KR890006546A - 불순한 메탄올의 개질방법 및 그를 위한 장치 - Google Patents

불순한 메탄올의 개질방법 및 그를 위한 장치 Download PDF

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Publication number
KR890006546A
KR890006546A KR1019880014248A KR880014248A KR890006546A KR 890006546 A KR890006546 A KR 890006546A KR 1019880014248 A KR1019880014248 A KR 1019880014248A KR 880014248 A KR880014248 A KR 880014248A KR 890006546 A KR890006546 A KR 890006546A
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South Korea
Prior art keywords
mixture
alcohol
water
methanol
gas
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KR1019880014248A
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English (en)
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KR960004876B1 (ko
Inventor
뒤뽕 르네
시모네 귀
Original Assignee
레르 리뀌드
쏘시에떼 아노뉨 뿌르 레뛰드에 렉스 쁠로와 따씨옹 데프로세드 죠르쥬 끌로드
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Publication of KR890006546A publication Critical patent/KR890006546A/ko
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Publication of KR960004876B1 publication Critical patent/KR960004876B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/04—Methanol
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

내용 없음

Description

불순한 메탄올의 개질방법 및 그를 위한 장치
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
불순한 메탄올의 수증기 개질을 위한 장치.

Claims (7)

  1. 메탄올에 비하여 무거운 알콜을 함유하는 불순한 메탄올을 개질하여 순수한 수소를 제조하는 방법에 있어서, 상기 불순한 메탄올의 증기와 수증기의 혼합물을 가열증발하고; 메탄올과 물의 혼합물을 개질하여 잔류기체를 산출하고; 상기 개질된 기체를 냉각하여 수소와 응축된 알콜-물 혼합물을 산출하고; 이때 상기 잔류 기체가 열-교환 액체의 가열에 사용되고; 개질된 기체의 냉각으로 부터 산출되는 알콜-물 혼합물과 잔류 기체의 동시 연소를 행하는 것으로 구성된 방법.
  2. 제1항에 있어서, 그 외의 증발성 액체가 응축된 알콜-물 혼합물에 유입되는방법.
  3. 제1항에 있어서, 혼합물이 응축된 알콜-물 혼합물과 잔류하는 정제기체로 형성되고 상기 혼합물의 분율은 상기 메탄올과 물의 혼합물의 증발에 앞서 개질단계로 재순환되는 것으로 구성되는 방법.
  4. 제3항에 있어서, 연소된 분율과 재순환되는 분율의 비율이 불순한 메탄올의 기능으로 조절되는 방법.
  5. 순환되는 공급액체를 혼합하기 위한 공급파이프; 수증기 개질을 위한 관형의 반응기; 반응혼합물 증발기; 배출되는 기체와 액체 공급원 사이의 열교환을 위한 열교환기; 분리기; 정제장치; 두개의 튜브 탱크와 재순환회로가 장치되었으며 잔류 정제 기체를 위한 연소로; 응축된 물-알콜 혼합물을 연소로에 유입시키기 위한 파이프로 구성된 불순한 메탄올의 개질을 위한 장치.
  6. 제5항에 있어서, 상기 공급파이프로부터 유입되는 응축된 물-알콜 혼합물을 재순환하기 위한 파이프를 부가적으로 포함하는 장치.
  7. 제5항에 있어서, 혼합물 탱크, 고체분리를 위한 필터, 상기 관형 반응기에 공급하기 위한 여과된 액체 탱크를 부가적으로 포함하는 장치.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880014248A 1987-10-29 1988-10-29 불순한 메탄올의 개질 방법 및 그를 위한 장치 KR960004876B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR8715006 1987-10-29
FR8715.006 1987-10-29
FR8715006A FR2622563B1 (fr) 1987-10-29 1987-10-29 Procede de reformage de methanol impur et dispositif de mise en oeuvre

Publications (2)

Publication Number Publication Date
KR890006546A true KR890006546A (ko) 1989-06-14
KR960004876B1 KR960004876B1 (ko) 1996-04-16

Family

ID=9356299

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019880014248A KR960004876B1 (ko) 1987-10-29 1988-10-29 불순한 메탄올의 개질 방법 및 그를 위한 장치

Country Status (11)

Country Link
US (1) US4986978A (ko)
EP (1) EP0318342B1 (ko)
JP (1) JPH01157401A (ko)
KR (1) KR960004876B1 (ko)
BR (1) BR8805542A (ko)
CA (1) CA1340383C (ko)
DE (1) DE3861187D1 (ko)
DK (1) DK594288A (ko)
FR (1) FR2622563B1 (ko)
PH (1) PH24185A (ko)
ZA (1) ZA888037B (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2835851B2 (ja) * 1989-06-23 1998-12-14 ヤマハ発動機株式会社 燃料電池用改質装置
WO2004103894A1 (en) * 2003-04-16 2004-12-02 Energy & Environmental Research Center Foundation, Inc. Process for producing high-pressure hydrogen
CA2627247C (en) * 2005-10-28 2013-04-02 Boehringer Ingelheim International Gmbh Hepatitis c virus ns2/3 activity assay
JP2008195585A (ja) * 2007-02-15 2008-08-28 Toshiba Corp 水素製造装置
WO2024133464A1 (de) * 2022-12-21 2024-06-27 BASF Catalysts Germany GmbH Verfahren und vorrichtung zur gewinnung von hochreinem wasserstoff aus methanol oder ammoniak

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE884720A (fr) * 1980-08-11 1981-02-11 Catalysts & Chem Europ Procede de reformage de methanol et dispositif mis en oeuvre
FR2572380B2 (fr) * 1984-10-30 1990-05-04 Catalysts Chemical Europ Procede de reformage de methanol et dispositif de mise en oeuvre

Also Published As

Publication number Publication date
DK594288A (da) 1989-04-30
FR2622563B1 (fr) 1990-02-16
FR2622563A1 (fr) 1989-05-05
EP0318342A1 (fr) 1989-05-31
PH24185A (en) 1990-03-22
DK594288D0 (da) 1988-10-26
JPH01157401A (ja) 1989-06-20
KR960004876B1 (ko) 1996-04-16
US4986978A (en) 1991-01-22
BR8805542A (pt) 1989-07-11
CA1340383C (fr) 1999-02-09
ZA888037B (en) 1989-07-26
DE3861187D1 (de) 1991-01-10
EP0318342B1 (fr) 1990-11-28

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