KR900018339A - Fuel oil composition - Google Patents

Fuel oil composition Download PDF

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KR900018339A
KR900018339A KR1019890007011A KR890007011A KR900018339A KR 900018339 A KR900018339 A KR 900018339A KR 1019890007011 A KR1019890007011 A KR 1019890007011A KR 890007011 A KR890007011 A KR 890007011A KR 900018339 A KR900018339 A KR 900018339A
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polymer
ester
group
derived
unsaturated
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KR960013611B1 (en
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드라이덴 택 로버트
모어 아이에인
류타스 케네쓰
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피터 챨스 보우덴
엑손 케미칼 패턴츠 인코포레이티드
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
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    • C10L1/236—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/146—Macromolecular compounds according to different macromolecular groups, mixtures thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/236—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof
    • C10L1/2364—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof homo- or copolymers derived from unsaturated compounds containing amide and/or imide groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/196—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof
    • C10L1/1963—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof mono-carboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/196—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof
    • C10L1/1966—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof poly-carboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/197—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid
    • C10L1/1973—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid mono-carboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C10L1/1985—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Lubricants (AREA)

Abstract

내용 없음No content

Description

연료유 조성물Fuel oil composition

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (31)

액체 탄화수소연료 대부분(중량기준), 및 1급, 2급 또는 3급 아민의 염 또는 4급 암모늄염인 아미노그룹 하나이상을 함유하는 중합체 소량(중량기준)을 포함하는 연료조성물.A fuel composition comprising a majority of liquid hydrocarbon fuels (by weight) and a small amount (by weight) of polymers containing at least one amino group which is a salt of a primary, secondary or tertiary amine or quaternary ammonium salt. 제1항에 있어서, 상기 연료가 증류연료유인 조성물.The composition of claim 1, wherein the fuel is distillate fuel oil. 제1항 도는 2항에 있어서, 상기 중합체가 유리산 그룹을 또한 함유하는 하나 이상의 불포화 에스테르 단량체들의 중합체 또는 적어도 하나가 유리산 그룹을 갖는 불포화 에스테르 단량체들의 공중합체로부터 유도된 조성물.The composition of claim 1 or 2, wherein the polymer is derived from a polymer of one or more unsaturated ester monomers, which also contains free acid groups, or at least one copolymer of unsaturated ester monomers having free acid groups. 제1항 또는 2항에 있어서, 상기 중합체가 불포화 에스테르 및/또는 올레핀과 불포화 카복실산 무수물의 공중 합체로부터 유도된 조성물.The composition of claim 1 or 2, wherein the polymer is derived from a copolymer of unsaturated esters and / or olefins and unsaturated carboxylic anhydrides. 제1항 또는 2항에 있어서, 상기 중합체가, 카복실산 그룹을 생성하도록 부분 가부순해되는 에스테르 그룹을 함유하는 중합체로부터 유도된 조성물.The composition of claim 1 or 2, wherein the polymer is derived from a polymer containing an ester group that is partially dispersible to produce carboxylic acid groups. 제1항 또는 2항에 있어서, 상기중합체가, 부분 가수분해된 후 카복실산 무수물과 반응되는 불포화 에스테르의 중합체로 부터 유도된 조성물.The composition of claim 1 or 2, wherein the polymer is derived from a polymer of unsaturated esters which is partially hydrolyzed and then reacted with carboxylic anhydride. 제1항 내지 6항중 어느 한 항에 있어서, 상기 중합체가 수소 및 탄소함유그룹(이때, 상기 그룹의 총탄소수는 적어도 10이다)적어도 하나를 함유하는 조성물.The composition of any one of claims 1 to 6, wherein the polymer contains at least one of hydrogen and a carbon containing group, wherein the total carbon number of the group is at least 10. 제7항에 있어서, 상기 그룹이 중합체의 주쇄에 직접 또는 카복실레이트 그룹을 통해 부착된 조성물.8. The composition of claim 7, wherein said group is attached directly to the main chain of the polymer or through a carboxylate group. 제7항에 있어서, 상기 그룹이 아민염 또는 4급 암모늄염의 질소원자에 부착된 조성물.8. A composition according to claim 7, wherein said group is attached to the nitrogen atom of the amine salt or quaternary ammonium salt. 제1항 내지 9항중 어느 한항에 있어서, 폴리옥시알킬렌 에스테르, 에테르, 에스테르/에테르 또는 아미드/에스테르, 에틸렌 불포화 에스테르 공중합체 흐름 개선제, 극성 질소함유 화합물또는 그들의 혼합물을 또한 포함하는 조성물.10. The composition according to any one of claims 1 to 9, further comprising a polyoxyalkylene ester, ether, ester / ether or amide / ester, ethylenically unsaturated ester copolymer flow improving agent, polar nitrogen-containing compound or mixtures thereof. 제10항에 있어서, 상기 폴리옥시 알킬렌 에스테르, 에테르, 에스테르/에테르또는 아미드/에스테르가 분자량 100 내지 5000인 폴리옥시 알킬렌 글리콜의 C10내지 C30선형 포화 알킬 그룹 적어도 두 개를 함유하는 조성물.The composition of claim 10 wherein said polyoxy alkylene ester, ether, ester / ether or amide / ester contains at least two C 10 to C 30 linear saturated alkyl groups of polyoxy alkylene glycols having a molecular weight of 100 to 5000. . 제1항 내지 11항중 어느 한항에 있어서, 상기 아민염 함유 중합체의 양이 탄화수소 연료의 중량을 기준으로 0.0001 내지 5.0 중량%(활성물질)인 조성물.The composition according to any one of claims 1 to 11, wherein the amount of the amine salt-containing polymer is 0.0001 to 5.0% by weight (active substance) based on the weight of the hydrocarbon fuel. 1급, 2급 또는 3급 아민의 염 또는 4급 암모늄염인 아미노 그룹 하나이상을 함유하는 중합체의 액체 탄화수소연료중에서의 흐름 개선제로서의 용도.Use of a polymer containing at least one amino group which is a salt of a primary, secondary or tertiary amine or a quaternary ammonium salt as a flow improving agent in a liquid hydrocarbon fuel. 제13항에 있어서, 상기 연료가 증류연료인 용도.Use according to claim 13, wherein the fuel is distillate fuel. 제13항 또는 14항에 있어서, 상기 중합체가 유리산 그룹을 또한 함유하는 하나 이상의 불포화 에스테르 단량체들의 중합체 또는 적어도 하나가 유리산그룹을 갖는 에스테르 단량체들의 공중합체로부터 유도된 용도.Use according to claim 13 or 14, wherein the polymer is derived from a polymer of one or more unsaturated ester monomers which also contains free acid groups or copolymers of ester monomers wherein at least one has free acid groups. 제13항 또는 14항에 있어서, 상기 중합체가 불포화 에스테르 및/또는 올레핀과 불포화 카복실산 무수물의 공중합체로부터 유도된 용도.Use according to claim 13 or 14, wherein the polymer is derived from a copolymer of unsaturated esters and / or olefins and unsaturated carboxylic anhydrides. 제13항 또는 14항에 있어서, 상기 중합체가, 카복실산 그룹을 생성하도록 부분 가수 분해되는 에스테르그룹을 함유하는 중합체로부터 유도된 용도.Use according to claim 13 or 14, wherein the polymer is derived from a polymer containing an ester group which is partially hydrolyzed to produce carboxylic acid groups. 제13항 또는 14항에 있어서, 상기 중합체가 부분 가수분해된 후 카복실산 무수물과 반응되는 불포화 에스테르의 중합체로부터 유도된 용도.Use according to claim 13 or 14, wherein the polymer is derived from a polymer of an unsaturated ester which is reacted with carboxylic anhydride after it is partially hydrolyzed. 제13항 내지 18항중 어느 한 항에 있어서, 상기 중합체가 수소- 및 탄소-함유그룹(이때 상기 그룹의 총탄소수는 적어도 10이다)적어도 하나를 함유하는 용도.Use according to any of claims 13 to 18, wherein the polymer contains at least one of a hydrogen- and carbon-containing group, wherein the total carbon number of the group is at least 10. 제19항에 있어서, 상기 그룹이 중합체의 주쇄에 직접 또는 카복실 레이트 그룹을 통해 부착된 용도.20. The use according to claim 19, wherein said group is attached directly to the main chain of the polymer or through a carboxylate group. 제19항에 있어서, 상기 그룹이 아민염 또는 4급 암모늄염인 질소원자에 부착된 용도.20. The use of claim 19 wherein the group is an amine salt or a quaternary ammonium salt. 제13항 내지 21항중 어느 한 항에 있어서, 상기 액체 탄화수소연료가 폴리옥시알킬렌 에스테르, 에테르, 에스테르/에테르 또는 아미드/에스테르, 에틸렌-불포화 에스테르 공중합체 흐름 개선제, 극성 질소-함유 화합물 또는 그들의 혼합물을 또한 포함하는 용도.22. The process of claim 13, wherein the liquid hydrocarbon fuel is a polyoxyalkylene ester, ether, ester / ether or amide / ester, ethylene-unsaturated ester copolymer flow improver, polar nitrogen-containing compound or mixtures thereof. Also included. 제22항에 있어서, 상기 폴리옥시 알킬렌 에스테르, 에테르, 에스테르/에테르 또는 아미드/에스테르가 분자량 100내지 5000인 폴리옥시알킬렌 글리콜의 C10내지 C30선형 포화 알킬그룹 적어도 두개를 함유하는 용도.23. The use according to claim 22, wherein said polyoxy alkylene ester, ether, ester / ether or amide / ester contains at least two C 10 to C 30 linear saturated alkyl groups of polyoxyalkylene glycols having a molecular weight of 100 to 5000. 용매 및 1급, 2급 또는 3급 아민의 염 또는 4급 암모늄염인 아미노그룹 하나이상을 함유하는 중합체 20내지 90중량%(용매기준)을 포함하는 농축물.A concentrate comprising 20 to 90% by weight (solvent basis) of a solvent and at least one amino group which is a salt of a primary, secondary or tertiary amine or a quaternary ammonium salt. 제24항에 있어서, 상기 중합체가 유리산그룹을 또한 함유하는 하나이상의 불포화 에스테르 단량체들의 중합체, 또는 적어도 하나가 유리산그룹을 갖는 불포화 에스테르 단량체들의 중합체, 또는 적어도 하나가 유리산그룹을 갖는 불포화 에스테르 단량체들의 공중합체로부터 유도된 농축물.The polymer of claim 24 wherein the polymer is a polymer of one or more unsaturated ester monomers also containing free acid groups, or at least one polymer of unsaturated ester monomers having free acid groups, or at least one unsaturated ester having free acid groups. Concentrate derived from a copolymer of monomers. 제24항에 있어서, 상기 중합체가 불포화된 카복실산 그룹을 생성하도록 부분 가수 분해되는 에스테르 그룹을 함유하는 중합체로부터 유도된 농축물.The concentrate of claim 24 wherein said polymer is derived from a polymer containing ester groups that are partially hydrolyzed to produce unsaturated carboxylic acid groups. 제24항에 있어서, 상기 중합체가 카복실산 그룹을 생성하도록 부분 가수 분해되는 에스테르 그룹을 함유하는 중합체로부터 유도된 농축물.The concentrate of claim 24 wherein said polymer is derived from a polymer containing ester groups that are partially hydrolyzed to produce carboxylic acid groups. 제24항에 있어서, 상기 중합체가 부분 가수분해된 후 카복실산 무수물과 반응되는 불포화 에스테르의 중합체로부터 유도된 농축물.The concentrate of claim 24 wherein the polymer is derived from a polymer of unsaturated esters which is reacted with carboxylic anhydride after being partially hydrolyzed. 제24항 내지 28항중 어느 한 항에 있어서, 상기 중합체가 수소- 및 탄소-함유그룹(이때, 상기 그룹의 총탄소수는 적어도 10이다)적어도 하나를 함유하는 농축물.29. The concentrate of any one of claims 24 to 28, wherein the polymer contains at least one of hydrogen- and carbon-containing groups, wherein the total carbon number of the groups is at least 10. 제29항에 있어서, 상기 그룹이 중합체의 주쇄에 직접 또는 카복실 레이트 그룹을 통해 부착된 농축물.30. The concentrate of claim 29 wherein said group is attached directly to the backbone of said polymer or through a carboxylate group. 제29항에 있어서, 상기 그룹이 아민 염 또는 4급 암모늄염의 질소 원자에 부착된 농축물.30. The concentrate of claim 29 wherein said group is attached to a nitrogen atom of an amine salt or quaternary ammonium salt. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019890007011A 1988-05-25 1989-05-25 Fuel oil composition KR960013611B1 (en)

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