KR900701882A - Thermosetting Stretchable Coating Composition - Google Patents

Thermosetting Stretchable Coating Composition

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KR900701882A
KR900701882A KR1019900700103A KR900700103A KR900701882A KR 900701882 A KR900701882 A KR 900701882A KR 1019900700103 A KR1019900700103 A KR 1019900700103A KR 900700103 A KR900700103 A KR 900700103A KR 900701882 A KR900701882 A KR 900701882A
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coating composition
range
polyester
amount
weight
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KR1019900700103A
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Korean (ko)
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조셉 버크메이어 윌리암
스마트 브래드포드 론다
웨인 카슨 데니스
토마스 맥코우 데이비드
알랜 몬타그 로버트
스티븐 리챠드슨 자멜
알렌 세네카 카알
Original Assignee
헬렌 에이. 파블릭크
피피지 인더스트리즈, 인코포레이티드
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Publication of KR900701882A publication Critical patent/KR900701882A/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C08G18/4219—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from aromatic dicarboxylic acids and dialcohols in combination with polycarboxylic acids and/or polyhydroxy compounds which are at least trifunctional
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • C08G18/4241—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols from dicarboxylic acids and dialcohols in combination with polycarboxylic acids and/or polyhydroxy compounds which are at least trifunctional
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

내용 없음No content

Description

열경화성 연신성 코팅 조성물Thermosetting Stretchable Coating Composition

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

제1도는 특허 청구한 코팅 조성물의 연심성을 평가할때 사용되는, 둥근 모서리를 갖는 연심된 정사각형 컵을 도시한 것이다.FIG. 1 shows a drawn square cup with rounded corners, used in evaluating the drawability of a claimed coating composition.

Claims (47)

필름형성제로, 디올 성분(a), 디카복실산 성분 또는 그의 작용성 등가물(b) 및 작용기가 하이드록실, 카복실산 또는 그의 작용성 등가물 또는 작용성 그룹 2개의 조합물중에서 선택된 다작용성 성분(c)(상기 다작용성 성분(c)의 양은 폴리에스테르 폴리올을 제조하는데 사용한 총 반응물 500g당 다작용성 성분을 약 O.25-몰 이하로 혼입시키도록 조절된 양이다)의 반응으로부터 생성되고, 조절된 양으로 분지되고 약 4000내지 약4O,OOO의 중량 평균 분자량, 약 10내지 약 100의 하이드록실가를 갖는 폴리에스테르 폴리올과 이소시아네이트 대 하이드록실의 당량비가 약 0.3/1내지 약 1.5/1의 범위가 되도록 하는 양의 폴리이소시아네이트 경화제를 포함하며: 약3.25인치(82.6mm)의 직경을 갖는 24게이지(gauge)의 냉각 압연 강 원형 소재판에 코팅 조성물을 약 0.8mil(2Oμ)의 건조 필림 두께로 직접 도포하고, 약 240℃의 최고 금속 온도에서 약 50초동안 경화시키고, 약 16인치(406mm)의 직경을 갖는 실린더에 약 40 1bs/in2(2.7×106dynes/㎠)의 공기 압력을 사용하는 9O톤(8×1O10dynes)의 프레스를 사용하여 둥근 모서리를 갖는 정사각형 컵(성형된 정사각형 컵은 깊이 약 26mm, 각모서리가 약6.5mm의 외반경을 갖는 둥근모서리, 및 약36mm의 번 너비를 갖는다)으로 연신(이때, 정사각형컵 바닥의 둥근모서리에 약120%의 신장율과 약50%의 압축력을 가했다)시킨 후, 비등 탈염수에 5분간 침지시켰을때 코팅 조성물이 본질적으로 점착성이 없고, 본질적으로 결합이 없는 필름을 생성시킴을 조건으로하는 코팅 조성물.As the film-forming agent, the diol component (a), the dicarboxylic acid component or functional equivalent thereof (b) and the multifunctional component (c) wherein the functional group is selected from hydroxyl, carboxylic acid or functional equivalent thereof or a combination of two functional groups ( The amount of the multifunctional component (c) is produced from the reaction of the amount of the polyfunctional component per 500 g of the total reactants used to make the polyester polyol, adjusted to incorporate up to about 0.25 moles or less), and in a controlled amount. A polyester polyol branched and having a weight average molecular weight of about 4000 to about 40O, OOO, having a hydroxyl value of about 10 to about 100, so that the equivalent ratio of isocyanate to hydroxyl ranges from about 0.3 / 1 to about 1.5 / 1 Comprising a positive amount of polyisocyanate curing agent: drying the coating composition to about 0.8 mil (20 μ) on a 24-gauge cold rolled steel circular sheet having a diameter of about 3.25 inches (82.6 mm) Apply directly to the film thickness, cure for about 50 seconds at the highest metal temperature of about 240 ° C., and air of about 40 1bs / in2 (2.7 × 10 6 dynes / cm 2) in a cylinder with a diameter of about 16 inches (406 mm) Square cups with rounded corners using presses of 10 tones (8 × 10 10 dynes) using pressure (rounded corners having a shaped radius of about 26 mm in depth and about 6.5 mm in angular corners, and about Stretched to 36 mm in width (approximately 120% elongation and 50% compressive force applied to the rounded corners of the square cup bottom) and then the coating composition is essentially tacky when immersed in boiling demineralized water for 5 minutes. A coating composition which is conditional to produce a film that is free and essentially free of bonding. 제1항에 있어서, 상기 필름 형성제가 폴리이소시아네이트로 쇄 연장되어 폴리에스테르-우레탄 폴리올을 생성하는 상기 폴리에스테르 폴리올인 코팅 조성물.The coating composition of claim 1, wherein said film former is said polyester polyol which chain extends to a polyisocyanate to produce a polyester-urethane polyol. 필름형성제로, 폴리에스테르 폴리올을 제조하는데 사용된 총 반응물 50Og당 각분자에 대해 2개보다 많은 하이드록실 그룹을 갖는 물질을 O.25g-몰을 초과하지 않는 정확한 양으로 포함하는 폴리올 성분과 폴리카복실산 성분 또는 그의 작용성 등가물의 반응으로부터 생성되고, 조절된 양으로 분지되고 중량 평균 분자량 약 4,OOO내지 약4O,OOO, 하이드록실과 약 1O내지 약 100을 갖는 폴리에스테르 폴리올과 이소시아네이드 대 하이드록실의 당량비가 약 O.3/1 내지 약 1.5/1의 범위이도록 하는 양의 폴리이소시아네이트 강화제를 포함하고; 약3.25인치(82.6mm)의 직경을 갖는 24게이지의 냉각 압연 강 원형 소재판에 코팅 조성물을 약 O.8mil(2Oμ)의 건조 필름 두께로 직접 도포하고, 약240℃의 최고 금속온도에서 약5O초동안 경화시키고, 약 16인치(406mm)의 직경을 갖는 실린더에 약4O 1bs/in2(2.7×106dynes/㎠)의 공기 압력을 사용하는 9O톤(8×1O10dynes)의 프레스를 사용하여 둥근 모서리를 갖는 정사각형 컵(성형된 정사각형 컵은 깊이 약 26mm, 각 모서리가 약 6.5mm의 의반경을 갖는 둥근 모서리, 및 약36mm의 변 너비를 갖는다)으로 연신(이때, 정사각형 컵 바닥의 둥근 모서리에 약 120%의 신장을 및 약 50%의 압축력을 가했다)시킨 후, 비등 탈염수에 5분간 침지시켰을때 본질적으로 점착성이 없고, 본질적으로 결합이 없는 필름을 생성시킴을 조건으로 하는 코팅 조성물.As film formers, polycarboxylic acid and polycarboxylic acids comprising in precise amounts no more than 0.2 g-mol of a material having more than two hydroxyl groups for each molecule per 50 g of the total reactants used to make the polyester polyols Polyester polyols and isocyanates to hydroxides produced from the reaction of a component or functional equivalent thereof and branched in controlled amounts and having a weight average molecular weight of about 4, OOO to about 40O, OOO, hydroxyl and about 10 to about 100 A polyisocyanate enhancer in an amount such that the equivalent ratio of loxyl is in the range of about 0.3 / 1 to about 1.5 / 1; The coating composition was applied directly to a dry film thickness of about 0.8 mil (20 microns) on a 24-gauge cold rolled steel circular sheet having a diameter of about 3.25 inches (82.6 mm) and about 50O at a maximum metal temperature of about 240 ° C. A 9 0 ton (8 × 10 10 dynes) press was used to cure for 2 seconds and use an air pressure of about 4O lbs / in 2 (2.7 × 10 6 dynes / cm 2) in a cylinder with a diameter of about 16 inches (406 mm). Stretched into square cups with rounded corners (molded square cups have a rounded corner with a depth of about 26 mm, each corner having a radius of about 6.5 mm, and a side width of about 36 mm), wherein Coating composition subject to rounded corners with about 120% elongation and about 50% compressive force), followed by 5 minutes immersion in boiling demineralized water to produce an essentially tacky and essentially bond-free film. . 제3항에 있어서, 하이드록실 그룹을 2개보다 많이 함유한 물질이 트리올인 코팅 조성물.The coating composition of claim 3, wherein the material containing more than two hydroxyl groups is a triol. 제4항에 있어서, 상기 필름 형성제가 폴리이소시아네이트로 쇄연장되어 폴리에스테르-우레탄 폴리올을 생성하는 상기 폴리에스테르 폴리올인 코팅 조성물.5. The coating composition of claim 4, wherein said film former is said polyester polyol which is extended with polyisocyanate to produce a polyester-urethane polyol. 제4항에 있어서, 상기 폴리에스테르 폴리올의 중량 평균 분자량이 약 5,O0O 내지 약 4O,OOO범위인 코팅조성물.The coating composition of claim 4 wherein the weight average molecular weight of the polyester polyol is in a range from about 5, OO to about 40O, OOO. 제6항에 있어서, 상기 폴리에스테르 폴리올의 중량 평균 분자량이 약 7,500 내지 약 4O,OOO범위인 코팅 조성물.The coating composition of claim 6, wherein the weight average molecular weight of the polyester polyol is in the range of about 7,500 to about 40, OO. 제7항에 있어서, 삭기 폴리에스테르 폴리올의 중량 평균 분자량이 약 1O,OOO내지 약 4O,OOO범위인 코팅 조성물.8. The coating composition of claim 7, wherein the weight average molecular weight of the cut polyester polyol is in the range of about 10, OOO to about 40, OOO. 제8항에 있어서, 상기 폴리에스테르 폴리올의 중량 평균 분자량이 약 15,O0O내지 약 3O,OOO범위인 코팅 조성물.The coating composition of claim 8, wherein the weight average molecular weight of the polyester polyol is in a range from about 15, OO to about 3O, OOO. 제9항에 있어서, 상기 폴리에스테르폴리올의 중량 평균분자량이 약 16,500내지 약25,OOO범위인 코팅 조성물.10. The coating composition of claim 9 wherein the weight average molecular weight of the polyester polyol is in a range from about 16,500 to about 25, OO. 제4항에 있어서, 상기 하이드록실가가 약 1O내지 약 7O범위인 코팅 조성물.The coating composition of claim 4, wherein the hydroxyl value ranges from about 10 to about 70. 제11항에 있어서, 상기 하이드록실가가 약 lO내지 약 5O범위인 코팅 조성물.The coating composition of claim 11, wherein the hydroxyl value ranges from about lO to about 50O. 제l2항에 있어서, 상기 하디드록실가가 약 1O내지 약 3O범위인 코팅 조성물.The coating composition of claim 12, wherein said hard hydroxyl value is in the range of about 10 to about 30. 제4항에 있어서, 상기 트리올의 양이 O.2Og-물을 초과하지 않는 정확한 양인 코팅 조성물.The coating composition of claim 4, wherein the amount of triol is an exact amount that does not exceed 0.2 Og-water. 제l4항에 있어서, 상기 트리올의 양이 O.l5g-물을 초과하지 않는 정확한 양인 코팅 조성물.The coating composition of claim 1, wherein the amount of triol is an exact amount that does not exceed 0.1 g-water. 제14항에 있어서, 상기 트리올의 양이 O.O3g-몰 내지 약 O.2Og-몰 범위인 코팅 조성물.15. The coating composition of claim 14, wherein the amount of triol is in the range of from about 0.1 g to about 0.2 g of moles. 제4항에 있어서, 상기 코팅 조성물이 유기 용매를 기본으로 하는 코팅 조성물.The coating composition of claim 4, wherein the coating composition is based on an organic solvent. 제4항에 있어서, 상기 폴리에스테르폴리올의 성분들이 5%이상의 방향족 성분들을 함유하는 코팅 조성물.The coating composition of claim 4, wherein the components of the polyesterpolyol contain at least 5% aromatic components. 제l8항에 있어서, 상기 폴리에스테르 폴리올의 구성 성분 비율을 폴리에스테르 폴리올중의 방향족 성분의 중량비가 약 5%내지 약 40%범위이도록 조절하는 코팅 조성물.The coating composition of claim 18, wherein the proportion of constituents of the polyester polyol is adjusted such that the weight ratio of aromatic components in the polyester polyol is in the range of about 5% to about 40%. 제19항에 있어서, 상기 퍼센트가 약 20%내지 약 35%범위인 코팅 조성물.The coating composition of claim 19, wherein the percent ranges from about 20% to about 35%. 제4항에 있어서, 상기 폴리에스테르 폴리올의 구성 성분들이 5%이상의 치환족 성분들을 함유하는 코팅 조성물.The coating composition of claim 4 wherein the constituents of the polyester polyol contain at least 5% substituted group components. 제21항에 있어서, 상기 폴리에스테르 폴리올의 구성 성분 비율을 폴리에스테르 폴리올중의 지환족 성분의 중량%가 약 5%내지 약 40%범위이도록 조절하는 코팅 조성물.The coating composition of claim 21, wherein the proportion of constituents of the polyester polyol is adjusted such that the weight percent of the cycloaliphatic component in the polyester polyol is in the range of about 5% to about 40%. 제22항에 있어서, 상기 폴리에스테르 폴리올의 구성 성분 비율을 폴리에스테르 폴리올중의 지환족 성분의 중량%가 약 20%내지 약 35%범위이도록 조절하는 코팅 조성물.The coating composition of claim 22, wherein the proportion of constituents of the polyester polyol is adjusted such that the weight percent of the cycloaliphatic component in the polyester polyol is in the range of about 20% to about 35%. 제5항에 있어서, 상기 폴리에스테르-우레탄 폴리올의 중량 평균 분자량이 약5,O0O내지 약 4O,O0O범위인 코팅 조성물.The coating composition of claim 5 wherein the weight-average molecular weight of the polyester-urethane polyol is in the range of about 5, OO to about 40O, OO. 제24항에 있어서, 상기 폴리에스테르-우레탄폴리올의 중량 평균분자량이 약7,500내지 약4O,O0O범위인 코팅 조성물.25. The coating composition of claim 24, wherein the weight average molecular weight of the polyester-urethane polyol is in the range of about 7,500 to about 4O, OO. 제25항에 있어서, 상기 폴리에스테르-우레탄 폴리올의 중량 평균 분자량이 약 1O,OOO내지 약 4O,O0O범위인 코팅 조성물.The coating composition of claim 25, wherein the weight-average molecular weight of the polyester-urethane polyol is in the range of about 10, OOO to about 4O, OO. 제26항에 있어서, 상기 폴리에스테르-우레탄 폴리올의 중량 평균 분자량이 약 15,OOO내지 약 3O,OOO범위인 코팅 조성물.The coating composition of claim 26, wherein the weight-average molecular weight of the polyester-urethane polyol is in a range from about 15, OO to about 30, OO. 제27항에 있어서, 상기 폴리에스테르-우레탄 폴리올의 중량 평균 분자량이 약 16,500내지 약 25,OOO범위인 코팅 조성물.The coating composition of claim 27 wherein the polyester-urethane polyol has a weight average molecular weight in the range of about 16,500 to about 25, OOO. 제5항에 있어서, 상기 하이드록실가가 약 1O내지 약 7O범위인 코팅 조성물.The coating composition of claim 5, wherein the hydroxyl value ranges from about 10 to about 70. 제29항에 있어서, 상기 하이드록실가가 약 1O내지 약 5O범위인 코팅 조성물.30. The coating composition of claim 29, wherein the hydroxyl value ranges from about 10O to about 50O. 제3O항에 있어서, 상기 하이드록실가가 약 1O내지 약 3O범위인 코팅 조성물.The coating composition of claim 30, wherein the hydroxyl value ranges from about 10 to about 30. 제5항에 있어서, 상기 트리올의 양이 O.2Og-몰을 초과하지 않는 정확한 양인 코팅 조성물.The coating composition of claim 5, wherein the amount of triol is an exact amount not exceeding 0.2 g-mole. 제32항에 있어서, 상기 트리올의 양이 O.15g-몰을 초과하지 않는 정확한 양인 코팅 조성물.33. The coating composition of claim 32, wherein the amount of triol is an exact amount that does not exceed 0.1 g-mol. 제32항에 있어서, 상기 트리올의 양이 약 O.O3g-몰 내지 약 O.20g-몰 범위인 코팅 조성물.33. The coating composition of claim 32, wherein the amount of triol is in the range of about 0.13 g-mol to about 0.20 g-mol. 제5항에 있어서, 상기 코팅 조성물이 유기 용매를 기본으로 하는 코팅 조성물.The coating composition of claim 5, wherein the coating composition is based on an organic solvent. 제5항에 있어서, 상기 폴리에스테르-우레탄폴리올의 구성 성분들이 5%이상의 방향족 성분들을 포함하는 코팅 조성물.6. The coating composition of claim 5, wherein the components of the polyester-urethanepolyol comprise at least 5% aromatic components. 제36항에 있어서, 상기 폴리에스테르-우레탄폴리올의 구성 성분 비율을 폴리에스테르-우레탄 폴리올중의 방향족 성분의 중량비가 약 5%내지 약 40%범위이도록 조절하는 코팅 조성물.37. The coating composition of claim 36, wherein the proportion of constituents of the polyester-urethane polyol is adjusted such that the weight ratio of aromatic components in the polyester-urethane polyol is in the range of about 5% to about 40%. 제37항에 있어서, 상기 퍼센트가 약 2O%내지 약 35%범위인 코팅 조성물.The coating composition of claim 37, wherein the percent ranges from about 20% to about 35%. 제5항에 있어서, 상기 폴리에스테르-우레탄폴리올의 구성 성분들이 5%이상의 치환족 성분들을 함유하는 코팅 조성물.The coating composition of claim 5 wherein the constituents of the polyester-urethanepolyol contain at least 5% substituted group components. 제39항에 있어서, 상기 폴리에스테르-우레탄폴리올의 구성 성분 비율을 폴리에스테르-우레탄 폴리올중의 치환족 성분의 중량%가 약 5%내지 약 40%범위이도록 조절하는 코팅 조성물.40. The coating composition of claim 39, wherein the proportion of constituents of the polyester-urethane polyol is adjusted such that the weight percent of substituted family components in the polyester-urethane polyol is in the range of about 5% to about 40%. 제5항에 있어서, 상기 쇄 연장 폴리이소시아네이트의 양이 폴리에스테르-우레탄 폴리올의 모든 구성 성분의 총 중량을 기준으로 15중량%를 초과하지 않는 정확한 양인 코팅 조성물.6. The coating composition of claim 5, wherein the amount of chain extending polyisocyanate is an exact amount of no greater than 15% by weight based on the total weight of all constituents of the polyester-urethane polyol. 제41항에 있어서, 상기 쇄 연장 폴리이소시아네이트의 양이 10%를 초과하지 않는 코팅 조성물.The coating composition of claim 41, wherein the amount of chain extending polyisocyanate does not exceed 10%. 제4O항에 있어서, 상기 쇄 연장 폴리이소시아네이트의 양이 약 1중량% 내지 약 15중량% 범위인 코팅 조성물The coating composition of claim 40 wherein the amount of chain extending polyisocyanate is in the range of about 1% to about 15% by weight. 제4항에 있어서, 상기 트리올의 양이 약O.O3g-몰 내지 약O.O7g-몰의 범위내에 있을때 상기 이소시아네이트 대 하이드록실의 당량비가 약 O.7/1 내지 약 1.5/1범위내에 있으며; 상기 트리올의 양이 약 O.1Og-몰 내지 약 O.25g-몰의 범위내에 있을에 상기 이소시아네이트 대 하이드록실의 당량비가 약O.3/1내지 약 O.7/1의 범위내에 있음을 또한 조건으로 하는 코팅 조성물.The equivalent ratio of isocyanate to hydroxyl is in the range of about 0.7 / 1 to about 1.5 / 1 when the amount of triol is in the range of about 0.3 g / mol to about 0.1 g / mol. And; The equivalent ratio of isocyanate to hydroxyl is in the range of about 0.3 / 1 to about 0.77 when the amount of triol is in the range of about 0.1 g-mole to about 0.2 g-mole. Moreover, the coating composition made into conditions. 제4항에 있어서, 상기 드리을의 양이 O.25g-몰일때 상기 이소시아네이트 대 하이드록실의 당량비가 약 O.3/1 내지 약 O.4/1의 범위내에 있는 코팅 조성물.5. The coating composition of claim 4, wherein the equivalent ratio of isocyanate to hydroxyl is in the range of about 0.3 to 1. 4/1 when the amount of dribbling is 0.2 g-mol. 제5항에 있어서, 상기 트리올의 양이 약O.O3g-몰 내지 약O.O7g-몰의 범위내에 있을때 상기 이소시아네이트 대 하이드록실의 당량비가 약O.7/1 내지 약 1.5/1범위내에 있으며; 상기 트리올의 양이 약 O.1Og-몰 내지 약O.25g-몰의 범위내에 있을때 상기 이소시아네이트 대 하이드록실의 당량비가 약O.3/1 내지 약 O.7/1의 범위내에 있음을 또한 조건으로 하는 코팅 조성물.6. The method of claim 5 wherein the equivalent ratio of isocyanate to hydroxyl is in the range of about 0.7 / 1 to about 1.5 / 1 when the amount of triol is in the range of about 0.3 g-mol to about 0.1 g-mol. And; It is further noted that when the amount of triol is in the range of about 0.1 g-mole to about 0.25 g-mole, the equivalent ratio of isocyanate to hydroxyl is in the range of about 0.3 / 1 to about 0.77 / 1. Coating composition on condition. 제5항에 있어서, 상기 트리올의 양이 O.25g-몰일때 상기 이소시아네이트 대 하이드록실의 당량비가 약 O.3/1내지 약 O.4/1의 범위내에 있는 코팅 조성물.6. The coating composition of claim 5 wherein the equivalent ratio of isocyanate to hydroxyl is in the range of about < RTI ID = 0.0 > O.3 / 1 < / RTI > to about O.4 / 1 when the amount of triol is 0.2 g-mol. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019900700103A 1988-05-20 1989-05-12 Thermosetting Stretchable Coating Composition KR900701882A (en)

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DE4114800A1 (en) * 1991-05-07 1992-11-12 Bayer Ag NEW POLYESTER POLYOLS AND THE USE THEREOF AS A ADHESIVE FOR POLYMER SYSTEMS AND AS A POLYMER SOFTENER
US5436056A (en) * 1991-12-20 1995-07-25 Showa Highpolymer Co., Ltd. Method of producing a high molecular weight aliphatic polyester and film thereof
DE19612898C1 (en) * 1996-03-30 1997-04-03 Herberts Gmbh Coating coils of sheet material
DE19638488A1 (en) * 1996-09-20 1998-03-26 Basf Ag Biodegradable polyester
DE19648517A1 (en) * 1996-11-23 1998-06-04 Herberts & Co Gmbh Process for multi-layer painting
US6207224B1 (en) 1999-10-06 2001-03-27 E. I. Du Pont De Nemours And Company Process for coating thermoplastic substrates with a coating composition containing a non-aggressive solvent
WO2010125105A1 (en) * 2009-04-29 2010-11-04 Dsm Ip Assets B.V. Powder coating composition comprising a polyester and a crosslinker with oxirane groups providing improved corrosion resistance to a substrate coated therewith

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NL151400B (en) * 1968-03-27 1976-11-15 Ashland Oil Inc PROCESS FOR THE PREPARATION OF MODIFIED POLYESTERS AND PROCESS FOR THE PREPARATION OF COATING PREPARATIONS USING THESE POLYESTERS.
US3804810A (en) * 1970-12-30 1974-04-16 Du Pont Cross-linked polyurethanes based on aromatic/aliphatic copolyesters
DE2216732A1 (en) * 1972-04-07 1973-10-18 Basf Ag WELDABLE POLYESTER PAINT RESINS
AT325738B (en) * 1972-12-19 1975-11-10 Ciba Geigy Ag POWDERED COATING AGENT
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