KR860001044B1 - Sumigant for gemicide and insecticide - Google Patents
Sumigant for gemicide and insecticide Download PDFInfo
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- KR860001044B1 KR860001044B1 KR1019840006844A KR840006844A KR860001044B1 KR 860001044 B1 KR860001044 B1 KR 860001044B1 KR 1019840006844 A KR1019840006844 A KR 1019840006844A KR 840006844 A KR840006844 A KR 840006844A KR 860001044 B1 KR860001044 B1 KR 860001044B1
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- insecticide
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- alkaline earth
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
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- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
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- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
내용 없음.No content.
Description
본 발명은 살충 또는 살균약제(이하 유효 약제라 함)에 일반식 ROOCN = NCOOR (식중 R은 탄소수 1-3 의 알킬기 또는 알카리토금속이다)으로 표시되는 아조디카 복실산의 에스텔 또는 알카리토금속염을 발연기재로 배합하고 여기에 일정 온도 이상으로 가열하면 지속적으로 발열하는 발열제를 배합한 훈증용 살균, 살충제 조성물에 관한 것이다.The present invention discloses ester or alkaline earth salts of azodicarboxylic acids represented by the general formula ROOCN = NCOOR (wherein R is an alkyl group or an alkali metal) having a pesticide or bactericidal agent (hereinafter referred to as an effective drug). The present invention relates to a fumigating bactericidal and insecticide composition containing a heat generating agent that is continuously mixed with a base material and heated to a predetermined temperature or more.
일반적으로 살충, 살균제를 단시간에 집중적으로 휘산시키는 방법으로는 1) 유효 약제를 연소체와 배합하고 점화용 심지를 장치하여 금속 용기에 충전한 다음 심지에 점화시켜 연소체가 연소할 때 발생하는 열에 의하여 우효 약제가 휘산하도록 하는 방법. 2) 유효 약제를 유기 발포제와 배합하여 금속용기에 충전하고 외부에서 간접 가열하므로서 유효 약제의 가열에 의한 휘산과 분해 가스에 의한 휘산이 동시에 일어나게 하는 방법. 3) 유효 약제를 다공성 담체에 담지시키고 간접 가열함으로써 유효 약제가 휘산하도록 하는 방법이 있다. 그러나, 1)의 방법은 연소체의 급격한 연소로 고열이 발생하므로 유효 약제가 분해되고 유독가스가 발생하며, 화재의 우려가 있고, 2), 3)의 방법은 유효 약제를 광범위하게 휘산시키는 휘산력이 적다는 결점이 있다.In general, the method of intensively killing insecticides and fungicides in a short period of time includes: 1) mixing an effective drug with a combustion body, filling a metal container with an ignition wick, and then igniting the wick by the heat generated when the combustion body burns. Method for causing the activator to volatilize. 2) A method in which the active agent is mixed with an organic blowing agent to fill a metal container and indirectly heated from the outside to simultaneously generate volatilization by heating of the effective agent and volatilization by decomposition gas. 3) There is a method in which the effective agent is volatilized by supporting the effective agent in a porous carrier and indirectly heating it. However, in the method of 1), high heat is generated due to the rapid combustion of the combustion body, so the effective drug is decomposed and toxic gas is generated, and there is a risk of fire, and the methods of 2) and 3) are volatilized to volatilize the effective drug widely. The drawback is that the force is low.
따라서, 본 발명은 상기 1), 2), 3)의 단점을 보완키 위한 것으로 본 발명 조성물은 유효 약제에 아조디카 복실산의 에스텔 또는 알카리토금속염인 발연제와 일정 온도 이상으로 가열하면 그 후에는 외부가열이 없어도 자체 반응에 의하여 열을 발생하는 발열제를 배합한 조성물로서 본 발명에 사용되는 아조디카복실산의 에스텔 또는 알카리토금속 염으로는 아조디카복실산디에틸, 아조디카복실산디이소프로필, 아조디카복실산바륨 등이며, 그 배합량은 훈증온도나 훈증 속도에 따라 다르나 일반적으로 조성물 전체에 대하여 5-50%가 적당하며, 본 발명에 사용되는 발열제는 질산구와니딘, 멸라민, 치오요소, 초화면, 질산멸라민을 1종 이상 혼합한 것으로 그 배합량은 조성물 전체에 대하여 10-40%이다.Therefore, the present invention is to supplement the disadvantages of the above 1), 2), 3) The composition of the present invention is heated to a effective agent and a certain temperature or more than a certain temperature and a fuming agent which is an ester or alkaline earth salt of azodicarboxylic acid A composition containing a heating agent that generates heat by self-reaction even without external heating. Examples of the ester or alkaline earth salt of azodicarboxylic acid used in the present invention include azodicarboxylic acid diethyl, azodicarboxylic acid diisopropyl, and azodicarboxylic acid. Barium and the like, and the amount thereof varies depending on the fumigation temperature and the fumigation rate, but in general, 5 to 50% is appropriate for the whole composition, and the heat generating agent used in the present invention is a guwan nitrate, thoramin, thiourea, initial screen, At least one kind of anthracyan nitrate was mixed, and the compounding quantity is 10-40% with respect to the whole composition.
본 발명에 사용되는 유효 약제로는 종래부터 해충구제, 살균제로 사용되든 것이면 어느 것이나 사용가능한데 그 대표적인 것으로는 퍼머트린(Permethrin), 데카메트린 (Decamethrin)등의 피레트로이드계 살충제, 다이아지논(Diazinon), 디디브이피(D.D.V.P.), 피라다펜치온 (Pyridafenthion)등의 유기 인계 살충제 등이다.As an effective drug used in the present invention, any conventionally used as a pest control agent or a fungicide can be used. Representative examples thereof include pyrethroid insecticides such as permethrin and decamethrin, and diazinon. ), Organophosphorus insecticides such as DDVP and Pyridafenthion.
본 발명 조성물은 상기와 같은 유효 약제, 발연제, 발연제 외에 훈증용 조물성에 통상 첨가하는 안정제, 효력증강제, 휘산향상제, 소취제 향료등을 소량첨가할 수 있으며, 사용 형태에 따라 각종 바인더, 중량제, 부형제로 규산, 활성탕, 탈크, 탄산칼슘, 구조로, 백카본, 전분, C.M.C., P.V.A. 등을 첨가하여 입상,봉상, 판상 등으로 성형하여 금속제 용기에 충전하여 사용함이 적당하지만 경우에 따라서는 그대로 사용할 수도 있다.The composition of the present invention can add a small amount of stabilizers, potentiators, volatilizers, deodorants, flavors, etc., which are normally added to fumigating compositions, in addition to the effective drugs, fuming agents, and fuming agents, and various binders, weighting agents, As excipient, silicic acid, activated bath, talc, calcium carbonate, structure, white carbon, starch, CMC, PVA Although it is suitable to use it by adding it to a granular shape, rod shape, plate shape, etc. and filling it into a metal container, it may be used as it is in some cases.
이와같이 조성된 본 발명 조성물을 성형하여 금속제 용기에 충전한 다음 열원을 밀폐형 외용기 내에 수용하고 외용기 내부에 본 발명 조성물이 충전된 금속제 용기를 놓고 열원에 의하여 간접 가열하면 본 발명 조성물 중의 발열제는 일정 온도 이하(약 140℃)에서는 안정하지만 일정 온도 이상에서는 자체 반응에 의하여 지속적으로 열을 발생하는 것이므로 간접 가열에 의하여 일단 140℃ 이상으로 가열하면 그 다음에는 외부가 열이 없어도 발열제에 의하여 지속적으로 열이 발생하여 이열에 의하여 발연제가 분해하여 가스가 발생함과 동시에 열에 의하여 유효 약제가 휘산하게 되므로 유효 약제는 열에 의한 휘산과 분해 가스에 의한 강제 휘산이 동시에 이루어 지므로 유효 약제의 열 분해가 되지 않는 온도에서 종래의 훈증용 살균, 살충제에 비하여 휘산 효율이 높은 특징이 있다.When the composition of the present invention thus formed is molded and filled into a metal container, the heat source is accommodated in a sealed outer container, the metal container filled with the present composition is placed inside the outer container, and indirectly heated by a heat source. It is stable below the temperature (approx. 140 ℃), but it generates heat continuously by self-reaction above a certain temperature, so once heated above 140 ℃ by indirect heating, it is continuously heated by the heating element even if there is no heat outside. As this occurs, the fuming agent decomposes due to heat, and gas is generated, and the effective drug is volatilized by heat. Therefore, the effective drug is a temperature at which pyrolysis of heat and forced volatilization by decomposition gas are performed simultaneously. In comparison with conventional fumigating sterilization, insecticide It is characterized by high volatilization efficiency.
따라서, 본 발명 조성물에 의하면 방이나 기타의 한정 공간 내에 깊숙이 서식하는 바퀴, 쥐벼룩, 개미등을 효과 적으로 구제할 수 있고, 더우기 본 발명 조성물은 종래 점화에 의한 연소방법 보다 휘산율이 높고 유효 약제의 분해가 적고, 화재의 위험도 수반치 않으므로 안전, 간편하게 훈증할 수 있는 이점이 있다.Therefore, according to the composition of the present invention, wheels, rat fleas, ants, etc., deeply inhabiting a room or other confined spaces can be effectively removed. Furthermore, the composition of the present invention has a higher volatilization rate and an effective agent than a combustion method by conventional ignition. There is little disassembly of the fire, and the risk of fire is not accompanied, so there is an advantage that can be fumigation safely.
[실시예]EXAMPLE
본 발명 조성물의 조성비 및 조성물의 훈증율은 다음과 같다.The composition ratio of the composition and the fumigation rate of the composition are as follows.
실시예 중의 부는 중량부이다.Parts in the examples are parts by weight.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019840006844A KR860001044B1 (en) | 1984-11-01 | 1984-11-01 | Sumigant for gemicide and insecticide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019840006844A KR860001044B1 (en) | 1984-11-01 | 1984-11-01 | Sumigant for gemicide and insecticide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR860003773A KR860003773A (en) | 1986-06-13 |
| KR860001044B1 true KR860001044B1 (en) | 1986-08-01 |
Family
ID=19236030
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019840006844A KR860001044B1 (en) | 1984-11-01 | 1984-11-01 | Sumigant for gemicide and insecticide |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR860001044B1 (en) |
-
1984
- 1984-11-01 KR KR1019840006844A patent/KR860001044B1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR860003773A (en) | 1986-06-13 |
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