KR870000935B1 - Polyester nontwist dipersed yarn's making method - Google Patents
Polyester nontwist dipersed yarn's making method Download PDFInfo
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- KR870000935B1 KR870000935B1 KR1019850003646A KR850003646A KR870000935B1 KR 870000935 B1 KR870000935 B1 KR 870000935B1 KR 1019850003646 A KR1019850003646 A KR 1019850003646A KR 850003646 A KR850003646 A KR 850003646A KR 870000935 B1 KR870000935 B1 KR 870000935B1
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
- D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
- D02J1/18—Separating or spreading
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D10/00—Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
- D01D10/02—Heat treatment
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/096—Humidity control, or oiling, of filaments, threads or the like, leaving the spinnerettes
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/098—Melt spinning methods with simultaneous stretching
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
- D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
- D02J1/22—Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
- D02J1/225—Mechanical characteristics of stretching apparatus
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
- D02J13/00—Heating or cooling the yarn, thread, cord, rope, or the like, not specific to any one of the processes provided for in this subclass
- D02J13/005—Heating or cooling the yarn, thread, cord, rope, or the like, not specific to any one of the processes provided for in this subclass by contact with at least one rotating roll
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical Treatment Of Fibers During Manufacturing Processes (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Artificial Filaments (AREA)
Abstract
Description
제1도는 본 발명의 공정을 표시한 개략도이고,1 is a schematic representation of the process of the invention,
제2도는 본 발명의 실시예에서 시험한 유제를 사용하였을 때의 방사(yarn)균 제도이다.2 is a yaw germ system when using the emulsion tested in the Examples of the present invention.
* 도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings
1 : 구금 2 : 폴리에스테르사()1: detention 2: polyester yarn ( )
3 : 냉각장치 4,6 : 방사가이드3: cooling device 4,6: radiation guide
5 : 오일링로울러 7 : 분리가이드5: Oil ring roller 7: Separation guide
8 : 인취로울러 9 : 연신열처리로울러8: drawing roller 9: drawing heat treatment roller
10 : 분사가이드 11 : 파지점 가이드10: injection guide 11: gripping point guide
12 : 귄취가이드12: Gunch Guide
a : 함수유제의 방사균제도(均製度) b, c : 비함수유제의 방사균제도a: radioactive bactericide of water-containing emulsion b, c: radioactive bactericide of non-water-containing emulsion
본 발명은 특수 직물용으로 사용되는 폴리에스테르 무연분섬용사(無撚分纖用)를 제조하는 방법에 관한 것으로서, 특히 방사와 연신을 동시에 실시하 단순한 공정이면서도 안정되게 분섬용사를 제조하는 방법에 관한 것이다.The present invention is a polyester lead-free spun yarn used for special fabrics (無 撚 分 纖 用 In particular, the present invention relates to a method for producing a spraying spray in a simple and stable process by simultaneously spinning and stretching.
종래의 분섬용원사는 방사기에서 방사속도 900내지 15000m/min으로 함수유제 (含水油劑)를 부여하여 권취하고 이렇게 방사된 미연신사를 다시 연신공정을 거친 다음 열처리로 하여서된 10내지 12T/M을 갖는 유연연신사를 사용하였는바, 이와같은 제조방법으로 얻어지는 종래의 연신사는 많은 공정을 거쳐야하므로 제조단가가 비쌀뿐 아니라 방사공정, 연신공정 및 열처리공정 등 각 공정에서 영향을 주는 외적인 저해요인이 상승적으로 작용하여 분섬용사에 적합한 균일한 원사를 생산하는데 많은 문제점을 갖고 있었다.Conventional spinning yarns are wound by imparting a water-containing emulsion at a spinning speed of 900 to 15000 m / min in a spinning machine, and the unstretched yarn thus spind is subjected to a stretching process and then subjected to heat treatment to have a 10 to 12T / M. Flexible stretched yarns are used, which means that the conventional stretched yarns obtained by such a manufacturing method have to go through a number of processes, resulting in a high manufacturing cost and an increase in external inhibitory factors such as spinning, stretching, and heat treatment. It had many problems in producing uniform yarns suitable for dispersing spraying.
즉, 이러한 유연분섬용사를 사용하여 분섬사를 생산하였을 경우의 문제점으로는That is, the problem in the case of producing a branched yarn using such a flexible branched yarn
첫재, 방사된 미연신사를 연신하기 위한 크릴(Creel)의 해사(解)과정에서 자연꼬임이 10내지 12T/M정도 발생하게 되고 연신사를 귄취할때 보빈(Bobbin)의 권량이 3.0kg이하로 제한되고, 분섬과정에서 매듭이 4내지 6EA/kg정도 발생되기 때문에 제직할 경우 제품의 고급화가 곤란하고,First, Creel's dismissal to stretch the undrawn yarn Natural twist occurs in the process of 10 to 12T / M, and the bobbin volume of the bobbin (Bobbin) is limited to less than 3.0kg when weaving the drawing yarn, weaving because the knot is generated 4 ~ 6EA / kg during the process If you do not have high quality products,
둘째, 유연분섬용사를 분섬할때 재래식 분섬기를 사용함으로 인해 발생되는 잔류꼬임으로 제거하면서 분섬을 실시하여야 하기 때문에 공정의 복잡성은 물론 분섬성이 불량하게 되고 분섬속도도 100내지 150m/min으로 제한됨으로 결국 생산성이 낮고 생산비용도 매우 높은 것으로 지적되고 있다.Second, since the splitting process should be performed while removing the residual twist generated by using the conventional splitting machine when splitting flexible spraying spray, the complexity of process as well as the splitting performance are poor and the splitting speed is limited to 100 to 150m / min. As a result, it is pointed out that productivity is low and production cost is very high.
또한, 분섬용사의 제조시 사용되는 유제의 함수율에 따라 필라멘트의 교락이 발생하기 쉬우며 융착이 발생하기 쉬운 바, 융착 및 교락의 발생원인은 멀티필라멘트가 높은 속도로 연신 열처리 로울러상에 통과될때 필라멘트간의 이동이 심하고 자유운동(필라멘트 마이크레이션)이 발생하기 쉽기 때문인 것이다.In addition, the filament is easily entangled and the fusion is easy to occur depending on the moisture content of the emulsion used in the production of the divided yarn, the cause of fusion and entanglement is the filament when the multifilament is passed on the stretch heat treatment roller at a high speed This is because the movement between the liver is severe and free movement (filament microphoneation) is likely to occur.
특히, 고온으로 열처리하기 때문에 단사간의 가벼운 융착이 발생되기 쉽고 교락이 생기기 쉬우므로 분섬용사를 생산할 때 사용되는 유제(油劑)타입에 따라 연신 열처리 로울러에서 품질의 큰 차이를 나타내게 되는 것이다.In particular, because the heat treatment at high temperature is easy to cause light fusion between single yarns and easy to entangle, there is a large difference in quality in the stretch heat treatment rollers according to the type of emulsion (때) used when producing the divided yarn.
앞서 설명한 함수유제를 부착시키는 종래의 방법을 이용할 경우에는 방사시 부여하는 함수유제의 수분량이 많게 되면 강력이 저하되고, 또 미연신 필라멘트의 외칙에 일종의 구정층(求晶層)이 발생하여 그것이 연신중에 열에 의하여 급속하게 성장하게 되면 연신반(延伸班)을 발생시키고 균제도가 불량해지며, 이로인하여 필라멘트 간의 이동이 심해지고 가벼운 융착현상이 나타나기 쉽다. 이때, 최외 구정층의 두께는 부여유제의 수분량에 따라 결정되는 것이지만 같은 정도의 구정층이라 하더라도 방사속도가 높게되면 변형이 급격히 일어나서 절사되기 쉽다.In the conventional method of attaching the water-containing emulsion described above, when the water content of the water-containing emulsion applied during spinning becomes large, the strength decreases, and a type of spherical layer is generated in the outer ring of the unstretched filament. Rapid growth by heat leads to drawboards and poor homogeneity, resulting in severe filament migration and mild fusion. At this time, the thickness of the outermost spherical layer is determined according to the moisture content of the imparting oil, but even if the spherical layer of the same degree, if the spinning speed is high, deformation occurs rapidly and is easily cut off.
결국 종래의 함수유제부여방법은 수분함량이 많으면 상기와 같은 수많은 문제점을 내포하고 있기 때문에 제조된 분섬용사의 질을 상당히 저하시키는 바, 함수유제를 사용할 경우 수분율을 낮게하는 것은 극히 어려운 문제였다.As a result, the conventional method for imparting a water-containing emulsion contains a number of problems as described above when the water content is high, and thus, significantly lowers the quality of the prepared spun-spray spray. When the water-containing emulsion is used, it is extremely difficult to lower the water content.
따라서, 본 발명은 상술한 바와 같은 종래의 분섬용사의 제조에서 나타난 여러가지 문제점을 해소하기 위한 것으로서, 비함수유제(STRAIGHT TYPE)를 오일링하면서 직접 방사연신하며, 열처리공정중 열처리로울러상에서 필라멘트간의 이동이 적고 연신중에 열에 의하여 연신반이 발생치 않으며 사()의 균제도가 양호하고 분섬성이 좋을 뿐 아니라 제조공정도 단순하여 제조경비도 절감시킬 수 있는 폴리에스테르 무연분섬용사의 제조방법을 제공하는데 그 목적이 있다.Accordingly, the present invention is to solve the various problems in the manufacturing of the conventional spraying yarns as described above, and directly spin-drawn while oiling a non-functional oil (STRAIGHT TYPE), the movement between the filament on the heat treatment roller during the heat treatment process There is little and no drawing board is generated by heat during drawing. The purpose of the present invention is to provide a method for producing a polyester smoke-free spun yarn which is good in homogeneity and good dispersibility and can reduce manufacturing cost due to its simple manufacturing process.
이하 본 발명을 첨부된 도면과 함께 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.
본 발명은 열가소성 폴리에스테르를 용융방사시켜서 분섬용 필라멘트사를 제조함에 있어서, 구금(1)으로부터 폴리에스테르(2)를 토출시켜 이를 교화한 후 오일링(oil ing)시키되 전후에 방사가이드(4,6)가 위치된 오일로울러(5)를 이용하여 점도가 1내지 5CTS인 비함수유제(非含水油劑)를 미연신사 단위무게당 0.3내지 1.4%가량되게 부착시켜 오일링시킨 다음, 연신 열처리 로울러(9)를 사용하여 직접 연신후에 3000m/min이상의 귄취속도로 드럼당 7내지 10kg정도가 되게 귄취함을 특징으로 하는 폴리에스테르 무연분섬용사를 제조하는 방법이다.In the present invention, in the manufacture of filament yarn for dispensing filament yarn by melt spinning thermoplastic polyester, the polyester (2) is discharged from the mold (1), the oil is edified and then the spinning guide (4, Using the oil roller (5) in which 6) is located, attach a non-water-containing oil having a viscosity of 1 to 5CTS to 0.3 to 1.4% per unit of unstretched yarn to oil it, and then stretch the heat treatment roller. (9) is a method for producing a polyester smoke-free island spraying, characterized in that the odor after the direct stretching to 7 to 10kg per drum at a odor speed of more than 3000m / min.
미설명부호 3은 냉각장치, 7은 분리가이드, 8은 인취로울러, 10은 분사가이드, 11은 파지점로울러, 12는 귄취장치이다.Reference numeral 3 is a cooling device, 7 is a separation guide, 8 is a draw roller, 10 is a spray guide, 11 is a grip point roller, 12 is a odor device.
이와같은 본 발명의 제조공정을 더욱 상세히 설명하면 다음과 같다.When explaining the manufacturing process of the present invention in more detail as follows.
제1도를 참고하여 본 발명의 제조공정을 설명하면, 본 발명은 구금(Ⅰ)에서 토출된 폴리에스테르(2)실가닥이 냉각장치(3)를 통하여 냉각, 고화(固化)된 후에 방사가이드(4, 6)에 안내되어 오일링로울러(5)에 접촉되면서 오일링하는 것이다. 이때 오일링된 멀티필라멘트는 방사가이드(4)에 의해 단사가 분할되어 본 발명에 따른 비함수유제의 부착이 이루어진 다음, 분리가이드(7)에 안내되면서 가열된 인취로울러(8)에서 예열되어 다시 연신 열처리로울러(9)와의 사이에서 일정배율로 연신된다. 이렇게 연신되면서 분사가이드(10)에 의해 분리된 멀티필라멘트는 파지점가이드(11)에 의해 접속되면서 귄취장치(12)에서 권취되는 것이다.Referring to FIG. 1, the manufacturing process of the present invention will be described. The present invention is directed to a spinning guide after the polyester (2) yarn strand discharged from the mold (I) is cooled and solidified through the cooling device (3). Guided to (4, 6) is to oil ring while contacting the oil ring roller (5). At this time, the oiled multifilament is divided into single yarns by the spinning guide 4 to be attached to the non-water-containing emulsion according to the present invention, and then preheated and heated again in the
본 발명에 따르면 일반적으로 구성본수가 4내지 12본이며 연신후의 단사데니어가 5내지 30데니어인 것이 좋다.According to the present invention, it is generally preferred that the number of components is 4 to 12 and the single yarn denier after the stretching is 5 to 30 denier.
본 발명은 이와같이 종래방식의 방사된 미연신사를 귄취하는 것이 아니라 직접 연신시켜서 무연연신사를 제조하는 것이며, 분섬성 향상을 위해서 비함수유제(STRAI GHT TYPE)를 사용하는 것으로서, 본 발명에 의하면 종래보다 월등히 우수한 분섬용사가 제조될 수 있는 것이다.The present invention is to produce a lead-free stretched yarn by stretching directly, rather than twisting the spun undrawn yarn of the conventional manner, and using a non-water-containing oil (STRAI GHT TYPE) to improve the dispersibility, according to the present invention It is possible to produce a superior spraying yarn better.
이러한 본 발명을 실시예에 의거 상세히 설명하면 다음과 같다.The present invention will be described in detail with reference to Examples.
[실시예]EXAMPLE
제1도에 예시된 장치를 이용하여 IV 0.64(OCP법)의 폴리에틸렌 텔레프탈레이트를 290℃에서 용융방사후 직접 연신한 다음, 표1에서와 같이 에멀죤유제와 비함수유제를 구분, 변경하여 사용하고 가열한 후, 인취로울러(8)의 속도 및 연신 열처리 로울러 (9)의 속도를 변경하면서 각각 분섬용사를 제조하여 방사균제도 및 분섬성을 비교 조사하였다.The polyethylene telephthalate of IV 0.64 (OCP method) was directly stretched after melt spinning at 290 ° C using the apparatus illustrated in FIG. 1, and then the emulsion and non-water emulsions were classified and used as shown in Table 1 below. After heating and heating, the spinning spraying agent was prepared while changing the speed of the take-out
여기서 사용한 비함수유제(A)는 20℃의 실온에서 5CTS의 정도를 갖으며 그 조성물로써는 광물유(65%), 고급알코올에스테르(25%), 고급알코올에테르(7%), 인산염(3%), 오일부착량(0.8%)를 함유하고 있는 것이며, 여기서 사용한 함수유제(B), 즉 에멀죤유제는 비함수유제(A)의 조성물을 10%로 희석시킨 유제이다.The non-water-containing oil (A) used here has a degree of 5CTS at room temperature of 20 ° C, and the composition includes mineral oil (65%), higher alcohol ester (25%), higher alcohol ether (7%), and phosphate (3%). The oil coating amount (0.8%) is contained, and the water-containing emulsion (B), that is, the emulsion zone emulsion, used here is an emulsion obtained by diluting the composition of the non-water-containing emulsion (A) to 10%.
[표 1]TABLE 1
표1에서 나타낸 바와같이 상기의 실시예에서 비교예로써 에멀죤유제(B)를 이용하여 분섬용사를 제조한 경우 본 발명의 방법에 비하여 각종 물성이 현저하게 나쁜 것으로 나타나 본 발명의 방법이 우수함을 알 수 있다.As shown in Table 1, when the powdered spray was prepared using the emulsion oil (B) as a comparative example in the above embodiment, various physical properties were significantly worse than those of the present invention, indicating that the method of the present invention is excellent. Able to know.
특히, 제2도를 참조하여 보면 (a)는 비교예 1 및 2의 경우이고 (b) 및 (c)는 각각 실시예 1 및 실시예 2의 경우를 나타낸 균제도로서, 이로부터 에멀죤유제를 이용하여 제조대 분섬용사는 방사균제도가 극히 불량한데 비하여 본 발명의 방법, 즉 비함수유제를 사용하여 직접 방사연신하여 분섬용사를 제조한 경우는 방사균제도가 좋음을 알 수 있다. 또한, 에멀죤유제를 사용한 종래방법은 염반 발생이 심하여 융착현상으로 인해 분섬이 불가능한 것에 비하여, 본 발명의 제품은 염반발생 융착현상이 없는 양호한 제품인 것으로 나타났다.In particular, referring to Figure 2 (a) is a case of Comparative Examples 1 and 2 and (b) and (c) is a bactericide showing the case of Example 1 and Example 2, respectively, from which the emulsion emulsion In contrast, the production-dispersed spraying spray is extremely poor in comparison with the poorly-developed spraying agent, in which case the spinning spraying agent is manufactured by direct spinning and stretching using the non-water-containing emulsion. In addition, the conventional method using the emulsion emulsion has been shown to be a good product without the occurrence of acupuncture fusion phenomenon, compared to the fact that the separation of the salt is not possible due to the fusion phenomenon is impossible.
상술한 바와같이 본 발명에 따른 폴리에스테르 무연분섬용사는 종래의 함수유제를 사용한 분섬용 원사와는 달리 비함수유제를 급여하였기 때문에 사균제도가 양호하고 분섬성이 매우 양호한 분섬용사의 생산이 가능하며, 연신중에 열에 의해서도 연신반이 발생하지 않으며, 수분율도 함수유제에 비해 자유로이 조절할 수도 있고, 방사균제도가 매우 양호하여 고락 및 융착현상이 발생되지 않아 분섬성이 좋은 분섬용사생산이 가능하며, 또한 제조공정이 복잡하지 않고 번거롭지 않는 단순공정이므로 연신사의 제조단가가 싸게 소요될 뿐만 아니라, 방사된 미연신사를 귄취하지 않고 직접 연신시키므로서 각 공정에서 발생되는 외적인 저해요인의 작용도 극소화 할 수 있어 물성이 좋은 분섬용 원사를 생산할 수 있는 효과 등 여러가지 잇점이 있는 것이다.As described above, the polyester lead-free spun yarn according to the present invention is supplied with a non-water-containing emulsion unlike a conventional yarn for spinning using a water-containing emulsion, so that a good bactericidal agent can be produced, and the production of a very good splitting yarn is possible. In addition, the drawing board does not occur by heat during drawing, and the moisture content can be adjusted freely compared to the water-containing emulsion, and the spinning bacterium is very good, so that the sedimentation and spraying production can be produced with good splitting properties. As the process is not complicated and cumbersome, it is not only a simple process, but also lowers the manufacturing cost of the drawn yarn, and directly draws the unstretched unstretched yarn, thus minimizing the effects of external inhibitors generated in each process. With various advantages, such as the effect of producing yarn for splitting The.
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KR1019850003646A KR870000935B1 (en) | 1985-05-28 | 1985-05-28 | Polyester nontwist dipersed yarn's making method |
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