KR840000133B1 - Method for manufacturing agriculture material from plant waste - Google Patents

Method for manufacturing agriculture material from plant waste Download PDF

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KR840000133B1
KR840000133B1 KR8202855A KR820002855A KR840000133B1 KR 840000133 B1 KR840000133 B1 KR 840000133B1 KR 8202855 A KR8202855 A KR 8202855A KR 820002855 A KR820002855 A KR 820002855A KR 840000133 B1 KR840000133 B1 KR 840000133B1
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urea
ammonia
plant waste
manufacturing
substrate
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KR8202855A
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KR840000183A (en
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조도진
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신종훈
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K10/00Animal feeding-stuffs
    • A23K10/30Animal feeding-stuffs from material of plant origin, e.g. roots, seeds or hay; from material of fungal origin, e.g. mushrooms
    • A23K10/37Animal feeding-stuffs from material of plant origin, e.g. roots, seeds or hay; from material of fungal origin, e.g. mushrooms from waste material
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K40/00Shaping or working-up of animal feeding-stuffs
    • A23K40/25Shaping or working-up of animal feeding-stuffs by extrusion

Abstract

Agricultural material was prepd. from plant waste. Thus, 100L H2O soln. contg. rice bran, sawdust, stems of Graminaceae sp., roots of herbs and barks of trees, and 3˜5kg urea was mixed with an equal volume of 1˜2kg NaOH in 100LH2O in a compressor (Fig) at 65˜120≰C to give agricultural materials.

Description

식물질 폐자원을 이용한 영농소재(營農素材)의 제조방법Manufacturing Method of Farming Materials Using Plant Waste Resources

제1도는 본 발명의 일부를 절개한 압축기의 예시 정면도.1 is an exemplary front view of a compressor with a portion of the present invention cut away;

제2도는 본 발명 제1도의 A-A'선 단면도.2 is a cross-sectional view taken along the line A-A 'of FIG. 1 of the present invention.

본 발명은 도시한 실시예시도와 같은 열압축 기계장치를 사용하여 농산폐자원인 톱밥, 왕겨, 화본과(禾本科)식물의 잔간(殘稈), 초근목피등을 요소(尿素)와 알카리액을 혼가(混加)하여 열압축 기계장치와 복합작용으로 압축과 마찰열의 물리적 화학처리를 가하여 식물질 기재조직에 암모니아 화합과 파해(破解), 비틀림, 증자작용을 거처 팽연(膨軟) 다공질로서 흡수성이 우수하고 조강성(粗剛性)이 없는 부드러운 미강상태(米糠狀態)로 간편하게 조작하여 가공 제조하므로서 반추가축의 조사료나 사료증량제, 미생물 배양제, 퇴비원료 및 육묘용상토(育苗用床土)등 다목적으로 재생(再生)가공하여 폐자원에 완전활용할 목적으로 연구된 식물폐자원을 이용한 영농소재의 제조방법에 관한 것이다.The present invention is a mixture of urea and alkaline liquids such as sawdust, rice hulls, plant stems, grass roots, etc., which are agricultural waste resources, using a heat compression mechanism as shown in the illustrated embodiment. It is combined with thermal compression machinery to apply physical and chemical treatment of compression and frictional heat to expand and absorb the ammonia into the vegetable base tissue through the action of ammonia compounding, breaking, twisting and increasing. It is a versatile product that can be easily manipulated and manufactured in a soft rice bran state with excellent roughness and no roughness. The present invention relates to a method for producing agricultural materials using plant waste resources, which has been studied for the purpose of being fully recycled and recycled to waste resources.

우리나라는 볏짚, 왕겨, 화본과 식물잔간, 초근목피등 상당한 량의 농산폐자원을 보유하고 있으면서도 아직 사료를 자급하지 못하고 있는데다가 농후사료를 외국도입에 의존하고 있는 실정이어서 초식가축 사양을 농후사료 위주로 사양을 하고 있으며, 조사료 급여부족 및 농후사료의 산성질 사료급여로 특히 낙농분야는 산유량, 번식율, 경제수명하락등 불합리한 경영으로 낙농발전에 지장이 있어 왔으며 또한 농촌에서는 한우(韓牛)를 사육하는데 관습적인 사육방법으로 현금에도 볏짚을 물에 삶아서 먹이고 있어 연료비나 인건비 및 다두사육이라는 것등을 감안할 때 축산가축의 에너지원인 조사료 자원의 개발과 농산부산물의 효과적인 이용이라는 점에서 본 발명의 의의가 있다할 것이다.Although Korea has a considerable amount of agricultural waste resources such as rice straw, rice hulls, flower roots and plant roots, and soybean bark, it has not yet been able to supply its own feeds. In particular, the dairy sector has been hampered by the unreasonable management of dairy production, breeding rate, and economic life due to the shortage of forage and the acidic feed of rich feeds. Rice straw is also boiled and fed to cash as a conventional breeding method, and thus the fuel consumption, labor cost, and multi-head breeding are considered to be meaningful in the present invention in terms of development of forage resources, which are energy sources for livestock raising, and effective use of agricultural by-products. will be.

폐자원을 이용하여 조사료를 제조하는 방법은 여러가지가 있다하겠으나 소규모로 하는 간편한 제조방법은 없었던 것이다.There are many ways to produce forages using waste resources, but there was no easy way to make them on a small scale.

미국에서 왕겨를 사용하여 조사료화하는데 비상(非常)한 고온고압(80-100㎏/㎠)에서 암모니아(NH3)처리를 하여 왕겨조직을 파괴한 다음 비단백 조사료로 하는 방법도 있었으나 이는 특수한 대규모 장치를 필요로 하므로 소규모 실시는 도저히 곤란하였고 또 볏짚의 산(酸)알카리 세척방법이나 암모니아 살포방법등이 있었으나 이 작업 또한 대단히 복잡하고 제조의 상당한 시간을 요하게 되며, 또 산이나 알카리 처리에서는 최후의 세척작업 과정에 많은량의 세척수를 필요로 함은 물론 산, 알카리의 폐수처리에 따른 공해요인도 발생하게 되는 것이다.Using the chaff from the American Science and Chemistry in an emergency (非常) a high-temperature high-pressure ammonia (80-100㎏ / ㎠) (NH 3 ) treatment destroys the chaff tissue but also the following method of a non-single-back Science This special large Small scale implementation was difficult due to the need for an apparatus, and there were acid cleaning methods for rice straw and ammonia spraying methods, but this work was also very complicated and required a considerable time for manufacturing. In addition to the need for a large amount of washing water during the cleaning process, pollution is also generated by wastewater treatment of acid and alkali.

본 발명에서는 이와 같은 상기한 요인을 개선연구한 결과 압축기와 요소, 알카리의 열물리적 화학의 복합작용을 발명하게 된 것으로 이를 첨부된 실시예도의 의거하여 상세히 설명하면 다음과 같다.In the present invention, as a result of improving the above-described factors, the present invention has been invented a complex action of the thermophysical chemistry of the compressor, urea, and alkali, which will be described in detail with reference to the accompanying drawings.

제1도에 도시한 바와 같이 압출기(1) 상단흡퍼(1')에 왕겨, 톱밥, 화본과, 식물잔간, 초근목피등을 6-10㎟로 조쇄한 것에다 요소(Urea)와 가성소다(NaOH)용액을 살포하여 함수율 20-35%로 한 후 투입하면 압축기(1)내에서 회전되는 스크류(2)의회전력에 의해 점차 그 선단부에 형성된 경사면(2')에서 강압된 상태로 가열되어 압축실(3)로 이송된 식물질 기재는 압축 마찰되므로 인해 그 상승온도가 65-120℃까지되며, 섬유질의 파해(破解)와 비틀림 및 요소(Urea)분해로 인한 암모니아가스의 화합흡수가 이루워진다.As shown in FIG. 1, the extruder (1) is made up of 6-10 mm2 of rice hulls, sawdust, flower roots, plant residues, root bark, etc. in the upper absorber (1 '), and urea (Urea) and sodium hydroxide (NaOH). After spraying the solution to make the water content 20-35%, and inputting it, it is heated in a state of being pressed down on the inclined surface 2 'formed at the distal end by the rotating power of the screw 2 rotated in the compressor 1, and the compression chamber The plant substrate transported to (3) has the elevated temperature up to 65-120 ℃ due to the compression friction, and the absorption of ammonia gas due to fiber breakdown, torsion and urea decomposition is achieved. .

이와 같이 가열압축실(3)에서 압축 및 가열된 식물질 기재는 배출구에서 절삭칼(4)에 의해 절삭되며 배출시 급속히 그 압력이 저하되므로서 식물질 기재내부에 축적되어 있던 수증기와 탄산가스 및 암모니아가스등이 급격히 팽창 확산되므로 인한 폭발력에 의해 섬유질 내부로부터 팽창파괴가 이루워지게 되고 생성된 물체는 조강성이 없는 부드러운 미강상태로 됨은 물론 침수률도 100%의 최대 흡수량으로 그 중량비 또한 400%가 되는 유연한 다공질체가 되는 것으로 이를 비교표에 의거 구체적으로 대비하면 다음과 같다.Thus, the vegetable substrate compressed and heated in the heating compression chamber (3) is cut by the cutting knife (4) at the discharge port, and the pressure rapidly decreases during discharge, so that the water vapor and carbon dioxide accumulated in the vegetable substrate and The explosive force caused by the explosive force caused by the rapid expansion and expansion of ammonia gas results in the expansion and destruction from the inside of the fiber, and the resultant object becomes the soft rice bran without roughness. Being a flexible porous material to be prepared in detail according to the comparison table as follows.

[비교표][Comparison Table]

Figure kpo00001
Figure kpo00001

요소(Urea)와 가성소다(NaOH)액의 혼합물을 가열하게 되면 2산화탄소(CO2)와 암모니아(NH3)가스로 변성(變成)된다.When the mixture of urea and sodium hydroxide solution is heated, carbon dioxide (CO 2 ) and ammonia (NH 3 ) gas are denatured.

본 발명에서 핵심요소가 되는 것으로서 압출시의 작용을 기술하면, 압출기에 스크류가 가압되면 먼저 기재의 살포된 요소와 알카리용액이 그 크스류의 압력과 비틀림으로 인하여 섬유질 내부에 완전히 침투되며 여기에 함유되어 있는 알카리는 기질과 강하게 결합된 수지류(樹脂類) 및 리구닝, 팬토산, 패주징등을 용해하거나 분해시켜 섬유질을 팽윤, 연화(軟化)시켜 주며 또 한편으로는 요소와 작용하여 2산화탄소(CO2)와 암모니아(NH3)가스를 발생하게 된다.When describing the action during extrusion as a key element in the present invention, when the screw is pressed in the extruder, the sprayed urea and alkaline solution of the substrate first completely penetrates into the fiber due to the pressure and twisting of the crumbs and is contained therein. Alkaline is dissolved or decomposed into resins, liguning, pantosan, and packaging that are strongly bound to the substrate to swell and soften the fibers, and on the other hand, it acts as a urea to deoxidize Carbon (CO 2 ) and ammonia (NH 3 ) gas will be generated.

고압하에 암모니아가스는 기재섬유질에 화합되여 유기체 질소로서 잔류되기 때문에 이것은 반추가축의 조사료로서 절대적으로 필요한 것이다. 가압에 의한 증기압은 10-15㎏/㎠로서 식물질 섬유질은 고압증자가 되는 것으로 기질의 분해가 용이하게 진행되며 가열압축실(3)에서는 기재가 고온고압을 받어 물리적 화학반응을 받는 것으로 유기질소체(有機窒素體)는 이곳에서 생성되는 것이다.Under high pressure, ammonia gas is combined with the base fiber and remains as organic nitrogen, which is absolutely necessary as a ruminant feedstock. The vapor pressure by pressurization is 10-15㎏ / ㎠ and the plant fiber becomes a high-pressure cooker and the decomposition of the substrate proceeds easily.In the heating compression chamber 3, the substrate is subjected to high temperature and high pressure to undergo a physical chemical reaction. (有機 窒 素 體) is created here.

이와같이 된 식물질 기재는 배출구에서 고형체(固型體)로 압출되므로 이를 절삭칼(4)로 절삭시킴과 동시에 급속으로 압력을 하강시켜 줌에따라 기질내부에 함유되어 있는 가스의 폭발적인 확산력으로 기재섬유질 내부로부터 파해가 이루워지도록 하여 부드러운 미강상태로 생성되게 하는 것이다.Thus, the vegetable substrate is extruded into a solid body at the outlet, so that it is cut with a cutting knife (4) and at the same time, the pressure is rapidly lowered, and the substrate is exploded by the explosive diffusion force of the gas contained in the substrate. The breakage is made from the inside of the fiber to create a smooth rice bran state.

상기한 방법으로 생성된 기질섬유는 스크류 압축으로 인한 가열. 증자. 비틀림, 파해등으로 섬유질 상호간의 결합이 끈기고 혼입된 알카리는 이 작용으로 리구닝(lignin)등이 용출되고 또한 연화팽윤(膨潤)된 상태에서 요소의 열분해로 발생한 암모니아가스의 요소분해, 유기질 소체화합물(有機窓素體化合物)이 되어서 반추가축에는 아주 적합한 조사료가 되며 가축의 급여시는 소화흡수(吸收)가 양호하며 "우레아제"로 인한 암모니아 중독이 전무한 조사료가 된다.The substrate fiber produced by the above method is heated by screw compression. Increase. Alkaline, which has been endured by the twisting, breaking, etc. of the fibers, is mixed with ligaments. It is a compound, which is a very suitable forage for ruminants, and it has good digestion absorption when feeding livestock and no ammonia poisoning due to "urease".

양축농가에서는 요소의 가축급여를 어렵게 여기는 이유는 반추동물의 암모니아 중독을 염려하는 까닭이나 요소가 반추가축에 급여되면 가축의 제1위(胃)에 상재(常在)하고 있는 미생물군(群)이 생산하는 "우레아제"로 인하여 단시간내에 급여된 요소가 급속히 암모니아가스로 분해되어 영양원으로 이용되기 전에 혈중(血中)의 고농도로 이행하여 암모니아 중독을 당하게 되기 때문이다. 그러므로 본 발명에서는 요소를 알카리와 작용시켜 열분해로 일단 암모니아가스로 분해한 것을 스크류의 작동으로 인한 고압으로 식물질 섬유에 유기체 질소로 화합하여서 단일요소 급여와는 달리 반추 제1위(胃)에서 생산되는 "우레아제"로 인한 암모니아발생은 전무한 것이다. 요소는 일단 암모니아 분해하여 기재섬유질과 고온고압에서 화합체(化合體)로 하여서 급여하면 "우레아제"로 인한 부작용이 발생치 않는 것이다.The reason why it is difficult for livestock farmers to raise urea is because they are concerned about ammonia poisoning of ruminants, but when urea is fed to ruminants, it is a microorganism group that is in the first place of livestock. This is because "urease" produced by the urea is rapidly decomposed into ammonia gas, which is rapidly decomposed into ammonia, and is converted into high concentrations in the blood and ammonia poisoning occurs. Therefore, in the present invention, the urea works with alkali, and once decomposed into ammonia gas by pyrolysis, it is combined with vegetable nitrogen at high pressure due to the operation of the screw with organic nitrogen and produced in the rumen No. 1, unlike single-element feeding. There is no ammonia generation due to the "urease". Urea is once decomposed into ammonia and fed as a compound at high temperature and high pressure so that no side effects due to "urease" occur.

[실시예]EXAMPLE

원료인 왕겨, 톱밥, 화본과, 식물의 잔간, 초근목피등을 6-10㎟로 조쇄한 것 100㎏에도 요소(Urea) 3-5㎏을 청수 100ℓ에다 용해한 것과 가성소다(NaOH) 1-2㎏을 청수 100ℓ에 용해한 것을 동량비로 혼합하여 조쇄된 식물질 기재에다 균등살포시켜 함수율을 20-35%로 스성한 후 압출기에 투입하여 스크류로 이송압축하여서 내부온도 65-120℃에서 배출시 절사칼로 절삭될 때 급속으로 압력을 하강시켜서 섬유질 내부로부터 팽창파해토록 한다.The raw material of rice husk, sawdust, flower, and plant residues, roots and bark is 6-10 mm2. In 100 kg of 100 kg of urea dissolved in 100 l of fresh water and 1-2 kg of sodium hydroxide (NaOH). Was dissolved in 100 liters of fresh water in equal proportions and evenly sprayed on the pulverized vegetable substrate, and the water content was 20-35% .Then, it was fed into an extruder and compressed by transfer with a screw. When the pressure is rapidly lowered to expand and break from the inside of the fiber.

Claims (1)

본문에 상술하고 도시한 바와같이 식물질기재에 1-2%의 가성소다(NaOH)용액과 3-5%의 요소(Urea)용액을 동량비로 살포한 후 함수율을 20-35%로 하여 축압기내에서 압축가열하고 압축실온도 65-120℃에서 배출되어 절삭될때 급속으로 압력이 하강하여 섬유질 내부조직이 팽창파해케 됨을 특징으로 하는 식물질 폐자원을 이용한 영농소재의 제조방법.As described above and shown in the text, 1-2% caustic soda (NaOH) solution and 3-5% urea (Urea) solution are sprayed in the same ratio, and the water content is 20-35%. A method of manufacturing a farm material using plant waste resources, characterized in that the internal pressure of the fibrous internal tissue expands and breaks down when the heat is compressed and discharged at a compression chamber temperature of 65-120 ° C.
KR8202855A 1982-06-26 1982-06-26 Method for manufacturing agriculture material from plant waste KR840000133B1 (en)

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