KR880013954A - 1,3-비스(디카르복시페닐)디실옥산 유도체 또는 이의 이무수물의 제조방법 - Google Patents
1,3-비스(디카르복시페닐)디실옥산 유도체 또는 이의 이무수물의 제조방법 Download PDFInfo
- Publication number
- KR880013954A KR880013954A KR1019880005780A KR880005780A KR880013954A KR 880013954 A KR880013954 A KR 880013954A KR 1019880005780 A KR1019880005780 A KR 1019880005780A KR 880005780 A KR880005780 A KR 880005780A KR 880013954 A KR880013954 A KR 880013954A
- Authority
- KR
- South Korea
- Prior art keywords
- general formula
- dicarboxyphenyl
- bis
- dimethylphenyl
- represented
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 4
- ZBXZXANUNUUCTF-UHFFFAOYSA-N OC(=O)C1=CC=CC([SiH2]O[SiH2]C=2C(=C(C(O)=O)C=CC=2)C(O)=O)=C1C(O)=O Chemical class OC(=O)C1=CC=CC([SiH2]O[SiH2]C=2C(=C(C(O)=O)C=CC=2)C(O)=O)=C1C(O)=O ZBXZXANUNUUCTF-UHFFFAOYSA-N 0.000 title 1
- 125000006159 dianhydride group Chemical group 0.000 title 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 14
- -1 dimethylphenyl (disubstituted silane) Chemical class 0.000 claims 11
- 239000000047 product Substances 0.000 claims 4
- 239000002904 solvent Substances 0.000 claims 4
- HEICRJWSSXJMKE-UHFFFAOYSA-N CC1=CC=CC([SiH2]O[SiH2]C=2C(=C(C)C=CC=2)C)=C1C Chemical class CC1=CC=CC([SiH2]O[SiH2]C=2C(=C(C)C=CC=2)C)=C1C HEICRJWSSXJMKE-UHFFFAOYSA-N 0.000 claims 2
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 claims 2
- GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 claims 2
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- 239000000843 powder Substances 0.000 claims 2
- 239000007818 Grignard reagent Substances 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 claims 1
- 238000009833 condensation Methods 0.000 claims 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims 1
- 150000004795 grignard reagents Chemical class 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 230000033444 hydroxylation Effects 0.000 claims 1
- 238000005805 hydroxylation reaction Methods 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 239000002244 precipitate Substances 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
- C07F7/0872—Preparation and treatment thereof
- C07F7/0874—Reactions involving a bond of the Si-O-Si linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
- C07F7/0872—Preparation and treatment thereof
- C07F7/0889—Reactions not involving the Si atom of the Si-O-Si sequence
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (5)
- 할로-O-크실렌의 그리나드시약을 하기 일반식(Ⅰ)로 나타내는 이치환 할로실란과 커플링시켜 하기 일반식(Ⅱ)로 나타내는 디메틸페닐(이치환 실란)을 생성시키고, 디메틸페닐(이치환 실란)을 히드록실화시켜 하기 일반식(Ⅲ)로 나타내는 디메틸페닐(이치환 히드록실란)을 생성시키고, 디메틸페닐(이치환 히드록시실란)을 생성시키고, 디메틸페닐(이치환 히드록시실란)을 탈수-축합시켜 하기 일반식(Ⅳ)로 나타내는 1,3-비스(디메틸페닐) 디실옥산유도체를 생성시키고, 이어서, 1,3-비스(디메틸페닐) 디실옥산 유도체를 산화시켜 하기 일반식(Ⅴ)의 목적한 1,3-비스(디카르복시페닐) 디실옥산 유도체를 수독하거나, 상기 생성물을 추가로 탈수폐환시켜 하기 일반식(Ⅵ)의 1,3-비스(디카르복시페닐)디실옥산 유도체 이무수물을 생성시키고, 생성 이성체 혼합물을 에테로 용매와 혼합하고 생성침전물을 회수하여 흰색 분말의 일반식(Ⅵ)의 목적 생성물을 수득함을 특징으로 하여, (ⅰ) 일반식 (Ⅴ)로 나타내는 1,3-비스(디카르복시페닐) 디실옥산 유도체 또는 (ⅱ) 일반식 (Ⅵ)로 나타내는 1,3-비스(디카르복시페닐) 디실옥산 유도체 이무수물을 제조하는 방법.상기식에서, R 및 R'는 각기 독립적으로 메틸기 또는 페닐기를 나타내고, X는 할로겐을 나타낸다.
- 제1항에 있어서, 1,3-비스(디카르복시페닐)디실옥산 유도체 이무수물이 구조식(XI)로 나타내는 1,3-비스(디카르복시페닐)-1,1,3,3-테트라메틸디실옥산 이무수물인 방법.
- 에테르 용매를 구조식(XI)로 나타내는 규소함유 테트라카르복실산 이무수물 이성체들의 혼합물과 혼합하고 생성된 침저눌을 회수하여 흰색 분말 형태의 목적 생성물을 수득함을 특징으로 하여, 1,3-비스(디카르복시페닐)-1,1,3,3-테트라메틸디실옥산 이무수물을 제조하는 방법.
- 제1항 또는 제2항에 있어서, 에테르 용매가 디에틸 에테르, 디이소프로필에테르 또는 디-n-프로필에테르인 방법.
- 제3항에 있어서, 에테르 용매가 디에틸에테르, 디이소프로필에테르 또는 디-n-프로필 에테르인 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62-121546 | 1987-05-19 | ||
| JP12154687A JPH0737465B2 (ja) | 1987-05-19 | 1987-05-19 | １，３−ビス（ジカルボキシフエニル）ジシロキサン誘導体又はその二無水物の製造方法 |
| JP15219987A JPH0725773B2 (ja) | 1987-06-18 | 1987-06-18 | １，３−ビス（３，４−ジカルボキシフエニル）−１，１，３，３−テトラメチルジシロキサン二無水物の製造法 |
| JP62-152199 | 1987-06-18 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR880013954A true KR880013954A (ko) | 1988-12-22 |
| KR900006209B1 KR900006209B1 (ko) | 1990-08-25 |
Family
ID=26458888
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019880005780A KR900006209B1 (ko) | 1987-05-19 | 1988-05-18 | 1,3-비스(디카르복시페닐)디실옥산 유도체 또는 이의 이무수물의 제조방법 |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0292260B1 (ko) |
| KR (1) | KR900006209B1 (ko) |
| DE (1) | DE3889004T2 (ko) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5242917A (en) * | 1987-12-10 | 1993-09-07 | Hitachi Chemical Company, Ltd. | Tetracarboxylic acid dianhydride having disiloxane linkage and process for producing the same |
| US4945148A (en) * | 1989-03-06 | 1990-07-31 | General Electric Company | Silicone-polycarbonate block copolymers |
| US4895965A (en) * | 1989-04-28 | 1990-01-23 | General Electric Company | Method for making carboxy aryl terminated organosiloxanes |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB706703A (en) * | 1950-03-24 | 1954-04-07 | Westinghouse Electric Int Co | Improvements in or relating to organosilicon compositions |
| GB981824A (en) * | 1962-03-29 | 1965-01-27 | Dow Corning | Improvements in or relating to organosilicon compounds |
| GB2164040B (en) * | 1984-09-04 | 1988-10-05 | Gen Electric | Method for silylating aromatic imides and imides made therefrom |
-
1988
- 1988-05-18 DE DE3889004T patent/DE3889004T2/de not_active Expired - Lifetime
- 1988-05-18 KR KR1019880005780A patent/KR900006209B1/ko not_active IP Right Cessation
- 1988-05-18 EP EP88304499A patent/EP0292260B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| KR900006209B1 (ko) | 1990-08-25 |
| EP0292260B1 (en) | 1994-04-13 |
| EP0292260A3 (en) | 1990-03-28 |
| DE3889004T2 (de) | 1994-07-21 |
| EP0292260A2 (en) | 1988-11-23 |
| DE3889004D1 (de) | 1994-05-19 |
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