KR900701656A - Synthetic porous crystalline material and its synthesis method - Google Patents

Synthetic porous crystalline material and its synthesis method

Info

Publication number
KR900701656A
KR900701656A KR1019900701645A KR900701645A KR900701656A KR 900701656 A KR900701656 A KR 900701656A KR 1019900701645 A KR1019900701645 A KR 1019900701645A KR 900701645 A KR900701645 A KR 900701645A KR 900701656 A KR900701656 A KR 900701656A
Authority
KR
South Korea
Prior art keywords
crystalline material
porous crystalline
synthetic porous
synthetic
reaction mixture
Prior art date
Application number
KR1019900701645A
Other languages
Korean (ko)
Other versions
KR970007310B1 (en
Inventor
추 포첸
쾨니히 루빈 매
Original Assignee
에드워드 에이취, 바란스
모빌오일 코퍼레이션
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 에드워드 에이취, 바란스, 모빌오일 코퍼레이션 filed Critical 에드워드 에이취, 바란스
Priority claimed from PCT/US1988/004251 external-priority patent/WO1990006283A1/en
Publication of KR900701656A publication Critical patent/KR900701656A/en
Application granted granted Critical
Publication of KR970007310B1 publication Critical patent/KR970007310B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition

Abstract

내용 없음No content

Description

합성다공질 결정성 물질 및 이의 합성방법Synthetic porous crystalline material and its synthesis method

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

제1도는 소성 생성물의 X-선 회절 패턴을 나타낸다.1 shows the X-ray diffraction pattern of the fired product.

Claims (10)

명세서중의 표 I에 있는 값을 지닌 X-선 회절패턴에 의해 특정지워지며, 수증기에 대한 평형 흡착용량이 10 무게 %이상, 사이클로헥산 증기에 대한 평형 흡착용량이 4.5무게 %이상 및 n-증기에 대한 평형 흡착용량이 10무게 %이상인 합성 다공질 결정성 물질.Specified by the X-ray diffraction pattern with the values in Table I of the specification, the equilibrium adsorption capacity for water vapor is at least 10% by weight, the equilibrium adsorption capacity for cyclohexane vapor is at least 4.5% by weight and n-vapor Synthetic porous crystalline material having an equilibrium adsorption capacity of at least 10% by weight. 제1항에서, 명세서중의 표 Ⅱ에 있는 값을 지닌 X-선 회절패턴에 의해 특정지워지는 합성 다공질 결정성물질.The synthetic porous crystalline material of claim 1, characterized by an X-ray diffraction pattern having the values in Table II of the specification. 제1항에서, 명세서중의 표 Ⅲ에 있는 값을 지닌 X-선 회절패턴에 의해 특정지워지는 합성 다공질 결정성 물질.The synthetic porous crystalline material of claim 1, characterized by an X-ray diffraction pattern having values in Table III of the specification. 제1항에서, 명세저중의 표 Ⅳ에 있는 값을 지닌 X-선 회절패턴에 의해 특정지워지는 합성 다공질 결정성 물질.The synthetic porous crystalline material of claim 1, characterized by an X-ray diffraction pattern having the values in Table IV in the specification. 제1-4항중 어느 하나에서 다음과 같은 몰 관계를 지닌 합성당공질 결정성 물질;Synthetic glycocrystalline crystalline material of any one of claims 1-4 having the following molar relationship; X203: (n)Y02 X 2 0 3 : (n) Y0 2 여기서 n은 최소한 10, X는 3가원소 및 Y는 4가 원소임.Where n is at least 10, X is a trivalent element, and Y is a tetravalent element. 제5항에서, X가 알루미늄이고 Y가 실리콘인 합성 다공질 결정성 물질.6. The synthetic porous crystalline material of claim 5, wherein X is aluminum and Y is silicon. 제6항에서, n이 20-40의 수인 합성 다공질 결정성 물질.The synthetic porous crystalline material of claim 6, wherein n is a number of 20-40. 충분한 양의 알칼리 또는 알칼리 토금속 양이온, 최소한 30무게%의 고체 YO2를 함유하고 있는 4가의 Y산화물원. 3가의 X산화물원, 물 및 헥사메틸렌이민을 함유하고 있는 것으로 결정화시 결정성 물질을 형성할 수 있는 반응 혼합물을 제조하고: 위의 반응 혼합물을 결정이 형성될때까지 충분한 결정화 조건을 유지시키는 단계로 이루어진 합성 결정성 물질의 제조방법.A tetravalent Y oxide source containing a sufficient amount of alkali or alkaline earth metal cations and at least 30 weight percent solids YO 2 . A reaction mixture is prepared which contains a trivalent X oxide source, water and hexamethyleneimine to form crystalline materials upon crystallization: maintaining the above reaction mixture in sufficient crystallization conditions until crystals are formed. Method of producing a synthetic crystalline material. 제8항에서, 반응 혼합물의 조성이 몰비에 관해 다음과 같은 제조방법 :The process according to claim 8, wherein the composition of the reaction mixture is as follows with respect to the molar ratio: YO2/X2O3= 10to 80YO 2 / X 2 O 3 = 10to 80 H2O/YO2= 5to 100H 2 O / YO 2 = 5to 100 OH-/YO2= 0.01to 1.0OH - / YO 2 = 0.01to 1.0 M/YO2= 0.01to 2.0M / YO 2 = 0.01 to 2.0 R/YO2= 0.05to 1.0R / YO 2 = 0.05to 1.0 위에서 R은 헥사메틸렌이민, M은 알칼리 또는 알칼리 토금속임.Wherein R is hexamethyleneimine and M is an alkali or alkaline earth metal. 제8항에서, 반응 혼합물의 조성이 몰비에 관해 다음과 같은 제조방법;The process according to claim 8, wherein the composition of the reaction mixture is as follows in terms of molar ratio; YO2/X2O3= 10to 60YO 2 / X 2 O 3 = 10to 60 H2O/YO2= 10to 50H 2 O / YO 2 = 10to 50 OH-/YO2= 0.1to 0.5OH - / YO 2 = 0.1to 0.5 M/YO2= 0.1to 1.0M / YO 2 = 0.1to 1.0 R/YO2= 0.1to 0.5R / YO 2 = 0.1to 0.5 ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019900701645A 1988-10-06 1988-11-28 Synthetic porous crystalline material, its synthesis KR970007310B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US254,524 1988-10-06
PCT/US1988/004251 WO1990006283A1 (en) 1988-11-28 1988-11-28 Synthetic porous crystalline material, its synthesis and use

Publications (2)

Publication Number Publication Date
KR900701656A true KR900701656A (en) 1990-12-04
KR970007310B1 KR970007310B1 (en) 1997-05-07

Family

ID=22209020

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900701645A KR970007310B1 (en) 1988-10-06 1988-11-28 Synthetic porous crystalline material, its synthesis

Country Status (3)

Country Link
KR (1) KR970007310B1 (en)
BR (1) BR8807882A (en)
DK (1) DK175290B1 (en)

Also Published As

Publication number Publication date
KR970007310B1 (en) 1997-05-07
DK179890D0 (en) 1990-07-27
DK175290B1 (en) 2004-08-09
BR8807882A (en) 1990-11-27
DK179890A (en) 1990-09-26

Similar Documents

Publication Publication Date Title
Hardie The gypsum—anhydrite equilibrium at one atmosphere pressure
ATE91673T1 (en) SYNTHETIC CRYSTALLINE POROUS MATERIAL CONTAINING OXIDES OF SILICON AND BORON.
ATE80129T1 (en) PROCESSES FOR THE PRODUCTION OF SYNTHETIC CALCIUM SILICATES AND THEIR USES.
ES2135329A1 (en) Zeolite itq-3
EP0142350A3 (en) Crystalline zeolite composition ecr-2 and process for its preparation
EP0269503A3 (en) Ferrierites, process for their preparation and their use
DE3767318D1 (en) BORSILICATE MOLECULAR SCREEN.
GB1466986A (en) Catalysts comprising a metal halide salt on an interstratified synthetic alumino-silicate carrier
EP0173901A3 (en) Process to make small crystallites of zsm-5
KR900701656A (en) Synthetic porous crystalline material and its synthesis method
GB1432707A (en) Anhydrous amorphous siliceous material derived from organic plant material its process of preparation and compositions containing same
JPS56160316A (en) Synthetic crystalline aluminosilicate composition and its manufacture
KR890001873A (en) Synthesis of Crystalline Silicate ZSM-II
Sharp et al. The effect of procedural variables on TG, DTG and DTA curves of magnesite and dolomite
KR840008769A (en) Catalyst Compositions Useful for Steam Reforming and Methanation
KR900016048A (en) Method for preparing magnesite, its application to the preparation of magnesium fluoride and magnesium fluoride obtained by this method
KR900700383A (en) Synthetic crystalline aluminophosphate composition and its synthesis method
RU94033348A (en) Catalyst component for hydrocarbons catalytic transformations in petrochemical processes
EP0173895A3 (en) A process for making crystalline siliceous materials
GB1341984A (en) Production of synthetic zeolites of faujasite structure
Iwamoto et al. Chemical reactions among clay minerals, calcium carbonate, and ammonium chloride
Saindrenan et al. Structural Study of Nickel--Calcium Alloys Containing Between 0 and 15 wt.% Calcium
GB1534727A (en) Building materials
GB1132883A (en) Process for the production of zeolites in nodular form
JPS5730546A (en) Adsorbing agent for organic material in water

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E902 Notification of reason for refusal
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20110830

Year of fee payment: 15

EXPY Expiration of term