KR927003554A - Heterocyclic Dione Derivatives As Insecticides and Plant Growth Regulators - Google Patents

Heterocyclic Dione Derivatives As Insecticides and Plant Growth Regulators Download PDF

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KR927003554A
KR927003554A KR1019920701501A KR920701501A KR927003554A KR 927003554 A KR927003554 A KR 927003554A KR 1019920701501 A KR1019920701501 A KR 1019920701501A KR 920701501 A KR920701501 A KR 920701501A KR 927003554 A KR927003554 A KR 927003554A
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South Korea
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group
compound
formula
hydrogen atom
alkyl group
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KR1019920701501A
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Korean (ko)
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시-후 리.
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예안 크레이머
산도즈 리미티드
한스 루돌프 하우스
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Publication of KR927003554A publication Critical patent/KR927003554A/en

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/49—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups
    • C07C205/57—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups having nitro groups and carboxyl groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C205/59—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups having nitro groups and carboxyl groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton the carbon skeleton being further substituted by singly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D265/00—Heterocyclic compounds containing six-membered rings having one nitrogen atom and one oxygen atom as the only ring hetero atoms
    • C07D265/02—1,2-Oxazines; Hydrogenated 1,2-oxazines

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)

Abstract

내용 없음No content

Description

살충제 및 식물 생장 조절제로서의 헤테로 사이클계 디온 유도체Heterocyclic Dione Derivatives As Insecticides and Plant Growth Regulators

[도면의 간단한 설명][Brief Description of Drawings]

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (9)

하기 일반식(I)의 화합물:A compound of formula (I) 상기식에서 R1, R2및 R3는 각각 수소원자, C1-8알킬기, 카르복실기, C1-8알콕시카르보닐기, 페닐기 또는 R과 같은 1 내지 3개의 치환기에 의해 치환된 페닐기이거나. 또는 R1과 R2는 함께 C3-6알킬렌 브리지(bridge)를 형성하고; R4는 수소원자, C1-8알킬기, C1-8알킬카르보닐기, C1-8알콕시카르보닐기, -C(O)NR7R8, C1-8알킬술포닐기, O(O)-(OR9)2, R7P(O)-OR9, 벤조일기 또는 일종의 양이온이며; R은 1 내지 6개의 할로겐 원자에 의해 임의로 치환된 C1-8알킬기, 1 내지 6개의 할로겐 원자에 의해 임의로 치환된 C1-8알콕시기, C1-8알킬카르보닐기, C1-8알콕시카르보닐기, NR7R8, OnS(O)nㆍR10, NR7SO2R8, 할로겐, 시아노기 또는 니트로기이고; R5는 1개 내지 6개의 할로겐 원자에 의해 치환된 C1-8알콕시기이고; R6는 수소원자 또는 상기 R에 대해 주어진 것들 중에서 선택되 것이고; R7및 R8은 각각 수소원자 또는 C1-8알킬기이고; R9는 C1-8알킬기이고; R10은 1개 6개의 할로겐 원자에 의해 임의로 치환된 C1-8알킬기이고, n은 0 또는 1이고; n'는 0, 1또는 2이며; R1, R2및 R3가 메틸기, R4및 R6는 수소원자이고 R이 니트로기인 경우에는 R5는 디플루오로메톡시기가 아니다.Wherein R 1 , R 2 and R 3 are each a hydrogen atom, a C 1-8 alkyl group, a carboxyl group, a C 1-8 alkoxycarbonyl group, a phenyl group or a phenyl group substituted by 1 to 3 substituents such as R. Or R 1 and R 2 together form a C 3-6 alkylene bridge; R 4 is a hydrogen atom, a C 1-8 alkyl group, a C 1-8 alkylcarbonyl group, a C 1-8 alkoxycarbonyl group, -C (O) NR 7 R 8 , a C 1-8 alkylsulfonyl group, O (O)-( OR 9 ) 2 , R 7 P (O) —OR 9 , a benzoyl group or a kind of cation; R is a C 1-8 alkyl group optionally substituted by 1 to 6 halogen atoms, a C 1-8 alkoxy group optionally substituted by 1 to 6 halogen atoms, a C 1-8 alkylcarbonyl group, a C 1-8 alkoxycarbonyl group , NR 7 R 8 , O n S (O) n占 R 10 , NR 7 SO 2 R 8 , halogen, cyano group or nitro group; R 5 is a C 1-8 alkoxy group substituted by 1 to 6 halogen atoms; R 6 will be selected from a hydrogen atom or those given for R above; R 7 and R 8 are each a hydrogen atom or a C 1-8 alkyl group; R 9 is a C 1-8 alkyl group; R 10 is a C 1-8 alkyl group optionally substituted by one six halogen atoms, n is 0 or 1; n 'is 0, 1 or 2; When R 1 , R 2 and R 3 are methyl groups, R 4 and R 6 are hydrogen atoms and R is a nitro group, R 5 is not a difluoromethoxy group. 제1항에 있어서, R1, R2, R3가 수소원자 또는 C1-4알킬기중에서 선택되고; R은 클로로, 브로모, 또는 플루오로에 의해 임의로 C1-4알킬기, -(O)n-S(O)n'-C1-4알킬기, 할로겐 또는 니트로기중에서 선택되고; R5는 플루오로 알콕시기이고; R6는 수소윈자; C1-4알킬기, C1-4알콕시기, 브로모, 클로로중에서 선택되며; R4는 H, C1-4알킬기, C4-8알킬카르보닐기, 벤조일기, C1-4알킬술포닐기 또는 일종의 양이온중에서 선택된 것인 화합물.The compound of claim 1 , wherein R 1 , R 2 , R 3 are selected from a hydrogen atom or a C 1-4 alkyl group; R is optionally selected from chloro, bromo, or fluoro from a C 1-4 alkyl group, a-(O) nS (O) n'-C 1-4 alkyl group, a halogen or a nitro group; R 5 is a fluoro alkoxy group; R 6 is a hydrogen atom; C 1-4 alkyl group, C 1-4 alkoxy group, bromo, chloro; R 4 is selected from H, C 1-4 alkyl group, C 4-8 alkylcarbonyl group, benzoyl group, C 1-4 alkylsulfonyl group or a kind of cation. 제2항에 있어서, R1, R2및 R3는 각각 H, C1-3알킬기중에서 선택되고; R4는 H이며; R은 NO2, Cl, CF3중에서 선택된 것인 화합물.The compound of claim 2, wherein R 1 , R 2 and R 3 are each selected from H, C 1-3 alkyl groups; R 4 is H; R is selected from NO 2 , Cl, CF 3 . 제3항에 있어서, R1, R2및 R3는 각각 메틸기이고, R4및 R6는 각각 수소원자이고, R은 니트로기이며 R5는 OCF인 화합물.4. A compound according to claim 3, wherein R 1 , R 2 and R 3 are each a methyl group, R 4 and R 6 are each a hydrogen atom, R is a nitro group and R 5 is OCF. 제1항 내지 제4항 중 어느 한항에서 정의한 일반식(I)의 화합물과 농학적 허용 부형제를 포함하는 살충제 조성물.A pesticide composition comprising a compound of formula (I) as defined in any one of claims 1 to 4 and an agriculturally acceptable excipient. 제1항 내지 제4항 중 어느 한항에서 정의한 일반식(I)의 화합물의 제초유효량을 잡초 또는 그 소재지에 살포하는 것을 포함하는 잡초의 생장 억제 방법.A method of inhibiting weed growth, comprising spraying an effective herbicidal amount of the compound of the general formula (I) as defined in any one of claims 1 to 4 to weeds or its location. 제1항 내지 제4항중 어느 한항에서 정의한 일반식(I)의 화합물의 진드기 살충 유효량을 진드기 또는 그것의 만연지에 살포하는 것을 포함하는 진드기 억제 방법.A method for inhibiting ticks, comprising spraying a tick-killing effective amount of the compound of formula (I) as defined in any one of claims 1 to 4 on a tick or its spread. (a)하기 일반식(II)의 화합물을 자리옮김(tearrange)시켜 R4가 H인 일반식(I)의 화합물을 생성시키거나; (b)R4가 수소원자 이외의 것인 일반식(I)의 화합물을 제조하고자 하는 경우에는, R4가 H인 일반식(I)의 화합물과, (1)R40-OH군 및 촉매, 또는 (2)R40-Q군(이때 Q는 할로겐 원자)및 온화한 염기중의 어느 하나를 반응시켜 R40이 소정의 치환기인 일반식(I)의 화합물을 생성시키는 단계를 포함하는, 제1항에 정의한 일반식(I)의 화합물의 제조방법:(a) replacing the compound of formula (II) to produce a compound of formula (I) wherein R 4 is H; (b) When preparing a compound of the general formula (I) wherein R 4 is other than a hydrogen atom, a compound of the general formula (I) wherein R 4 is H, (1) R 40 -OH group and catalyst Or (2) reacting any one of a group of R 40 -Q wherein Q is a halogen atom and a mild base to produce a compound of formula (I) wherein R 40 is a predetermined substituent; Method for preparing a compound of formula (I) as defined in claim 1: 상기식에서 R1, R2, R3, R, R5및 R6는 제1항에서 정의한 바와 같다.Wherein R 1 , R 2 , R 3 , R, R 5 and R 6 are as defined in claim 1. 2-니트로-4-트리플루오로메톡시 벤조산.2-nitro-4-trifluoromethoxy benzoic acid. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019920701501A 1990-10-25 1991-10-23 Heterocyclic Dione Derivatives As Insecticides and Plant Growth Regulators KR927003554A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US60470890A 1990-10-25 1990-10-25
US604,708 1990-10-25
PCT/EP1991/002014 WO1992007837A1 (en) 1990-10-25 1991-10-23 Heterocyclic dione derivatives as pesticides and plant growth regulators

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EP (1) EP0506907A1 (en)
JP (1) JPH05503106A (en)
KR (1) KR927003554A (en)
AU (1) AU642052B2 (en)
BR (1) BR9106194A (en)
CA (1) CA2072134A1 (en)
CS (1) CS193492A3 (en)
HU (1) HUT61534A (en)
IL (1) IL99834A0 (en)
PL (1) PL295411A1 (en)
WO (1) WO1992007837A1 (en)
ZA (1) ZA918535B (en)

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Publication number Priority date Publication date Assignee Title
US5716901A (en) * 1993-02-18 1998-02-10 Sandoz Ltd. Synergistic herbicidal compositions of dimethenamid, sulcotrione, and atrazine
US5900388A (en) * 1993-02-18 1999-05-04 Fenderson; John M. Synergistic compositions of dimethenamide and cyclohexanedion herbicides
ATE510454T1 (en) 1993-02-18 2011-06-15 Basf Se HERBICIDAL COMPOSITIONS
WO2001066522A1 (en) * 2000-03-09 2001-09-13 Syngenta Participations Ag Acylated phenyl or pyridine herbicides
GT200100103A (en) 2000-06-09 2002-02-21 NEW HERBICIDES
DE10117503A1 (en) 2001-04-07 2002-10-17 Bayer Cropscience Gmbh Derivatives of benzoylcyclohexanediones and their use as herbicides
WO2003011298A1 (en) * 2001-08-03 2003-02-13 Chirologix Pharmaceuticals Inc. Antibacterial oxazinones and methods for their use and synthesis
DE10144529A1 (en) * 2001-09-11 2003-03-27 Bayer Cropscience Gmbh New aminocarbonylalkyl-substituted 3-benzoyl-cyclohexane-1,3-dione derivatives, useful as broad-spectrum herbicides for selective pre- or post-emergence weed control, especially in wheat, maize or rice
DE10160007A1 (en) * 2001-12-06 2003-06-18 Bayer Cropscience Ag [1.2] oxazine-3,5-dione
DE10215723A1 (en) 2002-04-10 2003-10-30 Bayer Cropscience Gmbh 3-keto or 3-oxime ether substituted benzoylcyclohexanediones
WO2010102758A2 (en) 2009-03-11 2010-09-16 Bayer Cropscience Ag Halogenalkylmethylenoxy-phenyl-substituted ketoenols
DE102010008644A1 (en) 2010-02-15 2011-08-18 Bayer Schering Pharma Aktiengesellschaft, 13353 Cyclic ketoenols for therapy
DK2806741T3 (en) 2012-01-26 2020-05-18 Bayer Ip Gmbh PHENYL-SUBSTITUTED KETOENOLS TO FIGHT FISH PARASITES

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DE3382601T2 (en) * 1982-03-25 1993-01-07 Stauffer Chemical Co 2- (2-SUBSTITUTED BENZOYL) -1,3 CYCLOHEXANDIONE.
IL77350A (en) * 1984-12-20 1991-01-31 Stauffer Chemical Co Production of acylated diketonic compounds
TR24452A (en) * 1989-04-25 1991-11-01 Sandoz Ltd HETERCYCIC DIONS AS PESTICIDES AND PLANT BUEYUEME REGULATORS

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AU642052B2 (en) 1993-10-07
HU9202107D0 (en) 1992-10-28
PL295411A1 (en) 1993-06-28
HUT61534A (en) 1993-01-28
BR9106194A (en) 1993-03-23
CS193492A3 (en) 1992-10-14
AU8744291A (en) 1992-05-26
ZA918535B (en) 1993-04-26
WO1992007837A1 (en) 1992-05-14
EP0506907A1 (en) 1992-10-07
CA2072134A1 (en) 1992-04-26
IL99834A0 (en) 1992-08-18
JPH05503106A (en) 1993-05-27

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