KR870007968A - Coated substrate - Google Patents

Coated substrate Download PDF

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KR870007968A
KR870007968A KR870001077A KR870001077A KR870007968A KR 870007968 A KR870007968 A KR 870007968A KR 870001077 A KR870001077 A KR 870001077A KR 870001077 A KR870001077 A KR 870001077A KR 870007968 A KR870007968 A KR 870007968A
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weight
parts
polymer
group
ethylenically unsaturated
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KR870001077A
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Korean (ko)
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조재프 마리아 월헬퍼스 클래생 페테
드 베에 랙
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월리암 번스
폴리사 파이낸셜 서비시즈 소시에테 아노님
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/10—Latex
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L13/00—Compositions of rubbers containing carboxyl groups
    • C08L13/02—Latex
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02—Copolymers with acrylonitrile
    • C08L9/04—Latex
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425—Cellulose series
    • D04H1/4258—Regenerated cellulose series
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326—Condensation or reaction polymers
    • D04H1/4334—Polyamides
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326—Condensation or reaction polymers
    • D04H1/435—Polyesters
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • D04H1/645—Impregnation followed by a solidification process
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/904—Artificial leather
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31652—Of asbestos
    • Y10T428/31663—As siloxane, silicone or silane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2033—Coating or impregnation formed in situ [e.g., by interfacial condensation, coagulation, precipitation, etc.]

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paper (AREA)
  • Laminated Bodies (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

내용 없음No content

Description

피복 기판Coated substrate

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (10)

C3-6알켄일 나트릴 약 10 내지 약 45중량%, C4-6큰쥬계이트다올레핀 약 36 내지 85중량%, C1-4알켄 일라디칼 또는 염소 또는 브롬원자에 의해 미치환 또는 치환될 수 있는 C8-12비닐 방향족 단량체 100 내지 약 60%와 아크릴 또는 메타크릴산의 C1-2알킬 에스테르의 0 내지 40중량%로 구성되는 단량체 혼합물의 약 5 내지 20중량%, 적어도 하나의 C3-6에틸렌계 불포화 카르복실산 약 0.5 내지 10중량%와 C3-6에틸렌계 불포화 카르복실산의 아미드의 N-C1-4알킬을 유도체 약 0.1 내지 5중량%와로 이루어지는 중합체를 약 45 내지 60중량% 함유하는 라렉스에 있어서, 입상 무기물 중전계 60중량부와 상기 중합체 100중량부와로 본질적으로 이루어지는 화합물의 0.2 내지 0.3mm 두께 필름이 적어도 약 65kg/cm2의 인장강도를 지니는 것을 특징으로 하는 라텍스.About 10 to about 45 weight percent of C 3-6 alkenyl natryl, about 36 to 85 weight percent of C 4-6 large jugidapolyolefin, unsubstituted or substituted by C 1-4 alkenyl radicals or chlorine or bromine atoms About 5 to 20%, at least one C, of a monomer mixture consisting of from 100 to about 60% of a C 8-12 vinyl aromatic monomer, and 0 to 40% by weight of a C 1-2 alkyl ester of acrylic or methacrylic acid 3-6 ethylenically unsaturated carboxylic acid to about 0.5 to 10% by weight of C 3-6 ethylenically unsaturated carboxylic a NC 1-4 alkyl amide derivatives of the acid from about 0.1 to 5% by weight waro a polymer comprising from about 45 to 60 A weight percent LaRex containing 0.2 to 0.3 mm thick film of a compound consisting essentially of 60 parts by weight of a granular inorganic medium field and 100 parts by weight of said polymer has a tensile strength of at least about 65 kg / cm 2 . Latex. 제 1 항에 있어서, 상기 중량체가 C3-6알켄일 니트틸 약 30 내지 40중량%, C4-6콘쥬계이트디올레핀 약 40 내지 약 55중량%, C1-4알킬라디칼 또는 염소 또는 브롬원자에 의해 미치환 또는 치환될 수 있는 C8-12비닐 방향족 단량체 약 5 내지 약 15중량%, 적어도 하나의 C3-6에틸렌계 불포화 카르복실산 약 2 내지 약 6중량%와 아크릴아미드 또는 메타크릴아 미드의 N-C1-4알킬을 유도체 약 0.5 내지 약 2중량%와로 이루어지는 것을 특징으로 하는 라텍스.The method of claim 1, wherein the weight is about 30 to 40% by weight of C 3-6 alkenyl nitryl, about 40 to about 55% by weight of C 4-6 conjugateddiolefin, C 1-4 alkylradical or chlorine or bromine About 5% to about 15% by weight of C 8-12 vinyl aromatic monomer unsubstituted or substituted by an atom, about 2% to about 6% by weight of at least one C 3-6 ethylenically unsaturated carboxylic acid and acrylamide or meta A latex, comprising from about 0.5 to about 2 weight percent of a derivative of NC 1-4 alkyl of krillamide. 제 2 항에 있어서, 상기 알켄일 니트릴이 아크릴로니트로릴 및 메타크릴로니트릴로 이루어지는 군으로부터 선택되며, 상기 C4-6콘쥬계이트 디올레핀의 부타디엔 및 이소프렌으로 이루어지는 군으로부터 선택되고, 상기 비닐 방향족 단량체가 스티렌이며, 상기 C3-6에틸렌계 불포화 카르복실산이 아크릴산, 메타크릴산 및 이타콘산으로 이루어지는 군으로부터 선택되고, 상기 아미드가 N-메틸 아크릴 아미드 및 메틸을 메타크릴아미드로 이루어지는 군으로 부터 선택되는 것을 특징으로 하는 라텍스.The compound of claim 2, wherein the alkenyl nitrile is selected from the group consisting of acrylonitrile and methacrylonitrile, and is selected from the group consisting of butadiene and isoprene of the C 4-6 conjugated diolefin, wherein the vinyl The aromatic monomer is styrene, the C 3-6 ethylenically unsaturated carboxylic acid is selected from the group consisting of acrylic acid, methacrylic acid and itaconic acid, and the amide is a group consisting of N-methyl acrylamide and methyl methacrylamide Latex, characterized in that selected from. 부직 섬유상 웨브를 합성중합체의 타텍스 화합물의 웨브 약 30 내지 150중량%에 함침시키고 화합물을 결화시키고 경화시키는 것으로 이루어지는 강화 시이트상 물질을 제조하는 방법에 있어서, 상기 화합물 이 상기 중합체 건조중량 100부, 입상무기물 충전제 약 40 내지 100중량부, 유효량의 결화계 및 임의의 경화페이스트 당 C3-6알켄일 니트릴 약 10 내지 약 45중량%, C4-6콘쥬계이트디올레핀 약 36 내지 약 85중량%,C1-4알킬라디칼 또는 브롬 또는 염소원자에 의해 미치환 또는 치환될 수 있는 C8-12비닐 방향족 단량체 100 내지 약 60%와 아크릴 또는 메타크릴산의 C1-2알킬 에스테르 0 내지 40중량%로 이루어지는 단량체 혼합물 약 5 내지 20중량%, 적어도 하나의 C3-6에틸렌계 불포화 카르복실산의 약 0.5 내지 10중량%와 C3-6에틸렌계 불포화 카르복실산의 아미드의 N-C1-4알킬올 유도체의 약 0.1 내지 약 5중량%의 중합체를 약 50 내지 약 65중량% 함유하는 라텍스로 이루어지는 것을 특징으로 하는 강화 시이트상 물질의 제조방법.A method for preparing a reinforced sheet-like material comprising impregnating a nonwoven fibrous web in about 30 to 150 weight percent of a web of a texex compound of a synthetic polymer and curing and curing the compound, the compound comprising 100 parts by weight of the polymer dry weight, About 40 to 100 parts by weight of particulate inorganic filler, about 10 to about 45 weight percent of C 3-6 alkenyl nitrile, and about 36 to about 85 weight percent of C 4-6 conjugated diolefin per effective amount of the binder system and any curing paste 100 to about 60% of C 8-12 vinyl aromatic monomer, which may be unsubstituted or substituted by C 1-4 alkyl radicals or bromine or chlorine atoms and 0 to 40 weight of C 1-2 alkyl esters of acrylic or methacrylic acid % monomer mixture of about 5 to 20% by weight consisting of at least one C 3-6 ethylenically unsaturated carboxylic acid to about 0.5 to 10% by weight of C 3-6 ethylenically unsaturated carboxylic acid of the amino A method for manufacturing a reinforced sheet material which comprises a phase of about 0.1 to about 5 wt% of a polymer of a NC 1-4 alkylol derivative latex containing about 50 to about 65% by weight. 제 4 항에 있어서, 상기 중합체가 C3-6알켄일 니트릴의 약 30 내지 40중량%, C4-6콘쥬계이트 디올레 핀 약 40 내지 약 55중량%, C1-4알킬라디칼 또는 염소 또는 브룸원자에 의해 미치환 또는 치환될 수 있는 C8-12비닐 방향족 단량체 약 5 내지 약 15 중량%, 적어도 하나의 C3-6에틸렌계 불포화 카르복실산 약 2내지 약 6중량%와 아크릴 아미드 또는 메타크릴 아미드의 N-C1-4알킬올 유도체의 약 0.5 내지 약 2중량%와로 이루어지는 것을 특징으로 하는 제조 방법.The method of claim 4, wherein the polymer is about 30 to 40% by weight of C 3-6 alkenyl nitrile, about 40 to about 55% by weight of C 4-6 conjugated diolepin, C 1-4 alkylradical or chlorine Or about 5% to about 15% by weight of C 8-12 vinyl aromatic monomer unsubstituted or substituted by a broom atom, about 2% to about 6% by weight of at least one C 3-6 ethylenically unsaturated carboxylic acid and acrylamide Or from about 0.5 to about 2 weight percent of an NC 1-4 alkylol derivative of methacryl amide. 제 5 항에 있어서, 상기 경화 페이스트가 존재하지 않으며 상기 입상 무기물 충전제가 상기 중합체 100중량부당 약 50 내지 약 70중량부의 양으로 내재하는 것을 특징으로 하는 방법.6. The method of claim 5 wherein the curing paste is absent and the particulate inorganic filler is in an amount of from about 50 to about 70 parts by weight per 100 parts by weight of the polymer. 제 6 항에 있어서, 상기 알켄일 니트릴이 아크릴니트릴과 메타크릴로 니트릴로 이루어지는 군으로 부터 선택되며, 상기 C4-6콘쥬계이트 디올레핀이 부타디엔 및 이소프렌으로 이루어지는 군으로부터 선택되고, 상기 비닐 방향족 단량체가 스티렌이며, 상기 C3-6에틸렌계불 포화 카르복실산이 아크릴산, 메타크릴산 및 이타콘산으로 루어지는 이군으로부터 선택되고, 상기 아미드가 N-메틸올 아크릴 아미드 및 N-메틸올 메타크릴아미드로 이루어지는 군으로부터 선택되는 것을 특징으로 하는 방법.7. The vinyl aromatic of claim 6, wherein the alkenyl nitrile is selected from the group consisting of acrylonitrile and methacrylonitrile, and the C 4-6 conjugated diolefin is selected from the group consisting of butadiene and isoprene, and the vinyl aromatic The monomer is styrene, and the C 3-6 ethylenically saturated carboxylic acid is selected from the group consisting of acrylic acid, methacrylic acid and itaconic acid, and the amide is N-methylol acrylamide and N-methylol methacrylamide. And a method selected from the group consisting of: 제7 항에 있어서, 상기 결화제가 다음 화학식 (R3)SiO[(R)2SiO]P[(R)(H)SiO]|QSi(R)3의 실리콘 에레트로부터 제조되며, 중합체 100중량부당 약 0.05 내지 약 2중량부의 양으로 내재하는 것을 특징으로하는 방법.8. The composition of claim 7, wherein the binder is represented by the formula (R 3 ) SiO [(R) 2 SiO] P [(R) (H) SiO] | A process made from a silicone ele of Q Si (R) 3 and intrinsic in an amount of about 0.05 to about 2 parts by weight per 100 parts by weight of the polymer. 제 7 항에 있어서, 상기 결화제가 중합체 100중량부 당 약 5 내지 10중량부의 양으로 내재하며, 1:1 내지 1:3의 중량비로 아민 또는 암모늄 발생화합물과, C15-20포화 알코올 및 산화 에틸렌 약 20∼30물의 축합생성물와의 부가물인 유화제의 혼합물로 이루어지는 것을 특징으로 하는 방법.The method according to claim 7, wherein the binder is in an amount of about 5 to 10 parts by weight per 100 parts by weight of the polymer, the amine or ammonium generating compound, C 15-20 saturated alcohol and And a mixture of emulsifiers which are adducts with condensation products of about 20-30 ethylene oxide. 특허청구범위 제 5 항에 따라 제조된 강화 시이트상 물질.Reinforcing sheet-like material prepared according to claim 5. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR870001077A 1986-02-13 1987-02-10 Coated substrate KR870007968A (en)

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NL8600359A NL8600359A (en) 1986-02-13 1986-02-13 LATEX, PROCESS FOR THE MANUFACTURE OF A CONSOLIDATED FILES AND CONSOLIDATED FILES, MADE BY THE METHOD.
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