KR880004861A - Painting method - Google Patents

Painting method Download PDF

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Publication number
KR880004861A
KR880004861A KR870011906A KR870011906A KR880004861A KR 880004861 A KR880004861 A KR 880004861A KR 870011906 A KR870011906 A KR 870011906A KR 870011906 A KR870011906 A KR 870011906A KR 880004861 A KR880004861 A KR 880004861A
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KR
South Korea
Prior art keywords
coating method
solubility parameter
weight
resin particles
organic solvent
Prior art date
Application number
KR870011906A
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Korean (ko)
Other versions
KR950009547B1 (en
Inventor
데루아끼 구와지마
야마 가즈오 우에노
마사끼 다까에
히데후미 오꾸다
Original Assignee
사사끼 가즈오
닛뽕페인트 가부시끼가이샤
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Publication of KR880004861A publication Critical patent/KR880004861A/en
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Publication of KR950009547B1 publication Critical patent/KR950009547B1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D157/00—Coating compositions based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D157/04—Copolymers in which only the monomer in minority is defined
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/18—Spheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

내용 없음No content

Description

도장법Painting method

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (8)

(A) 산기를 갖는 에틸렌계 단량체, 히드록실기를 갖는 에틸렌계 단랑체 및 이와 공중합성인 또 다른 에틸렌계 단량체를 공중합하여 제조되는 산가 5∼100, 히드록실가 20∼100, 용해도 파라미터(δsp) 9.0∼13.0이고 수평균 분자량 3,000∼50,000인 비닐 공중합체 94∼30중량부, (B) 성분(A)와 반응성인 교차결합 성분 5∼40중량부, 그리고, (C) 용해도 파라미터 7.5∼13.0인 유기용매로 팽윤된 평균 입자 크기 0.01∼10μ인 팽윤된 수지 입자 1∼30중량부를 함유하는 수지 조성물(Ⅰ)로 만들어진 수성 메탈릭 도료를 하도 또는 중도가 제공되어져 있는 기질상에 피복하고; 상기 수성 메탈릭 도막을 경화시키지 않고 그 위에; (D) 히드록실기를 갖는 에틸렌계 단량체를 공중합하여 제조되는, 히드록실가 20∼100이며 상기 공중합체(A)와 (D)사이의 용해도 파라미터의 차이의 절대치가 0.3이상인 공중합체 95∼60중량부; 그리고 (E) 성분(D)와 반응성인 교차결합성분 5∼40중량부를 함유하는 수지조성물(Ⅱ)로 만들어진 열경화성 클리어 도료를 피복하는 것으로 이루어진 도장법.(A) an acid value of 5 to 100, a hydroxyl value of 20 to 100, a solubility parameter (δsp) prepared by copolymerizing an ethylene monomer having an acid group, an ethylene monomer having a hydroxyl group, and another copolymerizable ethylene monomer. 94 to 30 parts by weight of a vinyl copolymer having a number average molecular weight of 3,000 to 50,000 and 9.0 to 13.0, 5 to 40 parts by weight of a crosslinking component reactive with component (A), and (C) a solubility parameter of 7.5 to 13.0. Coating an aqueous metallic paint made of a resin composition (I) containing 1 to 30 parts by weight of swelled resin particles having an average particle size of 0.01 to 10 microns swelled with an organic solvent on a substrate provided with a base or medium weight; Thereon without curing the aqueous metallic coating; (D) Copolymer 95-60 which is manufactured by copolymerizing the ethylene-type monomer which has a hydroxyl group, and whose hydroxyl value is 20-100 and the absolute value of the difference of the solubility parameter between said copolymer (A) and (D) is 0.3 or more. Parts by weight; And (E) A coating method comprising coating a thermosetting clear paint made of resin composition (II) containing 5 to 40 parts by weight of a crosslinking component reactive with component (D). 제1항에 있어서, 팽윤된 수지입자는 수성용매내에서 유화중합으로 제조된 수지입자를 용해도 파라미터 7.0∼13.0인 유기용매내에서 팽윤시킴으로써 제조됨을 특징으로 하는 도장법.The coating method according to claim 1, wherein the swollen resin particles are prepared by swelling the resin particles prepared by emulsion polymerization in an aqueous solvent in an organic solvent having a solubility parameter of 7.0 to 13.0. 제1항에 있어서, 팽윤된 수지입자는 용해도 파라미터 8.5∼11.5인 유기용매로 팽윤되며 그 입자크기는 0.01∼0.5μ임을 특징으로 하는 도장법.The coating method according to claim 1, wherein the swollen resin particles are swollen with an organic solvent having a solubility parameter of 8.5 to 11.5, and the particle size thereof is 0.01 to 0.5 mu. 제1항에 있어서, 수지입자 팽윤용 유기용매의 용해도 파라미터는 공중합체(A)의 용해도 파라미터보다 더 작음을 특징으로 하는 도장법.The coating method according to claim 1, wherein the solubility parameter of the organic solvent for swelling the resin particles is smaller than the solubility parameter of the copolymer (A). 제1항에 있어서, 수지입자는 양쪽성 이온기를 갖는 유화제를 사용한 유화 중합으로써 제조됨을 특징으로 하는 도장법.The coating method according to claim 1, wherein the resin particles are prepared by emulsion polymerization using an emulsifier having an amphoteric ionic group. 제1항에 있어서 상기 공중합체(A)의 단량체들 중, 산기를 갖는 에틸렌계 단량체의 산기 부분이 술폰기임을 특징으로 하는 도장법.The coating method according to claim 1, wherein, among the monomers of the copolymer (A), the acid group portion of the ethylene monomer having an acid group is a sulfone group. 제1항에 있어서, 열경화성 클리어 도료는 수-희석형임을 특징으로 하는 도장법.The coating method according to claim 1, wherein the thermosetting clear paint is water-diluted. 제1항에 있어서, 열경화성 클리어 도료는 비휘발성분을 40% 이상 함유하는 유기용매형 클리어 도료임을 특징으로 하는 도장법.The coating method according to claim 1, wherein the thermosetting clear paint is an organic solvent clear paint containing 40% or more of nonvolatile components. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019870011906A 1986-10-27 1987-10-26 Method of painting KR950009547B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP256591/1986 1986-10-27
JP61256591A JPS63111976A (en) 1986-10-27 1986-10-27 Coating method
JP256591 1986-10-27

Publications (2)

Publication Number Publication Date
KR880004861A true KR880004861A (en) 1988-06-27
KR950009547B1 KR950009547B1 (en) 1995-08-24

Family

ID=17294756

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019870011906A KR950009547B1 (en) 1986-10-27 1987-10-26 Method of painting

Country Status (7)

Country Link
US (1) US4812335A (en)
EP (1) EP0266152B1 (en)
JP (1) JPS63111976A (en)
KR (1) KR950009547B1 (en)
AU (1) AU598047B2 (en)
CA (1) CA1295891C (en)
DE (1) DE3783325T2 (en)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2670314B2 (en) * 1988-10-25 1997-10-29 マツダ株式会社 Painting method
JP2989643B2 (en) * 1990-08-09 1999-12-13 関西ペイント株式会社 Coating method
US5221584A (en) * 1990-12-03 1993-06-22 E. I. Du Pont De Nemours And Company Waterbased coating composition of methylol(meth)acrylamide acrylic polymer, acrylic hydrosol and melamine crosslinking agent
US5166254A (en) * 1990-12-03 1992-11-24 E. I. Du Pont De Nemours And Company Waterbased coating composition of methylol (meth)acrylamide acrylic polymer, acrylic hydrosol and melamine crosslinking agent
US5227201A (en) * 1991-06-20 1993-07-13 E. I. Du Pont De Nemours And Company Low voc clear coating composition for basecoat clear coat finish
EP0554865B2 (en) † 1992-02-07 2001-10-24 Nippon Paint Co., Ltd. Use of water-based paint composition
DE4216613A1 (en) * 1992-05-20 1993-11-25 Basf Lacke & Farben Process for producing a two-layer coating and aqueous coatings suitable for this process
AU665876B2 (en) * 1992-12-15 1996-01-18 Nippon Paint Co., Ltd. Two coat one bake coating method
US5523349A (en) * 1993-11-08 1996-06-04 Nippon Paint Co., Ltd. Powder coating composition
US5635251A (en) * 1994-05-20 1997-06-03 Kansai Paint Company, Limited Wet-on-wet coating method
JPH09168764A (en) * 1995-12-19 1997-06-30 Nof Corp Method for forming paint film and coated article
EP0906925A3 (en) * 1997-10-03 2000-04-19 Kabushiki Kaisha Toyota Chuo Kenkyusho Resin for aqueous paint
US6342272B1 (en) 2000-04-21 2002-01-29 The United States Of America As Represented By The Secretary Of The Air Force Multi-layer corrosion resistant coatings
USH2035H1 (en) 2000-04-21 2002-07-02 The United States Of America As Represented By The Secretary Of The Air Force Method for applying a polymer coating to a substrate
JP2007054766A (en) * 2005-08-26 2007-03-08 Nissan Motor Co Ltd Brilliant feeling coating for repair and method for repairing of brilliant feeling coating film using the same

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US439858A (en) * 1890-11-04 Road-cart
US4122055A (en) * 1975-12-26 1978-10-24 Dai Nippon Toryo Co., Ltd. Aqueous dispersion type thermosetting coating composition
GB2073609B (en) * 1980-04-14 1984-05-02 Ici Ltd Coating process
JPS5744674A (en) * 1980-08-29 1982-03-13 Nippon Paint Co Ltd Resin composition for coating material
US4391858A (en) * 1981-11-20 1983-07-05 Glasurit America, Inc. Coating process
AT381499B (en) * 1985-02-27 1986-10-27 Vianova Kunstharz Ag WATER-DISCOVERABLE COATING AGENTS, METHOD FOR THE PRODUCTION AND THEIR USE FOR BASE LAYERS WITH TWO-LAYER TOP COATING

Also Published As

Publication number Publication date
DE3783325T2 (en) 1993-05-06
US4812335A (en) 1989-03-14
EP0266152A2 (en) 1988-05-04
CA1295891C (en) 1992-02-18
AU598047B2 (en) 1990-06-14
AU8012387A (en) 1988-04-28
KR950009547B1 (en) 1995-08-24
JPS63111976A (en) 1988-05-17
EP0266152A3 (en) 1989-10-11
DE3783325D1 (en) 1993-02-11
JPH0315507B2 (en) 1991-03-01
EP0266152B1 (en) 1992-12-30

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