KR840000160B1 - Method for the manufacture of a locked material of filament - Google Patents

Method for the manufacture of a locked material of filament Download PDF

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Publication number
KR840000160B1
KR840000160B1 KR7904590A KR790004590A KR840000160B1 KR 840000160 B1 KR840000160 B1 KR 840000160B1 KR 7904590 A KR7904590 A KR 7904590A KR 790004590 A KR790004590 A KR 790004590A KR 840000160 B1 KR840000160 B1 KR 840000160B1
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South Korea
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filament
adhesive
molded body
lock material
aggregate
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KR7904590A
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Korean (ko)
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KR830001467A (en
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사다아끼 다까기
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사다아끼 다까기
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Priority to KR7904590A priority Critical patent/KR840000160B1/en
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Priority to KR1019830004892A priority patent/KR840000161B1/en
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • D04H1/645Impregnation followed by a solidification process
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • D04H1/655Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions characterised by the apparatus for applying bonding agents
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4391Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece characterised by the shape of the fibres
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Nonwoven Fabrics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Treatment Of Fiber Materials (AREA)

Abstract

In the manufacture of a padding block of staple fibre material, shch as for upholstery, short fibres of a threedimensional crimped synthetic fibres are pressed into a shaped block and an adhesive is applied. The body is lifted in a general vertical direction and, at the same time, a dielectric heating with high frequency of 1MHz-300GHz is applied to dry the adhesive on the block. The adhesive is distributed evenly and bonds to the fibres.

Description

필라멘트 록크재의 제조방법Manufacturing method of filament lock material

제1도는 2중연 필라멘트의 사시도.1 is a perspective view of a double stranded filament.

제2도는 입체컬 필라멘트의 사시도.2 is a perspective view of a three-dimensional filament.

제3도는 본 발명에 따른 필라멘트 록크재의 제조를 위한 장치의 개략단면도.3 is a schematic cross-sectional view of an apparatus for producing a filament lock material according to the present invention.

제4도는 제3도에 도시한 장치의 주요부분 사시도.4 is a perspective view of the main part of the apparatus shown in FIG.

제5도는 본 발명에 따른 필라멘트 록크재의 제조를 위한 다른 실시를 도시한 개략단면도.Figure 5 is a schematic cross-sectional view showing another embodiment for the manufacture of the filament lock material according to the present invention.

본 발명은 필라멘트 록크재의 제조방법, 특히, 입체컬을 가진 합성섬유, 필라멘트 집합체로 되는 록크재에 있어서 사용되는 접착제가 균일하게 분산 부착된 필라멘트 록크재를 제조하는 방법에 관한 것이다.The present invention relates to a method for producing a filament lock material, in particular, to a method for producing a filament lock material in which an adhesive used in a lock material which is a synthetic fiber having a three-dimensional curl and a filament aggregate is uniformly attached.

입체컬을 갖는 필라멘트를 소정의 치수로 절단하여 재면한 다음 해면하면서 소정형상으로 압축성형하고 접착제로 필라멘트상호의 접착점을 결합한 필라멘트 록크재는 반발탄성이 크며 통기성이 있어 쿠션성이 우수함을 본 발명자는 이미 발견하였다. (미국특허제4,172,174호)The present inventors have already found that the filament lock material, which is formed by cutting the filament having three-dimensional curls to a predetermined dimension, is pressed into a predetermined shape while being sponged, and which combines the adhesive points of the filament with an adhesive, has a high rebound elasticity and breathability and excellent cushioning properties. Found. (U.S. Patent No. 4,172,174)

또한 제면된 입체컬을 갖는 합성섬유 필라멘트 집합체의 필라멘트 상호 각 접촉점이 접착제로 결합된 구성의 쿠션재로서 그 쿠션재의 필라멘트 컬형상이 부분적으로 방향성을 가지고 각각 신축변형하여 형성되는 각종 형상의 컬 필라멘트의 낙합부분(絡合部分)을 하중강도를 내려고 하는 방향으로 형성시키고 그 낙합부를 소요 하중강도에 용하여 분포시켜 성형되는 필라멘트 록크재가 더욱 우수한 효과를 갖는다는 것도 발견하였다.In addition, the filament of the synthetic fiber filament assembly having a three-dimensional curled face, each contact point of the adhesive material is combined with the adhesive material, the filament curl shape of the cushion material is partially oriented and stretched each of the curl filament of various shapes formed It has also been found that the filament lock material formed by forming a portion in a direction to lower the load strength and distributing the fusion portion by the required load strength has a better effect.

이들 필라멘트 록크재는 제면된 입체컬 필라멘트를 순환벨트 및/또는 롤러, 러빙(rubbing) 등의 수단에 의하여 압축하여 소정의 승밀도를 갖는 필라멘트 집합체블럭을 형성하고, 바브(barbs)를 갖춘 침으로 소정의 침밀도가 되도록 니들링한 후 수평방향으로 주행하는 순환벨트에 높인 필라멘트 성형체에 상부에서 접착제액을 분무하거나 또는 필라멘트 성형체를 접착제액에 침지한 다음 그액에서 인상하여 거의 수평방향으로 주행하는 순환벨트상에서 가열건조하여 제조된다.These filament-locking materials are compressed by means of a circulating belt and / or roller, rubbing, or the like to form a filament aggregate block having a predetermined multiplicity, and a needle with barbs. Circulating belt traveling in the horizontal direction by spraying adhesive liquid from the top or immersing the filament molded body in the adhesive liquid and then lifting it from the filament molded body raised on the circulating belt running horizontally after needling It is prepared by heating and drying in a phase.

그러나 그와같은 방법으로 필라멘트 성형체에 접착제를 도포하면, 성형체에 부착한 접착제는 건조가 완료될때까지 필라멘트 성형체내를 유하(流下)하여, 특히 가열에 의해 점도가 저하되므로 유하가 현저하여, 얻어지는 필라멘트록크재는 접착제의 부착량이 상부는 적고 하부로 갈수록 많아져 극히 불균일한 결점이 있었다. 그리고 접착제는 성형체내를 유하할 뿐만 아니라 성형체를 운송하는 순환벨트위에까지 유하하므로 벨트를 오손하고 작업성을 저하시킴과 아울러 접착제의 손실을 가져온다.However, when the adhesive is applied to the filament molded body in such a manner, the adhesive adhered to the molded body flows down in the filament molded body until the drying is completed, and in particular, the viscosity decreases due to heating, and thus the flow rate is remarkable, resulting in the obtained filament. In the lock material, the adhesive amount of the adhesive was small at the top and increased toward the bottom, resulting in an extremely non-uniform defect. In addition, the adhesive not only lowers the inside of the molded body but also falls on the circulating belt for transporting the molded body, thereby degrading the belt and degrading workability and causing loss of adhesive.

또한 침지법에 의하여 접착제를 도포하는 경우, 가열장치와 액조가 근접하여 있으면 가열장치에서의 복사열에 의하여 접착제액조중의 접착제액도 가열하므로 용제가 증발하여 조성이 변할뿐 아니라 접착제의 손실도 가져온다.In addition, in the case of applying the adhesive by the dipping method, when the heating apparatus and the liquid tank are in close proximity, the adhesive liquid in the adhesive liquid tank is also heated by the radiant heat from the heating apparatus, so that the solvent evaporates to change the composition and also the loss of the adhesive.

따라서 본 발명의 목적은 접착제가 균일하게 분산부착된 필라멘트 록크재의 제조방법을 제공하고자 하는 것이다. 이러하 목적은 입체컬을 갖는 합성섬유필라멘트 단성유를 소정형상으로 압축성형하여 얻은 필라멘트 성형체를 접착제액중에 침지하고 그 성형체를 거의 수직방향으로 인상하면서 유전가열에 의하여 부착된 접착제를 건조함을 특징으로 하는 본 발명의 방법에 의하여 달성된다.It is therefore an object of the present invention to provide a method for producing a filament lock material in which an adhesive is uniformly attached. This purpose is to dry the adhesive adhered by dielectric heating while immersing the filament molded body obtained by compression molding synthetic fiber filament single oil having three-dimensional curls into a predetermined shape in the adhesive liquid and raising the molded body in almost vertical direction. It is achieved by the method of the present invention.

본 발명에서 사용되는 합성섬유로서는 폴리에스테르, 폴리아미드, 폴리프로필렌등이 있으나 폴리에스테르가 가장 바람직하며 그 굵기는 모노필라멘트로서 30-2,000데니이르, 바람직하게는 50-1,000데니이르, 가장 바람직하게는 100-600데니이르인 입체컬 필라멘트이다. 여기서 입체컬이라 함은 이방향성 및 삼방향성컬등의 광범위한 입체컬을 의미하는 것이나 바람직한 것은 삼방향성 입체컬필라멘트이다.Synthetic fibers used in the present invention include polyester, polyamide, polypropylene, etc., but polyester is most preferred, and its thickness is 30-2,000 denier, preferably 50-1,000 denier, and most preferably monofilament. It is a three-dimensional filament that is 100-600 denier. Here, the three-dimensional curl means a wide range of three-dimensional curls such as two-way and three-way curl, but is preferably a three-way three-dimensional curl filament.

일예로, 본 발명자에 의한 미국특허 제4,154,051호에 개시되어 있는 방법 및 장치에 의하여 제1도에 도시한 바와같은 이중연필라멘트 D를 형성한 다음 소정 치수로 절단하고 해연하면 제2도에 도시한 바와같은 삼방향성 입체컬 필라멘트 F가 얻어진다.For example, by the method and apparatus disclosed in the US Patent No. 4,154,051 by the inventor, the double filament D as shown in FIG. 1 is formed, and then cut into a predetermined dimension and decomposed, as shown in FIG. The same tridirectional three-dimensional filament F is obtained.

제면후의 필라멘트 길이는 25-200mm가 바람직하며, 60-150mm가 특히 바람직하다. 필라멘트 F의 부분은 a부에 있어서는 b부분위로 코일하고, c부분을 d부분위로 코일한다. 그러나 e부분은 f부분위로 코일하는 것이 아니라 그 밑으로 코일한다. 그리하여 e로부터 d까지의 필라멘트부분은 2가닥이거나 또는 나선형코일이 된다. 이것은 통상말하는 무방향성 나선으로서 코일의 하나가 다른것에 대하여 무방향성으로 된, 상태가 나쁜 와선형 전화코드와 흡사한 것이다.The length of the filament after the making is preferably 25 to 200 mm, particularly preferably 60 to 150 mm. The part of the filament F is coiled on the b part in the a part, and the c part is coiled on the d part. However, the e part does not coil over the f part, but coils beneath it. Thus, the filament portions from e to d are two strands or spiral coils. This is commonly referred to as a non-directional spiral, similar to a poor helical telephone cord in which one of the coils is non-oriented relative to the other.

이하 도면과 함께 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

본 발명에 따른 필라멘트 록크재는 제3도-제4도에 도시된 장치에 의하여 제조된다.The filament lock material according to the invention is produced by the apparatus shown in FIGS. 3 to 4.

제2도에 도시한 큰 데니이르의 입체컬을 갖는 합성섬유필라멘트 F1는 제3도-제4도에 도시한 바와같이 벨트콘베이어 17에 의하여 해면기 16에 보내지고 풍압등에 의하여 출구 44에서 필라멘트 공급구 5에 공급된다. 공급된 필라멘트 F1는 공급구 5의 하부에 점차로 퇴적함과 동시에 성형장치 2의 압축부 10에 도달한다. 순환콘베이어 6,7에 의하여 반송되는 필라멘트 집합체는 압축부 10을 통과하는 사이에 전기공급구 5의 개구면적 S1과 압축부 10의 개구면적 S2와의 비 S1/S2(>1)의 관계에 의하여 소정의 압축비(승밀도)로 압축된다. 한편, 공급구 5에 있어서 필라멘트 F1의 퇴적고와 순환콘베이어 6,7의 이송속도는 압축 필라멘트 집합체 F2의 승밀도에 영향을 미치므로 검출기 20a, 20b, 20c에 의하여 퇴적고를 검출하여 필라멘트 F1의 공급속도와 순환콘베이어 6,7의 이송속도를 제어 조절한다.Synthetic fiber filament F 1 having a large denier three-dimensional curl shown in FIG. 2 is sent to the sea level machine 16 by a belt conveyor 17 as shown in FIGS. 3 to 4 and filament at exit 44 by wind pressure or the like. It is supplied to supply port 5. The filament F 1 supplied gradually accumulates in the lower part of the supply port 5 and at the same time reaches the compression section 10 of the molding apparatus 2. The filament aggregate conveyed by the circulating conveyors 6 and 7 has a relationship between the ratio S 1 / S 2 (> 1) between the opening area S 1 of the electrical supply port 5 and the opening area S 2 of the compression section 10 while passing through the compression section 10. By a predetermined compression ratio (raising density). On the other hand, since the deposition height of the filament F 1 and the conveying speed of the circulating conveyors 6 and 7 in the supply port 5 affect the density of the compressed filament aggregate F 2 , the deposition height is detected by the detectors 20a, 20b, and 20c. Control and adjust the feed rate of 1 and the feed rate of circulation conveyor 6,7.

압축필라멘트 집합체 F2는 필요에 따라 조밀화장치 21을 통과하는 사이에 바 24에 의하여 조밀화되어 소정의 승밀도를 갖게된다. 이와같이 압축성형된 필라멘트 집합체 블럭은 통상 0.002-0.2g/cm3, 바람직하게는 0.05-0.08g/cm3의 승밀도를 갖는다. 압축성형된 필라멘트 집합체블럭은 반송장치 28,29에 의하여 반송되어 접착제액조 30내의 접착제액 60에 침지된 다음 다른 반송장치 31에 의하여 수직내지는 거의 수직방향으로 인상된다. 집합체블럭이 인상되는 동안 그로부터의 접착제액의 유하는 액체자체의 표면장력에 의한 만큼 저지되며, 그 사이에 필라멘트 성형체 F3에 부착된 여분의 접착제는 성형체내로 유입된다. 이어 그것은 고주파 유전가열장치 32를 통과하면서 극히 순간적으로 부착된 접착제의 수분 또는 용매가 증발됨과 동시에 어느정도 경화되고 필라멘트 상호의 각 접촉점이 결합된 다음 반송장치 42,43으로 이동되며 얻어지는 필라멘트 록크재는 소정치수로 절단된다.The compressed filament aggregate F 2 is densified by the bar 24 between passing through the densification apparatus 21 as needed, and has a predetermined multiplicity. The filament aggregate block thus compressed usually has a multiplicity of 0.002-0.2 g / cm 3 , preferably 0.05-0.08 g / cm 3 . The press-molded filament aggregate block is conveyed by the conveying apparatuses 28 and 29, immersed in the adhesive liquid 60 in the adhesive liquid tank 30, and then lifted by the other conveying apparatus 31 in a substantially vertical direction. While the aggregate block is pulled up, the flow of the adhesive liquid therefrom is restrained by the surface tension of the liquid itself, while the extra adhesive adhering to the filament molded body F 3 flows into the molded body. Subsequently, it passes through the high-frequency dielectric heating device 32, and the moisture or solvent of the extremely instantaneous adhesive is evaporated and at the same time hardened to some extent, each contact point of the filaments are combined, and then moved to the conveying devices 42 and 43, and the resulting filament lock material has a predetermined dimension. Is cut into

한편, 수직방향으로 필라멘트 성형체를 인상할때 그 성형체가 분산될 우려가 있을 경우에는, 침지처리전에 수평주행하는 성형체에 소량의 접착제액을 분무 건조하여 가접착을 행하여도 좋다.On the other hand, when the filament molded body is pulled up in the vertical direction, if the molded body may be dispersed, a small amount of adhesive liquid may be spray-dried onto the molded body that runs horizontally before the immersion treatment to perform temporary adhesion.

대표적인 접착제는 스티렌-부타디엔 고무, 아크릴로니트릴-부타디엔 고무, 클로로프렌 고무, 우레탄고무 등과 같은 합성고무, 천연고무, 초산비닐계접착제, 초산셀룰로우즈계접착제, 아크릴계 접착제 등이 있으며, 라렉스 에멀젼이나 용액의 형태로 사용된다. 접착제도포량은 고형분을 기준으로 통상 10-200g/100g필라멘트, 바람직하게는 50-120g/100g필라멘트이다. 고주파 유전가열장치 32를 통과하는 필라멘트 성형체 F3은 주파수 1MHz-300GHz, 바람직하게는 10MHz-30GHz의 고주파로 접착제액이 가열 건조됨으로서 필라멘트 성형체에 부형성을 줌에 충분한 전력밀도, 즉 0.1-10KWh/cm3, 바람직하게는 0.5-5KWh/cm3의 전력이 투입되어 수분 및 용매가 가열건조 제거되고 필라멘트 상호접착점이 양호하게 결합되는 것이다.Typical adhesives include synthetic rubbers such as styrene-butadiene rubber, acrylonitrile-butadiene rubber, chloroprene rubber and urethane rubber, natural rubber, vinyl acetate-based adhesives, cellulose acetate-based adhesives and acrylic adhesives. Used in the form of a solution. The amount of adhesive applied is usually 10-200 g / 100 g filaments, preferably 50-120 g / 100 g filaments, based on the solid content. The filament molded body F 3 passing through the high-frequency dielectric heating device 32 has a power density sufficient to give the filament molded body by the heat-drying of the adhesive liquid at a high frequency of 1 MHz to 300 GHz, preferably 10 MHz to 30 GHz, that is, 0.1-10 KWh / A power of cm 3 , preferably 0.5-5KWh / cm 3 is applied to heat and remove the moisture and solvent, and the filament interconnection points are combined well.

따라서 필라멘트 성형체 F3을 인상하여 올려도 그의 자중 및 접착제 중량에 의하여 도중에서 절단되는 일은 없다.Therefore, even if the filament molded body F 3 is raised, it is not cut | disconnected midway by its own weight and adhesive weight.

또한 경우에 따라서는 통상의 건조로(도시않음)를 통과시켜 열풍, 적외선, 과열증기등으로 80-200℃(바람직하게는 100-150℃)의 온도로 10-60분(바람직하게는 15-40분)동안 가열한 후 경화가 행하여지고 절단기에 의하여 소정치수로 절단된다.In some cases, it may be passed through an ordinary drying furnace (not shown), and 10-60 minutes (preferably 15-) at a temperature of 80-200 ° C (preferably 100-150 ° C) by hot air, infrared rays or superheated steam. 40 minutes), then curing is performed and cut into predetermined dimensions by a cutter.

록크재가 쿠션재로서 사용될 수 있도록 양호한 반발탄력성이 요구되는 경우에는 접착제처리를 하기전에 리들링장치 22로서 필라멘트 집합체 블럭 F2에 리들링을 실시한다.If good resilience is required so that the lock material can be used as a cushioning material, the filament assembly block F 2 is subjected to a riding device 22 as a ridding device 22 before the adhesive treatment.

리들링은 예를들면 미국특허 제4,172,174호에 개시되어 있는 장치 및 방법을 사용하여 선단부에 적어도 하나의 바브(barb)를 갖는 침을 사용하여 적당한 침밀도로 소정회수 찌름으로서 행할 수 있다.Ridling can be done as a predetermined number of pricks with a suitable needle density using a needle having at least one barb at the tip, for example using the apparatus and method disclosed in US Pat. No. 4,172,174.

침은 목적에 따라 지름 및 길이가 결정되나, 일반적으로 지름은 1.8-3.6mm이고 길이는 50-2,000mm이며, 침 1본당 통상 4-12개의 바브를 갖는다.The needles are determined in diameter and length depending on the purpose, but are generally 1.8-3.6 mm in diameter and 50-2,000 mm in length and typically have 4-12 barbs per needle.

구체적으로 예를들면, 벨트콘베이어 상에서 압축성형된 필라멘트 집합체 블럭 F2의 하면을 평판, 즉, 다공판, 슬리트판, 슬리트상 콘베이어등으로 지지하면서 그에 대향하는 면에 혈명판, 예를들면 다공판, 슬리트판등을 설하고 또는 설하지 아니하고 침취구부를 상하운동시킴에 의하여 필라멘트 집합체블록은 적의밀도로 리들링된다.Specifically, for example, the lower surface of the filament aggregate block F 2 compression molded on the belt conveyor is supported by a flat plate, i.e., a porous plate, a slit plate, a slit conveyor, and the like on the surface facing the plate. The filament assembly block is riddled at an appropriate density by moving up and down the intake openings with or without the slits and the like.

침밀도는 최종적으로 얻어지는 쿠션재의 사용목적내지는 소망되는 압축탄성에 따라 변화하는데, 소망의 압축탄성이 클수록크나, 즉 침간격이 좁아지나 통상 1-100본, 바람직하게는 4-50본/100cm3이다.The sediment density varies depending on the intended use of the cushioning material finally obtained and the desired compressive elasticity. The larger the desired compressive elasticity is, the larger the needle spacing becomes, but usually 1-100, preferably 4-50 / 100/100 cm 3 to be.

또한 상기 리들링대신에 롤링법, 러빙법등에 의하여 필라멘트를 압축하여도 좋다.In addition, the filament may be compressed by a rolling method, a rubbing method, or the like instead of the ridding.

제6도는 본 발명에 따른 필라멘트 록크재를 제조하는 다른 실시태양을 개략적으로 도시한 것으로서 이를 상세히 설명하면 다음과 같다.6 is a schematic view showing another embodiment of manufacturing a filament lock material according to the present invention.

여기서 필라멘트 공급장치 101, 성형장치 102, 제1접착제부착장치 103 및 제1유전가열장치 104는 앞서 제3도-제4도에 도시한 장치와 동일 유사한 것으로 그에 따른 제조공정 역시 동일유사하다. 따라서 제1접착제 부착장치 103에서 접착제도포된 필라멘트 집합체 F3은 제1유전가열장치 104에서 거의 수직방향으로 인상되면서 유전가열되어 필라멘트 집합체 F3내의 필라멘트의 상호접착점이 결합되어 가접착이 행하여진다.Here, the filament supply apparatus 101, the molding apparatus 102, the first adhesive attaching apparatus 103 and the first dielectric heating apparatus 104 are similar to the apparatus shown in FIGS. 3 to 4, and the manufacturing process thereof is also similar. Accordingly, the filament aggregate F 3 coated with the adhesive agent in the first adhesive attachment device 103 is pulled in a substantially vertical direction in the first dielectric heating apparatus 104 to be dielectrically heated so that the interadhesive points of the filaments in the filament aggregate F 3 are bonded to each other to perform temporary bonding.

이것은 반송장치 142, 143에 의하여 제1건조장치 153에 보내지고 거기서 열풍, 적외선등에 의하여 80-200℃로 가열되어 집합체 F4에 도포된 접착제의 건조가 완결된다. 건조처리된 집합체 F4는 증기프레스장치 154에서 수증기존재하 100-125℃로 30초-5분간, 바람직하게는 1-3분간 프레스된 다음 20-60℃로 냉각된다. 프레스 처리된 필라멘트 집합체 F5는 다시 제2접착제 부착장치에 유입되어 제1접착제 부착장치에서와 같이 천연고무계 접착제로 도포된다.This is sent to the first drying apparatus 153 by the conveying apparatuses 142 and 143, where it is heated to 80-200 ° C. by hot air, infrared rays or the like to complete drying of the adhesive applied to the aggregate F 4 . The dried aggregate F 4 is pressed in a steam press apparatus 154 at 100-125 ° C. for 30 seconds-5 minutes, preferably 1-3 minutes, in the presence of steam and then cooled to 20-60 ° C. Pressed filament aggregate F 5 flows back into the second adhesive attachment device and is applied with a natural rubber adhesive as in the first adhesive attachment device.

제2접착제 처리된 필라멘트 집합체 F6는 거의 수직방향으로 인상되면서 제2유전가열장치 156을 통과하며 수분 또는 용제의 대부분이 제거된다.The second adhesive-treated filament aggregate F 6 is pulled in a substantially vertical direction and passes through the second dielectric heating apparatus 156 to remove most of the water or the solvent.

이어 가열처리된 필라멘트 집합체 F7은 순환콘베이어등의 반송장치 159-160에 의하여 제2건조장치 157에 보내지고 여기서 완전 건조된 다음 절단장치 158에서 소정치수로 절단되어 소정의 필라멘트 록크재로 제조된다.The heated filament aggregate F 7 is then sent to a second drying apparatus 157 by a conveying device 159-160, such as a circulating conveyor, which is completely dried and then cut into a predetermined dimension by the cutting device 158 to produce a predetermined filament lock material. .

본 발명에 의한 필라멘트 록코재의 제조는 상술한 바와같이, 개면된 입체컬 합성섬유 필라멘트를 소정형상으로 압축성형하여 얻은 필라멘트 성형체에 접착제액을 부착한 다음 그 성형체를 거의 수직방향으로 인상하면서 고주파에 의한 유전가열로서 부착된 접착제를 건조 경화하는 것이므로 접착제액조중에서 성형체에 부착된 여분의 접착제액은 거의 수직방향으로 인상되는 동안 성형체내로 유하하게 된다. 따라서 사용된 접착제액의 농도, 필라멘트 집합체의 인상속도등에 상응한 양만큼만이 성형체에 균일하게 부착된다. 더우기 성형체에 균일부착된 접착액은 고주파에 의하여 유전가열되므로 순식간에 건조된다. 따라서 성형체를 상방으로 인상하여도 접착제액의 유하량은 적고 필요한 양만큼만 부착할 수 있으며, 또한 필라멘트의 자중 및 부착된 접착제액의 중량에 의하여 중도에서 절단되거나 늘어나는 등의 우려는 없는 것이다.As described above, the filament lock material according to the present invention is attached to the filament molded body obtained by compression molding the opened three-dimensional synthetic fiber filament into a predetermined shape, and then the molded body is pulled in a nearly vertical direction by high frequency. Since the adhesive adhered as dry heating is dried and hardened, the excess adhesive liquid adhered to the molded body in the adhesive liquid tank flows down into the molded body while being pulled almost in the vertical direction. Therefore, only the amount corresponding to the concentration of the adhesive liquid used, the pulling speed of the filament assembly, etc. are uniformly attached to the molded body. Moreover, since the adhesive liquid uniformly attached to the molded body is dielectrically heated by high frequency, it is dried quickly. Therefore, even if the molded body is pulled upward, the amount of the adhesive liquid is small and can be attached only as much as necessary, and there is no fear of being cut or elongated due to the weight of the filament and the weight of the adhesive liquid attached.

이와같이 본 발명에 있어서는 접착제액이 부착된 필라멘트성형체의 가열을 고주파에 의하여 유전적으로 행함으로서 접착제 액중의 용제, 특히 물이 최초로 가열증발되고 다음 합성섬유 필라멘트를 손상시킴이 없이 접착제매개물, 즉, 고무등이 가열경화된다. 또한 피가열체가 필라멘트집합체이므로 고주파의 침투깊이가 커서 내부까지 균일하게 가열또며 접착제의 손실이 감소되는 것이다.Thus, in the present invention, by heating the adhesive filament molded article adhered to the dielectric by high frequency, the solvent in the adhesive liquid, in particular water, is first heated and evaporated without damaging the next synthetic fiber filament, that is, the adhesive medium, that is, rubber, etc. This is heat cured. In addition, since the heating element is a filament assembly, the penetration depth of the high frequency is large, so that the heating is uniformly performed and the loss of the adhesive is reduced.

따라서 본 발명의 방법에 의하여 접착제분포가 균일한 필라멘트록크재가 제조되는 것이다.Therefore, the filament lock material with a uniform adhesive distribution is produced by the method of the present invention.

이하 실시예와 함께 본 발명을 상세히 설명한다.The present invention will be described in detail with the following examples.

[실시예 1-7]Example 1-7

300데니이르의 폴리에스테르 모노필라멘트를 꼬아서 총 30만 데니이르의 토탈필라멘트로 형성한 약 60mm의 입체컬 필라멘트를 압축성형한 다음 약 16본/100cm2의 비율로 니들링을 실시하고 소정치수로 절단한후, 천연고무 라텍스(고형분 60중량퍼센트) 100부(parts : 중량비), 유황분산제 1-3부, 아연화 6-7부, 디티오카바메이트계 가류촉진제(녹셀라-PX) 1-3부 및 물 30중량부로 되는 천연고무계 접착제라텍스중에 침지하고 수직방향으로 인상하면서 주파수 2540 MHz의 고주파를 약 1KWh/cm3의 전력밀도로 조사하여 유전가열을 행하였다. 제조된 성형체의 실시조건 및 시험결과가 도표 1에 표시되어 있다. 한편, 그와같은 유전가열을 행한 다음 120℃로 30분간 후경화를 행하였다. 결과의 필라멘트 록크재를 종으로 2등분하여 승밀도를 측정한바 어느 시료에 있어서도 그 값은 각각 동일하였다.Twisting 300 denier polyester monofilament to form a total filament of 300,000 denier total filaments of about 60mm three-dimensional filament compression molding, and then needled at a ratio of about 16 bone / 100 cm 2 After cutting, 100 parts of natural rubber latex (60% by weight solids) (parts: weight ratio), 1-3 parts of sulfur dispersant, 6-7 parts of zincated agent, dithiocarbamate-based vulcanization accelerator (Noxella-PX) 1-3 Dielectric heating was performed by immersing in a natural rubber adhesive latex consisting of 30 parts by weight and water and pulling it in the vertical direction, irradiating a high frequency of 2540 MHz at a power density of about 1 KWh / cm 3 . The performance conditions and test results of the produced molded articles are shown in Table 1. On the other hand, such dielectric heating was carried out and then post-cured at 120 ° C. for 30 minutes. When the resultant filament lock material was divided into two parts by the length and the density was measured, the values were the same in each of the samples.

[실시예 8-11]Example 8-11

스티렌-부타디엔 고무계 접착제 라텍스를 사용한 것을 제외하고는 실시예 1-7에서와 동일하게 행하였다. 실시조건 및 시험결과는 도표 1에 표시되어 있다.The same procedure as in Example 1-7 was carried out except that styrene-butadiene rubber-based adhesive latex was used. The test conditions and test results are shown in Table 1.

한편, 유전가열후 120℃로 30분간 후경화하여 제조된 필라멘트 록크재를 종으로 2등분하여 승밀도를 각각 측정한 바 어느 시료에 있어서도 그값은 각각 동일하였다.On the other hand, the filament lock material prepared by post-curing at 120 ° C. for 30 minutes after dielectric heating was divided into two parts and the density was measured, respectively. The values were the same in each sample.

[도 표 1][Table 1]

Figure kpo00001
Figure kpo00001

(주) ※ 필라멘트 단위중량에 대하여 부착된 접착제의 중량비(Note) ※ Weight ratio of adhesive attached to unit weight of filament

[비교예][Comparative Example]

실시예 1에서와 같은 필라멘트 성형체를 수평으로 놓고 상방에서 동일한 천연고무계 접착제를 분무한 다음 130℃로 30분간 가열하여 필라멘트록크재를 제조하였다. 제조된 필라멘트 록크재(승밀로 0.055g/cm3)을 상하로 2등분하여 각각 승밀도를 측정한바 상편은 0.044g/cm3이었고 하편은 0.066g/cm3이었다. 또한 침지법에 의하여 접착제 처리한 경우에 동일유사한 양상을 나타내었다.The filament molded body as in Example 1 was placed horizontally, sprayed with the same natural rubber adhesive from above, and heated at 130 ° C. for 30 minutes to prepare a filament lock material. The filament lock material (0.05g / cm 3 in the winmill) was divided into two up and down to measure the density of each, the upper side was 0.044g / cm 3 and the lower side was 0.066g / cm 3 . In addition, when the adhesive treatment by the dipping method showed a similar aspect.

[실시예 12-16]Example 12-16

실시예 1에서와 같은 필라멘트 성형체들을 각각 폴리우레탄 에멀젼인 본딕(Vondic) 1050, 본딕 1030, 본딕 1050, 본딕 1310-B 및 히드란(hydran) HW-311에 침지시킨후 인상하면서 고주파로 유전가열시키고 100℃에서 60분간 후경화시켰다. 산출된 필라멘트 록크재를 종으로 2등분하여 승밀도를 측정한바 어느 시료에 있어서도 그값은 각각 동일하였다.The filament shaped bodies as in Example 1 were immersed in polyurethane emulsions Vondic 1050, Bondic 1030, Bondic 1050, Bondic 1310-B and Hydlan HW-311, and then dielectrically heated at high frequency while being pulled up. Postcure at 100 ° C. for 60 minutes. The filament-locked material was divided into two, and the density was measured. The values were the same in each sample.

Claims (1)

입체컬을 갖는 합성섬유 필라멘트 단섬유를 소정형상으로 압축성형하여 얻은 필라멘트 성형체를 접착제액에 침지한다음 그 성형체를 수직 내지 거의 수직방향으로 인상하면서 1MHz-300GHz의 고주파로 유전가열하여 부착된 접착제를 건조시킴을 특징으로 하는 필라멘트 록크재의 제조방법.The filament molded body obtained by compression molding a synthetic fiber filament short fiber having three-dimensional curls into a predetermined shape is immersed in an adhesive liquid, and then the adhesive is attached by dielectric heating at a high frequency of 1 MHz to 300 GHz while raising the molded body in a vertical to almost vertical direction. Method for producing a filament lock material characterized in that the drying.
KR7904590A 1979-12-24 1979-12-24 Method for the manufacture of a locked material of filament KR840000160B1 (en)

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