KR910000350A - Multi-layer coating system, coating method using same and coated product - Google Patents

Multi-layer coating system, coating method using same and coated product Download PDF

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KR910000350A
KR910000350A KR1019900008345A KR900008345A KR910000350A KR 910000350 A KR910000350 A KR 910000350A KR 1019900008345 A KR1019900008345 A KR 1019900008345A KR 900008345 A KR900008345 A KR 900008345A KR 910000350 A KR910000350 A KR 910000350A
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resins
acid
coating system
film
group
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KR1019900008345A
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Korean (ko)
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패너시 숄
엠 겔미니 제임즈
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원본미기재
비이에이에스에프 코오포레이션
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/53—Base coat plus clear coat type
    • B05D7/536—Base coat plus clear coat type each layer being cured, at least partially, separately
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • B05D5/067—Metallic effect
    • B05D5/068—Metallic effect achieved by multilayers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/38—Paints containing free metal not provided for above in groups C09D5/00 - C09D5/36
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31605—Next to free metal
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y10T428/31681—Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y10T428/31688—Next to aldehyde or ketone condensation product
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y10T428/31692—Next to addition polymer from unsaturated monomers

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)
  • Laminated Bodies (AREA)

Abstract

내용 없음No content

Description

다중-충 코우팅계, 그를 이용한 코우팅처리 방법 및 코우팅 처리된 제품Multi-fill coating system, coating method using same and coated product

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (14)

a)ⅰ) 아크릴 수지, 알키드 수지, 폴리우레탄수지, 폴리에스테르 수지 및 아미노플라스트 수지로 구성된 군중에서 선택된 첫 번째 필름-형성물질, ⅱ)리핑(leafing)알루미늄 플레이크: 및 ⅲ) 상기 첫 번째 필름-형성물질을 위한 휘발성 유기 용매로 구성된 베이스 코우트 조성물로부터 지지체상에 형성된 경화된 베이스 코우트층: b) ⅰ) 아크릴수지, 알키드 수지, 폴리우레탄 수지, 폴리에스테르 수지 및 아미노플라스트 수지로 구성된 군중에서 선택된 두 번째 필름-형성물질: ⅱ)상기 두 번째 필름-형성물질을 위한 휘발성 유기 용매: 및 ⅲ) 인산, 알킬기가 C1-C12를 포함하는 알킬 벤젠술폰산, 및 알킬기가 C1-C12를포함하는 알킬나프틸렌술폰산 및 디알킬 나프틸렌술폰산으로 구성된 군중에서 선택된 다중-층 코우팅계의 이층(delamination)을 방지하기에 효과적인 양인 산성 접착제로 구성된 탑 코우트 조성물로부터 형성되고 상기 경화된 베이스코우트층상에 부착된 경화된 투명탑 코우트층으로 구성된 금속 지지체상에 부착성, 장식성, 고반사성 코우팅을 제조하기 위한 다중-층 코우팅계.a) iii) the first film-forming material selected from the group consisting of acrylic resins, alkyd resins, polyurethane resins, polyester resins and aminoplast resins, ii) leafing aluminum flakes: and iii) the first film A cured base coat layer formed on a support from a base coat composition consisting of a volatile organic solvent for the forming material: b) iii) a crowd consisting of acrylic resins, alkyd resins, polyurethane resins, polyester resins and aminoplast resins. A second film-forming material selected from: ii) a volatile organic solvent for the second film-forming material: and iii) an alkyl benzenesulfonic acid in which the phosphoric acid, the alkyl group comprises C 1 -C 12 , and the alkyl group is C 1 -C Effective to prevent delamination of a multi-layer coating system selected from the group consisting of alkylnaphthylenesulfonic acid and dialkyl naphthylenesulfonic acid comprising 12 Multiple to prepare adherent, decorative, highly reflective coatings on a metal support formed from a top coat composition composed of an excessive amount of acid adhesive and composed of a cured transparent top coat layer attached to the cured basecoat layer. Floor coating system. 제1항에 있어서, 상기 베이스 코우트 조성물이 a)가-교제: 및 b) ⅰ) 아크릴산 및 메타크릴산으로 구성된 군중에서 선택된 적어도 하나의 에틸렌형 불포화산 약 0.2%-약 10%: ⅱ) C1-C10의 포화 알콜과의 아크릴 산또는 메타크릴산의 약 1%-약50%: ⅲ) C1-C10의모노히드록실화된 포화알콜과의 아크릴산 또는 메타크릴산의 에스테르 약 35%이하: ⅳ) 스티렌 약 25%이하: ⅴ) 그들과 함께 공중합가능한 폴리에스테르 폴리올 약 50%이하의 반응 생성물인 공중합체로 구성되는 다중-층 코우팅계.The method of claim 1 wherein said base coot composition comprises a) a cross-linking agent: and b) iii) at least one ethylenically unsaturated acid selected from the group consisting of acrylic acid and methacrylic acid about 0.2% to about 10%: ii) About 1% to about 50% of acrylic acid or methacrylic acid with a saturated alcohol of C 1 -C 10 : i) about an ester of acrylic acid or methacrylic acid with a monohydroxylated saturated alcohol of C 1 -C 10 35% or less: i) up to about 25% styrene: i) a multi-layer coating system consisting of a copolymer that is a reaction product of about 50% or less of a polyester polyol copolymerizable with them. 제1항에 있어서, 상기 산성 정착제가 인산, p-톨루엔술폰산, 도데실 벤젠 술폰산, 및 디노닐나프탈렌술폰산으로 구성된 군중에서 선택되는 다중-층 코우팅계.The multi-layer coating system of claim 1, wherein the acidic fixative is selected from the group consisting of phosphoric acid, p-toluenesulfonic acid, dodecyl benzene sulfonic acid, and dinonylnaphthalenesulfonic acid. 제3항에 있어서, 상기 산성 정착제가 상기 탑 코우드 조성물의 총 부피를 기준으로 약 0.05부피%-1.0부피%의 양으로 존재하는 다중-층 코우팅계.The multi-layer coating system of claim 3, wherein the acidic fixative is present in an amount of about 0.05% -1.0% by volume based on the total volume of the top wood composition. 제4항에 있어서, 상기 산성 정착제가 인산인 다중-층 코우팅계.The multi-layer coating system of claim 4, wherein the acidic fixative is phosphoric acid. 제5항에 있어서, 상기 인산이 상기 탑 코우트 조성물의 총 부피를 기준으로 약0.25부피%의 양으로 존재하는 다중-층 코우팅계.6. The multi-layer coating system of claim 5, wherein said phosphoric acid is present in an amount of about 0.25 volume percent based on the total volume of said top coat composition. 제1항에 있어서, 상기 베이스 코우트 조성물이 상기 베이스 코우트 조성물을 탈리핑에 대해 안정화시키기에 효과적인 양인 알킬아민/지방산 에스테르 혼합물을 포함함을 특징으로 하는 다중-층 코우팅계.2. The multi-layer coating system of claim 1, wherein said base coat composition comprises an alkylamine / fatty acid ester mixture in an amount effective to stabilize said base coat composition against deliping. 제7항에 있어서, 상기 알킬아민/지방산 에스테르 혼합물이 상기 베이스 코우트 조성물내에 상기 베이스코우트 조성물의 총 중량을 기준으로 약 0.25중량%-2.0중량%의 양으로 존재하는 다중-층 코우팅계.8. The multi-layer coating system of claim 7, wherein the alkylamine / fatty acid ester mixture is present in the base coat composition in an amount of about 0.25% -2.0% by weight based on the total weight of the basecoat composition. 제1항에 있어서, 투명한 무기 되는 유기 안료제를 포함함을 특징으로 하는 다중-층 코우팅계.The multi-layer coating system of claim 1, comprising a transparent inorganic pigmented organic pigment. 제9항에 있어서, 상기 투명한 무기 또는 유기 안료제가, 상기 리핑 알류미늄과 함께, 상기 베이스 코우트 조성물의 총 비-휘발성 함량을 기준으로, 상기 베이스 코우트 조성물의 약1중량%-약20중량%를 구성하는 다중-층 코우팅계.10. The method according to claim 9, wherein the transparent inorganic or organic pigment, together with the ripping aluminum, is based on about 1% to about 20% by weight of the base coat composition, based on the total non-volatile content of the base coat composition. Multi-layer coating system constituting. 제10항에 있어서, 상기 안료제가 투명한 산화철, 프탈로시아닌 녹색, 프탈로시아닌 청색, 안트라피리미딘 황색, 팔라반트론 황색, 이미다졸 오렌지색, 퀴나크리드론 적색, 카르바졸 디옥사진 자색, 인단트렌 청색, 아조갈색, 이소인돌리논, 및 고분자량 아조 안료로 구성된 군중에서 선택되는 다중-층 코우팅계.The pigment of claim 10, wherein the pigment is transparent iron oxide, phthalocyanine green, phthalocyanine blue, anthrapyrimidine yellow, palavantron yellow, imidazole orange, quinacridron red, carbazole dioxazine purple, indanthrene blue, azobrown, Multi-layer coating system selected from the group consisting of isoindolinone, and high molecular weight azo pigments. a) 지지체에 ⅰ) 아크릴 수지, 알키드 수지, 폴리우레탄 수지, 폴리에스테르 수지 및 아미노플라스트 수지로 구성된 군중에서 선택된 첫 번째 필름-형성물질, ⅱ) 리핑 알루미늄 플레이트: 및 상기 첫 번째 필름-형성 물질을 위한 휘발성 유기 용매로 구성된 베이스 코우트코우팅을 적용시키는 단계: b) 상기 베이스 코우트 코우팅을 단단한, 내구성 코우팅층으로 경화시키는 단계: c)경화된 베이스 코우트 코우팅의 상부상에ⅰ)아크릴 수지, 알키드 수지, 폴리우레탄 수지, 폴리에스테르 수지 및 아미노플라스트 수지로 구성된 군중에서 선택된 두 번째 필름-형성물질: ⅱ) 상기 두 번째 필름-형성물질을 위한 휘발성 유기 용매: 및 ⅲ)인산, 알킬기가 C1-C12를 포함하는 알킬벤젠술폰산, 및 알킬기C1-C12를 포함하는 알킬나프틸렌술폰산 및 디알킬나프틸렌술폰산으로 구성된 군중에서 선택된 상기 코우팅계의 이층을 방지하는 효과적인 양인 산성 정착제로 구성된 적어도 하나의탑 코우트 코우팅을 적용시키는 단계: d)상기 탑 코우트 코우팅을 단단한, 내구성 코우팅층을 경화시키는 단계로 구성된 장식성, 부착성, 고반사성 코우팅으로 지지체를 코우팅 처리시키는 방법.a) a first film-forming material selected from the group consisting of acrylic resins, alkyd resins, polyurethane resins, polyester resins and aminoplast resins, ii) ripping aluminum plates: and the first film-forming material Applying a base coat coating consisting of a volatile organic solvent for the process: b) curing the base coat coating into a hard, durable coating layer: c) on top of the cured base coat coating A second film-forming material selected from the group consisting of acrylic resins, alkyd resins, polyurethane resins, polyester resins and aminoplast resins: ii) volatile organic solvents for the second film-forming material: and iii) phosphoric acid. , alkyl benzene sulfonic acid that comprises a C 1 -C 12 alkyl group, and the alkyl group C 1 -C 12 alkyl naphthylene sulfonate and dialkyl naphthylene containing Applying at least one top coat coating consisting of an acidic fixative which is an effective amount to prevent a double layer of the coating system selected from a crowd of phonic acids: d) curing the top coat coating to harden, durable coating layer A method of coating a support with a decorative, adhesive, highly reflective coating consisting of steps. 제12항에 있어서, 상기 지지체가 금속인 방법.The method of claim 12, wherein the support is a metal. a) ⅰ) 아크릴 수지, 알키드 수지, 폴리우레탄 수지, 폴리에스테르 수지 및 아미노플라스트 수지로 구성된 군중에서 선택된 첫 번째 필름-형성물질, ⅱ) 리핑 알루미늄 플레이트: 및 ⅲ) 상기 첫 번째 필름-형성 물질을위한 휘발성 유기 용매로 구성된 베이스 코우트 조성물로부터 형성된 경화된 베이스 코우트 층: b)ⅰ)아크릴 수지, 알키드 수지, 폴리우레탄 수지, 폴리에스테르 수지 및 아미노플라스트 수지로 구성된 군중에서 선택된 두 번째 필름-형성물질: ⅱ) 상기 두 번째 필름-형성물질을 위한 휘발성 유기 용매: 및 ⅲ)인산, 알킬기가 C1-C12를 포함하는 알킬벤젠술폰산, 및 알킬기가 C1-C12를 포함하는 알킬나프틸렌술폰산 및 디알킬나프틸렌술폰산으로 구성된 군중에서 선택된 상기 코우팅계의 이층을 방지하기에 효과적인 양인 산성 정착제로 구성된 탑 코우트 조성물로부터 형성된 적어도 하나의 경화된 투명한 탑 코우트 층으로 구성된, 다중-층, 장식성, 부착성, 고반사성 코우팅을 갖는 제품.a) iii) the first film-forming material selected from the group consisting of acrylic resins, alkyd resins, polyurethane resins, polyester resins and aminoplast resins, ii) ripping aluminum plates: and iii) the first film-forming materials A cured base coat layer formed from a base coat composition composed of a volatile organic solvent for the preparation of: b) a second film selected from the group consisting of acrylic resins, alkyd resins, polyurethane resins, polyester resins and aminoplast resins -forming materials: ⅱ) the second film-volatile organic solvents for the forming material: and ⅲ) phosphate, alkyl which alkyl group is an alkyl benzene sulfonic acid, and alkyl group including a C 1 -C 12 include C 1 -C 12 An acidic fixative which is an amount effective to prevent double layering of the coating system selected from the group consisting of naphthylenesulfonic acid and dialkylnaphthylenesulfonic acid. An article having a multi-layered, decorative, adherent, highly reflective coating, consisting of at least one cured transparent top coat layer formed from the formed top coat composition. ※ 참고사항: 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the original application.
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