KR910006367A - 인-함유 공중합체와 그의 제법 및 용도 - Google Patents
인-함유 공중합체와 그의 제법 및 용도 Download PDFInfo
- Publication number
- KR910006367A KR910006367A KR1019900015477A KR900015477A KR910006367A KR 910006367 A KR910006367 A KR 910006367A KR 1019900015477 A KR1019900015477 A KR 1019900015477A KR 900015477 A KR900015477 A KR 900015477A KR 910006367 A KR910006367 A KR 910006367A
- Authority
- KR
- South Korea
- Prior art keywords
- copolymer according
- epoxy resin
- phosphorus
- diphosphite
- glycidyl ether
- Prior art date
Links
- 229920001577 copolymer Polymers 0.000 title claims 12
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims 6
- 229910052698 phosphorus Inorganic materials 0.000 title claims 6
- 239000011574 phosphorus Substances 0.000 title claims 6
- 239000003822 epoxy resin Substances 0.000 claims 9
- 229920000647 polyepoxide Polymers 0.000 claims 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 6
- -1 epoxide compound Chemical class 0.000 claims 6
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 claims 5
- 239000000203 mixture Substances 0.000 claims 5
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 238000004132 cross linking Methods 0.000 claims 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 239000008096 xylene Substances 0.000 claims 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 1
- GXURZKWLMYOCDX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.OCC(CO)(CO)CO GXURZKWLMYOCDX-UHFFFAOYSA-N 0.000 claims 1
- YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical group CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 claims 1
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 claims 1
- 239000004593 Epoxy Substances 0.000 claims 1
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 claims 1
- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 claims 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims 1
- 150000001334 alicyclic compounds Chemical class 0.000 claims 1
- 150000007824 aliphatic compounds Chemical class 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 150000001491 aromatic compounds Chemical class 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- ZWAJLVLEBYIOTI-UHFFFAOYSA-N cyclohexene oxide Chemical compound C1CCCC2OC21 ZWAJLVLEBYIOTI-UHFFFAOYSA-N 0.000 claims 1
- FWFSEYBSWVRWGL-UHFFFAOYSA-N cyclohexene oxide Natural products O=C1CCCC=C1 FWFSEYBSWVRWGL-UHFFFAOYSA-N 0.000 claims 1
- 150000002118 epoxides Chemical class 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 150000002391 heterocyclic compounds Chemical class 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 229920003986 novolac Polymers 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- 238000010992 reflux Methods 0.000 claims 1
- 238000005809 transesterification reaction Methods 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/22—Di-epoxy compounds
- C08G59/30—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4071—Curing agents not provided for by the groups C08G59/42 - C08G59/66 phosphorus containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/22—Di-epoxy compounds
- C08G59/30—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen
- C08G59/304—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Epoxy Resins (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (16)
- 에폭시드 화합물을 하기 일반식(Ⅰ)의 디알킬 펜타에리트리틸 디포스파이트와 반응시킴으로써 얻어질 수 있는 인-함유 공중합체,상기식에서, R1과 R2는 서로 독립적으로 C1-C4알킬기이다.
- 제1항에 있어서, R1과 R2가 동일하며 바람직하게는 n-부틸 또는 메틸인 공중합체.
- 제1항 또는 제2항에 있어서, 에폭시드 화합물 1몰당 0.05 내지 5몰의 디포스파이트가 사용되는 공중합체.
- 제1항 내지 제3항중 어느 하나에 있어서, 에폭시드 화합물이 모노에폭시드, 바람직하게는 알킬 글리시딜에테르, 아릴 글리시딜에스테르 또는 에폭시드화 올레핀인 공중합체.
- 제4항에 있어서, 모노-에폭시드가 n-부틸 글리시딜에테르, 시클로헥센옥사이드, 스티렌옥사이드 또는 바람직하게는 페닐글리시딜에테르인 공중합체.
- 제4항 또는 제5항에 있어서, 모노에폭시드 1몰당 디포스파이트 1몰이 사용되는 공중합체.
- 제1항 내지 제3항중 어느 하나에 있어서, 에폭시드 화합물이 에폭시 수지인 공중합체.
- 제7항에 있어서, 에폭시 수지가 2 내지 10당량/㎏의 에폭시드 함량을 가지며, 방향족, 헤테로고리형, 지환족 또는 지방족 화합물의 글리시딜에테르, 글리시딜에테르 또는 N-글리시딜유도체, 바람직하게는 비스페놀 A 디글리시딜에테르, 1,1,1-트리메틸올프로판의 글리시딜에테르 또는 에폭시-노볼락인 공중합체.
- 제7항 또는 제8항에 있어서, 에폭시 수지의 에폭시 당량에 대하여 0.1 내지 1몰의 디포스파이트가 사용되는 공중합체.
- 제7항 내지 제9항에 어느 하나에 있어서, 2 내지 10중량％의 인을 함유한 인-함유 에폭시 수지가 생성되도록 디포스파이트 및 에폭시 수지의 양을 선택하는 공중합체.
- 반응 혼합물을 80 내지 220℃의 온도에서 가열함으로써 제1항에 따른 공중합체를 제조하는 방법.
- 알킬기의 탄소수가 1 내지 4인 트리알킬포스파이트를 촉매 존재하에 펜타에리트리톨로 에스테르 교환반응을 시키며, 이때 에스테르 교환 반응을 환류온도 하에 톨루엔 또는 크실렌중에서 실시하고 반응도중 생성된 알칸올을 톨루엔 또는 크실렌과의 공비혼합물로서 증류시켜 제거하는 것을 포함하는, 제1항에 따른 일반식(Ⅰ)의 디알킬 펜타에리트리틸 디포스파이트의 제조 방법.
- (a) 제1항에 따른 인-함유 공중합체 및 (b) 에폭시 수지를 함유하는 조성물.
- (a) 제10항에 따른 인-함유 에폭시 수지 및 (b) 에폭시 수지용 경화제를 함유하는 경화성 조성물.
- 제13항에 따른 조성물을 에폭시 수지용 경화제로 경화시킴으로써 얻어질 수 있는 가교 생성물.
- 제14항에 따른 경화성 조성물을 경화시킴으로써 얻어질 수 있는 가교 생성물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH351089 | 1989-09-28 | ||
| CH3510/89-7 | 1989-09-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR910006367A true KR910006367A (ko) | 1991-04-29 |
Family
ID=4257546
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019900015477A KR910006367A (ko) | 1989-09-28 | 1990-09-28 | 인-함유 공중합체와 그의 제법 및 용도 |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0420811A3 (ko) |
| JP (1) | JPH03124728A (ko) |
| KR (1) | KR910006367A (ko) |
| CA (1) | CA2026255A1 (ko) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW280824B (ko) * | 1993-09-09 | 1996-07-11 | Ciba Geigy Ag | |
| EP4342925A1 (en) | 2022-09-26 | 2024-03-27 | EMPA Eidgenössische Materialprüfungs- und Forschungsanstalt | Phosphonate epoxy thermosets |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5371153A (en) * | 1976-12-07 | 1978-06-24 | Sakai Chem Ind Co Ltd | Chlorine-containing resin composition |
-
1990
- 1990-09-19 EP EP19900810719 patent/EP0420811A3/de not_active Withdrawn
- 1990-09-26 CA CA002026255A patent/CA2026255A1/en not_active Abandoned
- 1990-09-28 KR KR1019900015477A patent/KR910006367A/ko not_active Application Discontinuation
- 1990-09-28 JP JP2260315A patent/JPH03124728A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JPH03124728A (ja) | 1991-05-28 |
| CA2026255A1 (en) | 1991-03-29 |
| EP0420811A3 (en) | 1992-04-01 |
| EP0420811A2 (de) | 1991-04-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |