KR880001783A - 양이온 코우팅 조성물의 제법 - Google Patents

양이온 코우팅 조성물의 제법 Download PDF

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Publication number
KR880001783A
KR880001783A KR1019870006732A KR870006732A KR880001783A KR 880001783 A KR880001783 A KR 880001783A KR 1019870006732 A KR1019870006732 A KR 1019870006732A KR 870006732 A KR870006732 A KR 870006732A KR 880001783 A KR880001783 A KR 880001783A
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South Korea
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range
polyglycidyl
ether
epoxy
mixture
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KR1019870006732A
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English (en)
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KR960006083B1 (en
Inventor
반 이페렌 뢰란트
게라르두스 쿠이만스 페트루스
마리아 반 데어 마르크 요하네스
Original Assignee
오노 알버어스
셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이
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Publication of KR960006083B1 publication Critical patent/KR960006083B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
    • C09D5/443—Polyepoxides
    • C09D5/4434—Polyepoxides characterised by the nature of the epoxy binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1405—Polycondensates modified by chemical after-treatment with inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
    • C08G59/1444—Monoalcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C08G59/38—Epoxy compounds containing three or more epoxy groups together with di-epoxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
    • C08G59/4284—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof together with other curing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/56—Amines together with other curing agents
    • C08G59/58—Amines together with other curing agents with polycarboxylic acids or with anhydrides, halides, or low-molecular-weight esters thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Epoxy Resins (AREA)

Abstract

내용 없음

Description

양이온 코우팅 조성물의 제법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 아래의 1)과 2를, 2)의중화 전 또는 후에 혼합시키는 것을 포함하는, 물에 희석될 수 있고, 가수분해에 안정하며, 열경화성인, 양이온 코우팅 조성물의 제조방법:1)5-35 중량%의 카복실화 가교 화합물과 2) 65-95중량%의 하기 a)와 b)의 반응 생성물을 포함하는 아미노 기-함유수지 결합체, a)암모니아,b)폴리글리시딜 에테르와 디글리시딜 에테르의 혼합물 내에 존재하는 글리시딜 에테르의 평균 몰 에폭시관능가는 〈1.75인〉하기 b1과 b2〉의 혼합물, 즉b1)분자당n(1〈n〈1.9)개의 에폭시기를 갖는 폴리글리시딜 에테르로서 분자당 x(x〉2)개의 에폭시기를 갖는 다관능가 폴리글리시딜 에테르와, 다관능가 폴리글리시딜폴레에테르 몰당 (x-n)몰의 일관능가 페놀과의 반응 생성물ㅇ니 폴리글리시딜 에레르와 b2)1.0내지 5.5범위 내의 EGC를 갖는 디글리시딜 에테르를 된 혼합물.
  2. 제1항에 있어서, 다관능가 폴리글리시딜 에테르가 2.5〈x〈3.5인 에폭시 노블락 수지인 방법.
  3. 제1항 또는 제2항에 있어서, 일관능가 페놀이 C4-12알킬 치환체에 의해 따라 위치에서 치환된 페놀인 방법.
  4. 제1항 내지 제3항중 어느 한항에 있어서, 디글리시딜 에테르가 1.8내지 2.4범위 내의 EGC르 갖는, 2,2-비스(4-히드록시-페닐)프로판의 디글리시딜에테르인 방법.
  5. 제1항내지 4항중 어느 한 항에 있어서,폴리글리시딜 에테르와 디글리시딜 에테르가 75:25내지 45:55범위 내의 중량 비율로 b)에서 언급된 혼합물 내에 존재하는 방법.
  6. 제1항내지 5항중 어느 한항에 있어서, 20내지 120℃범위 내의 온도에서, 대기압 또는 대기압보다 약간 높은 압력으로 암모니아와 b)에서 언급된 혼합물을 반응시켜 아미노 기-함유 결합제를 제조하는 방법.
  7. 제6항에 있어서, 에폭시 당량 당 아미노-수소를 4.5당량 이상으로 채택되는 방법.
  8. 제1항 내지 7항중 어느 한항에 있어서, 가교 화합물과 아미노기-함유 결합제가 15:85 내지 25:75범위내의 중량비율로 존재하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR87006732A 1986-07-02 1987-06-30 Process for the preparation of cationic coating compositions KR960006083B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8616162 1986-07-02
GB868616162A GB8616162D0 (en) 1986-07-02 1986-07-02 Cationic coating compositions

Publications (2)

Publication Number Publication Date
KR880001783A true KR880001783A (ko) 1988-04-26
KR960006083B1 KR960006083B1 (en) 1996-05-08

Family

ID=10600462

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Application Number Title Priority Date Filing Date
KR87006732A KR960006083B1 (en) 1986-07-02 1987-06-30 Process for the preparation of cationic coating compositions

Country Status (8)

Country Link
US (1) US4772669A (ko)
EP (1) EP0251360B1 (ko)
JP (1) JP2525610B2 (ko)
KR (1) KR960006083B1 (ko)
CA (1) CA1283994C (ko)
DE (1) DE3785251T2 (ko)
ES (1) ES2053520T3 (ko)
GB (1) GB8616162D0 (ko)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8621491D0 (en) * 1986-09-05 1986-10-15 Shell Int Research Cationic coating compositions
DE3909593A1 (de) * 1989-03-23 1990-09-27 Hoechst Ag Bindemittel, ihre herstellung und anwendung in haertbaren mischungen
AU2003286758A1 (en) 2003-07-17 2005-03-07 Honeywell International Inc Planarization films for advanced microelectronic applications and devices and methods of production thereof

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2844553A (en) * 1953-04-24 1958-07-22 Sherwin Williams Co Polyhydric phenol-aldehyde-epihalo-hydrin resins
US3630977A (en) * 1967-12-08 1971-12-28 Reichhold Albert Chemie Ag Water-dilutable phenoplasts having carboxyl groups
GB1221906A (en) * 1968-09-23 1971-02-10 Shell Int Research Amino-type curing agents for epoxy resins, and their preparation and use
IT1051397B (it) * 1975-12-19 1981-04-21 S I R S P A Procedimento per la preparazione di resine novolacche epossidate
US4066525A (en) * 1975-12-22 1978-01-03 Scm Corporation Cathodic electrocoating process
GB2001991B (en) * 1977-06-30 1982-01-06 Shell Int Research Preparation of polyglycidyl ethers of polyhydric phenols
US4174333A (en) * 1978-11-02 1979-11-13 Ppg Industries, Inc. Carboxylated amide polymers and coating compositions containing same
DE2914297C2 (de) * 1979-04-09 1981-10-01 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Polyadditionsprodukten aus Ammoniak und Epoxidverbindungen und ihre Verwendung
JPS56116717A (en) * 1980-02-20 1981-09-12 Yuka Shell Epoxy Kk Preparation of novolak-type epoxy resin
GB8405139D0 (en) * 1984-02-28 1984-04-04 Shell Int Research Binders for thermosetting coating compositions
EP0127915B1 (en) * 1983-06-03 1988-12-07 Shell Internationale Researchmaatschappij B.V. Novel polyglycidyl ethers, their preparation and their use as thermosetting coating compositions
GB8315230D0 (en) * 1983-06-03 1983-07-06 Shell Int Research Polyglycidyl ethers
US4686248A (en) * 1984-02-28 1987-08-11 Shell Oil Company Preparation of binders for coatings, thermosetting coating compositions and their use
JPS62100520A (ja) * 1985-10-25 1987-05-11 Hitachi Ltd エポキシ樹脂組成物

Also Published As

Publication number Publication date
KR960006083B1 (en) 1996-05-08
DE3785251D1 (de) 1993-05-13
JP2525610B2 (ja) 1996-08-21
EP0251360B1 (en) 1993-04-07
CA1283994C (en) 1991-05-07
EP0251360A2 (en) 1988-01-07
ES2053520T3 (es) 1994-08-01
JPS6323979A (ja) 1988-02-01
US4772669A (en) 1988-09-20
DE3785251T2 (de) 1993-07-15
GB8616162D0 (en) 1986-08-06
EP0251360A3 (en) 1989-10-18

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