KR900005431B1 - Process for mixing sintered materials - Google Patents

Process for mixing sintered materials Download PDF

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KR900005431B1
KR900005431B1 KR1019870015118A KR870015118A KR900005431B1 KR 900005431 B1 KR900005431 B1 KR 900005431B1 KR 1019870015118 A KR1019870015118 A KR 1019870015118A KR 870015118 A KR870015118 A KR 870015118A KR 900005431 B1 KR900005431 B1 KR 900005431B1
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quicklime
mixing
sintered
water
sintering
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KR890010248A (en
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배석환
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포항종합제철 주식회사
정명식
재단법인 산업과학기술연구소
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/14Agglomerating; Briquetting; Binding; Granulating
    • C22B1/16Sintering; Agglomerating

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Abstract

Method for producing mixing material for sintering is characterised by preparing the mixing solution of 0.6-1.5 wt.% limestone and 6 wt.% water before mixing sintering materials, and sprinkling the mixed sintering materials with the above solution in granulating process.

Description

소결원료배합시 물과 생석회의 혼합첨가방법Mixing method of water and quicklime when mixing sintered raw materials

제1도는 생석회 첨가에 따른 통기도 및 소결시간과의 관계를 나타낸 그래프.1 is a graph showing the relationship between air permeability and sintering time according to the addition of quicklime.

제2도는 생석회 첨가에 따른 상온강도 및 저온환원분화성과의 관계를 나타낸 그래프.2 is a graph showing the relationship between room temperature intensity and low temperature reduction differentiation according to the addition of quicklime.

본 발명은 소결광을 제조하는데 있어서, 소결층내 통기성의 확보 및 소결과정중 인공생성물인 칼슘-페라이트(Calcium-ferrites)의 생성을 촉진시켜 소결광의 성상을 향상시키기위한 소결원료 배합시 물과 생석회의 혼합첨가방법에 관한 것이다.In the present invention, in the manufacture of sintered ore, the mixing of water and quicklime in the mixing of sintered raw materials to improve the properties of the sintered ore by improving the breathability in the sintered layer and promoting the production of calcium-ferrites, artificial products during the sintering process It relates to a method of addition.

일반적으로 소결광제조는 철광석과 부원료인 생석회, 사문암, 규사 및 석회석등에 적정코크스를 혼합한후 약 6%의 수분을 첨가하여, 원통형혼합기(drum-mixer)에서 균일하게 혼합하고, 의사입화(擬似粒化)를 시킨다. 이와같이 균일하게 혼합되고 조립화가 이루어진 배합원료를 소결기에 장입하고 점화로에서 2분정도 배합원료의 표면을 착화시킨후, 소결기 하부의 흡입닥트(suction duct)에서 공기를 흡입하면 배합원료중 코크스의 연소에 의해 소결반응이 진행되어 소결광이 제조된다.In general, sintered ore is manufactured by mixing appropriate coke with iron ore and raw materials such as quicklime, serpentine, silica sand and limestone, adding about 6% water, and mixing uniformly in a drum-mixer. Make a change. In this way, uniformly mixed and granulated compounding material is charged into the sintering system, and the surface of the compounding material is ignited in the ignition furnace for about 2 minutes. Then, the air is sucked from the suction duct below the sintering machine. Sintering reaction advances by combustion and a sintered ore is manufactured.

이때 소결층내 최고온도는 1300-1400℃까지 온도가 상승하며, 제조된 소결광은 고로 장입조건에 적합한 5-50mm로 파쇄하여 사용하며, 5mm이하는 반광으로 재사용된다. 한편, 조립화된 배합원료가 점화로에서 점화시 의사입자의 붕괴가 일어나서 소결층내 통기성이 불량하여 소결성에 악영향을 미치는 요인이된다. 따라서 종래에는 소결배합원료중에 소결층내 통기성확보를 위해 생석회를 첨가하는 방법과 또한 동시에 온수를 첨가하여 생석회의 활성도를 향상시키는 방법등이 있다. 그러나 배합원료와 생석회의 혼합시에 배합원료중 수분, 혼합시의 불균일성 및 살수시 생석회의 불균일응집현상등의 이유로 배합원료중 생석회의 편석분포의 문제점이 있었다.At this time, the maximum temperature in the sintered layer is elevated to 1300-1400 ℃, and the sintered ore is crushed to 5-50mm suitable for the blast furnace charging conditions, less than 5mm is reused as semi-glossy. On the other hand, the granulated compound raw material collapses when ignited in the ignition furnace, and the air permeability in the sintered layer is poor, which is a factor that adversely affects the sinterability. Therefore, conventionally, there is a method of adding quicklime to secure air permeability in the sintered layer in the sintered blended material, and at the same time, a method of improving the activity of quicklime by adding hot water. However, there was a problem of segregation distribution of quicklime in the blended raw materials due to the mixing of the blended raw material and quicklime due to the moisture in the blended material, the nonuniformity of the mixed raw material and the non-uniform agglomeration of the quicklime when spraying.

소결층내 통기성개선을 위해 첨가되는 생석회의 효과기구는 생석회중 Ca++는 의사입자의 부착분중에 균일하게 분포하여 1μmm이하 미세결정의 Ca(OH)2로 변하고, 원료입자와 잘 결합하여 단단하게 원자입자간의 간격을 메꾸어 입화를 촉진한다. 또한 미세한 Ca(OH)2는 소결과정중에 인공광물인 칼슘-페라이트의 생성을 촉진시켜 상온강도 및 저온환원분화성을 개선시킨다. 따라서, 본 발명은 생석회를 배합원료에 첨가하여 혼합한 후 물을 살수하는 종래의 방법과는 달리, 생석회와 물을 사전에 혼합하여 그 혼합액을 배합원료에 살수하므로서, 소결광의 통기도, 상온강도 및 저온환원분화성을 개선시키고자 하는 것이다.The effect mechanism of quicklime added to improve breathability in the sintered layer is that Ca ++ in quicklime is uniformly distributed in the adhesion of pseudoparticles and changes to Ca (OH) 2 of microcrystalline below 1μmm, and binds well with raw particles Filling the gap between atomic particles promotes granulation. In addition, fine Ca (OH) 2 promotes the production of artificial mineral calcium-ferrite during the sintering process, thereby improving room temperature strength and low temperature reduction differentiation. Therefore, in the present invention, unlike the conventional method of adding and mixing quicklime to the blended raw material and then sprinkling water, the mixture is preliminarily mixed with the quicklime and the mixed solution is sprayed on the blended raw material, so that the air permeability of the sintered ore, room temperature strength and It is to improve the low temperature reduction differentiation.

이하, 본 발명에 대하여 상세히 설명한다.EMBODIMENT OF THE INVENTION Hereinafter, this invention is demonstrated in detail.

본 발명은, 소결광을 제조하기위하여 소결원료배합시 물과 생석회를 혼합하는 방법에 있어서, 소결배합원료인 생석회를 물 6중량%에 대하여 0.6-1.5중량%로 사전에 혼합하여 그 혼합용액을 조립시 균일 살수함을 특징으로하는 소결원료배합시 물과 생석회의 혼합첨가 방법에 관한 것이다.The present invention, in the method of mixing water and quicklime in the sintering raw material blending in order to manufacture a sintered ore, the quick-mixing of the quicklime which is a sintered blending raw material to 0.6-1.5% by weight with respect to 6% by weight of water to assemble the mixed solution The present invention relates to a method of mixing water and quicklime when mixing raw materials for sintering raw materials, characterized by uniform watering.

이하, 실시예를 통하여 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail through examples.

[실시예 1]Example 1

하기 표 1과 같이 조성된 배합원료를 하기 표 2와 같이 종래방법 및 본 발명에 의해 소결광을 제조하고, 각각에 대하여 점화온도 : 1,200℃, 점화시간 : 2분, 부압 : -1000mmH2O, 염기도 : 1.65 및 코우크스 : 3.4%의 조건에서 소결와(pot)실험을 실시하여 그 결과치를 제1도 및 제2도에 나타내었다. 하기 표 3은 상기 배합원료의 화학성분을 나타낸다.To prepare a sintered ore by the conventional method and the present invention as shown in Table 2 to the blended raw material prepared as shown in Table 1, the ignition temperature: 1,200 ℃, ignition time: 2 minutes, negative pressure: -1000mmH 2 O, basicity : 1.65 and coke: A sintering pot experiment was carried out under conditions of 3.4% and the results are shown in FIGS. 1 and 2. Table 3 below shows the chemical components of the blended raw materials.

[표 1]TABLE 1

Figure kpo00001
Figure kpo00001

[표 2]TABLE 2

Figure kpo00002
Figure kpo00002

[표 3]TABLE 3

Figure kpo00003
Figure kpo00003

소결층내 통기도 및 소결시간과의 관계를 나타낸 제1도에서 알 수 있는 바와같이, 본 발명예(4, 5, 6)은 종래예(1)에 비하여 소결층내 통기성이 양호하고, 소결시간이 단축되었으며, 종래예(2)에 비해서는 비슷하거나 우수하게 나타났다. 또한, 제2도는 소결광의 품질과의 관계를 나타낸 것으로서, 상온강도는 종래예(1, 2)가 47.30, 48.90인데 비해 본 발명예(4, 5, 6)은 49.01, 50.23 및 50.87로 나타났으며, 저온 환원 분화율은 종래예(1, 2)가 31.08, 28.81인데 비하여 본 발명의 방법(4, 5, 6)은 29.02, 28.05 및 27.33으로 현저히 개선되었다.As can be seen from FIG. 1 showing the relationship between the air permeability in the sintered layer and the sintering time, the inventive examples (4, 5, 6) have better air permeability in the sintered layer and shorter sintering time than the conventional example (1). And similar or superior to the conventional example (2). In addition, Figure 2 shows the relationship between the quality of the sintered ore, the room temperature intensity is 47.30, 48.90 in the prior art (1, 2), while the examples of the invention (4, 5, 6) was 49.01, 50.23 and 50.87 The low temperature reduction differentiation rate was 31.08 and 28.81 of the conventional examples (1, 2), whereas the methods (4, 5, 6) of the present invention were significantly improved to 29.02, 28.05 and 27.33.

상기한 바와같이, 본 발명은 생석회와 물을 사전에 혼합하여 그 혼합용액을 균일하게 살수하여 소결배합원료중에 생석회를 균일하게 분포시키고, 미세한 Ca(OH)2가 소결광의 결합물질(bonding materals)인 칼슘-페라이트의 생성을 균일하게 촉진시키므로써, 소결광의 상온강도, 통기도 및 저온환원분화성을 현저히 개선시키는 효과가 있는 것이다.As described above, in the present invention, the quicklime and water are mixed in advance, and the mixed solution is uniformly sprayed to distribute the quicklime evenly in the sintered blended material, and the bonding material of fine Ca (OH) divalent sintered ore (bonding materals) By promoting the production of phosphorus calcium-ferrite uniformly, there is an effect of remarkably improving the room temperature strength, air permeability and low temperature reduction differentiation of the sintered ore.

Claims (1)

소결광을 제조하기위하여 소결원료 배합시 물과 생석회를 혼합하는 방법에 있어서, 소결배합원료인 생석회를 물 6중량%에 대하여 0.6-1.5중량%로 사전에 혼합하여 그 혼합용액을 조립시 균일 살수함을 특징으로하는 소결원료 배합시 물과 생석회의 혼합첨가방법.In the method of mixing water and quicklime when mixing sintered raw materials to prepare sintered ore, the quicklime, which is a sintered blended raw material, is mixed in advance at 0.6-1.5% by weight with respect to 6% by weight of water and uniformly sprayed when the mixed solution is assembled. Mixing method of water and quicklime when formulating a sintered raw material characterized in that.
KR1019870015118A 1987-12-28 1987-12-28 Process for mixing sintered materials KR900005431B1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100421736B1 (en) * 1999-06-08 2004-03-10 주식회사 포스코 Method of surface treatment of sinter ore for improvement of RDI
KR101296732B1 (en) * 2011-10-27 2013-08-20 주식회사 포스코 Method and apparatus for manufacturing sintered ore

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100388241B1 (en) * 1999-11-29 2003-06-19 주식회사 포스코 Improvement of reduction degradation strength of iron sinter by carbonic acid gas injection

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100421736B1 (en) * 1999-06-08 2004-03-10 주식회사 포스코 Method of surface treatment of sinter ore for improvement of RDI
KR101296732B1 (en) * 2011-10-27 2013-08-20 주식회사 포스코 Method and apparatus for manufacturing sintered ore

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