KR930000236B1 - Plat hollow fibers and production thereof - Google Patents

Plat hollow fibers and production thereof Download PDF

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KR930000236B1
KR930000236B1 KR1019900017273A KR900017273A KR930000236B1 KR 930000236 B1 KR930000236 B1 KR 930000236B1 KR 1019900017273 A KR1019900017273 A KR 1019900017273A KR 900017273 A KR900017273 A KR 900017273A KR 930000236 B1 KR930000236 B1 KR 930000236B1
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spinneret
slits
hollow
slit
manufacturing
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KR1019900017273A
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KR920008231A (en
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조구현
박찬수
최영근
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주식회사 선경인더스트리
이승동
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/24Formation of filaments, threads, or the like with a hollow structure; Spinnerette packs therefor

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Abstract

The method employing two circular hollow-shaped cross sections with hollow rate more than 25 % comprises: using spinneret (S) with orifices (Q) comprising adjacently separated four semicircular slits (J), (K), (L), (M); satisfying; 0.07<=A<= 0.12 (where A; slit width, unit; mm), 0.3<=B<=0.5 (B; inner redius of slit, mm), 0.07<=C<=<=0.12 (C; interval between upper portion and lower port; an of slit; mm) and 0.9<=D<=1.2 (D; central distance between slits; mm); and injecting cooled air folw from one side (H) of spinneret (S). The flat highly-hollowed fiber prepared by using this method features improved bulkiness, voluminous feel, thermo-retention property, light-weight as well as good luster.

Description

편평 중공사 및 그 제조방법Flat hollow fiber and its manufacturing method

제1도는 본 발명에 의해 제조된 편평중공사의 단면 확대도.1 is an enlarged cross-sectional view of the flat hollow fiber produced by the present invention.

제2도는 본 발명에 적용되는 방사구금의 정면도.Figure 2 is a front view of the spinneret applied to the present invention.

제3도는 제2도 방사구금공의 확대도.3 is an enlarged view of the spinnerette of FIG.

* 도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings

S : 방사구금 Q : 방사구금공S: Spinneret Q: Spinneret

J, K, L, M : 반원형슬리트J, K, L, M: Semicircle Slit

본 발명은 편평중공사 및 그 제조방법에 관한 것으로, 특히 중공율이 크며 2개의 중공이 측면으로 밀착되어 단면이 편평도를 갖는 편평중공사 및 그 제조방법에 대한 것이다.The present invention relates to a flat hollow fiber and a method for manufacturing the same, and more particularly, to a flat hollow fiber and a method of manufacturing the hollow hollow has a large cross-sectional close contact with the side hollow.

일반적으로 중공사는 다른 일반 섬유에서 얻을 수 없는 벌키성, 볼륨감, 보온성이 뛰어나고 중량이 가벼운 특징이 있어, 중공사 특유의 효과를 더욱 증대시키기 위하여 추가적인 기능을 부여시켜 단면 형태를 변화시키는 방법이 확산되고 있는바, 이러한 방법이 종래에는 기존의 방사구금을 그대로 사용하였기 때문에 10-15%의 중공율 밖에 얻지 못하여 기능 향상에 한계가 따르게 되었으며, 특히, 합성 섬유의 큰단점인 번들거리는 광택 및 촉감을 개선 할 수 없게되는 단점이 있었다.In general, hollow fiber is characterized by excellent bulkiness, volume, warmth, and light weight, which are not obtained from other general fibers, and the method of changing the cross-sectional shape by adding additional functions to further increase the effect of hollow fiber is spreading. Since this method has conventionally used the existing spinneret as it is, only a hollow rate of 10-15% is obtained, which leads to a limitation in improving the function. Particularly, the big disadvantage of the synthetic fiber is the shiny gloss and feel. There was a disadvantage of not being able to improve.

따라서 이를 해결하기 위한 또다른 방법으로 폴리머와 기체를 시쓰-코아 형태의 복합방사구금을 이용하여 중공율 이 다소 큰 중공사를 얻을 수 있게 하였으나, 이는 장치가 복잡하고 설비비가 많이드는 문제점이 있었다.Therefore, as another method to solve this problem, the hollow fiber having a large hollow ratio can be obtained by using a composite spinneret having a polymer and a gas in the form of Si-core, but this has a problem in that the apparatus is complicated and the equipment cost is high.

본 발명은 이같은 제반 문제점을 해결하기 위한 것으로, 복합방사 및 기계 주입장치를 별도로 부착시키지 않고 기존의 폴리에스터 방사장치에 개량된 방사구금을 적용시킴과 아울러 냉각기류의 방향을 편측방향에서 주입 방사함으로써 광택 및 촉감을 개선하고 벌키성, 볼륨감, 보온성 및 경량성이 향상되도록 한 중공율 25% 이상의 고중공 편평사를 제공코저 함에 그 목적이 있는 것이다.The present invention is to solve the above problems, by applying the spinneret improved to the existing polyester spinning equipment without attaching the composite spinning and machine injection device separately, and by injection spinning the direction of the cooling air flow in one side The purpose of the present invention is to provide a high hollow flat yarn having a hollow ratio of 25% or more to improve gloss and feel and to improve bulkiness, volume, warmth and lightness.

이하 본 발명을 첨부된 도면과 관련하여 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

제3도는 본 발명 편평중공사 제조에 적합토록 개량한 방사구금공의 정면도로서, 방사구금(S)의 표면에 천공된 다수의 방사구금공(Q)은 인접분리된 4개의 반원형슬리트(J), (K), (L), (M)로 구성되어 있어, 슬리트의 폭을 A, 내반경을 B, 슬리트의 상호간격을 C, 슬리트의 중심거리를 D라고 하였을때, A, C는 0.07-0.12mm인바, 이 경우 A가 0.12mm 보다 커지면 중공율이 15% 미만으로 감소되며, 반대로 0.07mm보다작아지면 방사후 세정이 곤란하게 되고 C가 0.12mm 보다 커지면 폴리머의 밀착력이 감소하여 원형 중공이 형성되지 않아 파괴되며, 반대로 0.07mm 보다 작아지면 이부분이 방사시 압력을 견디지 못해 슬리트 내부의 원이 밑으로 빠져나와 방사구금(S) 자체가 파괴될 우려가 있었다.Figure 3 is a front view of the spinneret ball improved to be suitable for manufacturing the flat hollow fiber of the present invention, a plurality of spinneret holes (Q) perforated on the surface of the spinneret (S) is adjacent to the four semi-circular slits (J) ), (K), (L), and (M), where the width of the slits is A, the inner radius is B, the distance between the slits is C, and the center distance of the slits is A, , C is 0.07-0.12mm. In this case, if A is larger than 0.12mm, the hollow ratio is reduced to less than 15%. On the contrary, if it is smaller than 0.07mm, it is difficult to clean after spinning. If C is larger than 0.12mm, the adhesion of polymer is increased. When the circular hollow is not formed and is destroyed, it is destroyed. On the contrary, when it is smaller than 0.07 mm, this part cannot endure the pressure during spinning, and the circle inside the slits may fall out, causing the spinneret (S) itself to be destroyed.

그리고, 슬리트의 내반경 B는 0.3-0.5mm가 적당하였는데 B가 0.3mm 보다 작아지면 중공율이 현저히 감소하거나 중공이 형성되지 않게되고, 0.5mm 이상일 경우는 슬리트 내부의 원이 지나치게 커지게 되어 방사시 압력을 받는 면적의 증가로 인해 내부의 원이 밑으로 빠져나와 이 또한 방사구금(S) 자체가 피과될 우려가 있어 부적합 하였다.In addition, the inner radius B of the slit was 0.3-0.5 mm, but when B is smaller than 0.3 mm, the hollow ratio is significantly reduced or no hollow is formed. Due to the increase in the area under pressure during spinning, the inner circle is pulled out, which is also unsuitable because the spinneret (S) itself may be overlooked.

다음 슬리트간의 중심거리 D는 0.9-1.2mm가 적당하는였데 D가 1.2mm 보다 커지면 2개의 중공이 밀착된 편평중공이 형성되지 않아 각각 단독으로 떨어진 중공사 형태가 되며, 0.9mm 보다 작아지면 중공율이 감소할 뿐만 아니라 편평도가 현저히 감소하여 편평효과인 번들거리는 광택 및 촉감을 개선할 수가 없었고, 제2도의 냉각기류 주입방향이 단측방향(I)일때는 2개의 원형중공의 크기가 균일하지 않고 불규칙하게 형성되어 중공율이 현저히 감소되므로 냉각기류의 방향을 편측(H)방향에서 주입하게 되면 중공을 25% 이상의 고중공편평사를 얻을 수 있는 것이다.The center distance D between the next slits was 0.9-1.2mm, and if D is larger than 1.2mm, the flat hollow with two hollows is not formed. Not only is the rate decreased, but the flatness was significantly reduced, so that the flatness, the shine, and the touch could not be improved, and when the cooling air flow direction of FIG. 2 was unilateral (I), the size of the two circular hollows was not uniform. Because the irregularity is formed and the hollow ratio is significantly reduced, when the direction of the cooling air is injected from the one side (H) direction, the hollow hollow spun yarn of 25% or more can be obtained.

이상과 같은 본 발명은 별도의 설비없이 기존의 폴리에스터 방사장치에 본 발명의 개량된 방사구금을 적용하게 되면 공중공편평사를 얻을 수 있고, 고중공편평사를 사용하여 제직, 제편한 직·편물은 단위 실부피에 대한 공기층이 차지하는 부피가 크기 때문에 보온성 소재, 스포츠의류등 가벼운 특징을 이용한 경량화 소재나 공기층으로 인한 절연성 소재로 사용할 수 있으며, 편평단면의 효과로 인해 번들거리는 광택 및 촉감을 개선할 수 있는 매우 유용한 발명인 것이다.The present invention as described above can be obtained by applying the improved spinneret of the present invention to the existing polyester spinning device without a separate equipment, it is possible to obtain the aerial coarse yarn, weaving, knitted fabrics using a high hollow yarn plain yarn The air layer occupies the actual volume of the unit, so it can be used as a lightweight material using light features such as heat-insulating material and sports clothing, or as an insulating material due to the air layer. It is a very useful invention that can be.

[실시예와 비교예][Examples and Comparative Examples]

실험에 사용한 섬유형성 폴리머는 통상의 방법으로 제조한 폴리에스터 중합체로서 올소클로로페놀 35℃에서 극한점도 0.635인 것을 사용하였다.As the fiber-forming polymer used in the experiment, an polyester having an intrinsic viscosity of 0.635 at 35 ° C. in osochlorophenol was used as a polyester polymer prepared by a conventional method.

그리고 제사조건은 285℃로 용융압출하였고, 토출량은 분당 30g, 권취속도는 분당 1200m로 하였으며, 이를 다시 연신비 3.0으로 연신한 후 75데니어의 멀티필라멘트를 제조하였다. 이때 방사구금의 홀수는 12홀이었다.The spinning conditions were melt-extruded at 285 ° C., the discharge amount was 30 g per minute, and the winding speed was 1200 m per minute. After the stretching was performed at a draw ratio of 3.0, 75 denier multifilaments were prepared. The odd number of spinnerets was 12 holes.

이하 실시예 및 비교예의 결과를 표1에 나타내었다.Table 1 shows the results of Examples and Comparative Examples.

[실시예 1]Example 1

방사구금의 슬리트 폭이 0.09mm, 슬리트 내반경이 0.4mm, 반원 슬리트의 간격이 0.08mm, 슬리트간 중심거리 1.10mm, 랜드장은 0.3mm로 하였다.The slitting width of the spinneret was 0.09 mm, the slitting inner radius was 0.4 mm, the interval between the semicircle slits was 0.08 mm, the center distance between slits was 1.10 mm, and the land length was 0.3 mm.

[비교예 1]Comparative Example 1

방사구금의 슬리트 폭이 0.13mm, 슬리트 내반경이 0.4mm, 반원 슬리트의 간격이 0.08mm, 슬리트간 중심거리 1.10mm, 랜드장은 0.3mm로 하였다.The slotting width of the spinneret was 0.13 mm, the slitting inner radius was 0.4 mm, the interval between the semicircle slits was 0.08 mm, the center distance between the slits was 1.10 mm, and the land length was 0.3 mm.

[비교예 2]Comparative Example 2

방사구금의 슬리트 폭이 0.09mm, 슬리트 내반경이 0.55mm, 반원 슬리트의 간격이 0.08mm, 슬리트간 중심거리 1.15mm, 랜드장은 0.3mm로 하였다.Slit width of spinneret was 0.09 mm, inner diameter of slits was 0.55 mm, spacing between semicircle slits was 0.08 mm, center distance between slits was 1.15 mm, and land length was 0.3 mm.

[비교예 3]Comparative Example 3

방사구금의 슬리트 폭이 0.09mm, 슬리트 내반경이 0.4mm, 반원 슬리트의 간격이 0.13mm, 슬리트간 중심거리 1.10mm, 랜드장은 0.3mm로 하였다.Slit width of spinneret was 0.09 mm, inner diameter of slits was 0.4 mm, gap between semicircle slits was 0.13 mm, center distance between slits was 1.10 mm, and land length was 0.3 mm.

[비교예 4][Comparative Example 4]

방사구금의 슬리트 폭이 0.09mm, 슬리트 내반경이 0.4mm, 반원 슬리트의 간격이 0.06mm, 슬리트간 중심거리 1.10mm, 랜드장은 0.3mm로 하였다.Slit width of spinneret was 0.09 mm, inner diameter of slits was 0.4 mm, gap between semicircle slits was 0.06 mm, center distance between slits was 1.10 mm, and land length was 0.3 mm.

[비교예 5][Comparative Example 5]

방사구금의 슬리트 폭이 0.09mm, 슬리트 내반경이 0.4mm, 반원 슬리트의 간격이 0.08mm, 슬리트간 중심거리 1.25mm, 랜드장은 0.3mm로 하였다.The slotting width of the spinneret was 0.09 mm, the slitting inner radius was 0.4 mm, the interval between the semicircle slits was 0.08 mm, the center distance between slits was 1.25 mm, and the land length was 0.3 mm.

[표 1]TABLE 1

1. 고정상태 : 매우양호 -◎, 양호-○, 보통-△, 불량-×1. Fixed: Very good-◎, Good- ○, Normal- △, Bad- ×

2. 중공율 구하는 공식 : (내부중공면적/필라멘트단면의 총면적)×1002. Formula for calculating the void ratio: (internal hollow area / total area of the filament section) × 100

3. 편평도 구하는 공식 : 필라멘트편측방향길이(제1도의 m)/3. Formula for calculating flatness: filament one-way length (m in Fig. 1) /

필라멘트단측방향 평균길이(제1도의 n)Filament One Side Average Length (n in Fig. 1)

Claims (4)

편평중공사에 있어서 2개의 원형중공 형태의 단면구조와 중공률이 25% 이상되는 것을 특징으로 하는 편평중공사.The flat hollow fiber is characterized in that the cross-sectional structure of the two hollow hollow form and the hollow ratio is more than 25%. 제1항 기재의 편평중공사를 제조함에 있어서 방사구금(S)의 표면에 천공된 방사구금공(Q)은 인접분리된 4개의 반원슬리트(J), (K), (L), (M)로 구성되는 것을 특징으로 하는 편평중공사의 제조방법.In manufacturing the flat hollow fiber according to claim 1, the spinneret hole Q drilled on the surface of the spinneret S has four semicircle slits J, K, L, and M) The manufacturing method of flat hollow fiber, characterized in that consisting of. 제2항에 있어서 방사구금공(S)은 하기조건 0.07A0.12(A-슬리트 폭, 단위는 mm임), 0.3B.5(B-슬리트 내반경, 단위는 mm임), 0.07C0.12(C-슬리트 상하간격, 단위는 mm임) 0.9D1.2(D-슬리트간 중심거리, 단위는 mm임)을 만족시켜 제조하는 것을 특징으로 하는 편평중공사의 제조방법.The spinneret ball (S) of claim 2 has the following condition 0.07 A 0.12 (A-slit width, in mm), 0.3 B .5 (B-slit inner radius in mm), 0.07 C 0.12 (C-slit top and bottom intervals in mm) 0.9 D The manufacturing method of the flat hollow fiber characterized in that the manufacturing satisfies 1.2 (center distance between the D-slit, the unit is mm). 제2항에 있어서 냉각기류를 방사구금(S)의 편측(H)방향에서 주입시켜 제조하는 것을 특징으로 하는 편평 중공사의 제조방법.The method for manufacturing a flat hollow yarn according to claim 2, wherein the cooling airflow is produced by injecting the cooling airflow in the one side (H) direction of the spinneret (S).
KR1019900017273A 1990-10-27 1990-10-27 Plat hollow fibers and production thereof KR930000236B1 (en)

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