KR850000271B1 - The composition of artificial slate - Google Patents

The composition of artificial slate Download PDF

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Publication number
KR850000271B1
KR850000271B1 KR1019830002306A KR830002306A KR850000271B1 KR 850000271 B1 KR850000271 B1 KR 850000271B1 KR 1019830002306 A KR1019830002306 A KR 1019830002306A KR 830002306 A KR830002306 A KR 830002306A KR 850000271 B1 KR850000271 B1 KR 850000271B1
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composition
barite
artificial
polyamide resin
present
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KR1019830002306A
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Korean (ko)
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KR840008794A (en
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지연화
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지연화
조은수
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/38Fibrous materials; Whiskers
    • C04B14/46Rock wool ; Ceramic or silicate fibres
    • C04B14/4643Silicates other than zircon
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/04Macromolecular compounds
    • C04B16/06Macromolecular compounds fibrous
    • C04B16/0675Macromolecular compounds fibrous from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B16/0691Polyamides; Polyaramides
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/14Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Architecture (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

Artificial stone slate for building materials is composed of barite (70-80%), polyamide resin (15-22%), and additives (sepiolite 2-5%, white cement 2-3%). The mixture of the above compositions is mixed at 190-200≰C by a screw mixer, which has a heating device. The heated and mixed mixture is pressed by a mold to produce products. The polyamide resin is thermoplastic, has high tensile strength, and is used a bonding material.

Description

인조 석판재의 조성물Composition of artificial slabs

본 발명은 인조 석판재의 조성물에 관한 것으로, 특히 중정석분(重晶石粉)과 폴리아미드 수지를 주제로 하여 내연성(耐燃性), 단열성(斷熱性), 방음성(防音性), 내습성( 耐濕性), 가공성과 압축 및 인장강도가 크고 경량성인 건축용 석판재를 제공하기 위한 조성물에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a composition of artificial slab, particularly with respect to barite powder and polyamide resins, which are flame retardant, heat insulating, soundproof and moisture resistant. The present invention relates to a composition for providing a building slab that is light in workability, compressive and tensile strength and is light in weight.

인조석판 건축자재로서는 슬레이트(slate)가 널리 알려져 있다. 이것은 주로 일반 건축물위 지붕재로 사용되며, 공장, 창고, 가건물의 벽판재로도 사용된다.Slate is widely known as an artificial stone building material. It is mainly used as a roofing material on general buildings and as a wall board of factories, warehouses, and buildings.

제법은 포오틀란드 시멘트 또는 마그네시아 시멘트 외에 모래자갈, 깬돌(碎石)등을 주원료로 한 분말에 석면을 혼합하는 것이 보통이고, 제품의 표면은 시멘트 안료, 방수제등을 섞은 엷은 층으로 만든다.It is common to mix asbestos with powder mainly made of sand gravel or crushed stone, in addition to portland cement or magnesia cement, and the surface of the product is made of a thin layer of cement pigment and waterproofing agent.

시멘트와 석면만을 주원료로 하는 것을 시멘트 레이스라고도 한다.It is also known as cement lace that mainly contains cement and asbestos.

이러한 인조 슬레이트와 같은 조성물을 기재로 한 제품은 특히 충격에 약해서 시공시 못질을 한다든가 또는 운반, 적재등 취급시에 쉽게 갈라지고 깨지는 결점이 있다.Products based on compositions such as artificial slate are particularly susceptible to impact and are easily cracked and cracked during handling such as nailing or during transportation or loading.

또, 인장강도 및 압축강도가 낮으므로 루핑(지붕재), 문틀, 기둥, 타일 따위의 건축자재라든가 탁자, 칠판, 철도레일용 침목과 같은 다른 용도로써 사용하기에는 부적합할 뿐 아니라 무겁고 값이 비싼 흠이다.In addition, the low tensile and compressive strengths are not only unsuitable for use in other materials such as roofing materials, door frames, columns, tiles, tabletops, blackboards, sleepers for railway rails, etc. .

본 발명자들은 이러한 환경하에서 종래 인조 슬레이트의 결점을 극복하여 인장 및 압축강도가 크고 가벼우며 일반 합성수지에 비교될 가공성을 가진 새로운 건축용 인조 석판재를 제조할 수 있는 조성물을 발명하게 된 것이다.The present inventors have overcome the drawbacks of the conventional artificial slate under such circumstances to invent a composition that can produce a new building artificial slab with a large and light tensile and compressive strength and processability comparable to a general synthetic resin.

본 발명 내용을 상세히 설명하면 중정석 광미(鑛尾) 70-80%와 폴리아미드 수지 15-22%를 주제로 하고 여기에 세피올라이트(Sepiotite) 2-5%와 백시멘트 2-3%을 혼합하여 건축용 석판재로서 적합한 조성물을 제공한다.The present invention will be described in detail based on 70-80% of barite tailings and 15-22% of polyamide resin, and 2-5% of sepiotite and 2-3% of cement To provide a composition suitable as building slabs.

본 발명에서 주제로 사용하는 중정석(barite)은 국내 각지에 널리 분포되어 있어 값싸게 구할 수 있다. 문헌에 따르면, 중정석은 사방정계(斜方晶系)로서 판모양이거나 기둥모양을 한 결정체이고, 경도 3-3.5, 비중 4.3-4.7이며 무색, 백, 회, 황, 청, 적색 진주광택등 다양한 색조를 띠고 산출된다.Barite used as a subject in the present invention is widely distributed throughout the country can be obtained cheaply. According to the literature, barite is a tetragonal system, a plate- or columnar crystal, hardness 3-3.5, specific gravity 4.3-4.7, colorless, white, ash, yellow, blue, red pearlescent, etc. Calculated in hue.

이 광석의 용도는 유리의 원료외 제지용(충전체)및 백색 안료등에 사용되는 것으로 알려졌다.It is known that the use of this ore is used for papermaking (fillers), white pigments, etc. in addition to glass raw materials.

중정석은 채광된 것 가운데 325메쉬 이상만이 공업적 활용가치가 있고 그 이하의 저급 광석은 광미(鑛尾)라 하여 이용가치가 적어 대부분 폐기한다.Barite has only industrial use value of more than 325 mesh mined, and low grade ore is less tailings.

본 발명자들은 이와 같은 유용광물을 회수하고 남은 버려지는 광미(鑛尾)를 공업적으로 사용하여 자원화하는 한편 광산마다 광미의 누적으로 인하 문제 해결에도 기여할 수 있는 방안을 제시한다.The present inventors propose a method of industrializing the waste tailings left after recovering such useful minerals and industrializing them, and contributing to solving the reduction problem by accumulating tailings in each mine.

본 발명에서 중정석 다음으로 비중의 차지하는 주재인 폴리아미드 수지는 열가소성이며, 잡아당기는 힘이 강하고, 내충격성, 내마모성, 윤활성이 플라스틱 가운데 가장 뛰어난 장점이 있다.In the present invention, the polyamide resin, which is the main component of the specific gravity next to barite, is thermoplastic, has a strong pulling force, and has excellent impact resistance, abrasion resistance, and lubricity among plastics.

이 폴리아미드 수지는 중정석 광미(대체로 분말 형상)의 입자와 입자를 강력히 결속하는 정결제로서 그리고 중전재로서 사용된다. 폴리아미드 수지로 대표되는 것은 나일론이 있고 범광위한 의미로는 연질 수지도 포함된다.This polyamide resin is used as a purifying agent which strongly binds particles and particles of barite tailings (mostly in powder form) and as a heavy material. Representative of polyamide resins are nylon, and soft resins are also included in the broader sense.

예를들면, 폴리프로필렌(P.P) 폴리에틸렌(P.E)같은 연질합성수지 중에서도 특히 폐합성수지류이다.For example, especially among soft synthetic resins such as polypropylene (P.P) polyethylene (P.E), it is a waste synthetic resin.

최근 농가의 농한기 부업으로 각광을 받고 있는 비닐 하우스 경작은 도시인의 식생활 개선에 기여한 바 크지만, 소채류 재배후에 수거한 비닐필름의 처리문제로 큰 곤란을 겪고 있다.Recently, vinyl house cultivation, which has been spotlighted as a farming side job of farmers, has contributed to improving the diet of urban people, but is experiencing great difficulties due to the disposal of vinyl film collected after vegetable growing.

거둬들인 비닐필름을 소각할 경우 매연과 유독가스를 내기 때문에 대기오염의 문제가 생기고, 땅속에 그대로 묵어버리면 섞지 않을 뿐더러 토질을 오염시키고 나아가 이후 계속될 소채류 재배에 여러모로 장애 요인이 되기 때문이다.Incineration of the collected vinyl film produces soot and toxic gas, which causes air pollution, and if left in the ground, it does not mix and contaminates the soil.

이러한 합성수지 쓰레기의 처리 문제는 비단 농촌에만 국한 되는 것이 아니라 도시에서도 비슷한 현상이 일고 있다.The problem of disposal of synthetic resin waste is not limited to rural areas, but a similar phenomenon is occurring in cities.

이를테면, 매일 같이 쏟아져 나오는 과자, 가공식품등의 합성수지 포장지라든가 기타 각종 수지류 쓰레기이다.For example, synthetic resin packaging such as sweets, processed foods, etc. which are poured out every day, and other various kinds of resin waste.

이 엄청난 양을 되도록이면 공해를 최소한으로 줄이면서 가장 효과적으로 처리할 수 있는 대책 수립에 상당한 관심을 갖고 각 방면으로 연구가 진행되고 있으나 묘책은 없고 소각 또는 쓰레기 집적장에 그대로 버릴 수밖에 없다.This enormous amount is being studied in each direction with considerable interest in establishing the measures that can be most effectively handled with the least possible pollution, but there is no guilt and no choice but to discard it in an incineration or waste dump.

그러나, 이러한 대책만으로는 미흡하다. 본 발명은 또한 이같은 문제를 안고 있는 폐합성수지를 유용 자원으로 재활용할 수 있는 방안을 제시한다.However, such measures are insufficient. The present invention also proposes a method for recycling waste synthetic resins having such problems as useful resources.

새피올라이트(Mg2Si3O8·2H2O)는 첨가제로 사용되며 영롱하고 활감(滑感)도가 좋고 조직이 치밀하여 비중이 낮은 특징을 갖고 있다. 이러한 첨가제를 선택함으로서 성형품의 표면의 매끈하고 광택이 돋보이며 제품의 경량화를 실현할 수 있다. 다음에 본 발명의 실시 예를 설명한다.Sapiolite (Mg 2 Si 3 O 8 · 2H 2 O) is used as an additive and has the characteristics of low specific gravity because it is bright, has a good feeling, and has a dense structure. By selecting such an additive, the surface of the molded article can be smooth and glossy, and the weight of the product can be realized. Next, an embodiment of the present invention will be described.

1. 배합1. Formulation

미분말상의 중정석분 75% 새피올라이트 5%Barite powder in fine powder 75% Sapiolite 5%

나일론(미세하게 절단한것) 18% 백시멘트 2%Nylon (finely cut) 18% Back cement 2%

를 보통의 방법으로 배합한다.Formulate in the usual way.

여기서 %는 중량비를 나타낸다.% Is weight ratio here.

2. 가열 및 혼련2. Heating and kneading

제 1과정에서 얻은 배합물을 가열장치가 붙어 있는 스크류 혼련기를 사용 190-200℃에서 가열 혼련한다.The blend obtained in the first step is heated and kneaded at 190-200 ° C. using a screw kneader with a heating device.

3. 성형3. Molding

스크류 혼련기에서 가열 및 혼련된 배합물은 연속해 있는 사출성형기에 의하여 소정 형태의 제품을 얻는다. 시험결과 본원 제품은 압축 및 인장강도가 인조 스레이트에 비하여 현저히 증가 되었고 광택이 우월하며 또한 현미경 조직검사 결과 치밀한 조직상태를 보였다.The blend heated and kneaded in a screw kneader yields the desired type of product by a continuous injection molding machine. As a result of the test, the product showed a significant increase in compressive and tensile strength compared to artificial slate, superior gloss, and microscopic biopsy showed dense texture.

본 발명의 조성물에 의한 석판재는 불에 타지 않는 돌의 특성인 내열성과 단열성이 우수하고 깨지거나 갈라지지 않으며 못질이나 톱질등 가공성이 우수한 합성수지의 특징을 겸비하고 좋으며 외관이 미려하므로 장식용 가구나, 전자산업용 외장케이스등 용도가 다양하다.The slab according to the composition of the present invention combines the characteristics of synthetic resin, which is excellent in heat resistance, heat insulation, cracking, cracking, nailing and sawing, such as nailing and sawing. Various uses such as exterior cases.

또한 조직을 살펴보면 중정석, 합성수지 새피올라이트등이 고루중첩 성형되므로서 단열(斷熱), 방음(防音), 내습(耐濕) 효과가 목재에 비하여 월등하다.In addition, the structure shows that barite, synthetic resin sapiolite, etc. are evenly overlapped, so that the insulation, sound insulation, and moisture resistance are superior to wood.

본원 조성물에 의한 제품의 특성을 대용품과 비교하면 다음과 같다.The characteristics of the product according to the present composition are compared with the substitutes as follows.

Figure kpo00001
Figure kpo00001

양호:

Figure kpo00002
보통:
Figure kpo00003
불량: ×Good:
Figure kpo00002
usually:
Figure kpo00003
Poor: ×

본 발명의 조성물에 의한 석판재의 용도를 살펴보면, 건축분야에는, 판재, 벽재, 문틀, 기와, 탁자, 타일, 벽돌, 칠판, 아파트난간, 주방기기 외장품. 토목분야에는, 보도블록, 보도경계석, 철도침목, 지하철침목, 케이불덕트. 농수산분야에는, 해태 양식 고정목, 과수원 받침목, 비닐하우스 받침대, 전자산업 및 주방기기분야에는, 욕조, 싱크대 외장품, 스피커 캐비넷, 턴테이블 캐비넷등 다양하다. 상기한 바와 같이 본원 조성물의 제품은 나무와 석재와 쇠의 장점만을 채택 구비한 것으로서 각 분야에 걸처 용도가 다양하다. 부수적으로는 공업적 가치가 희소한 광미와 공해 문제로 지적된 페합성수지를 주재로 채택함으로서 폐기물의 자원화와 공해문제 감소 효과도 거둘 수 있는 유용한 발명이다.Looking at the use of the slab according to the composition of the present invention, in the field of construction, plate, wall, door frame, tile, table, tile, brick, blackboard, apartment railings, kitchen appliances exterior. Civil engineering fields include sidewalk blocks, sidewalk boundaries, railway sleepers, subway sleepers, and K-bul ducts. In agriculture and fisheries, Haitai aquaculture stationary, orchard support, vinyl house pedestal, electronics and kitchen appliances, bathtub, sink exterior, speaker cabinet, turntable cabinet and so on. As described above, the product of the present composition adopts only the advantages of wood, stone, and iron, and has various uses in various fields. Incidentally, it is a useful invention that can utilize waste materials and reduce pollution problems by adopting synthetic resins, whose industrial value is pointed out as a rare tailings and pollution problem.

Claims (1)

1. 중정석 70-80%, 폴리아미드 수지 15-22%를 주재로 하고 여기에 새피올라이트 2-5%와 백시멘트 2-3%를 첨가한 것을 특징으로 하는 인조 석판재의 조성물.1. A composition of artificial slab comprising 70-80% of barite and 15-22% of polyamide resin, and 2-5% of sapiolite and 2-3% of cementite added thereto.
KR1019830002306A 1983-05-26 1983-05-26 The composition of artificial slate KR850000271B1 (en)

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