KR890017263A - β-alkoxycarbonylethyltin dithiocarbamate derivatives and preparation method thereof - Google Patents

β-alkoxycarbonylethyltin dithiocarbamate derivatives and preparation method thereof Download PDF

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KR890017263A
KR890017263A KR1019880005639A KR880005639A KR890017263A KR 890017263 A KR890017263 A KR 890017263A KR 1019880005639 A KR1019880005639 A KR 1019880005639A KR 880005639 A KR880005639 A KR 880005639A KR 890017263 A KR890017263 A KR 890017263A
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dithiocarbamate
group
dimethyl
alkoxycarbonylethyltin
methyl
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KR1019880005639A
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Korean (ko)
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KR900003409B1 (en
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손연수
정옥상
강진희
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전학제
한국과학기술원
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Priority to KR1019880005639A priority Critical patent/KR900003409B1/en
Priority to JP1101857A priority patent/JPH01313486A/en
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/22—Tin compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

내용 없음No content

Description

β-알콕시카르보닐에틸주석 디티오카르바메이트 유도체 및 그 제조방법β-alkoxycarbonylethyltin dithiocarbamate derivatives and preparation method thereof

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (5)

일반식(I)로 표시되는 신규한 알콕시카르보닐에틸주석 디티오카르바메이트 유도체Novel alkoxycarbonylethyltin dithiocarbamate derivatives represented by formula (I) 일반식(I)에 있어서, R은 메틸 또는 에틸기를 표시하며 n은 1 또는 2의 정수이고, X는 클로로와 디티오카르바메이트 또는에틸렌 비스 디티오카르바메이트기를 표시한다. 다만 n이 1인 경우 X는 모노클로로와 에틸렌 비스 디티오카르바메이트기로 구성하거나 또는 디클로로와 디메틸 디티오카르바메이트기로 구성하거나 또는 모노클로로와 비스(디메틸 디티오카르바메이트)기로 구성하거나 또는 디클로로와 디메틸 디티오카르바메이트기로 구성하거나 또는 모노클로로와 비스(디메틸 디티오카르바메이트)기로 구성하거나 또는 트리스(디에틸 디티오카르바메이트)기로 구성된다. 그리고 n이 2인 경우에는 X가 에틸렌 비스 디티오카르바메이트기로 구성된다.In general formula (I), R represents a methyl or ethyl group, n is an integer of 1 or 2, X represents a chloro and dithiocarbamate or ethylene bis dithiocarbamate group. Provided that when n is 1, X is composed of monochloro and ethylene bis dithiocarbamate groups or is composed of dichloro and dimethyl dithiocarbamate groups or is composed of monochloro and bis (dimethyl dithiocarbamate) groups or It consists of a dichloro and dimethyl dithiocarbamate group or a monochloro and bis (dimethyl dithiocarbamate) group or a tris (diethyl dithiocarbamate) group. And when n is 2, X is composed of an ethylene bis dithiocarbamate group. 일반식(II)의 알콕시카르보닐에틸주석 할라이드와 일반식(III)의 디티오카르바메이트 금속염을 알코올 용매 존재하에 반응시키는 것을 특징으로 하는 일반식(I)의 β-알콕시카르보닐에틸주석 디티오카르바메이트 유도체의 제조방법.[Beta] -alkoxycarbonylethyltin dity, wherein the alkoxycarbonylethyltin halide of the formula (II) and the dithiocarbamate metal salt of the formula (III) are reacted in the presence of an alcohol solvent. Method for preparing ocarbamate derivatives. 일반식(I)에 있어서, R은 메틸 또는 에틸기를 표시하며 n은 1 또는 2의 정수이고 X는 클로로와 디티오카르바메이트 또는에틸렌 비스 디티오카르바메이트기를 표시한다. 다만 n이 1인 경우 X는 모노클로로와 에틸렌 비스 디티오카르바메이트기로 구성하거나 또는 디클로로와 디메틸 디티오카르바메이트기로 구성하거나 또는 모노클로로와 비스(디메틸 디티오카르바메이트)기로 구성하거나 또는 디클로로와 디메틸 디티오카르바메이트기로 구성하거나 또는 모노클로로와 비스(디메틸 디티오카르바베이트)기로 구성하거나 트리스(디메틸 디티오카르바메이트)기로 구성한다. 그리고 n이 2인 경우에는 X가 에틸렌 비스 디티오카르바메이트기로 구성된다. 일반식(II)에 있어서, R은 메틸 또는 에틸기를 표시한다. n은 1 또는 2의 정수이다. X는 2 또는 3의 정수로서 n가 1인 경우 X는 3이어야 하며 n가 2인 경우에는 X가 2이어야 한다. 일반식(III)에 있어서, R1은 수소, 메틸, 에틸기를 표시한다. R2도 수소, 메틸, 에틸기를 표시한다. 그러나, R1과 R2에 있어서, 한쪽이 수소이면 다른쪽은 반드시 에틸렌 디티오카르바메이트 나트륨기 이어야 한다.In formula (I), R represents a methyl or ethyl group, n represents an integer of 1 or 2 and X represents a chloro and dithiocarbamate or ethylene bis dithiocarbamate group. Provided that when n is 1 X is composed of monochloro and ethylene bis dithiocarbamate groups or is composed of dichloro and dimethyl dithiocarbamate groups or is composed of monochloro and bis (dimethyl dithiocarbamate) groups or It consists of a dichloro and dimethyl dithiocarbamate group, or a monochloro and bis (dimethyl dithiocarbabate) group or a tris (dimethyl dithiocarbamate) group. And when n is 2, X is composed of an ethylene bis dithiocarbamate group. In general formula (II), R represents a methyl or an ethyl group. n is an integer of 1 or 2. X is an integer of 2 or 3, where n is 1, X must be 3, and when n is 2, X must be 2. In general formula (III), R <1> represents hydrogen, methyl, an ethyl group. R 2 also represents hydrogen, methyl or an ethyl group. However, in R 1 and R 2 , if one is hydrogen, the other must be an ethylene dithiocarbamate sodium group. 제 2 항에 있어서, 알코올 용매로 메틸알코올, 에틸알코올 또는 메틸알코올과 에틸일코올 혼합액 중에서반응시키는 것을 특징으로 하는 일반식(I)의 β-알콕시카르보닐에틸주석 디티오카르바메이트 유도체의 제조방법.The preparation of β-alkoxycarbonylethyltin dithiocarbamate derivatives of the general formula (I) according to claim 2, wherein the alcohol is reacted in methyl alcohol, ethyl alcohol, or a mixture of methyl alcohol and ethyl alcohol. Way. 제 2 항에 있어서, 반응온도를 -20℃-80℃에서 반응시키는 것을 특징으로 하는 일반식(I)의 β-알콕시카르보닐에틸주석 디티오카르바메이트 유도체의 제조방법.The method for producing β-alkoxycarbonylethyltin dithiocarbamate derivative of the general formula (I) according to claim 2, wherein the reaction temperature is reacted at -20 ° C-80 ° C. 제 2 항에 있어서, 트랜스에스테르화 하고자 할 경우 에틸 알코올을 용매로 하고 60-70℃에서 반응시켜 메톡시기를 에톡시기로 치환시키는 것을 특징으로 하는 일반식(I)의 β-알콕시카르보닐에틸주석 디티오카르바메이트 유도체의 제조방법.3. The β-alkoxycarbonylethyl tin of formula (I) according to claim 2, wherein when transesterification is performed, ethyl alcohol is used as a solvent and reacted at 60-70 DEG C to replace the methoxy group with an ethoxy group. Process for the preparation of dithiocarbamate derivatives. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019880005639A 1988-05-14 1988-05-14 B-alkoxy carbonylethyltin di thio carbamate derivatives and preparation method thereof KR900003409B1 (en)

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KR1019880005639A KR900003409B1 (en) 1988-05-14 1988-05-14 B-alkoxy carbonylethyltin di thio carbamate derivatives and preparation method thereof
JP1101857A JPH01313486A (en) 1988-05-14 1989-04-24 Beta-alkoxycarbonylethyl tin dithiocarbamate derivative, its production and sterilizing agent containing the same

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KR1019880005639A KR900003409B1 (en) 1988-05-14 1988-05-14 B-alkoxy carbonylethyltin di thio carbamate derivatives and preparation method thereof

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KR890017263A true KR890017263A (en) 1989-12-15
KR900003409B1 KR900003409B1 (en) 1990-05-18

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100745239B1 (en) * 1999-02-18 2007-08-01 메디녹스, 인크. Method for Preparation of Pharmaceutical-Grade Dithiocarbamate

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GB1598451A (en) * 1977-01-17 1981-09-23 Netherlands Central Org Scient Antifungal and/or antibacterial organotin compounds there preparation and uses
US4324798A (en) * 1980-10-08 1982-04-13 M&T Chemicals Inc. Fungicidal bis(substituted phenyl)alkyltin compounds
DD155001B1 (en) * 1980-12-03 1988-11-30 Bitterfeld Chemie WOOD PROTECTIVE PAINTINGS
US4427695A (en) * 1981-06-04 1984-01-24 The Dow Chemical Company Compositions of asymmetric diphenyl organotins and use for control of plant diseases

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100745239B1 (en) * 1999-02-18 2007-08-01 메디녹스, 인크. Method for Preparation of Pharmaceutical-Grade Dithiocarbamate

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KR900003409B1 (en) 1990-05-18

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