KR920010532B1 - Making process for chisel steels - Google Patents
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- KR920010532B1 KR920010532B1 KR1019900018151A KR900018151A KR920010532B1 KR 920010532 B1 KR920010532 B1 KR 920010532B1 KR 1019900018151 A KR1019900018151 A KR 1019900018151A KR 900018151 A KR900018151 A KR 900018151A KR 920010532 B1 KR920010532 B1 KR 920010532B1
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C38/00—Ferrous alloys, e.g. steel alloys
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Abstract
Description
본 발명은 암반굴삭, 콘크리트 구조물의 해체 파쇄, 채석등의 토목건설 등에 사용되는 굴삭기의 브레이카용 치즐(Chisel)로서 특유의 내마모성과 내충격성을 가진 치즐강의 제조방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method of manufacturing a chisel steel having a unique wear resistance and impact resistance as a chisel for a brake car of an excavator used for civil construction such as rock excavation, dismantling crushing of concrete structures, quarrying, and the like.
종래에 사용되어온 치즐의 재질로서는 주로 크롬, 몰리브덴강(SCM440) 크롬, 니켈, 몰리브덴강(SNCM8)이 사용되어 왔으며 사용에 있어서는 강재를 정해진 형상으로 기계 가공한 후에 열처리를 실시하여 사용된다. 그러나 보통 치즐선단부는 사용에 의해 마모가 심하게 되어 수명이 짧고, 형상을 보수하여 반복사용할 경우 보수작업이 복잡하여 비경제적이었다. 한편 종래 치즐의 또 한가지 문제점은 암반의 굴삭 또는 파쇄작업시 유압 브레이카의 계속적인 타격(충격)으로 치즐의 행가(Hanger)부위에서 잦은 절손사고가 발생한다는 것이다. 이 때문에 교체작업 시간이 많이 걸리고 작업의 연속성이 유지되지 않아 비능률적인 작업이 되었다. 이와 같은 문제점은 내마모성을 높이기 위하여 강도를 높이는 것은 좋으나 인성이 떨어져 충격에 약하고 인성을 높이면 강도가 떨어져 내마모성이 나빠지는 강의 일반적인 성질 때문이다.As a material of the chisel used in the related art, chromium, molybdenum steel (SCM440), chromium, nickel, and molybdenum steel (SNCM8) have been mainly used. In use, the steel is machined into a predetermined shape and then subjected to heat treatment. However, the chisel chisel end is severely worn by use, and the life is short, and it is uneconomical because the maintenance work is complicated when the shape is used repeatedly. On the other hand, another problem of the conventional chisel is that frequent breakage accidents occur in the hanger area of the chisel due to continuous hitting (impact) of the hydraulic brake car during the excavation or crushing of the rock. Because of this, the replacement work takes a long time and the continuity of the work is not maintained, resulting in inefficient work. This problem is due to the general properties of the steel is good to increase the strength in order to increase the wear resistance, but the toughness is weak to impact and the toughness is lowered strength is worse wear resistance.
본 발명은 이러한 종래강의 상기 문제점을 해결하여 내마모성이 필요한 경도를 얻음과 동시에 인성도 유지하여 내충격성이 우수한 치즐강을 제공하기 위한 것이다. 위의 서로 상반된 두가지 품질조건을 만족시키기 위하여 첫째 화학성분조건과 둘째 열처리 조건을 고안하여 설계하였다. 그 설계내용은 다음과 같다.The present invention is to provide a chisel steel excellent in impact resistance by solving the above problems of the conventional steel to obtain the required hardness and at the same time maintain the toughness. First chemical composition and second heat treatment were devised and designed to satisfy the two opposing quality conditions. The design contents are as follows.
(1) 화학성분설계 중량비로서 C 0.35-0.60%, Si 0.70-1.50%, Mn 0.60-1.20%, p 0.030% 이하, s 0.030% 이하, Cu 0.30% 이하, Ni 0.25% 이하, Cr 0.70-1.60%, Mo 0.15-0.50%, V 0.05-0.20% 또는 Nb 0.01-0.20%, Ai 0.020-0.040%, 나머지 Fe를 함유하는 것이다. 즉, 본 발명 강은 종래의 크롬, 몰리브덴강에 비하여 치즐의 중심부까지 균일하게 소입이 되어서 내마모성이 좋은 것이다.(1) As chemical composition weight ratio, C 0.35-0.60%, Si 0.70-1.50%, Mn 0.60-1.20%, p 0.030% or less, s 0.030% or less, Cu 0.30% or less, Ni 0.25% or less, Cr 0.70-1.60 %, Mo 0.15-0.50%, V 0.05-0.20% or Nb 0.01-0.20%, Ai 0.020-0.040%, and the remaining Fe. That is, the steel of the present invention is uniformly quenched to the center of the chisel as compared with the conventional chromium and molybdenum steel, and has good abrasion resistance.
다음에 이 발명강의 화학성분 한정이유에 관하여 설명한다. C는 소입하여 필요한 경도를 얻기 위하여 첨가하며 탄화물을 형성하여 내마모성을 향상시킨다. 그러나 C함량이 증가하면 인성 저하로 인해 사용중에 파손되는 위험성이 있으므로 상한을 0.60% 이하로 했다. Si는 고온에서 내마모, 내연화성을 향상시키며, Cr, Mo양의 많은 경우 0.70% 이상 첨가하나 이성 저하와 소입온도를 상승시키므로 소려 연화저항을 개선할 목적으로 0.50% 이하로 첨가한다. Mn은 소입성을 향상시키는 원소로서 열처리의 균질성, 고온강도를 개선하므로 치즐의 필요경도 HRC 47 이상을 얻기 위하여 0.60% 이상이 필요하나 소려 취성과 잔류 오오스테나이트를 증가시키며 100mm 이상의 직경의 대형품은 사용중에 파단이 되는 위험이 있으므로 1.20% 이하로 하였다. Cr은 탄화물을 형성하며 내마모성을 향상시키는 이외에 균일한 경도분포, 강도의 향상 및 사용중의 마찰열에 의한 연화를 방지하는 효과가 있으며 이들을 위하여 0.70% 이상 함유시킬 필요가 있으나 1.6% 이상이 되면 소입온도가 상승하여 소입 작업이 복잡하게 되므로 상한을 1.6%로 하였다. Mo는 소입성, 내소려성, 고온특성, 석출 2차 경화능의 부여나 소려취성의 완화 방지에 효과가 있으므로 0.15-0.50%의 범위에서 첨가하나, Mo은 고가이며, 또 다량 첨가시는 안정 탄화물의 증량을 가져와 첨가효과를 감쇄시키므로 상한치를 0.50%로 제한하였다. Nb는 가장 강력한 탄화물 형성 원소에 속하며 경질의 안정한 탄화물을 형성하여 그 결과로 탄소를 고정화한다. 한편 결정립의 미세화와 성장억제 효과가 크므로 소입성 및 소입경도를 저하시키나 내마모성, 인성을 개선시키는 효과가 있다. 그러나 과량첨가는 조대한 Nb 탄화물을 형성하며 강의 재질을 열화시키므로 0.01-0.20%로 하였다.Next, the reason for limitation of chemical composition of this invention steel is demonstrated. C is quenched and added to obtain the required hardness, and carbides are formed to improve wear resistance. However, if the C content is increased, the upper limit is set to 0.60% or less because there is a risk of breakage during use due to the decrease in toughness. Si improves abrasion resistance and softening resistance at high temperatures, and in the case of Cr and Mo amounts, it adds 0.70% or more, but it adds 0.50% or less for the purpose of improving so-called softening resistance because it lowers the ratio and raises the quenching temperature. Mn is an element that improves the hardenability, and improves the homogeneity of heat treatment and high temperature strength, so that 0.60% or more is required in order to obtain the required hardness of chisel HRC 47 or more. However, Mn increases the brittleness and retained austenite. The risk of breakage during use is 1.20% or less. Cr forms carbides and improves abrasion resistance, and has the effect of uniform hardness distribution, strength improvement and softening due to frictional heat during use. The upper limit was made 1.6% because it increased and the hardening work was complicated. Mo is added in the range of 0.15-0.50% because it is effective in imparting hardenability, antifriction resistance, high temperature characteristics, precipitation secondary hardening ability, and preventing loose brittleness, but Mo is expensive and stable carbide when added in large amounts The upper limit was limited to 0.50% because the added effect was reduced to decrease the effect of addition. Nb belongs to the most powerful carbide-forming element and forms hard stable carbides, resulting in immobilization of carbon. On the other hand, since the effect of miniaturization and growth suppression of grains is great, the quenching property and the quenching hardness are lowered, but the wear resistance and toughness are improved. However, excessive addition forms coarse Nb carbide and degrades the material of the steel, so it is 0.01-0.20%.
V은 치즐 사용중의 열 상승에 수반하는 연화를 방지함과 동시에 C 및 N와 결합하여 탄질화물을 형성하여 내마모성을 향상시킨다. 그러나 0.30%를 넘게 함유시켜도 그 효과 작으므로 그 상한을 0.20%로 하였다. Ni은 Mn과 같은 효과를 가지는 이외에, 인성, 피로강도를 향상시켜서 치즐의 절손방지를 위하여 첨가하는 것이나, 첨가량이 다량이 되면 소입경도의 저하 및 피삭성이 저하되므로 그 상한을 0.25%로 하였다. Al은 결정립을 미세화하는 효과를 가지므로 0.02-0.04%로 제한하였다. P, S, Cu 등은 불순물로서 억제 상한치만을 가진다.V prevents softening accompanying heat rise during chisel use and simultaneously forms carbonitrides in combination with C and N to improve wear resistance. However, even if it contained more than 0.30%, since the effect was small, the upper limit was made into 0.20%. In addition to the effect similar to Mn, Ni is added to improve toughness and fatigue strength to prevent chisel breakage, but when the addition amount is large, the particle size decreases and machinability decreases, so the upper limit is 0.25%. Al was limited to 0.02-0.04% because it has an effect of miniaturizing grains. P, S, Cu, and the like have only an upper limit of inhibition as impurities.
(2) 열처리설계 : 이상과 같은 화학성분을 가진 재질을 충분한 특성을 발휘하여 만족할 만한 기계적 성질을 얻기 위하여 다음과 같은 열처리를 행한다. 즉, 본 소재를 열처리로에서 800-900℃로 가열하여 소입한 후에 인성을 갖도록 350-550℃의 온도에서 소려(Tempering)를 행하면 우수한 인성을 갖는 제품을 만들 수 있다.(2) Heat treatment design: In order to obtain satisfactory mechanical properties by showing sufficient properties of materials with chemical composition as above, the following heat treatment is performed. That is, the material is heated to 800-900 ° C. in a heat treatment furnace and then annealed at a temperature of 350-550 ° C. to have toughness, thereby making a product having excellent toughness.
[실시예]EXAMPLE
다음에 본 발명강의 특징을 종래강에 비교한 실시예를 가지고 밝힌다.Next, the characteristic of this invention steel is revealed with the Example compared with the conventional steel.
[제1표][Table 1]
전기로에서 제1표와 같은 성분으로 용해 및 출강하여 래들에서 탈가스 처리와 2차 정련을 실시한 후 강괴로 주입하였다. 이 강괴를 가열로에서 1250℃로 가열하여 각종 원형강으로 압연 또는 단조한 후 가공하였다. 이렇게 만들어진 강재를 열처리로에서 850℃로 가열하여 소입한 후에 인성을 부여하기 위하여 500℃에서 소려를 행하였다. 종래강과의 기계적 특성을 비교하기 위하여 소려온도를 조정하여 시료를 만들어 시험한 결과 제2표와 같은 기계적 특성을 얻었다.After melting and tapping with the same components as those in the first table in the electric furnace, degassing and secondary refining were carried out in the ladle, followed by injection into steel ingots. The ingot was heated to 1250 ° C. in a heating furnace and rolled or forged into various circular steels before processing. The steel thus produced was heated to 850 ° C. in a heat treatment furnace and then quenched at 500 ° C. to give toughness. In order to compare the mechanical properties with conventional steel, the sample was made by adjusting the sowing temperature, and the mechanical properties as shown in the second table were obtained.
[제2표][Table 2]
제2표를 보면 본 발명강 시료 C, D와 종래강 시료(A)의 열처리 조건을 동일하게 시행했을 때 종래강보다 본 발명강의 경도와 인장강도가 15-25% 정도 우수했으며, 한편 종래강의 경도를 본 발명강의 경도와 비슷한 수준으로 맞추기 위해 열처리 조건을 조절했을 때(B와 C, D시료) 본 발명강의 연신율이나 충격치가 종래강보다 약 70% 이상 우수함을 알 수 있다.Table 2 shows that when the heat treatment conditions of the inventive steel samples C, D and the conventional steel sample (A) were performed in the same manner, the hardness and tensile strength of the inventive steel were superior to those of the conventional steel by about 15-25%. When the heat treatment conditions are adjusted to adjust the hardness to a level similar to that of the inventive steel (B, C, D samples), the elongation or impact value of the inventive steel is about 70% or more superior to that of the conventional steel.
이상에서 본 바와 같이 본 발명강은 화학성분과 열처리 조건을 최적 조건으로 설계하여 치즐재료의 내마모성에 필요한 높은 경도를 얻음과 동시에 인성을 갖게 하며 높은 연신율과 충격치를 유지하게 됨에 따라 실제로 굴삭기에 장착된 치즐이 절손되어 반품되는 사례가 급격히 감소하였고 또한 종래 치즐보다 수명이 1.5배-2배 정도 연장되어 우수한 내충격 내마모성을 입증하였으며 따라서 작업의 연속성 및 효율성이 제고를 기할 수 있게 되었다.As described above, the present invention steel is designed to the optimum conditions of chemical composition and heat treatment conditions to obtain the high hardness required for wear resistance of the chisel material, to make toughness and to maintain high elongation and impact value, which is actually mounted on the excavator In the case of the chisel, the returned cases were drastically reduced, and the lifespan was extended by 1.5 times to 2 times as compared to the conventional chisel, thereby demonstrating excellent impact resistance to wear, thereby improving the continuity and efficiency of the work.
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