 그의 효과를 일층 높이기 위해서는 필터에 채워서 원수를 통수하는 것이 바람직하다. 또 가정용의 정수제로서 사용할 수 있는 것도 물론이다.Coral sand, which is the object of the present invention as described above, may be immersed in the raw water of the water purification plant, but in order to further enhance the effect thereof, it is preferable to fill the filter with water and pass the raw water. Of course, it can also be used as a household water purifier.

본 발명의 정수제는 다음과 같이 제조할 수 있다. 효과적인 제균작용을 하는 정수제를 제공하기 위해서, 우선 천연으로 얻어지는 코랄샌드를 수세하여 염분 및 불순물을 제거한 후, 80 내지 150℃의 품온에서 열소독, 건조 및 활성화시켜 제조할 수 있다. 상기와 같이 처리함으로써 코랄샌드는 염분 및 유기동물등의 불순물이 제거되고, 10마이크론 이하의 미세한 세공들이 발달하여 그 표면적이 크게됨으로서 활성화된다.The water purification agent of this invention can be manufactured as follows. In order to provide a water purifying agent having an effective bactericidal action, it is possible to first prepare a coral sand obtained by washing with water to remove salts and impurities, and then heat disinfection, drying and activating at a temperature of 80 to 150 ° C. By treating as described above, the coral sand is activated by removing impurities such as salt and organic animals, and developing fine pores of 10 microns or less and increasing its surface area.

상기와 같이 처리하여 얻은 코랄샌드에 물을 접촉시켜 원수를 정수하면 원수의 염소취가 탈취되고, 원수가 알카리화될 뿐만 아니라 원수에 양질의 미네랄을 제공하게 된다. 또한 코랄샌드의 주성분인 칼슘이 중금속과 치환되고 동시에 코랄샌드의 미세 세공에 중금속이 흡착됨으로써 중금속이 제거된다. 또한 상기와 같이 처리된 코랄샌드는 본 발명의 가장 특징적인 부분인 효과적인 제균작용을 발휘하여, 은과 같은 별도의 제균효과를 나타내는 성분을 부착하지 아니해도 방부제로서의 효과를 충분히 발휘하여 종래의 화학물질과는 다른 인체에 안전한 천연의 정수제를 제공하게 된다.When the raw water is purified by contacting the coral sand obtained by treatment as described above, the chlorine odor of the raw water is deodorized, and the raw water is not only alkaline but also provides high quality minerals to the raw water. In addition, calcium, which is a major component of coral sand, is replaced with heavy metals, and heavy metals are removed by adsorption of heavy metals into the fine pores of coral sands. In addition, the coral sand treated as described above exhibits an effective bactericidal action, which is the most characteristic part of the present invention, and exhibits sufficient effects as a preservative even without attaching a component that exhibits a separate bactericidal effect such as silver, and thus, a conventional chemical substance And will provide a natural cleanser that is safe for the human body.

본 발명에 따라 처리된 코랄샌드는 가정용 및 업무용 정수기등의 카트리지 중에 넣음으로써 음료수의 정수제로 사용할 수 있고, 활성탄이나 중공사막등과 병용하여 가정용 및 업무용 정수기등의 카트리지에 넣음으로서 음료수의 정수제로 사용할 수도 있다. 또한 천연의 코랄샌드를 수세하여 염분 및 불순물을 제거한후, 80 내지 150℃의 품온에서 열소독, 건조 및 활성화시켜 얻은 코랄샌드를 10 내지 100메시의 입도로 가지런히 하여, 가정용 및 업무용 정수기의 카트리지 중에 넣음으로써 음료수의 정수제로 사용할 수 있고, 3g 내지 30g 정도의 티백타입 정수제로서도 사용가능하다.Coral sand treated according to the present invention can be used as a water purifier for drinking water by putting it in a cartridge such as water purifiers for home and business, and used as a water purifier for drinking water by putting it in cartridges for domestic and commercial water purifiers in combination with activated carbon or hollow fiber membranes. It may be. In addition, to remove salt and impurities by washing the natural coral sand, and to prepare the coral sand obtained by heat sterilization, drying and activation at a temperature of 80 to 150 ℃ to a particle size of 10 to 100 mesh, cartridges for household and commercial water purifier It can be used as a water purifier for drinking water by placing it in the water, and can also be used as a tea bag type water purifier of about 3 g to 30 g.

본 발명을 정리하면 다음과 같다.The present invention is summarized as follows.

(1) 코랄샌드의 주성분인 탄산칼슘이 용출되어 원수를 약알칼리성으로 이행시켜, 음료수로서 최적한 pH로 된다.(1) Calcium carbonate, which is a major component of coral sand, elutes and transfers the raw water to weak alkalinity, so that the pH is optimal as a drink.

(2) 동시에, 코랄샌드에서 용출되는 탄산칼슘이 살균을 위해 사용된 원수중의 염소를 중화하고, 생석회 냄새가 없어진다.(2) At the same time, calcium carbonate eluted from the coral sand neutralizes the chlorine in the raw water used for sterilization, and the smell of quicklime disappears.

(3) 코랄샌드에 함유된 칼슘, 마그네슘등의 미네랄이 서서히 용출되어, 양질의 미네랄워터로 되어, 인체에 필요한 원소의 보급원으로 유효하다.(3) Minerals such as calcium and magnesium contained in the coral sand are gradually eluted to become a high quality mineral water, which is effective as a source of supply of elements necessary for the human body.

(4) 본 발명의 가장 특징적인 부분인 본 발명의 방법에 따라 처리된 코랄샌드가 가지는 제균작용에 의해 원수중의 대장균 및 세균등을 제균하고, 물의 부패를 방지한다.(4) Sterilize E. coli and bacteria in raw water by the bactericidal action of the Coral sand treated according to the method of the present invention, which is the most characteristic part of the present invention, and prevents the corruption of water.

(5) 코랄샌드의 주성분인 탄산칼슘의 칼슘이 교환기로 작용하여, 중금속 이온과 칼슘이온이 치환되어 중금속등이 본 발명의 정수제에 흡착되며, 동시에 코랄샌드가 갖는 미세한 구멍에 의해서도 중금속이 흡착된다.(5) Calcium carbonate calcium, which is a major component of the coral sand, acts as an exchanger, and heavy metal ions and calcium ions are substituted, so that heavy metals are adsorbed to the water purifying agent of the present invention, and at the same time, heavy metals are adsorbed by the fine pores of the coral sand. do.

(6) 가열 활성화된 코랄샌드는 10마이크론 이하의 미세한 구멍을 무수히 갖는 다공질물질이며, 이 무수한 세공과 극히 큰 표면적의 존재로 수중의 불순물등이 흡착제거된다.(6) The heat-activated coral sand is a porous material having a myriad of fine pores of 10 microns or less, and the impurities in the water are adsorbed and removed by the presence of the myriad pores and the extremely large surface area.

Claims (1)

천연의 코랄샌드를 수세하여 염분 및 불순물을 제거한 후, 80 내지 150℃의 품온에서 열소독, 건조 및 활성화한 코랄샌드로 이루어진 것을 특징으로 하는 음료수의 정수제.A water purifier for drinking water, characterized by consisting of natural sand, washed with water to remove salts and impurities, and then heat sterilized, dried and activated at a temperature of 80 to 150 ° C.
KR1019860008319A 1986-10-04 1986-10-04 Water purifying material KR930001810B1 (en)

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KR1019860008319A KR930001810B1 (en) 1986-10-04 1986-10-04 Water purifying material

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KR1019860008319A KR930001810B1 (en) 1986-10-04 1986-10-04 Water purifying material

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KR880004838A KR880004838A (en) 1988-06-27
KR930001810B1 true KR930001810B1 (en) 1993-03-13

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