KR910009277B1 - Polishing composition - Google Patents

Polishing composition Download PDF

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KR910009277B1
KR910009277B1 KR1019880007136A KR880007136A KR910009277B1 KR 910009277 B1 KR910009277 B1 KR 910009277B1 KR 1019880007136 A KR1019880007136 A KR 1019880007136A KR 880007136 A KR880007136 A KR 880007136A KR 910009277 B1 KR910009277 B1 KR 910009277B1
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weight
water
acid
oil
polishing
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KR1019880007136A
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Korean (ko)
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KR900000445A (en
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홍성우
심건섭
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홍성우
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09GPOLISHING COMPOSITIONS; SKI WAXES
    • C09G1/00Polishing compositions
    • C09G1/02Polishing compositions containing abrasives or grinding agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09GPOLISHING COMPOSITIONS; SKI WAXES
    • C09G1/00Polishing compositions
    • C09G1/04Aqueous dispersions

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Lubricants (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)

Abstract

A polishing agent for removing impurities of the coated metal or plastic surface is produced by (a) heating the mixt. of 20 wt.% stearic acid, 6 wt.% oleic acid, 0.5 wt.% sodium fluoride and 2.5 wt.% water up to 80 deg.C, (b) mixing the aq. alkali metal oil with 25 wt.% chromium oxide, 15 wt.% silica oxide, 10 wt.% boric acid and 10 wt.% magnesium carbide, and (c) mixing the mixt. with 5 wt.% methyl silicon oil and 20 wt.% solvent [acetome/water = 1/ 2 .

Description

오물 제거 광택제의 제조 방법Manufacturing method of dirt removal polish

본 발명품은 각종 금속표면 푸라스틱에 표면 도장면등 각종표면에 오물을 제거, 표면처리하고 각종 기기 및 기구의 재료(원료)의 원색 광택을 내면 판면은 면경(거울)과 같은 광택을 내는 오물 제거하는 광택제의 제조 방법에 관한 것이다.The present invention is to remove and surface dirt on various surfaces, such as surface coating surface, various metal surface plastics, and to give the primary color gloss of materials (raw materials) of various equipments and devices, the surface of the surface to remove the gloss such as mirror (mirror) It relates to a manufacturing method of a brightener.

오늘날의 세척제는 각종의 종류가 있다. 화학적인 화합물로 세척하는 것과 세척하고 도포한다. 응집부착되어 있는 이들의 오물을 제거할려면 물과 용제타입의 오일로 청정제거한 다음 광택을 내기 위하여 왁스타입을 사용하고 있다.Today's cleaners come in many varieties. Wash with chemical compounds and wash and apply. To remove their contaminated dirt, water and solvent-type oils are used to remove them, and then wax type is used to give luster.

또는 각종 기기 및 기구의 제조 및 제작시 금속류 판면은 두가지로 분류 구분한다. 제품에 미세한 많은 산화물과 상처등의 오물을 제거할려면 첫째 금속면에 산화물을 처리할려면 금속 재료에 의하여 우선 희석된 염산·황산·인산 등의 용액을 선정하여 용액속에 담금질하고 물로 세척한 다음 연마 또는 도장으로 광택을 내는 복잡한 과정을 거쳐야 되는 많은 인력과 치밀하고 세밀한 장시간의 노력과 공정상의 문제점이 있다. 둘째 일반적으로 와이야솔·쎈드페파 등을 사용하는 예도 있다.Or in the manufacture and manufacture of various devices and appliances, the metal plate surface is divided into two categories. To remove a lot of fine oxides and wounds on the product First, to treat the oxide on the metal surface First, select a solution of hydrochloric acid, sulfuric acid, phosphoric acid, etc. diluted by the metal material, immerse it in the solution, wash it with water, and then polish or paint There are many manpower that need to go through the complicated process of polishing, and detailed and detailed long time effort and process problems. Second, there is an example that generally uses wire sole and chopped pepper.

각종 표면을 미세한 상처를 내는 문제도 있다. 그래서 오물을 제거하는 여러 가지로 조사하면 오물의 종류는 크게 나누어 3가지로 본다. 각종표면 즉 금속면·푸라스틱면·도장면등 각종 표면은 거의가 자체표면을 유지하고 있는 것은 거의 없다. 금속표면의 각종류에 산화물·먼지에 응결·거푸집·지문·땀등 여러 가지가 부착하고 있으므로 그 오물에 질과 량은 잘 생각하여 적절한 처리를 하게 된다. 그럼으로 각종 오물은 편이상 대별하여 보면 다음과 같이 분류된다.There is also a problem of making minute wounds on various surfaces. So, if you look into the various ways to remove the dirt is divided into three types of dirt. Various surfaces, such as metal surfaces, plastic surfaces, and painted surfaces, rarely maintain their own surfaces. Various kinds of metal surfaces are attached to oxides and dusts such as condensation, formwork, fingerprints, and sweat, so that the quality and quantity of the dirt are well considered and appropriately treated. Therefore, various kinds of dirt are classified as follows.

(1) 유기물 : 탄화물 유지·음식등에 속하는 유기물은 산 및 알카리 유지로 참화하는 것과 연마하여야 된다.(1) Organic matters: Organic matters belonging to carbide fats and oils, etc., should be polished with acid and alkaline fats and oils.

(2) 무기물 : 각종에 산화물이나 역시 산류처리와 연마처리등이다.(2) Inorganic matters: Oxides and various acid treatments and polishing treatments.

(3) 유기 및 무기 혼합물 : 유지와 산화물의 미세입자가 혼합된 오물은 각종의 표면을 연마시 산화물 1종류로 연마하면 연마에 의한 열에 의해 상당히 강하게 부착하는 성질이 생긴다. 그럼으로 상기된 오물은 미세한 상처등과 같은 취급을 하게 된다. 그래서 화학적인 방법과 연마하는 방법으로 효과적인 오물제거와 광택내는 방법을 발견하였다.(3) Organic and inorganic mixtures: Dirt mixed with fats and oils and fine particles of oxides is very strongly adhered by the heat of polishing when polishing various surfaces with one kind of oxide. Thus, the above-mentioned dirt is treated like a fine wound. So chemical and polishing methods were found to effectively remove dirt and polish.

(4) 본 발명은 지방산·알카리·실리콘유·산화물등 특성과 성질을 이용 화합 및 혼합된 것으로 다음과 같은 방법으로 열거하여 보겠다.(4) The present invention combines and mixes the properties and properties of fatty acids, alkalis, silicone oils, oxides, and the like.

4-1. 지방산4-1. fatty acid

스테아린산(고형) 올레인산(액상)은 내용에서 예를 들겠다. 유지산은 동물성과 식물성으로서 고형으로부터 액상까지 유연성을 사용목적에 따라 조절하는 것으로 필요에 따라서는 실리콘유로만 사용하여도 가능하다. 실리콘유의 량을 조절하여 사용할 수도 있다.Stearic acid (solid) oleic acid (liquid) is given in the contents. Oils and fats are animal and vegetable and adjust the flexibility from solid to liquid according to the purpose of use. The amount of silicone oil can also be adjusted.

4-2. 산화크롬과 산화규소4-2. Chromium oxide and silicon oxide

산화물과 탄화물은 일반적으로 사용되는 범위가 다양하겠으나 종류로는 약 57종이 일반적으로 사용된다. 그 중에서 산화크롬과 산화규소를 선택하여 실시하여본 것이다. 그런데 여기서 주지하여야할 것은 반드시 2종류를 선택하여 사용하되 연질과 강질을 연마할 수 있어야 하며 물로 희석된 알콜·산·알카리류에 화학적인 변화가 거의 없어야 된다. 상기된바 여기서는 올바른 사용방법이다.Oxides and carbides may be used in a wide range, but about 57 species are commonly used. Among them, chromium oxide and silicon oxide are selected and carried out. By the way, it should be noted that two kinds should be used, and soft and steel can be polished and there should be almost no chemical change in alcohol, acid and alkali diluted with water. As mentioned above, this is the correct method of use.

4-3. 탄산 마그네슘4-3. Magnesium carbonate

연마보조제로써 화합물에 의하여 반유상 상태로 알카리금속유에 화합된다. 물에 안녹는 성질을 이용 연마시 물을 첨가 사용할 때 산화크롬과 산화규소의 분산을 방지하고 산화물 상호간에 윤활을 도와주고 연마시 자체열을 감소시키며 연마를 도와준다.As a polishing aid, the compound is compounded with alkali metal oil in a semi-oil phase. Water-soluble property prevents the dispersion of chromium oxide and silicon oxide when water is added, and helps lubrication between oxides, reduces self-heat during polishing and helps polishing.

4-4. 붕산4-4. Boric acid

연마보조제로서 화합물에 의하여 반유상 상태로 알카리금속유에 화합된다. 물에 녹는다. 연마시 물을 사용하지 않을 때 윤활을 도와주고 산화물의 분말에 분산을 방지하고 상호간에 마찰열을 감소시켜주며 연마효과를 도와준다. 그리고 살충 및 방부제 역할도 한다.As a polishing aid, the compound is compounded with alkali metal oil in a semi-oil phase. Dissolve in water. It helps lubrication when water is not used in polishing, prevents dispersion in oxide powder, reduces frictional heat between each other and helps polishing effect. It also acts as a pesticide and preservative.

4-5. 메틸 실리콘유4-5. Methyl silicone oil

메틸 실리콘유는 {(CH3)2Si(OH)2}n여기서 n는 점도가 원료배합에 따라 적당히 n를 조절한다. 변질 고형화를 방지하고 유연성을 조절하여주며 피막현상을 도와준다. 즉 화학적으로는 안정되어 있지 않다. 그래서 반응성 실리콘유라고 한다. 또는 방부제 역할 및 연마시 윤활을 돕고 피막을 도와준다.Methyl silicone oil is {(CH 3 ) 2 Si (OH) 2 } n Where n is the viscosity is appropriately adjusted according to the raw material formulation. It prevents deterioration of solidification, controls flexibility, and helps with film development. That is, it is not chemically stable. Therefore, it is called reactive silicone oil. Or as a preservative and helps to lubricate and coat during polishing.

4-6. 아세톤4-6. Acetone

저불점 용제로써 특성과 성질을 이용하여 사용한다. 즉 아세톤은 푸라스틱 용제로써 물에 희석하고 타화합물과 화합하여 푸라스틱의 표면의 선제역할과 금속표면에 탈지 또는 불화소다·실리콘유·탄화마그네슘·물등 가용 혼합제로 촉매 역할도 한다.As a low-solvent solvent, use it with its properties and properties. In other words, acetone is diluted with water as a plastic solvent and combined with other compounds to act as a prerequisite on the surface of the plastic and as a soluble mixture such as degreasing or soda fluoride, silicon oil, magnesium carbide, and water on the metal surface.

4-7. 불화소다4-7. Soda Fluoride

불소는 단독으로 공기중에서 존재하지 못한다. 딴 화합물질과 화합하여 공존한다. 그럼으로 불소는 금속 표면처리제로써 산화물 제거에 도움을 주고 소다(나트륨)는 금속표면처리 및 염기제거와 지방산에 반참화의 목적이 있다. 그러나 각종금속표면 및 푸라스틱표면을 부식하지 않는 범위내에서 적절히 처리하여야 한다.Fluorine alone does not exist in air. Coexists with other compounds. Therefore, fluorine is a metal surface treatment agent to help remove oxides, and soda (sodium) is intended for metal surface treatment, base removal and anti-fatty acid. However, various metal surfaces and plastic surfaces should be treated properly within the range not to corrode.

(5) 본 발명의 화학적인 조성물은 제조하는 공정과 공정별로 실시예를 들면서 설명한다.(5) The chemical composition of the present invention will be described with reference to Examples according to the manufacturing process and the processes.

[제1공정][Step 1]

스테아린산 20중량%, 올레인산 6중량%, 불화소다 0.5중량%에 물 2.5중량%, 물에 희석하여 묽은 농도로 화합하여 80℃까지 가열하면 액체상태에서 곽반하면서 반참화한다.20% by weight of stearic acid, 6% by weight of oleic acid, 0.5% by weight of sodium fluoride, 2.5% by weight of water, diluted with water, combined with dilute concentration, and heated to 80 ℃, they become bounced in a liquid state.

[제2공정][Step 2]

액체 상태의 알카리금속유에 산화크롬 25중량%, 산화규소 15중량%, 붕산 10중량%, 탄화마그네슘 10중량%등을 액체에서 혼합 곽반한다.25 wt% chromium oxide, 15 wt% silicon oxide, 10 wt% boric acid, 10 wt% magnesium carbide and the like are mixed and mixed in the liquid alkali metal oil in the liquid.

[제3공정][Step 3]

제2공정에서 완전히 화합된 상태에서 상온으로 냉각하면서 50℃정도에서 메틸실리콘유 5중량% 아세톤과 물 1 : 2로 희석된 것을 20중량%로 화합 및 혼합하여 곽반하면서 완전히 상온으로 냉각 제조한다.In a completely combined state in the second step while cooling to room temperature while diluting 5% by weight of methylsilicone oil 5% by weight of acetone and water 1: 2 at 20 ℃ compounded and mixed to 20% by weight and completely cooled to room temperature.

그러나 참고예로써 수십종에 지방산과 유기물등 산화물, 탄화물로 실시하여본 결과 여러 가지 현상이 일어난다. 악조건인 경우 화합 및 혼합물중 3염화 에틸렌(트리크롤레에틸렌트리크로렌)을 함유하였을 때 물보다 무겁고 거의 물에 녹지 않으나 물로 표면에서 증발을 방지하여 사용할 수는 있다. 그러나 물에 분해되어 소량의 염산을 생기게 함으로써 아연이나, 알루미늄 등의 합금 금속 표면에는 특히 산에 녹기 쉬운 바탕의 표면인 경우 사용가치가 없다.However, as a reference example, a variety of phenomena occur as a result of conducting oxides and carbides such as fatty acids and organic substances. In adverse conditions, when the compound and the mixture contain ethylene trichloride (trichloroethylene trichlorene), it is heavier than water and hardly soluble in water, but water can be used to prevent evaporation from the surface. However, by decomposing in water to produce a small amount of hydrochloric acid, the surface of alloy metals such as zinc or aluminum is not particularly useful in the case of the surface of the base which is easily soluble in acid.

그래서 이러한 현상을 보완하여 불화소다와 물 또는 화합물에 화합시키기 위하여 아세톤을 화합물에 가용촉매제로 사용 인체에 장해를 주지 않는 화합 및 혼합물로써 오물제거가 편리하게 각종표면에 원색보다 더 한층 미려한 면경(거울)과 같은 광택이 나며 표면에는 메틸실리콘유로 피막을 형성 광택 효과를 지연시켜준다.Therefore, in order to compensate for this phenomenon, acetone is used as a soluble catalyst for compound to combine with fluoride and water or a compound. It is a compound and mixture that does not harm the human body, and it is convenient to remove dirt on various surfaces. It is glossy like) and the surface of methylsilicone oil forms a film that delays the gloss effect.

Claims (1)

본 발명은 스테아린산, 올레인산, 산화크롬 및 산화규소를 구성 성분으로 하는 공지의 광택제에, 메틸실리콘유({(CH3)2Si(OH)2}N) 4중량%-8중량%, 불화소다(NaF) 0.5중량%-2중량%, 아세톤(CH3COCH3) 5중량%-15중량%, 탄산마그네슘(MgCO3) 10중량%-25중량%, 붕산(B203) 5중량%-10중량%를 첨가함을 특징으로 하는 오물제거에 광택제의 제조방법.The present invention relates to methyl polish oil ({(CH 3 ) 2 Si (OH) 2 } N ) 4% by weight to 8% by weight, in a known brightener comprising stearic acid, oleic acid, chromium oxide, and silicon oxide as components. (NaF) 0.5% -2% by weight, 5% -15% by weight of acetone (CH 3 COCH 3 ), 10% -25% by weight magnesium carbonate (MgCO 3 ), 5% by weight boric acid (B 2 0 3 ) -10% by weight of the manufacturing method of the polish to remove dirt, characterized in that the addition.
KR1019880007136A 1988-06-15 1988-06-15 Polishing composition KR910009277B1 (en)

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