KR850006686A - 고도의 선택적 흡수력을 가진 안정한 붕소수지의 제조방법 - Google Patents
고도의 선택적 흡수력을 가진 안정한 붕소수지의 제조방법 Download PDFInfo
- Publication number
- KR850006686A KR850006686A KR1019850001852A KR850001852A KR850006686A KR 850006686 A KR850006686 A KR 850006686A KR 1019850001852 A KR1019850001852 A KR 1019850001852A KR 850001852 A KR850001852 A KR 850001852A KR 850006686 A KR850006686 A KR 850006686A
- Authority
- KR
- South Korea
- Prior art keywords
- resin
- phenylboroxine
- general formula
- iii
- amino resin
- Prior art date
Links
- 229920005989 resin Polymers 0.000 title claims 9
- 239000011347 resin Substances 0.000 title claims 9
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 title claims 2
- 229910052796 boron Inorganic materials 0.000 title claims 2
- 238000010521 absorption reaction Methods 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- INGFKPJXXCEHLX-UHFFFAOYSA-N 2-phenyl-1,3,5,2,4,6-trioxatriborinane Chemical compound B1OBOB(O1)c1ccccc1 INGFKPJXXCEHLX-UHFFFAOYSA-N 0.000 claims 7
- 229920003180 amino resin Polymers 0.000 claims 6
- 238000000034 method Methods 0.000 claims 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 3
- 229910052736 halogen Inorganic materials 0.000 claims 3
- 150000002367 halogens Chemical class 0.000 claims 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 3
- 238000009833 condensation Methods 0.000 claims 2
- 230000005494 condensation Effects 0.000 claims 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims 2
- 239000003960 organic solvent Substances 0.000 claims 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims 1
- OWLWFGQXFWHNKV-UHFFFAOYSA-N BrB1OB(OBO1)C1=C(C=CC=C1)C Chemical group BrB1OB(OBO1)C1=C(C=CC=C1)C OWLWFGQXFWHNKV-UHFFFAOYSA-N 0.000 claims 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims 1
- 150000001450 anions Chemical class 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 238000007306 functionalization reaction Methods 0.000 claims 1
- 150000004820 halides Chemical class 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 239000011159 matrix material Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- 230000008961 swelling Effects 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F30/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F30/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
- C08F30/06—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing boron
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K13/00—Sugars not otherwise provided for in this class
- C13K13/005—Lactulose
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/42—Introducing metal atoms or metal-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/44—Preparation of metal salts or ammonium salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/08—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing boron
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K13/00—Sugars not otherwise provided for in this class
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Pens And Brushes (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Developing Agents For Electrophotography (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (8)
- 하기 일반식(II)의 아미노수지를 적당히 예비 처리한 다음, 촉매로서 알칼리성 요오드화물의 존재하에 25° 내지 55℃의 유기 매질중에서, 하기 일반식(III)의 페닐보록신과 축합시키고, 생성된 X가 할로겐인 하기 일반식(I)의 수지를, 알칼리성 수산화물 수용액으로 처리함으로써, 상응하는 X가 OH인 수지로 전환시킬 수 있음을 특징으로 하여, 하기 일반식(I)의 붕소 수지를 제조는 방법.상기식에서, ⓟ는 폴리아크릴계 매트릭스이고; R 및 R3는 동일하거나 상이할 수 있으며, -(CH2)n- (여기서 n은 0 내지 5이다)이고; R1및 R2는 동일하거나 상이할 수 있으며, C1내지 C5알킬이고;X-는 OH 및 할라이드 중에서 선택된 음이온이며; Y는 할로겐이다.
- 제1항에 있어서, 페닐보록신(III)과 축합시키기 전에, 일반식(II)의 아미노 수지를, Cl-형태를 재생시켜, 탈염수로 세척한 다음, OH-형태로 재생시켜, 탈염수로 세척하고, 물을 제거할 수 있는 유기 용매로 세척하여, 건조시킨 다음 유기 용매로 팽윤시키는 방법.
- 제1항에 있어서, 아미노수지(II) 및 페닐보록신(III)를 위한 유기 축합 매질을, 디메틸 포름아미드, 디옥산 및 디메틸아세트아미드 중에서 선택하고, 유기매질과 수지의 비율이 5 내지 50ℓ/kg인 방법.
- 제1항에 있어서, 아미노수지(II)와 페닐보록신(III)을 0.5 내지 1.5의 중량비로 반응시키는 방법.
- 제1항에 있어서, 알칼리성 요오드화물에 대한 아미노 수지(II)의 중량비가 1.2 내지 10인 방법.
- 제1항에 있어서, X가 할로겐인 수지(I)을 X가 OH인 수지(I)로 전환시키는 반응을, 농도 20 내지 60g/ℓ의 NaOH 수용액으로 처리함으로써 수행하는 방법.
- 제1항에 있어서, 페닐보록신이 브로모톨릴보록신인 방법.
- 제1항에 있어서, B함량이 1 내지 8%이고 관능화도가 수지 그램당 B의 1 내지 8meg이며, -NR1R2기가 수지 그램당 2 내지 9meg인 방법.※ 참고사항:최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT20177A/84 | 1984-03-22 | ||
| IT20177/84A IT1173459B (it) | 1984-03-22 | 1984-03-22 | Resine boroniche stabili ad elevato potere assorbente selettivo |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR850006686A true KR850006686A (ko) | 1985-10-16 |
| KR910008314B1 KR910008314B1 (ko) | 1991-10-12 |
Family
ID=11164447
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019850001852A KR910008314B1 (ko) | 1984-03-22 | 1985-03-21 | 고도의 선택적 흡수력을 가진 안정한 붕소수지의 제조방법 |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US4506036A (ko) |
| EP (1) | EP0159521B1 (ko) |
| JP (1) | JPS60217206A (ko) |
| KR (1) | KR910008314B1 (ko) |
| AT (1) | ATE31068T1 (ko) |
| CA (1) | CA1202746A (ko) |
| DE (1) | DE3561063D1 (ko) |
| DK (1) | DK127585A (ko) |
| GB (1) | GB2156356B (ko) |
| IE (1) | IE57855B1 (ko) |
| IT (1) | IT1173459B (ko) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1173459B (it) * | 1984-03-22 | 1987-06-24 | Sirac Spa | Resine boroniche stabili ad elevato potere assorbente selettivo |
| IT1215407B (it) * | 1987-04-03 | 1990-02-08 | Sirac Spa | Resine boroniche di elevato potere assorbente selettivo. |
| IT1215406B (it) * | 1987-04-03 | 1990-02-08 | Sirac Spa | Resine boroniche stabili di elevato poytere assorbente selettivo. |
| AU628674B2 (en) * | 1989-10-19 | 1992-09-17 | Nippon Oil And Fats Company, Limited | Polymer complexes of a sugar response type |
| IT1271449B (it) * | 1993-04-28 | 1997-05-28 | Inalco Spa | Procedimento per la preparazione di lattulosio cristallino da sciroppi commerciali |
| CA2251700A1 (en) * | 1996-05-03 | 1997-11-13 | Warner-Lambert Company | Rapid purification by polymer supported quench |
| US6171503B1 (en) * | 1998-03-16 | 2001-01-09 | Dalhousie University | Use of tetraphenyloborate for extraction of ammonium ions and amines from water |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2834539A1 (de) * | 1978-08-07 | 1980-02-21 | Basf Ag | Makroporoese polymere als traegermaterial zur kovalenten bindung von proteinen |
| JPS5664657A (en) * | 1979-11-01 | 1981-06-01 | Asahi Chem Ind Co Ltd | Hydrophilic filler for chromatography |
| US4357311A (en) * | 1980-10-03 | 1982-11-02 | Warner-Lambert Company | Substrate for immunoassay and means of preparing same |
| IT1173459B (it) * | 1984-03-22 | 1987-06-24 | Sirac Spa | Resine boroniche stabili ad elevato potere assorbente selettivo |
-
1984
- 1984-03-22 IT IT20177/84A patent/IT1173459B/it active
- 1984-07-16 US US06/631,104 patent/US4506036A/en not_active Expired - Fee Related
- 1984-07-17 GB GB08418208A patent/GB2156356B/en not_active Expired
- 1984-07-17 CA CA000459005A patent/CA1202746A/en not_active Expired
- 1984-12-26 US US06/686,272 patent/US4542161A/en not_active Expired - Lifetime
-
1985
- 1985-03-14 IE IE660/85A patent/IE57855B1/en not_active IP Right Cessation
- 1985-03-14 EP EP85102934A patent/EP0159521B1/en not_active Expired
- 1985-03-14 DE DE8585102934T patent/DE3561063D1/de not_active Expired
- 1985-03-14 AT AT85102934T patent/ATE31068T1/de not_active IP Right Cessation
- 1985-03-21 DK DK127585A patent/DK127585A/da not_active Application Discontinuation
- 1985-03-21 KR KR1019850001852A patent/KR910008314B1/ko not_active IP Right Cessation
- 1985-03-22 JP JP60055746A patent/JPS60217206A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| KR910008314B1 (ko) | 1991-10-12 |
| CA1202746A (en) | 1986-04-01 |
| GB8418208D0 (en) | 1984-08-22 |
| DE3561063D1 (en) | 1988-01-07 |
| DK127585A (da) | 1985-09-23 |
| JPH0323085B2 (ko) | 1991-03-28 |
| IE57855B1 (en) | 1993-04-21 |
| US4542161A (en) | 1985-09-17 |
| IT1173459B (it) | 1987-06-24 |
| EP0159521B1 (en) | 1987-11-25 |
| IT8420177A0 (it) | 1984-03-22 |
| JPS60217206A (ja) | 1985-10-30 |
| GB2156356A (en) | 1985-10-09 |
| EP0159521A1 (en) | 1985-10-30 |
| US4506036A (en) | 1985-03-19 |
| ATE31068T1 (de) | 1987-12-15 |
| IE850660L (en) | 1985-09-22 |
| DK127585D0 (da) | 1985-03-21 |
| GB2156356B (en) | 1987-06-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| G160 | Decision to publish patent application | ||
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant | ||
| LAPS | Lapse due to unpaid annual fee |