KR840005420A - 수성 수력 유체용 폴리에테르 농화제 - Google Patents

수성 수력 유체용 폴리에테르 농화제 Download PDF

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KR840005420A
KR840005420A KR1019830002957A KR830002957A KR840005420A KR 840005420 A KR840005420 A KR 840005420A KR 1019830002957 A KR1019830002957 A KR 1019830002957A KR 830002957 A KR830002957 A KR 830002957A KR 840005420 A KR840005420 A KR 840005420A
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South Korea
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olefin
copolymer
polyether polyol
oxide
reacting
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KR1019830002957A
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English (en)
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제이. 코스타글리올라 에밀 (외 1)
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비. 밋첼 로빈
이. 에프. 허어턴 앤드 캄파니
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Publication of KR840005420A publication Critical patent/KR840005420A/ko

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00Ethers; Compounds having groups, groups or groups
    • C07C43/02Ethers
    • C07C43/03Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04Saturated ethers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • C10M173/02Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2603Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
    • C08G65/2606Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
    • C08G65/2609Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups containing aliphatic hydroxyl groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645Metals or compounds thereof, e.g. salts
    • C08G65/2648Alkali metals or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645Metals or compounds thereof, e.g. salts
    • C08G65/2654Aluminium or boron; Compounds thereof

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Polyethers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음

Description

수성 수력 유체용 폴리에테르 농화제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (14)

  1. 분자량이 약 5,000내지 약 75,000이며, 알칸폴리올과 알켄폴리올과 알킨폴리올 및 옥시알킬렌폴리올로 구성되는 군으로부터 선택된 적어도 하나의 다가알콜을 산화에틸렌과, 3내지 4개의 탄소원자를 함유하는 적어도 하나의 저급산화알킬렌과 반응시켜서 헤테르 또는 블록 공중합체를 제조하고, 이 공중합체를 약 10내지 30개의 탄소원자를 함유하는 저급 지방족 산화 α-올레핀과 반응시킴으로써 제조되며, 상기 산화 α-올레핀은 상기 공중합체와 산화 α-올레핀의 전체중량을 기준으로 약 1내지 약 20중량%로 존재하는 것을 특징으로 하는, 수성시스템 농화에 특히 유용한 폴리에테르 폴리올.
  2. 제1항에 있어서, 산화에틸렌과 상기 저급 산화알킬렌의 혼합물을 공중합시켜서 헤테르 공중합체를 형성하고, 다음에 이 공중합체를 상기 산화 α-올레핀과 반응시킴으로써 제조되는 것을 특징으로 하는 폴리에테르 폴리올.
  3. 제1항에 있어서, 산화에틸렌을 저급산화알킬렌과 반응시켜서 블록공중합체를 형성하고, 다음에 상기 공중합체를 상기 산화 α-올레핀과 반응시킴으로써 제조되는 것을 특징으로 하는, 폴리에테르 폴리올.
  4. 제3항에 있어서, 상기 저급산화알킬렌이 산화 1,2-푸로필렌인 것을 특징으로 하는, 폴리에테르 폴리올.
  5. 제1항에 있어서 상기 공중합체 제조에 이용된 저급산화알킬렌에 대한 산화에틸렌의 비율이 약 65내지 약 85중량%의 산화에틸렌과 약 35내지 약 15중량%의 저급산화알킬렌인 것을 특징으로 하는, 폴리에테르폴리올.
  6. 제1항에 있어서, 상기 다가알콜이 알칸폴리올인 것을 특징으로 하는, 폴리에테르 폴리올.
  7. 제1항에 있어서, 상기 다가알콜이 에틸렌글리콜인 것을 특징으로 하는, 폴리에테르 폴리올.
  8. 제6항에 있어서, 상기 다가알콜이 디에틸렌글리콜인 것을 특징으로 하는, 폴리에테르 폴리올.
  9. 제1항에 있어서, 상기 지방족산화 α-올레핀이 12내지 18개의 탄소원자를 함유하는 것을 특징으로 하는, 폴리에테르 폴리올.
  10. 제1항에 있어서, 상기 산화 α-올레핀이 1,2-에폭시헥사데칸과, 1,2-에폭시헵타데칸과 1,2-에폭시옥타데칸의 혼합물로 구성되는 것을 특징으로 하는, 폴리에테르폴리올.
  11. 분자량이 약 10,000내지 15,000이며, 약 75중량%의 산화에틸렌과 약 25%의 산화 1,2-푸로필렌을 에틸렌글리콜과 디에틸렌글리콜로 구성되는 군으로부터 선택된 하나의 알칼폴리올과 반응시켜서 블록공중합체를 제조하고, 이 공중합체를 1,2-에폭시헥사데칸, 1,2-에폭시 헵타데칸 및 1,2-에폭시옥타데칸의 혼합물과 더 반응시킴으로써 제조된 것을 특징으로 하는 수성시스템 농화에 특히 유용한 폴리에테르 폴리올.
  12. 산화에틸렌과 3내지 4개의 탄소원자를 함유하는 산화저급알킬렌의 실질적으로 무수인공중합체를 3불화붕소, 수산화나트륨, 나트륨메톡사이드 및 수산화칼륨으로 구성되는 군으로부터 선택된 일개 촉매의 존재하에 약 12내지 18개의 탄소원자를 함유하는 지방족 산화 α-올레핀과 반응시키며, 상기 산화 α-올레핀은 공중합체와 산화 α-올레핀의 전체중량을 기준으로 약 1내지 약 10중량%의 양으로 존재하는 것을 특징으로 하는, 수성시스템농화에 특히 유용한 폴리에테르폴리올의 제조방법.
  13. 제12항에 있어서, 상기 공중합체는 약 65 내지 약 85중량%의 산화에틸렌을 약 35내지 약 15%의 저급산화알킬렌과 반응시킴으로서 제조되는 것을 특징으로 하는, 폴리에테르폴리올의 제조방법.
  14. 제12항에 있어서, 상기 공중합체는 약 75중량%의 산화에틸렌과 약 25%의 산화 1,2-푸로필렌을 함유하는 블록공중합체이고, 상기 산화 α-올레핀은 1,2-에폭시헥과 데칸과 1,2-에폭시헵타데칸과 1,2-에폭시옥타데칸의 혼합물로 구성되는 것을 특징으로 하는, 폴리에테르폴리올의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019830002957A 1982-07-08 1983-06-29 수성 수력 유체용 폴리에테르 농화제 KR840005420A (ko)

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US39630182A 1982-07-08 1982-07-08
US396301 2003-03-25

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EP (1) EP0116564A1 (ko)
KR (1) KR840005420A (ko)
CA (1) CA1333811C (ko)
IT (1) IT8348649A0 (ko)
WO (1) WO1984000361A1 (ko)

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DE3531915A1 (de) * 1985-09-07 1987-03-19 Bayer Ag Verdickungssysteme fuer hoch wasserhaltige funktionelle fluessigkeiten und die diese verdickungssysteme enthaltenden hoch wasserhaltigen funktionellen fluessigkeiten
DE3807235A1 (de) * 1988-03-05 1989-09-14 Basf Ag Fliesenklebstoff
DE4017688A1 (de) * 1990-06-01 1991-12-05 Bayer Ag Verbesserte funktionelle fluessigkeiten und neue polyoxyalkylenpolymere
DE4017687A1 (de) * 1990-06-01 1991-12-05 Bayer Ag Verbesserte funktionelle fluessigkeiten
AU2015213022B9 (en) * 2014-01-28 2018-05-24 Basf Se The use of alkoxylated polyethylene glycols in lubricating oil compositions

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US3829506A (en) * 1971-06-01 1974-08-13 Basf Wyandotte Corp Biodegradable surface active agents having good foam properties and foam stabilizing characteristics
US3748276A (en) * 1971-07-19 1973-07-24 Basf Wyandotte Corp Aqueous gel composition containing polyether polyol gelling agents
US4310436A (en) * 1979-10-22 1982-01-12 Basf Wyandotte Polyether-based thickeners with additives for increased efficiency in aqueous systems
US4312768A (en) * 1979-10-22 1982-01-26 Basf Wyandotte Corporation Synergistic polyether thickeners for water-based hydraulic fluids
US4312775A (en) * 1979-10-22 1982-01-26 Basf Wyandotte Corporation Polyether thickeners for aqueous systems containing additives for increased thickening efficiency
US4381205A (en) * 1982-04-05 1983-04-26 E. F. Houghton & Company Metal quenching process

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WO1984000361A1 (en) 1984-02-02
CA1333811C (en) 1995-01-03
IT8348649A0 (it) 1983-07-08
EP0116564A1 (en) 1984-08-29

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