KR920000739B1 - A concertrated material for the glass duct and its manufacturing method - Google Patents

A concertrated material for the glass duct and its manufacturing method Download PDF

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KR920000739B1
KR920000739B1 KR1019870000828A KR870000828A KR920000739B1 KR 920000739 B1 KR920000739 B1 KR 920000739B1 KR 1019870000828 A KR1019870000828 A KR 1019870000828A KR 870000828 A KR870000828 A KR 870000828A KR 920000739 B1 KR920000739 B1 KR 920000739B1
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focusing body
glass
manufacturing
wool
surfactant
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KR1019870000828A
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KR880008880A (en
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이호진
고영균
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주식회사 금강
박가경
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/20Layered products comprising a layer of metal comprising aluminium or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/42Layered products comprising a layer of synthetic resin comprising condensation resins of aldehydes, e.g. with phenols, ureas or melamines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2311/00Metals, their alloys or their compounds
    • B32B2311/24Aluminium

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  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Laminated Bodies (AREA)
  • Duct Arrangements (AREA)

Abstract

The stuff forming plate or tube shape, is used for wrapping glass- wool duct in heating or cooling apparatus. The method comprising flame spraying or centrifugal method, has a first process of spraying phenolic resin reacted with 2-6 % phenol, 90-96 % water, 0.9-3 % ammonium sulfate, 0.3-3 % ammonia on mono-fibric glass wool and hot-compressing and hardening; second process of spraying surface-treating agent mixed with 50-55 % ammonium sulfate, 0.2-0.8 % surfactant,20-30 % inorganic hardening agent, 2-6 % dust-collecting and water-repellent agent, 10-25 % inorganic dyestuff on the first-processed glass-wool and bonding aluminium foil on the other side of the stuff.

Description

유리면 덕트 시공용 집속체의 제조방법Manufacturing method of focusing body for glass surface duct construction

제1도는 본 발명의 제조 공정도.1 is a manufacturing process diagram of the present invention.

제2도는 본 발명의 다른 제조 공정도.2 is another manufacturing process diagram of the present invention.

본 발명은 냉난방 급기관으로 사용되는 유리면으로 된 덕트를 시공하기 위한 판상이나 관상으로된 집속체 제조방법에 관한 것이다.The present invention relates to a plate- or tubular focusing body manufacturing method for constructing a glass surface duct used as a cooling and heating supply pipe.

최근에는 시공 후 별도의 보온공사가 불필요하며 이송되는 기류에 의한 소음 발생이나 공기누설 등의 문제점이 없는 유리면을 소재로한 덕트가 실용화되었으나 이러한 유리면 덕트를 조립 제작하기 위하여 유리면 집속체를 재단하는 경우에 집속체의 가공성이 좋지 않아 재단면이 균일하지 못하고 유리면 집속체를 절곡하는 경우에 “ㄱ”자 또는 “V”자 형태로 요부를 형성하는 절삭작업시 절삭부위에 부풀음이 발생하고 절삭면이 균일하게 되지 못하는 문제점이 있어서, 시공 후 사용시 판상의 집속체와 집속체 사이의 결합을 위한 조인트 스리브 형상부위나 관상의 집속체와 집속체 사이의 결합을 위한 접합부위에 공기누설이 발생하는 폐단이 있으며 또한 유리면으로된 집속체 표면이 충분히 경화되지 못하여 이송기류에 의하여 미세한 유리섬유 조각이 비산되는 등의 문제점이 발견되었다.Recently, no additional insulation work is required after construction, and ducts made of glass surface that are free from problems such as noise generation or air leakage due to the airflow being transferred have been put into practical use. When the cutting surface is not uniform because the workability of the focusing body is not uniform, and the glass surface focusing body is bent, swelling occurs at the cutting part during the cutting operation to form the recessed portion in the form of “a” or “v”. There is a problem that can not be uniform, there is a closed end in which the air leakage occurs in the joint sleeve shape portion for the coupling between the plate-shaped focusing body and the focusing body or the jointing site for coupling between the tubular focusing body and the focusing body when used after construction. In addition, the glass surface of the focusing body is not sufficiently cured, the fine glass fiber by the transport stream Problems such as fragments scattering have been found.

본 발명의 목적은 이러한 유리면 덕트 시공용 집속체가 안고 있는 문제점을 감안하여 집속체의 가공성을 증진시켜 주고 유리면 소재의 표면을 충분히 경화시켜 줌으로써 사용시 집속체의 이음부분에 이송기류에 누설현상이 발생되지 않으며 유리섬유의 비산현상이 발생되지 않도록 함에 있으며 이러한 본 발명의 목적은 화염분사법이나 원심법 제조방식으로 얻은 단섬유상의 울(wool)에 페놀, 암노니아, 유안을 주제로한 페놀수지를 적정공기압으로 분사하여 수지 처리된 울을 제조한 후 이를 판상의 열판이나 관상의 열판 사이에 넣고 가열하여 경화시켜 줌으로써 판상이나 관상의 울 집속체를 얻고 덕트 시공시 내면이 되는 표면에 페놀수지, 암모니아, 유안, 계면활성제, 무기질경화제, 집진발수제, 무기질염료를 배합하여 공기압으로 분사하여 표면처리하여, 이때의 증가된 수분함유율을 낮추기 위하여 열풍건조기에서 건조시켜 표면처리된 집속체의 표면이 경화되게 하고 그의 이면에는 그라스얀이나 크라프트지가 부착된 알루미늄 박지를 접착하여 줌으로써 달성될 수 있는 것으로 이를 첨부된 실시예에 따라 상세히 설명하면 다음과 같다.The object of the present invention is to improve the processability of the focusing body in consideration of the problems of the glass surface duct construction focusing body and to fully harden the surface of the glass surface material does not cause leakage phenomenon in the air flow at the joint portion of the focusing body during use In order to prevent the scattering of glass fibers, the object of the present invention is a phenolic resin based on phenol, amnonia and yuan in monofiber wool obtained by flame spraying or centrifugal manufacturing. After spraying with proper air pressure, resin-treated wool is manufactured, and it is inserted into a hot plate or tubular hot plate and heated and cured to obtain a plate or tubular wool concentrator, and phenolic resin and ammonia on the inner surface during duct construction , Oil, surfactant, inorganic hardener, dust repellent, inorganic dye Thus, in order to lower the increased water content at this time, the surface of the surface-treated focusing material may be hardened by drying in a hot air dryer, and the back surface thereof may be achieved by bonding an aluminum foil having glass yarn or kraft paper attached thereto. When described in detail according to the embodiment as follows.

[실시예 1]Example 1

화염분사법이나 원심법 제조방식으로 단섬유상의 울(wool)을 얻고 이에 페놀수지 4.4%, 물94.4%, 유안 0.9%, 암모니아 0.3%로 반응된 페놀수지를 공기압으로 분사한다. 이때 울의 수지 부착율이 10% 이하로 되면 울 집속체가 연하게 되고 유리섬유간의 결합력이 약하게 되어 재단 작업시나 절삭작업시에 밀림현상이 발생하여 가공성이 저하되는 문제점이 있고, 울의 수지 부착율이 17% 이상으로 되면 울 집속체가 지나치게 단단하게 되고 열전도율 및 불연 성능이 저하되므로 페놀수지를 분사하는 공기압 및 노즐의 직경을 조절하여 울의 수지 부착율이 10-17% 정도로 유지되도록 한다. 이와같이 하여 얻은 수지가 부착된 울은 집면기에서 적정한 두께로 집속되어 60kg/㎥이나 48kg/㎥ 등의 비중을 갖는 울의 집속체로 된다.The short-fiber wool is obtained by flame spraying or centrifugal manufacturing, and the phenol resin reacted with 4.4% phenol resin, 94.4% water, 0.9% yuan and 0.3% ammonia is sprayed with air pressure. At this time, when the resin adhesion rate of the wool is less than 10%, the wool concentrator becomes soft and the bonding force between the glass fibers is weakened, so that the sliding phenomenon occurs during cutting work or cutting work, and the workability decreases. If the amount is more than 17%, the wool concentrator becomes too hard, and the thermal conductivity and the non-combustible performance are reduced, so that the resin adhesion rate of the wool is maintained at about 10-17% by adjusting the air pressure and nozzle diameter injecting phenolic resin. The resin-attached wool obtained in this way is concentrated at an appropriate thickness in the collector and becomes a wool concentrator having a specific gravity of 60 kg / m 3 or 48 kg / m 3.

이와같이 하여 얻은 집속체는 2개의 상하열판으로 된 판상의 열판을 갖는 가열기나 2개의 내외열관으로된 관상의 열판을 갖는 가열기에 넣고 10분간 가열 경화시키면 집속체는 경화된 판상의 형태를 갖는 것이 되거나 경화된 관상의 형태를 갖는 것이 된다. 이때 가열기의 열판은 180℃-200℃ 정도로 유지시켜 주는 것이 바람직하며 또한 가열기의 상하열판이나 내외열관 양단에 요철면을 형성하여 경화되는 집속체 양단에 요철형 스리브가 성형되게하면 시공시 다수의 집속체를 용이하게 결합시켜 줄 수 있게 되는 것이고 아울러 가열기의 상하열판이나 내외열관의 간격을 조절하여 줌에 따라 판상이나 관상으로 성형되는 집속체의 두께가 20,25,50미리미터 등으로 조절될 수 있는 것이다.The focusing body thus obtained is placed in a heater having a plate-shaped hot plate made of two upper and lower heating plates or a heater having a tubular hot plate made of two internal and external heat pipes, and heat-cured for 10 minutes. It becomes what has a hardened tubular form. At this time, it is preferable to keep the heating plate of the heater at about 180 ° C-200 ° C. Also, if the uneven type rib is formed at both ends of the condensing body that is formed by forming irregularities on both ends of the upper and lower heating plates of the heater and the inner and outer heat pipes, a large number of concentratings are applied during construction Sieves can be easily combined, and the thickness of the converging body formed into a plate or tubular shape can be adjusted to 20, 25, 50 mm, etc., by adjusting the distance between the upper and lower plates of the heater and the inner and outer heat pipes. It is.

이와같이 하여 판상이나 관상의 집속체를 얻은 후에는 이를 덕트로 시공하였을 때 이송기류에 접하게되는 내면에 표면처리 공정을 시행하여야 한다. 이러한 표면처리를 위하여 페놀수지에 암모니아를 넣고 1분 정도 혼합한 후 유안을 첨가하여 완전 용해될때까지 3분 정도 혼합시키고 이에 계면활성제, 무기질 경화제, 집진 발수제를 순차적으로 투입하면서 10분 정도 혼합시키며 착색을 위하여 무기질 염료를 추가로 투입하고 2분 정도 더 혼합하여 표면처리제를 얻고 집속체가 판상의 것인 경우는 덕트 내면이 되는 면이 표면이 되도록 한 상태로 컨베이어에 의하여 이송되게 하면서 그 상방에서 공기압 5kg/㎠, 노즐수 5개로하여 상기의 표면처리제를 분사시켜 줌으로써 표면처리제가 집속체 표면에 고루 침투되도록 하고 관상의 집속체인 경우에는 집속체의 관 내부에 원통형 다공 스프레이 노즐을 통과시켜 표면처리제가 집속체 내주면에 고루 침투되도록 한다.In this way, after the plate or tubular focusing body has been obtained, the surface treatment process should be carried out on the inner surface which is in contact with the transport airflow when it is constructed by duct. For this surface treatment, add ammonia to phenolic resin, mix for about 1 minute, mix it for 3 minutes until it is completely dissolved by adding yuan, and mix it for 10 minutes while sequentially adding surfactant, inorganic hardener, and dust repellent agent. In order to obtain the surface treatment agent by adding an additional inorganic dye and mixing for about 2 minutes, and if the focusing body is plate-shaped, it is transported by the conveyor with the surface that becomes the inner surface of the duct to be the surface, and the air pressure 5kg above. / Cm2 and 5 nozzles to spray the above surface treatment agent so that the surface treatment agent is evenly penetrated into the surface of the focusing body, and in the case of tubular focusing body, the cylindrical porous spray nozzle passes through the inside of the tube of the focusing body to concentrate the surface treatment agent. Make sure to penetrate the inner circumference of the body evenly.

그리고 이때의 표면처리제의 각 성분은 페놀수지 50.62%, 암모니아수 2.30%, 유안 0.48%, 계면활성제 0.20%, 무기질 경화제 28.10%, 집진발수제 4.4%, 무기질염료 13.90%를 배합하였으며 또한 표면처리제가 집속체 표면에 부착된 표면수지 부착율이 40% 이하로 되면 사용중 이송기류에 의하여 유리섬유가 유리되어 비산될 위험이 있으며 가공성이 저조하게 되고 표면수지 부착율을 50% 이상으로 하면 흡음율이 저하되고 덕트의 조립을 위한 절곡 작업시 유리섬유가 꺾이게 되는 문제점이 있으므로 표면수지 부착율은 40%-50%로 하였다.At this time, each component of the surface treatment agent was 50.62% of phenol resin, 2.30% of ammonia water, 0.48% of surfactant, 0.20% of surfactant, 28.10% of inorganic curing agent, 4.4% of dust collecting water repellent, 13.90% of inorganic dye. If the surface resin adhesion rate adhered to the surface is 40% or less, there is a risk of glass fiber being scattered and scattered by the conveying airflow during use, and the workability is low. If the surface resin adhesion rate is 50% or more, the sound absorption rate is lowered and Surface resin adhesion rate was 40% -50% because there is a problem that the glass fiber is bent during bending work for assembly.

아울러 집속체의 유리섬유경은 8μ 이상이 되면 열전도율이 저하되고 섬유조직 및 배열상태가 불량하게 될 우려가 있으므로 집속체의 유리섬유경은 8μ 이하로 하는 것이 적당하다.In addition, when the glass fiber diameter of the focusing body is 8 µm or more, the thermal conductivity may decrease and the fiber structure and the arrangement state may be poor. Therefore, the glass fiber diameter of the focusing body is preferably 8 µm or less.

이와같이 하여 얻은 표면처리된 집속체는 함수율이 상당히 증가된 상태이므로 140℃의 온도 분위기가 유지되는 이송식 열풍건조기에서 건조시켜 주면 열전도율이 0.030±0.003KCal/mh℃가 되고 절삭(Grooving)성, 재단성, 흡음성이 양호하며 색상이 선명한 유리면 덕트 시공용 판상 또는 관상의 집속체를 얻게 되었다.The surface-treated focusing body thus obtained has a significantly increased moisture content, so when dried in a transfer hot air dryer maintaining a temperature atmosphere of 140 ° C., the thermal conductivity becomes 0.030 ± 0.003 KCal / mh ° C. and the cutting property, cutting The plate-like or tubular focusing body for glass surface duct construction with good color and sound absorption and clear color was obtained.

이와같이 하여 얻은 집속체가 판상의 것인 경우는 가로와 세로를 원하는 규격으로 재단하고 집속체가 관상의 것인 경우는 정하여진 길이로 재단하며, 판상 또는 관상의 집속체 이면이나 외주면에 크라프트지나 그라스얀, 폴리에틸렌필름이 부착된 알루미늄 박지로된 보온 단열막을 열이나 본드로 접착하면 덕트 시공용 집속체가 완성되는 것이다.If the focusing body obtained in this way is plate-shaped, the horizontal and vertical cuttings are made to the desired standard, and if the focusing body is tubular, it is cut to a predetermined length. Kraft paper, glass yarn, When the thermal insulation film made of aluminum foil with a polyethylene film is bonded with heat or bond, the duct construction focusing body is completed.

[실시예 2]Example 2

본 실시예에서는 실시예 1과 동일하게 화염분사법이나 원심법 제조방식으로 얻은 단섬유상의 울에 페놀수지를 분사하여 수지부착율이 10-15%정도로 되도록 하고 이를 60kg/㎥ 이나 48kg/㎥의 비중을 갖는 울의 집속체로 집면하여 판상이나 관상의 가열판을 갖는 가열기에서 가열하여 경화, 성형시켜 얻은 판상이나 관상 집속체 이면이나 외주면에 크라프트지나 그라스얀, 폴리에틸렌 필름이 부착된 알루미늄 박지를 열이나 본드로 접착하고 이어서 판상이나 관상의 집속체의 표면이나 내주면에 표면처리제를 분사하되 본 실시예에서는 표면처리제의 배합비를 실시예 1과는 달리 페놀수지 51.20%, 암모니아수 2.10%, 유안 0.43%, 계면활성제 0.27%, 무기질 경화제 26.40%, 집진발수제 4.60%, 무기질염료 15.00%로 하였으며, 이때의 표면수지 부착율이 40-50%로 되도록 하고 유리섬유경이 8μ 이하가 되도록하여 얻은 표면처리된 집속체를 이송식 열풍건조기에서 건조시키고 적정한 규격으로 재단하면 덕트 시공용 집속체가 완성되는 것이다. 이러한 집속체는 실시예 1의 경우와 마찬가지로 열전도율이 0.030±0.003KCal/mh℃가 되었으며, 절삭성, 흡음성, 재단성이 모두 양호하고 색상이 선명하게 되었다.In this embodiment, in the same manner as in Example 1, by spraying phenolic resin on the short-fiber wool obtained by the flame spraying method or the centrifugal manufacturing method, the resin adhesion rate is about 10-15%, which is 60 kg / m 3 or 48 kg / m 3 Heated and bonded aluminum foil with kraft paper, glass yarn, or polyethylene film on the back or outer surface of the plate or tubular collector obtained by collecting with a bundle of wool having specific gravity and heating by heating in a heater having a plate or tubular heating plate The surface treatment agent was sprayed onto the surface or the inner circumferential surface of the plate-like or tubular concentrator, and in this embodiment, the compounding ratio of the surface treatment agent was 51.20% phenol resin, 2.10% ammonia water, 0.43% fluoride, and surfactant, unlike Example 1. 0.27%, inorganic curing agent 26.40%, dust-repellent water repellent 4.60%, inorganic dye 15.00%, the surface resin adhesion rate at this time is 40-50% When dried in a hot air re-fiber wonder 8μ or less transferred to the treated surface so that the bundling body obtained by drying and cutting into an appropriate size to the finished body for converging duct construction. As in the case of Example 1, the focusing body had a thermal conductivity of 0.030 ± 0.003 KCal / mh ° C., and the cutting, sound absorbing, and cutting properties were all good and the color became clear.

[실시예 3]Example 3

본 실시예에서는 실시예 1 및 실시예 2와 동일한 방법으로 판상 또는 관상의 집속체를 제조하되, 다만 표면처리제의 배합비에 있어서, 페놀수지 52.28%, 암모니아수 3.60%, 유안 0.29%, 계면활성제 0.33%, 무기질경화제 29.00%, 집진발수제 3.50%, 무기질염료 11.00%로 하였던바, 절삭성 및 흡음성, 재단성이 모두 양호하고 열전도율이 0.030±0.003KCal/mh℃이며, 색상이 선명하게된 제품을 얻을 수 있었다.In this embodiment, a plate-like or tubular focusing body is manufactured in the same manner as in Examples 1 and 2, except that in the blending ratio of the surface treatment agent, 52.28% of phenol resin, 3.60% of ammonia water, 0.29% of fluoride, and 0.33% of surfactant , 29.00% mineral hardener, 3.50% dust repellent agent, 11.00% inorganic dye. The product has good cutting, sound absorption and cutting property, and thermal conductivity is 0.030 ± 0.003KCal / mh ℃. .

[실시예 4]Example 4

본 실시예에서도 실시예 1 및 실시예 2와 마찬가지 방법으로 판상 또는 관상의 집속체를 제조하되 다만 표면처리제의 배합비에 있어서, 페놀수지 53.01%, 암모니아수 3.50%, 유안 0.20%, 계면활성제 0.49%, 무기질경화제 29.80%, 집진발수제 3.00%, 무기질염료 10.00%로 하였던바, 절삭성 및 흡음성, 재단성이 모두 양호하고 열전도율이 0.030±0.003KCal/mh℃이며, 색상이 선명하게된 제품을 얻을 수 있었다.In this embodiment, a plate-like or tubular focusing body was prepared in the same manner as in Examples 1 and 2, except that in the mixing ratio of the surface treatment agent, 53.01% of phenol resin, 3.50% of ammonia water, 0.20% of surfactant, 0.49% of surfactant, Inorganic curing agent 29.80%, dust collecting water repellent 3.00%, inorganic dye 10.00%, the cutting, sound absorption, cutting properties are all good, the thermal conductivity is 0.030 ± 0.003KCal / mh ℃, it was possible to obtain a product with a clear color.

[실시예 5]Example 5

본 실시예 역시 실시예 1 및 실시예 2와 마찬가지 방법으로 판상 또는 관상의 집속체를 제조하되 표면처리제의 배합비에 있어서, 페놀수지 55.00%, 암모니아수 3.07%, 유안 0.34%, 계면활성제 0.35%, 무기질경화제 24.34%, 집진발수제 4.00%, 무기질염료 12.90%로 하였던바, 열전도율이 0.030±0.003KCal/mh℃이며, 색상이 선명하고 절삭성 및 흡음성, 재단성이 모두 양호한 제품을 얻게 되었다.This embodiment is also prepared in the same manner as in Example 1 and Example 2 in the production of a plate-like or tubular focusing agent in the mixing ratio of the surface treatment agent, phenolic resin 55.00%, ammonia water 3.07%, yuan 0.34%, surfactant 0.35%, inorganic The curing agent was 24.34%, the dust collecting water repellent 4.00%, and the inorganic dye was 12.90%. The thermal conductivity was 0.030 ± 0.003 KCal / mh ° C., and the product was vivid in color and had excellent cutting, sound absorption, and cutting properties.

[비교예 1]Comparative Example 1

본 비교예에서도 본 발명의 실시예 1 및 실시예 2와 같은 방법으로 판상 또는 관상의 집속체를 제조하되, 표면처리제의 배합비에 있어서, 페놀수지를 43.70%, 암모니아수 5.00%, 유안 0.40%, 계면활성제 0.50%, 무기질경화제 40.00%, 집진발수제 2.00%, 무기질염료 8.40%로 하였던바, 이와같이 하여 얻은 제품은 가공시에 절삭면에 밀림현상과 부풀음 현상이 발생하고 색상은 옅게 표출되었으며 열전도율은 본 발명의 실시예들과 동일한 수준이고 재단성이 불량하여 재단면이 균일하지 못하였으며 흡음성은 양호하였다. 그러므로 비교예 1은 절삭성과 재단성 그리고 색상에 문제가 있음을 알수 있다.In this comparative example, a plate-like or tubular focusing body was produced in the same manner as in Examples 1 and 2 of the present invention, but in the blending ratio of the surface treatment agent, 43.70% of phenol resin, 5.00% of ammonia water, 0.40% of yuan, and interface 0.50% of active agent, 40.00% of inorganic hardener, 2.00% of water repellent agent, 8.40% of inorganic dye. Thus, the product obtained in this way has a swelling phenomenon and swelling on the cutting surface, and the color is lightly expressed. The same level as the Examples and the poor cutting property was not uniform cutting surface and sound absorption was good. Therefore, it can be seen that Comparative Example 1 has problems in machinability, cutting property and color.

[비교예 2]Comparative Example 2

본 비교예에서도 본 발명의 실시예 1 및 실시예 2와 같은 방법으로 판상 또는 관상의 집속체를 제조하되, 표면처리제의 배합비에 있어서, 페놀수지를 47.00%, 암모니아수 4.70%, 유안 0.50%, 계면활성제 0.40%, 무기질경화제 35.20%, 집진발수제 2.80%, 무기질염료 9.40%로 하였던바, 비교예 1과 마찬가지로 절삭성과 재단성 그리고 색상에 문제가 있는 것을 확인할 수 있었다.In this comparative example, a plate-like or tubular focusing body was produced in the same manner as in Examples 1 and 2 of the present invention, but in the blending ratio of the surface treatment agent, 47.00% of phenol resin, 4.70% of ammonia water, 0.50% of yuan, and interface. 0.40% of the active agent, 35.20% of the inorganic hardener, 2.80% of the water repellent agent, and 9.40% of the inorganic dye. As in Comparative Example 1, it was confirmed that there were problems in machinability, cutting property and color.

[비교예 3]Comparative Example 3

본 비교예 역시 실시예 1 및 실시예 2와 같은 방법으로 판상 또는 관상의 집속체를 제조하되, 표면처리제의 배합비에 있어서, 페놀수지를 48.40%, 암모니아수 2.30%, 유안 0.75%, 계면활성제 0.65%, 무기질 경화제 36.90%, 집진발수제 2.00%, 무기질염료 9.00%로 하였던바, 비교예 1,2와 마찬가지로 절삭성과 색상에 있어서 문제가 있고 열전도율과 재단성, 흡음성은 양호한 상태임을 알수 있었다.This comparative example was also prepared in the same manner as in Examples 1 and 2, but in the form of a plate-like or tubular concentrator, in the mixing ratio of the surface treatment agent, 48.40% phenol resin, 2.30% ammonia water, 0.75% fluoride, 0.65% surfactant , 36.90% of an inorganic curing agent, 2.00% of a dust repellent agent, and 9.00% of an inorganic dye. As in Comparative Examples 1 and 2, there were problems in machinability and color, and thermal conductivity, cutting property, and sound absorption were found to be in good condition.

[비교예 4][Comparative Example 4]

본 비교예에서도 실시예 1 및 실시예 2와 같은 방법으로 판상 또는 관상의 집속체를 제조하되, 표면처리제의 배합비에 있어서, 페놀수지를 57.00%, 암모니아수 1.50%, 유안 0.35%, 계면활성제 0.25%, 무기질경화제 18.40%, 집진발수제 6.00%, 무기질염료 16.50%로 하였던바, 절삭성이 좋지 않으나 색상은 매우 어둡게 표출되었고 열전도율이 불량하여 매우 단단하여 재단이 어렵고 흡음성도 불량하였다.In this comparative example, a plate-like or tubular focusing body was produced in the same manner as in Example 1 and Example 2, but in the blending ratio of the surface treatment agent, 57.00% of phenol resin, 1.50% of ammonia water, 0.35% of fluoride, 0.25% of surfactant. , 18.40% mineral hardener, 6.00% dust collector and 16.50% inorganic dye. The cutting performance is not good, but the color is very dark and the thermal conductivity is very hard, so cutting is difficult and sound absorption is poor.

[비교예 5][Comparative Example 5]

본 비교예에서도 실시예 1 및 실시예 2와 같은 방법으로 판상 또는 관상의 집속체를 제조하되, 표면처리제의 배합비에 있어서, 페놀수지를 60.00%, 암모니아수 2.30%, 유안 0.7%, 계면활성제 0.80%, 무기질경화제 15.00%, 집진발수제 3.70%, 무기질염료 17.50%로 하였던바, 비교예 4와 마찬가지로 절삭성이 좋지 않고 색상이 어둡게 표출되었으며, 열전도율이 불량하고 재단이 어려우며 흡음성도 불량하였다.In this comparative example, a plate-like or tubular focusing body was produced in the same manner as in Example 1 and Example 2, but in the blending ratio of the surface treatment agent, the phenol resin was 60.00%, ammonia water 2.30%, aviation 0.7%, and surfactant 0.80%. , Inorganic curing agent 15.00%, dust-repellent agent 3.70%, inorganic dyes 17.50% bar, similar to Comparative Example 4 was not good cutting and dark color, poor thermal conductivity, difficult cutting and poor sound absorption.

이상에서의 본 발명에 의한 실시예 1 내지 실시예 5 그리고 비교예 1 내지 비교예 5에서 알 수 있는 바와 같이 표면처리제의 배합비는 페놀수지 50-55%, 암모니아수 1-5%, 유안 0.1-0.75%, 계면활성제 0.2-0.8%, 무기질경화제 20-30%, 집진발수제 2-6%, 무기질염료 10-25%인 것이 절삭성, 색상, 열전도율, 재단성, 흡음성에 있어서 바람직하다는 결론을 얻었다.As can be seen from Examples 1 to 5 and Comparative Examples 1 to 5 according to the present invention, the compounding ratio of the surface treatment agent is 50-55% phenol resin, 1-5% ammonia water, 0.1-0.75 yuan. %, Surfactant 0.2-0.8%, inorganic hardener 20-30%, dust repellent 2-6%, inorganic dye 10-25% was concluded that it is preferable in cutting, color, thermal conductivity, cutting properties, sound absorption.

이와같이 하여 얻은 본 발명에 의한 판상 또는 관상의 집속체는 흡음성과 열전도율이 기존의 유리면과 같은 수준이며, 따라서 덕트로 시공하였을 때 별도의 보온공사가 불필요하고 경량이며, 불연성이므로 시공이 간편한 덕트재로서 활용이 가능할 뿐만 아니라 적당한 탄력과 파단성이 부여되어 재단이나 절삭시에 섬유조직의 밀림과 부풀음이 없어서 정확하게 가공할 수 있는 것이어서 다수의 집속체들을 연결하였을시 연결부위가 완전밀폐되어 이송기류가 누설될 염려가 전혀없게 되고 덕트내면이 표면처리제에 의하여 충분히 경화되어 송풍시에 유리면 조각의 비산이 없게되는 우수한 품질의 제품을 얻을 수 있게 된다. 그리고 본 발명의 집속체를 사용한 유리면 덕트는 최대 허용풍속이 약 15m/sec이므로 국제규격의 철제 저속덕트 최대 허용풍속과 동일하여 다용도로 실용가능하게 되는 것이다.The plate-like or tubular focusing body according to the present invention obtained in this way has sound absorption and thermal conductivity at the same level as the existing glass surface. Therefore, when a duct is constructed, a separate thermal insulation work is unnecessary, light weight, and incombustible. Not only can it be used, but it is also provided with proper elasticity and breaking property so that it can be processed accurately without cutting or swelling of the fiber tissue during cutting or cutting. There is no possibility of any damage, and the inner surface of the duct is sufficiently hardened by the surface treatment agent, so that a good quality product can be obtained without scattering of the glass surface fragments during the blowing. In addition, the glass surface duct using the focusing body of the present invention has a maximum allowable wind speed of about 15 m / sec, which is the same as the maximum allowable wind speed of iron low speed duct of the international standard.

Claims (4)

화염분사법이나 원심법 제조방식으로 생성된 섬유상의 유리면으로 냉난방 급기관으로 사용되는 유리면 덕트 시공용 집속체를 제조함에 있어서, 단섬유상의 울에 페놀 2-6%, 물 90-96%, 유안 0.9-3%, 암모니아 0.3-3%로 반응된 페놀수지를 1차 분사하여 도포시키고 적층시킨 상태에서 상당기간 열가압하여 경화시켜 얻은 집속체 일면에 페놀수지 50-55%, 암모니아수 1-5%, 유안 0.1-0.75%, 계면활성제 0.2-0.8%, 무기질경화제 20-30%, 집진발수제 2-6%, 무기질염료 10-25%로 배합된 표면처리제로 2차 분사하여 도포시켜주며 집속체 타면에는 알루미늄박판을 접착하여서됨을 특징으로 하는 유리면 덕트 시공용 집속체의 제조방법.In the manufacturing of glass-fiber duct construction focusing body used for air-conditioning and air supply pipe, which is produced by flame spraying or centrifugal manufacturing, 2-6% of phenol in wool, 90-96% of water, and yuan Phenolic resin reacted with 0.9-3% and 0.3-3% ammonia was first sprayed and laminated, and 50-55% phenolic resin and 1-5% aqueous ammonia on one surface of the cluster obtained by heat-pressing and curing for a considerable period of time. It is applied by spraying with a second surface treatment agent composed of 0.1-0.75% of surfactant, 0.2-0.8% of surfactant, 20-30% of mineral hardener, 2-6% of dust repellent agent, and 10-25% of inorganic dye. Method for producing a glass surface duct construction focusing body, characterized in that by adhering a thin aluminum plate. 제1항에 있어서, 단섬유상의 울에 1차 분사하여 도포시킨 페놀수지의 부착율이 10-17%임을 특징으로 하는 유리면 덕트 시공용 집속체의 제조방법.The method according to claim 1, wherein the adhesion ratio of the phenol resin applied by primary injection to the short-fiber wool is 10-17%. 제1항에 있어서, 표면처리제를 2차 분사하여 도포시킨 집속체 일면의 표면 수지 부착율이 40-50%임을 특징으로 하는 유리면 덕트 시공용 집속체의 제조방법.The method for manufacturing a glass surface duct construction focusing body according to claim 1, wherein the surface resin adhesion rate of one surface of the focusing body to which the surface treating agent is applied by secondary injection is 40-50%. 제1항에 있어서, 집속체의 유리섬유경이 8ν 이하임을 특징으로 하는 유리면 덕트 시공용 집속체의 제조방법.The method of manufacturing a glass surface duct construction focusing body according to claim 1, wherein the glass fiber diameter of the focusing body is 8 m or less.
KR1019870000828A 1987-01-31 1987-01-31 A concertrated material for the glass duct and its manufacturing method KR920000739B1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008000436A1 (en) * 2006-06-28 2008-01-03 H.K.O. Isolier-Und Textiltechnik Gmbh Fibrous part, and method for the production thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008000436A1 (en) * 2006-06-28 2008-01-03 H.K.O. Isolier-Und Textiltechnik Gmbh Fibrous part, and method for the production thereof

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