KR880010107A - Low phosphorus and zinc content lubricants - Google Patents

Low phosphorus and zinc content lubricants Download PDF

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Publication number
KR880010107A
KR880010107A KR1019880002059A KR880002059A KR880010107A KR 880010107 A KR880010107 A KR 880010107A KR 1019880002059 A KR1019880002059 A KR 1019880002059A KR 880002059 A KR880002059 A KR 880002059A KR 880010107 A KR880010107 A KR 880010107A
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South Korea
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composition
copper
fat
ppm
soluble
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KR1019880002059A
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Korean (ko)
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KR960014934B1 (en
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테렌스 콜클로흐
존 프레드릭 마쉬
프레드릭 알리스테어 깁슨
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원본미기재
엑숀 케미칼 페이턴츠 아이엔씨
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Abstract

Lubricants having antiwear, corrosion inhibition and antioxidant performance appropriate to modern oil requirements with reduced or zero amounts of zinc and phosphorous and without the need for large amounts and/or expensive forms of antioxidant comprise 5 to 500 parts per million by weight (ppm) of added copper present in oil-soluble form, one or more added oil-soluble sulphur-containing compounds and a bearing corrosion inhibitor.

Description

인과 아연 함량이 낮은 윤활유Low phosphorus and zinc content lubricants

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (24)

대부분의 윤활유와 지용성 형태로 부가된 구리 5-500 ppm(질량), 하나 이상의 부가된 지용성 황 함유 화합물로 구성되어 총 황 함량이 0.5-2.0 wt% 이상이 되고 효과적인 양이 베어링 부식 억제제를 함유하며 0.01 wt% 미만의 인 및 0.05 wt% 미만의 아연을 함유하는 자동차 엔진에 이용되는 크랭크실 윤활유 조성물.Consists of most lubricants and 5-500 ppm (mass) of added copper in fat-soluble form, one or more added fat-soluble sulfur-containing compounds with a total sulfur content of at least 0.5-2.0 wt% and an effective amount of bearing corrosion inhibitor A crankcase lubricating oil composition for use in automotive engines containing less than 0.01 wt% phosphorus and less than 0.05 wt% zinc. 제 1항에 있어서, 부가된 구리의 양이 10-400 ppm 인 조성물.The composition of claim 1 wherein the amount of copper added is 10-400 ppm. 제 2항에 있어서, 부가된 구리의 양이 10-200 ppm 인 조성물.The composition of claim 2 wherein the amount of copper added is 10-200 ppm. 제 3항에 있어서, 부가된 구리의 양이 60-200 ppm 인 조성물.The composition of claim 3 wherein the amount of copper added is 60-200 ppm. 전기한 항중 어느 한 항에 있어서, 구리가 C10-C18지방산, 불포화 카복실산, 분자량이 200-500인 나프텐산 또는 알킬 또는 알케닐 치환된 디카복실산등의 구리염 형태로서 오일에 혼합되거나 또는 n이 1 또는 2이고 R 및 R'가 동일하거나 상이한 바 C1-18을 함유하는 하이드로카빌 라디칼인 일반식(RR'NCSS)nCu 인 지용성 코퍼 디티오카바메이트, 코퍼 설포네이트, 코퍼 페네이트 또는 코퍼 아세틸아세토네이트 등으로 오일에 혼합되는 조성물.The method of claim 1, wherein the copper is mixed with oil in the form of a copper salt such as C 10 -C 18 fatty acids, unsaturated carboxylic acids, naphthenic acids having a molecular weight of 200-500 or alkyl or alkenyl substituted dicarboxylic acids, or n A fat-soluble copper dithiocarbamate, copper sulfonate, copper phenate, or a general formula (RR'NCSS) n Cu which is 1 or 2 and R and R 'are hydrocarbyl radicals containing the same or different bars C 1-18 A composition mixed with oil with copper acetylacetonate or the like. 전기한 항중 어느 한 항에 있어서, 지용성 황 화합물이 일반식 (RR'NCSS)nM(여기서 R, R' 및 n은 제3항에서와 동일하고 M은 적당한 금속)의 디티오카바메이트 또는 머캅타이드, 황화된 불포화 유기 화합물, 설파이드, 티오에테르, 티오페놀, 티옥산테이트, 황화된 에스테르, 티오에스테르, 티오아미드, 티아졸 또는 티아디아졸인 조성물.The dithiocarbamate or mercap of any one of the preceding claims, wherein the fat soluble sulfur compound is of the general formula (RR'NCSS) n M where R, R 'and n are the same as in claim 3 and M is a suitable metal. Tide, sulfurized unsaturated organic compounds, sulfides, thioethers, thiophenols, thioxanthates, sulfurized esters, thioesters, thioamides, thiazoles or thiadiazoles. 제 6항에 있어서, 지용성 황 화합물이 C2-12를 함유하는 디알킬 디티오카바메이트인 조성물.7. The composition of claim 6, wherein the fat soluble sulfur compound is a dialkyl dithiocarbamate containing C 2-12 . 전기한 항중 어느 한 항에 있어서, 0.5-1.0 wt% 이상의 전체 S를 함유하고 부가된 지용성 황 함유 화합물로서 0.1-0.5 wt%의 S를 포함하는 조성물.The composition of claim 1, containing at least 0.5-1.0 wt% total S and comprising 0.1-0.5 wt% S as an added fat-soluble sulfur containing compound. 전기한 항중 어느 한 항에 있어서, 실제로 Zn이 전혀 없는 조성물.The composition of claim 1, wherein the composition is virtually free of Zn. 제 6항에 있어서, 0.5-3 wt%의 황화 에스테르를 함유하는 조성물.7. A composition according to claim 6, containing 0.5-3 wt% sulfided ester. 전기한 항중 어느 한 항에 있어서, 베어링 부식 억제제가 다음 일반식의 하나 이상의 보레이트 에스테르 ; B(OR)3, (RO)2B-O-B(OR)2, (ROBO)3또는 (RO2) BOR1OB(OR)2식중, R은 치환되거나 비치환된 알킬, 아릴 또는 아랄킬 그룹 또는 두개의 그룹 R이 함께 치환된 또는 비치환된 알킬렌 그룹을 형성하고, R1은 치환되거나 또는 비치환된 알킬렌 그룹 및/또는 C5-50을 함유하는 티아디아졸 폴리설파이드 및 이들 중합체의 유도체로 구성된 조성물.The bearing corrosion inhibitor according to any one of the preceding claims, wherein the bearing corrosion inhibitor is at least one borate ester of the general formula; B (OR) 3 , (RO) 2 BOB (OR) 2 , (ROBO) 3 or (RO 2 ) BOR 1 OB (OR) 2 wherein R is a substituted or unsubstituted alkyl, aryl or aralkyl group or two Groups R together form a substituted or unsubstituted alkylene group, R 1 is a substituted or unsubstituted alkylene group and / or C 5-50 containing thiadiazole polysulfide and derivatives of these polymers Composition consisting of. 제11항에 있어서, 0.01-10 wt%의 보레이트 에스테르를 함유한 조성물.The composition of claim 11 containing 0.01-10 wt% of borate ester. 제11항 또는 제12항에 있어서, 보레이트 에스테르가 트리스(에톡시에틸) 오르토보레이트 에스테르 또는 부탄-1,3-디올의 바이보레이트인 조성물.The composition of claim 11 or 12, wherein the borate ester is tris (ethoxyethyl) orthoborate ester or biborate of butane-1,3-diol. 제11항에 있어서, 0.01-10 wt%의 2.5-비스(t-노닐디티오)-1,3,4-티아디아졸을 함유하는 조성물.The composition of claim 11 containing 0.01-10 wt% of 2.5-bis (t-nonyldithio) -1,3,4-thiadiazole. 전기한 항중 어느 한 항에 있어서, 0.005 wt% 미만 인을 함유하는 조성물.The composition of claim 1 containing less than 0.005 wt% phosphorus. 제15항에 있어서, 실제로 인이 전혀 없는 조성물.The composition of claim 15 which is virtually free of phosphorus. 전기한 항중 어느 한 항에 있어서, (A) 1-10 wt%의 무회 분산제 화합물 및/또는 (B) 점도지수 개선 중합체 분산제를 함유하는 0.3-10 wt%의 질소 또는 에스테르로 더욱 구성된 조성물.The composition according to any one of the preceding claims, further comprising 0.3-10 wt% of nitrogen or ester containing (A) 1-10 wt% ashless dispersant compound and / or (B) viscosity index improving polymer dispersant. 전기한 항중 어느 한 항에 있어서, 2-8000 ppm의 칼슘 및/또는 마그네슘으로 구성된 조성물.The composition of claim 1 consisting of 2-8000 ppm calcium and / or magnesium. 제18항에 있어서, 염기성 칼슘 및/또는 마그네슘 설포네이트로서 500-5000 ppm의 칼슘 및/또는 마그네슘으로 구성된 조성물.19. The composition of claim 18 consisting of 500-5000 ppm calcium and / or magnesium as basic calcium and / or magnesium sulfonate. 전기한 항중 어느 한 항에 있어서, 하나이상의 녹억제제, 유동점 강하제(Pour point depressants), 부가 산화방지제 및 점도지수 개선제로 더욱 구성된 조성물.The composition of claim 1, further comprising one or more green inhibitors, Pour point depressants, addition antioxidants, and viscosity index improvers. (1) 0.1 wt% 미만의 인 및 0.1 wt% 미만의 아연 ; (2) 1-50 wt%의 지용성 황 함유 화합물 ; (3) 0.005-2 wt%의 구리 ; (4) 0.1-20 wt%의 베어링 부식억제제 ; 및 (5) 0-60 wt%의 무회의 분산제 및/또는 점도지수 개선 중합체 분산제를 함유하는 오일용액으로 구성된 농축물.(1) less than 0.1 wt% phosphorus and less than 0.1 wt% zinc; (2) 1-50 wt% of a fat-soluble sulfur containing compound; (3) 0.005-2 wt% copper; (4) 0.1-20 wt% of bearing corrosion inhibitor; And (5) an oil solution containing 0-60 wt% ashless dispersant and / or viscosity index improving polymer dispersant. 제21항에 있어서, 0.01-8 wt%의 칼슘 및/또는 마그네슘으로 더욱 구성된 조성물.The composition of claim 21 further composed of 0.01-8 wt% calcium and / or magnesium. 지용성 황 함유 화합물, 베어링 부식억제제, 무회의 분산제 및/또는 점도지수 개선 중합체 분산제, 및 칼슘 및/또는 마그네슘을 함유하는 청정제로 구성된 아연과 인이 없는 윤활유 조성물내에서의 지용성 구리의 산화방지제로서의 용도.Use of fat-soluble copper as antioxidant in zinc and phosphorus-free lubricating oil compositions consisting of fat-soluble sulfur containing compounds, bearing corrosion inhibitors, ashless dispersants and / or viscosity index improving polymer dispersants, and detergents containing calcium and / or magnesium . 0.01 wt% 미만의 인과 0.05 wt% 미만의 아연을 함유하고 지용성 형태로 존재하는 부가된 구리 5-500 ppm, 총 S 0.5-2.0 wt% 이상, 산화, 마모, 부식등을 조절하기 위한 베어링 부식 억제제등을 함유하며 최소한 API 엔진 요구 규격의 표준 규격 SF 및/또는 CD의 품질 규격에 부합되는 자동차 엔진용 크랭크실 윤활유 조성물로서의 용도.Bearing corrosion inhibitor to control added copper 5-500 ppm, total S 0.5-2.0 wt% or more, containing less than 0.01 wt% phosphorus and less than 0.05 wt% zinc, in fat-soluble form Use as a crankcase lubricant composition for automotive engines containing, and at least conforming to the quality specifications of standard specifications SF and / or CD of API engine requirements. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019880002059A 1987-02-27 1988-02-27 Low phosphorus and zinc lubricants KR960014934B1 (en)

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