KR860004137A - Detergent composition containing ethoxylated amine oxide to prevent soil decontamination / re-deposition - Google Patents

Abstract

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Description

Detergent composition containing ethoxylated amine oxide to prevent soil decontamination / re-deposition

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Claims (53)

About 1-75% by weight of non-ion, characterized by containing about 0.05-95% by weight of a water-soluble amine oxide having a soil decontamination / predeposition resistance selected from the group consisting of (1)-(5), Detergent composition consisting of anionic, zwitterionic or zwitterionic detergent surfactants or mixtures thereof. (1) an ethoxylated monoamine oxide of formula (I) below; (XL) ₃ -N... … O (Ⅰ) (2) an ethoxylated amine oxide of the following structural formulas (IIA), (IIB) or (IIC); Where M ¹ or Group; M ² each or At least one M ² is Ki) (3) an ethoxylated amine oxide of the following structural formula (III); (4) an ethoxylated amine oxide polymer composed of one polymer backbone and at least two M ³ groups and at least one LX group, wherein M ³ is an amine oxide group attached to or incorporated into the polymer backbone and L is a group Linking M ³ and X or group X to the polymer backbone). (5) mixtures thereof; In the above formulas, Or -O-, R is H or C ₁ -C ₄ alkyl or hydroxyalkyl, R ¹ is C ₂ -C ₁₂ alkylene, hydroxyalkylene, alkenylene, arylene or alkarylene or any ON bond C ₂ -C ₃ oxyalkylene containing about 2-20 oxyalkylene units under conditions which are not formed, and R ² is each C ₁ -C ₄ alkyl or hydroxyalkyl or -LX or two R ² together form-(CH ₂ ) _r -A ^2- (CH ₂ ) _s- , where A ² is -O- or -CH _2- , r is 1 or 2, s is 1 or 2 r + s is 3 or 4); R ³ is a substituted C ₃ -C ₁₂ alkyl, hydroxyalkyl, alkenyl, aryl or alkaryl group with p substituents; R ⁴ is C ₁ -C ₁₂ alkylene, hydroxyalkylene, alkenylene, arylene or alkylene or C ₂ containing about 2-20 oxyalkylene units under the condition that no ON bond is formed -C ₃ oxyalkylene; X is a nonionic group or a mixture of nonionic and anionic groups; L is a hydrophilic chain containing the polyoxyalkylene moiety-[(R ⁵ O) _m (CH ₂ CH ₂ O) _n ]-, where R ⁵ is C ₃ -C ₄ alkylene or hydroxy alkylene m and n are such numbers that-(CH ₂ CH ₂ O) _n -constitutes at least about 50% of the polyoxyalkylene moiety; n is at least about 12 in the monoamine oxide of formula I above, At least about 6 in the amine oxide of formula (IIA), (IIB) or (IIC), at least 3 in the amine oxide and amine oxide polymer of formula (III); p is 3-8; q is 1 or 0; t is 1 or 0 provided t is 1 when q is 1. The composition of claim 1 wherein the amine oxide is a monoamine oxide of formula (I) wherein m is zero and n is at least about 15. The composition of claim 1, wherein the amine oxide has the formula (IIA), (IIB), (IIC) or (III) and each R ² in the formula is -LX. The composition of claim 1, wherein the amine oxide has the formula (IIA) (IIB) or (IIC) and each R ¹ in the formula is C ₂ -C ₆ alkylene. The compound of claim 1, wherein the amine oxide has formula III and R ³ is a substituted C ₃ -C ₆ alkyl, hydroxyalkyl or aryl group; A ¹ tooth And p is 3-6. The method of claim 4 or 5, wherein M ¹ and M ² are each Attributable composition. The method of claim 1 wherein the amine oxide is polyurethane, polyester, polyether, polyamide, polyimide, polyacrylate, polyacrylamide, polyvinyl ether, polyalkylene, polyalkylene, polyalkyleneamine, A composition having a backbone selected from the group consisting of polyalkyleneimines, polyvinylamines, polyallylamines, polydiallylamines, polyvinylpyridine, polyaminotriazoles, polyvinyl alcohols, aminopolyureylenes and mixtures thereof . 8. The composition of any one of claims 4-7, wherein m is 0 and n is at least about 12. 8. The composition of claim 3 or 7, wherein m and n are such numbers that-(CH ₂ CH ₂ O) _n -will constitute at least about 85% by weight of the polyoxyalkylene moiety. 8. The composition of claim 7, wherein the ratio of group M ³ to group X is about 1: 1-1: 5. The composition of claim 10, wherein the units containing groups M ³ and LX make up about 50-100 of the polymer. The composition of claim 11, wherein the number of groups M ³ and LX are each about 3-40. 8. The composition of claim 7, wherein the polymer consists of units selected from those having the following structures (IV), (V) and (VI). Where A is Is; X is 0 or 1; R is H or C ₁ -C ₄ alkyl or hydroxy alkyl; R ¹ is C ₂ -C ₁₂ alkylene, hydroxyalkylene, alkenylene, cycloalkylene, arylene or alkarylene or about 2-20 groups under the condition that no 0-0 or ON bond is formed with A C ₂ -C ₃ oxyalkylene moieties containing oxyalkylene units; If X is 1 then R ² is A Except that is -R ⁵ -or-(OR ⁷ ) -OR ⁴ -under conditions that do not form any 0-0 or NO bond with _y or A and R ³ is Except when the -R ⁵ - or or - (R ⁷ O) _y -, or A and any 0-0 or ON coupling under conditions that do not form an -R ⁴ O-; If X is 0, then R ² is R ³ is -R ⁴ -and R ⁴ is C ₁ -C ₁₂ alkylene, hydroxyalkylene, alkenylene, arylene, or alkarylylene; R ⁵ is C ₁ -C ₄ alkyl or hydroxyalkyl; R ⁶ is H, C ₁ -C ₄ alkyl or hydroxyalkyl or-(R ⁴ ) _k -[(C ₃ H ₆ O) _m (CH ₂ CH ₂ O) _m -X; R ⁷ is C ₂ -C ₃ -alkylene or hydroxyalkylene; X is H, -R ⁸ or a mixture thereof, wherein R ⁸ is C ₁ -C ₄ alkyl or hydroxyalkyl; k is 0 or 1; m and n are at least about 85% by weight of the-(CH ₂ CH ₂ O) _m -moiety-[(C ₃ H ₆ O) _m (CH ₂ CH ₂ O) _m ] -part Is such a number that constitutes; m is 0- about 5; n is at least about 3; y is 2-about 20; u, v and w are at least two It is such a number that a group and at least two X groups exist. The compound of claim 13, wherein A is or Is; X is 1; R ¹ is C ₂ -C ₆ alkylene; R ² is -OR ⁴ -or (OR ⁷ ) _y- ; R ³ is -R ⁴ O- or-(R ⁷ O) _y- ; R ⁴ is C ₂ -C ₃ alkylene; R ⁵ is methyl; R ⁶ is H or C ₁ -C ₃ alkyl; R ⁷ is ethylene; X is H or methyl; k is 0; wherein m is 0 and y is 2-about 12. 8. A composition according to claim 7, wherein the polymer consists of units selected from those having the following structures (iii), (iii) and (iii). In the above structures Is; R is H or C ₁ -C ₄ alkyl or hydroxyalkyl; R ¹ is substituted C ₂ -C ₁₂ alkylene, hydroxyalkylene, alkenylene, arylene or alkarylene or C ₂ -C ₃ oxyalkylene; Each R ² is C ₁ -C ₁₂ alkylene, hydroxyalkylene, alkenylene, arylene or alxylene; Each R ³ is C ₁ -C ₄ alkyl or hydroxyal or is O- (R ² ) _k -[(C ₃ H ₆ O) _m (CH ₂ CH ₂ O) _n ] -X; R ⁴ is each C ₁ -C ₄ alkyl or hydroxyalkyl or two R ⁴ together form-(R ₂ ) _r -A ^2- (CH ₂ ) _s -wherein A ² is -O- or -CH _2- ; X is H, Or a mixture thereof, wherein R ⁵ is C ₁ -C ₄ alkyl or hydroxyalkyl; j is 1 or 0; k is 1 or 0; m and n are each such that the-(CH ₂ CH ₂ O) _n -part constitutes at least 85% by weight of the-[(C ₃ H ₆ O) _m (CH ₂ CH ₂ O) _n ] -part; m is 0- about 5; n is at least about 3; r is 1 or 2, s is 1 or 2, and r + s is 3 or 4; u, v and w are at least two It is such a number that a group and at least two X groups exist. The compound of claim 15, wherein A ¹ is Or -O-; R ¹ is -CH ₂ CH- or Is; R ² is C ₂ -C ₃ alkylene; R ³ is methyl; Each R ⁴ is methyl; X is H or methyl; j is 1; k is 0; m is zero. The composition of claim 13, 14 or 15 wherein v and w are each 0 and u is about 3-40. 8. A composition according to claim 7, wherein the polymer consists of units selected from those having the following structures (XIII), (XI) and (XII). In the above structures, R ¹ is C ₂ -C ₁₂ alkylene, hydroxyalkylene, alkenylene, cycloalkylene, arylene or alxarylene or under the condition of not forming any ON bond. C ₂ -C ₃ oxyalkylene moieties containing oxyalkylene units; R ² is C ₁ -C ₁₂ alkylene, hydroxyalkylene, alkenylene, arylene or alxarylene; R ³ is C ₁ -C ₄ alkyl or hydroxyalkyl or — (R ² ) _k -[(C ₃ H ₆ O) _m (CH ₂ CH ₂ O) _n ] -X; M ⁴ is Group; X is H, Or a mixture thereof, wherein R ⁴ is C ₁ -C ₄ alkyl or hydroxyalkyl; k is 1 or 0; m and n are _{- (CH 2 CH 2 O)} n - is _{- [(C 3 H 6 O} ) m (CH 2 CH 2 O) n] - in such a number and at least comprises about 85% by weight; m is 0- about 5; n is at least about 3; x, y and z are such numbers in which at least two X groups and at least two M ⁴ groups and at least two -NO groups exist. The compound of claim 18, wherein R ¹ is C ₂ -C ₆ alkylene; R ³ is a methyl or — (CH ₂ CH ₂ O) _n —H moiety; R ⁴ is methyl; X is H; k is 0; m is zero. 20. The composition of claim 18 or 19, wherein M is from about 70-100% Roof tiles 0- about 30% group, A composition which is a mixture of groups or mixtures thereof. The composition of claim 20, wherein x + y + z is 2-9. The composition of claim 20, wherein x + y + z is at least 10. 8. The composition of claim 7, wherein the polymer consists of units selected from those having the following structures (XVI) and (XVII). In the above structure, R ¹ is C ₁ -C ₁₂ alkylene, hydroxyalkylene, arylene or alxarylene; R ² is C ₁ -C ₄ alkyl or hydroxyalkyl; X is H, Or a mixture thereof, wherein R ⁵ is C ₁ -C ₄ alkyl or hydroxyalkyl; k is 1 or 0; m and n are each such that-(CH ₂ CH ₂ O) _n -constitutes at least about 85% of the-[(C ₃ H ₆ O) _m (CH ₂ CH ₂ O) _n ]-moiety; m is 0- about 5; n is at least about 3; x is 1 or 0; y is 1 when x is 0 and 0 when x is 1; u and v are at least two It is such a number in which a group and at least two X groups exist. The compound of claim 23, wherein R ² is methyl; X is H; wherein k is zero and X is zero. The compound of claim 24, wherein m is at least about 12; v is 0; wherein u is from about 2 to about 40. The composition of any one of claims 1-25, wherein it comprises about 1-3% by weight of amine oxide. 27. The composition of any one of the preceding claims, wherein it comprises about 0-80% by weight of a detergent builder. The composition of claim 1 wherein the amine oxime is an amine oxide polymer having the general formula: Wherein M ⁴ is 70-100% Roof tiles 0- about 30% Group or mixtures thereof; X is H; a is 0 or 1 and x + y + z is at least 2. ※ Note: The disclosure is based on the initial application.