KR920702851A - 사이클로부타렌 케토안하이드라이드 및 케토카복시 단량체 및 중합체 조성물 - Google Patents

사이클로부타렌 케토안하이드라이드 및 케토카복시 단량체 및 중합체 조성물

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KR920702851A
KR920702851A KR1019910700320A KR910700320A KR920702851A KR 920702851 A KR920702851 A KR 920702851A KR 1019910700320 A KR1019910700320 A KR 1019910700320A KR 910700320 A KR910700320 A KR 910700320A KR 920702851 A KR920702851 A KR 920702851A
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제이. 브루자 케네쓰
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원본미기재
더 다우 케미칼 캄파니
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    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/60—Two oxygen atoms, e.g. succinic anhydride
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    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/44—Iso-indoles; Hydrogenated iso-indoles
    • C07D209/48—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/64—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings
    • C07C233/77—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by amino groups
    • C07C233/80—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by amino groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a six-membered aromatic ring
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C65/00—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C65/32—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing keto groups
    • C07C65/34—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing keto groups polycyclic
    • C07C65/36—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing keto groups polycyclic containing rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C08G63/185—Acids containing aromatic rings containing two or more aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/20—Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors

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Abstract

내용 없음

Description

사이클로부타렌 케토안하이드라이드 및 케토카복시 단량체 및 중합체 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (29)

  1. 다음 일반식의 단량체.
    상기식에서, Ar은 아릴 잔기 또는 헤테로사이클릭 아릴 잔기이며, R은 서로 독립적으로 수소원자, 전자 공여성 잔기 또는 전자 구인성 잔기이고, R1는 산소원자, 질소원자 또는 황원자이며, R2는 수소원자, 탄소수 10이하의 알킬 잔기, 아릴 잔기 또는 헤테로사이클릭 잔기이고, m은 1 또는 2이며, p는 0또는 1의 정수이고, 단 R1이 질소원자일 경우에만 p는 2이다.
  2. 제1항에 있어서, 다음 구조식의 단량체;
  3. 하기 일반식 단량체.
    상기식에서, Ar은 아릴 잔기 또는 헤테로사이클릭 아릴 잔기이며, R은 개별적이며 각각 독립적으로 수소원자, 전자 공여성 잔기 또는 구인성 잔기이고, R1및 R2는 개별적이며 각각 독립적으로 질소원자, 산소원자 또는 황원자이고, R3및 R4는 개별적이며 각각 독립적으로 수소원자, 탄소수 10이하의 알킬 잔기, 아릴 잔기 또는 헤테로사이클릭 잔기이고, m은 1 또는 2의 정수이고, q는 1 또는 2이고, 단 R1또는 R2가 질소원자인 경우 q는 1이다.
  4. 제3항에 있어서, 다음 구조식의 단량체
  5. 제3항에 있어서, 하기 일반식을 갖는 단량체.
    상기식에서, R3및 R4는 탄소수가 10개 미만인 동일한 알킬 잔기이다.
  6. 제5항에 있어서, R3및 R4가 에틸인 단량체.
  7. 반응동안 전자쌍을 받아들이거나 양성자를 제공할 수 있는 반응 촉매의 존재하에 사이클로부타렌을 무수물-치환된 방향족 산 할라이드와 반응시키는 단계를 포함함을 특징으로 하여 제1항의 단량체를 제조하는 방법.
  8. 제7항에 있어서, 산 할라이드가 하기 일반식을 갖는 방법.
    상기식에서, Ar은 아릴 잔기 또는 헤테로사이클릭 아릴 잔기이고, R1는 산소원자, 질소원자 또는 황원자이며, R2는 수소원자, 탄소수 10개 미만의 알킬 잔기 또는 헤테로사이클릭 잔기이고; R3는 염소원자, 브롬원자 또는 요오드원자이며; p는 0 또는 1의 정수이고, 단 R1이 질소원자인 경우에만 p는 1이다.
  9. 제8항에 있어서, 산 할라이드가 트리멜리트산 무수물 산클로라이드인 방법.
  10. 제7항에 잇어서, 사이클로부타렌이 벤조사이클로부텐인 방법.
  11. 제7항에 있어서, 반응 촉매가 루이스산으로 작용하는 화합물, 강한 양성자성산 및 철과 트리플루오로 아세트산 무수물의 유기 착화합물로 이루어진 그룹중에서 선택되는 방법.
  12. 제11항에 있어서, 반응 촉매가 금속철, 산화철(III)및 산화아연 중에서 선택되는 방법.
  13. 제12항에 있어서, 반응 촉매가 산화철(III)인 방법.
  14. 제7항에 있어서, 사이클로부타렌/산 할라이드의 몰비가 5:4내지 12:4인 방법.
  15. 제14항에 있어서, 사이클로부타렌/산 할라이드의 몰비가 약 6:4인 방법.
  16. 제14항에 있어서, 산 할라이드/반응 촉매의 몰비가 10내지 500범위인 방법.
  17. 제16항에 있어서, 반응 혼합물의 온도가 135 내지 150℃ 범위인 방법.
  18. 제1항의 단량체, 및 두가지 이상의 형태로 축합 반응할 수 있는 다작용성 단량체를 축중합 조건에서 반응시킴을 특징으로하여, 제1항의 단량체로부터 공중합체를 제조하는 방법.
  19. 제3항의 단량체, 및 두가지 이상의 형태로 축합 반응할 수 있는 다작용성 단량체를 축중합 조건에서 반응시킴을 특징으로 하여, 제3항의 단량체로부터 공중합체를 제조하는 방법.
  20. 제18항 또는 제19항에 있어서, 제조된 공중합체가 올리고머인 방법.
  21. 제18항 또는 제19항에 있어서, 다작용성 단량체가 1급 방향족 디아민, 2급 방향족 디아민, 포화 지방족디올, 디페노이스, 및 디티올 중에서 선택되는 방법.
  22. 제18항 또는 제19항에 있어서, 다작용성 단량체가 메틸렌 디아닐린, 1,4-부탄 디올, 비스페놀 A, 및 벤젠 디티올 중에서 선택되는 방법.
  23. 제2항의 단량체와 적어도 축합 반응을 수행할 수 있는 다작용성 단량체에 축중합반응 조건을 가하는 단계를 포함함을 특징으로하여, 제2항의 단량체로부터 공중합체를 제조하는 방법.
  24. 적어도 2개의 축합반응을 수행할 수 있는 올리고머와 제1항 또는 3항의 단량체에 축중합반응 조건을 가하는 단계를 포함함을 특징으로하여, 사이클로부타렌 잔기로 말단캡핑된 올리고머를 제조하는 방법.
  25. 제24항에 있어서, 오리고머가 폴리에스테르, 폴리아미드 및 폴리이미드 올리고머로 이루어진 그룹중에서 선택되는 방법.
  26. 제24항에 있어서, 사용되는 제1항 또는 3항의 단랴에의 양 범위가 반응 혼합물 중 단량체와 올리고머의 전체 몰양을 기준으로 5 내지 20몰%인 방법.
  27. 제18또는 19항의 방법으로부터 제조된 공중합체에 환교차 중합반응 조건을 가하는 단계를 포함함을 특징으로하여, 상기 공중합체로 부터 가교결합된 네트워크를 제조하는 방법.
  28. 제24항의 방법으로부터 제조된 말단캡핑된 올리고머에 환 교차 중합반응 조건을 가하는 단계를 포함함을 특징으로하여, 상기 말단캡핑된 올리고머로부터 가교결합된 네트워크를 제조하는 방법.
  29. 제1항의 단량체에 환 교차 중합반응 조건을 가하는 단계를 포함함을 특징으로하여, 상기 단량체로부터 동종중합체를 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910700320A 1989-07-26 1989-07-26 사이클로부타렌 케토안하이드라이드 및 케토카복시 단량체 및 중합체 조성물 KR920702851A (ko)

Applications Claiming Priority (2)

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PCT/US1989/003249 WO1991001983A1 (en) 1989-07-28 1989-07-26 Cyclobutarene ketoanhydride and ketocarboxy monomeric and polymeric compositions
EP89113932A EP0410039A1 (en) 1989-07-28 1989-07-28 Cyclobutarene ketoanhydride and ketocarboxy monomeric and polymeric compositions

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AR242947A1 (es) * 1983-06-15 1993-06-30 Ciba Geigy Procedimiento para la obtencion de derivados de acidos 4-benzoil-5-hidroxi-benzoilciclobuten-1-carboxilico y sus sales.
EP0175647A1 (de) * 1984-09-13 1986-03-26 Ciba-Geigy Ag Verfahren zum Leimen von Papier oder Karton mit anionischen, hydrophoben Leimungsmitteln und kationischen Retentionsmitteln
US4795827A (en) * 1987-10-16 1989-01-03 The Dow Chemical Company Cyclobutarene ketoaniline monomeric and polymeric compositions
US4825001A (en) * 1987-10-16 1989-04-25 The Dow Chemical Company Cyclobutarene ketoaniline monomeric and polymeric compositions

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