KR850000816A - Electrolytic Cell with Cooperative Mesh Electrode - Google Patents

Electrolytic Cell with Cooperative Mesh Electrode Download PDF

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KR850000816A
KR850000816A KR1019830003192A KR830003192A KR850000816A KR 850000816 A KR850000816 A KR 850000816A KR 1019830003192 A KR1019830003192 A KR 1019830003192A KR 830003192 A KR830003192 A KR 830003192A KR 850000816 A KR850000816 A KR 850000816A
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electrode
foam
negative electrode
separator
negative
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KR1019830003192A
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Korean (ko)
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제이 스튜워어트 제이므즈 (외 2)
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원본미기재
엘텍 시스템즈 리미팃드
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Priority to KR1019830003192A priority Critical patent/KR850000816A/en
Publication of KR850000816A publication Critical patent/KR850000816A/en

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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/03Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
    • C25B11/031Porous electrodes
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B13/00Diaphragms; Spacing elements
    • C25B13/04Diaphragms; Spacing elements characterised by the material
    • C25B13/08Diaphragms; Spacing elements characterised by the material based on organic materials
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00Operating or servicing cells
    • C25B15/08Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • C25B9/23Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms comprising ion-exchange membranes in or on which electrode material is embedded
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/60Constructional parts of cells
    • C25B9/63Holders for electrodes; Positioning of the electrodes
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/60Constructional parts of cells
    • C25B9/65Means for supplying current; Electrode connections; Electric inter-cell connections

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Fuel Cell (AREA)

Abstract

내용 없음.No content.

Description

협력망사 전극을 가지는 전해전지Electrolytic Cell with Cooperative Mesh Electrode

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

첨부 도면은 본 발명의 양극조립체를 포함하는 전해화학전지의 단면도이다.The accompanying drawings are cross-sectional views of an electrochemical cell including the positive electrode assembly of the present invention.

Claims (20)

분리막에 의해 분리되는 양극부위와 음극부위로 구성되는 전해 전지에 있어서, (a) 개구 다공성 망사 1차 전극에 1개 부위의 적어도 일부를 차지하고 또 분리막과 완벽한 물리적 접촉을 이루며, (b) 전류공급자가 전극에 내부 금속적으로 연결됨으로써 전류가 전극 및 전류공급자간의 전기 저항없이 전극에 분배되며, 또 (c) 전해액을 전극부위내로 또 전극부위외로 순환시킬 수 있는 분배장치로 구성되는 전극 조립체.In an electrolytic cell composed of a positive electrode portion and a negative electrode portion separated by a separator, (a) at least part of one portion of the opening porous mesh primary electrode and in perfect physical contact with the separator, (b) a current supplier And (c) a distributing device capable of circulating the electrolyte solution into and out of the electrode region, wherein the current is distributed to the electrode without electrical resistance between the electrode and the current supplier. 제1항에 있어 전극이 양극인 전극조립체.The electrode assembly of claim 1, wherein the electrode is an anode. 분리막에 의해 분리되는 양극 부위와 음극부위로 구성되는 전해 전지에 있어서, (a) 개구다공성 망사 1차 음극이 음극부위를 대부분 차지하고 또 분리막과 완벽한 물리적 접촉을 이루며, (b) 음극전류 공급자가 음극에 내부금속적으로 연결됨으로써 전류가 음극 및 전류 공급자간의 전기 저항없이 음극에 분배되며, 또 (c) 음극 전해액을 음극부위내로 또 음극부위외로 순환시킬 수 있는 음극분배장치로 구성되는 음극조립체.In an electrolytic cell composed of a positive electrode portion and a negative electrode portion separated by a separator, (a) the open porous net primary cathode occupies most of the negative electrode portion and makes perfect physical contact with the separator, and (b) the negative electrode current supplier is negative A negative electrode assembly comprising a negative electrode distributing device in which a current is distributed to the negative electrode without the electrical resistance between the negative electrode and the current supplier by being internally connected to the negative electrode, and (c) the negative electrode electrolyte can be circulated into and out of the negative electrode. 전지내에서 양극부위와 음극부위가 분리막에 의해 분리되며, 전지내의 적어도 1개이상 전극이 분리막과 완벽한 물리적 접촉을 이루는 협격전지에 있어서, (a) 1개 이상의 개구다공성 망사 1차전극이 0.5밀 내지 10밀 범위의 기공을 갖고, 분리막과 완벽한 물리적 접촉을 이루며, 또 전지의 적어도 1개 부위를 완전히 충진시키고, (b) 전류공급자가 전극을 전류원과 내부금속적으로 연결시킴으로써 전류공급자와 전극간 전류저항을 무시할 수 있을 정도로 만들고, 또 (c) 1개이상의 전해질 입구로서 전해질을 전극구조물에 장입시키고 또 1개 이상의 출구로서 전해질을 전극 구조물로부터 제거시킴을 특징으로 하는 협격전극 조립체.In a narrow cell where the positive and negative portions are separated by a separator in the cell, and at least one electrode in the cell is in perfect physical contact with the separator, (a) at least one aperture porous mesh primary electrode is 0.5 mil. Having pores in the range of 10 to 10 mils, making perfect physical contact with the separator, and completely filling at least one portion of the cell, and (b) the current supply between the current supply and the And (c) inserting the electrolyte into the electrode structure as one or more electrolyte inlets and removing the electrolyte from the electrode structure as one or more outlets. 제4항에 있어서, 전극이 양극인 협격전극 조립체.The narrow electrode assembly of claim 4, wherein the electrode is an anode. 전지내에서 양극부위와 음극부위가 분리막에 의해 분리되고, 또 전지내 음극이 분리막이 완벽한 물리적 접촉을 이루는 협격 전지에 있어서, (a) 개구다공성 망사 1차 음극이 0.5밀 내지 10밀 범위의 기공을 갖고 분리막과 완벽한 물리적 접촉을 이루며, 또 전지의 음극부위를 완전히 충진시키고, (b) 음극전류 공급자가 음극을 전류원과 내부 금속적으로 연결시킴으로써 전류공급자와 전극간 전류저항을 무시할 수 있을 정도로 만들고, (c) 1개 이상의 음극전해질 입구로서 음극전해질을 음극구조물에 장입시키고 또 1개 이상의 음극 전해질 출구로서 음극 전해질을 음극 구조물로부터 제거시킴을 특징으로 하는 협격 음극 조립체.In a narrow cell where the positive and negative portions are separated by a separator in the cell, and the negative electrode in the cell is in perfect physical contact with the separator, (a) the porous porous primary cathode is in the range of 0.5 to 10 mils. Make perfect physical contact with the separator, and completely fill the negative electrode of the cell, and (b) the negative current provider connects the negative electrode internally with the current source to make the current resistance between the current supply and the electrode negligible and (c) charging the negative electrolyte into the negative electrode structure as one or more negative electrolyte inlets and removing the negative electrolyte from the negative electrode structure as the one or more negative electrolyte outlets. (a) 1개 이상의 전극부위를 개구다공성 플라스틱 포옴으로 완전히 충진시키고, 이포옴은 박막과 완벽한 물리적 접촉을 이루며, (b) 전류공급자를 플라스틱 포옴 내부에 적어도 일부를 투입시켜 포옴충진된 각 부위에 전도성 금속 전류공급자를 설치하고, (c) 포옴 상부에 필요로 하는 두께의 전기 전도성 피막이 침적될 때까지 개구다공성 플라스틱 포옴을 무극도금액과 접촉시키며, (d) 포옴을 음극으로 대전시키고, 또 (e) 포옴 상부에 필요로 하는 두께의 전극 침적이 형성될 때까지 포옴전극을 통해 도금용액을 순환시킴을 특징으로 하여, 분리막에 의해 분리되는 양극부위와 음극부위를 갖고 또 이들 부위에 1개 이상의 전해질 입구와 출구를 갖는 전해 전지용 전극 조립체 제조방법.(a) one or more electrode portions are completely filled with an open porous plastic foam, the foam is in perfect physical contact with the thin film, and (b) at least a portion of the current supply is introduced into each of the foam filled portions of the plastic foam. Installing a conductive metal current source, (c) contacting the porous porous plastic foam with the non-polarizing solution until the required thickness of the electrically conductive film is deposited on the foam, (d) charging the foam with the cathode, and ( e) circulating the plating solution through the foam electrode until an electrode deposit of the required thickness is formed on the foam, and having one or more anode and cathode portions separated by a separator; A method of manufacturing an electrode assembly for an electrolytic cell having an electrolyte inlet and an outlet. 제7항에 있어서, 전해 침적중의 발생열에 의하여 포옴을 제거시키는 전극조립체 제조방법.8. The method of claim 7, wherein the foam is removed by heat generated during electrolytic deposition. 제7항에 있어서, 포옴이 0.5 내지 10.0 밀리미터의 개구기공도를 갖는 전극 조립체 제조방법.8. The method of claim 7, wherein the foam has an opening porosity of 0.5 to 10.0 millimeters. 제7항에 있어서, 도금용액이 포옴 음극상에 닉켈 금속 피막을 제공하는 전극조립체 제조방법.8. The method of claim 7, wherein the plating solution provides a nickel metal film on the foam cathode. (a) 1개 이상의 전극부위를 개구다공성 전도 플라스틱포옴으로 완전히 충진시키고, 이 포옴은 박막과 완벽한 물리적 접촉을 이루며, (b) 전류 공급자를 플라스틱 포옴 내부에 적어도 일부를 투입시켜, 포옴 충진된 각 부위에 전도성 전류 공급자를 설치하고, (c) 포옴을 음극으로 대전시키고, 또 (d) 포옴상부에 필요로 하는 두께의 전극침적이 형성될 때까지 전극도금액을 포옴전극과 접촉시킴을 특징으로 하는 분리막에 의해 불리되는 양극부위와 음극부위를 갖고 또 이들 각 부위에 1개 이상의 전해질 입구와 출구를 갖는 전해 전지용 전극조립체 제조방법.(a) one or more electrode portions are completely filled with an open porous conductive plastic foam, which forms a complete physical contact with the thin film, and (b) at least a portion of the current supplier is introduced into the plastic foam to form a foam filled angle. (C) charge the foam with the cathode, and (d) contact the electrode plating solution with the foam electrode until an electrode deposit of the required thickness is formed on the foam. A method for producing an electrode assembly for an electrolytic cell, comprising an anode portion and a cathode portion, which are disadvantageous by a separator, and at least one electrolyte inlet and outlet at each of these portions. 제11항에 있어서, 포옴이 전기 전도성물질로 함침시킨 형태의 것이 전극조립체 제조방법.The method of claim 11, wherein the foam is impregnated with an electrically conductive material. 제11항에 있어서, 음극을 음극대전시키기 이전에 포옴 음극상에 필요로 하는 금속피막을 입히기 위하여 무극도금액을 포음 음극과 접촉시키는 전극조립체 제조방법.12. The method of claim 11, wherein the non-electrode solution is brought into contact with the foam negative electrode to coat a metal film required on the foam negative electrode before the negative electrode is charged. 제7항 또는 제11항에 있어서, 전해 도금용액이 포옴 음극상부 전해 침적에 필요한 닉켈 이온전부를 함유하는 전극 조립체 제조방법.12. The method of claim 7 or 11, wherein the electrolytic plating solution contains all Nickel ions necessary for electrolytic deposition on the top of the cathode of the foam. 제7항 또는 제11항에 있어서, 분리막이 전극부위간의 액체 이동에 대해서는 수압 불투명 과성이지만, 전극부위간 양이온의 자유 이동이 손쉽게 이루어질 수 있는 박막인 전극 조립체 제조방법.12. The method of claim 7 or 11, wherein the separator is a thin film that is hydraulically opaque for liquid movement between electrode sites, but freely moves cations between electrode sites. 제15항에 있어서 박막이 부착 설포닐 또는 카보닐 기재 양이온 교환기능기를 갖는 퍼플루오로카본공중합체가 전부분을 이루는 전극조립체 제조방법.16. The method of claim 15, wherein the thin film is composed entirely of perfluorocarbon copolymers having attached sulfonyl or carbonyl based cation exchange functional groups. 제1항 내지 제6항중 어느 하나에 있어서, 분리막이 전극부위간의 액체 이동에 대해서는 수압불투과성이나 전극 부위간 양이온의 자유이동이 손쉽게 이루어질 수 있는 박막인 전극조립체 제조방법.The electrode assembly manufacturing method according to any one of claims 1 to 6, wherein the separator is a thin film capable of easily performing hydraulic impermeability or free movement of cations between electrode portions with respect to liquid movement between electrode portions. 제17항에 있어서, 박막이 부착성 설포닐 또는 카보닐 기재 양이온 기능기를 갖는 퍼플루오로 카본공중합체가 전부분을 이루는 전극 조립체 제조방법.18. The method of claim 17, wherein the thin film consists entirely of perfluoro carbon copolymer having an adherent sulfonyl or carbonyl based cationic functional group. 제7항 또는 제11항에 있어서, 전류수집체를 가열하여 이를 포옴에 투입시킴으로써 전류 수집체가 포옴에 투입되는 전극 조립체 제조방법.12. The method of claim 7 or 11, wherein the current collector is introduced into the foam by heating the current collector and introducing it into the foam. (a) 기공성 망사 포옴 음극물질을 선정하고 또 이 포옴의 전지의 음극 부위에 충진시켜 포옴이 음극부위 전공간을 충진시켜서 분리막과 완전한 물리적 접촉을 이루게 하고, (b) 이 포옴을 전도성으로 만들며, (c) 음극 전류공급자를 설치하고, 또 이 공급자를 포옴음극과 전기적 접촉이 이루어지게 하고, 또 (d) 이 포옴음극상에 음극금속을 전해칭적시킴을 특징으로 하여, 분리막에 의해 분리되는 양극부위와 음극부위를 갖고 또 1개 이상의 음극전해액 입구와 또 1개 이상의 음극전해액 출구를 갖는 전해 화학 전지용 음극 조립체 제조방법.(a) selecting a porous mesh foam negative electrode material and filling the negative electrode portion of the cell of the foam so that the foam fills the entire space of the negative electrode portion to make complete physical contact with the separator; and (b) makes the foam conductive. (c) installing a cathodic current supply and bringing this supplier into electrical contact with the foam cathode, and (d) electrolytically electrolyzing the cathode metal on the foam cathode. A method for producing a negative electrode assembly for an electrochemical cell having an anode portion and a cathode portion, and having at least one cathode electrolyte inlet and at least one cathode electrolyte outlet. ※참고사항:최초출원 내용에 의하여 공개하는 것임.※ Note: This is to be disclosed based on the first application.
KR1019830003192A 1983-07-13 1983-07-13 Electrolytic Cell with Cooperative Mesh Electrode KR850000816A (en)

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