KR830006381A - Manufacturing method of crosslinked vinyl chloride foam - Google Patents

Manufacturing method of crosslinked vinyl chloride foam

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Publication number
KR830006381A
KR830006381A KR1019810002255A KR810002255A KR830006381A KR 830006381 A KR830006381 A KR 830006381A KR 1019810002255 A KR1019810002255 A KR 1019810002255A KR 810002255 A KR810002255 A KR 810002255A KR 830006381 A KR830006381 A KR 830006381A
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KR
South Korea
Prior art keywords
vinyl chloride
chloride resin
stabilizer
producing
blowing agent
Prior art date
Application number
KR1019810002255A
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Korean (ko)
Other versions
KR840000566B1 (en
Inventor
쥰노스께 사사지마
히로시 나가이
겐지 모기
아끼오 노지리
나오노리 시이나
Original Assignee
후나하시 마사오
후루가와뎅끼 고오교 가부시끼 가이샤
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Priority to KR1019810002255A priority Critical patent/KR840000566B1/en
Publication of KR830006381A publication Critical patent/KR830006381A/en
Application granted granted Critical
Publication of KR840000566B1 publication Critical patent/KR840000566B1/en

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/70Material containing nitrile groups
    • D06P3/76Material containing nitrile groups using basic dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/70Material containing nitrile groups

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

내용 없음No content

Description

가교염화비닐 수지 발포체의 제조방법Manufacturing method of crosslinked vinyl chloride foam

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (14)

염화비닐수지, 가소제, 안정제, 가교조제 및 발포제로써 되고, 겔화처리를 거친 혼합물을 소기의형상으로 성형하는 제1공정과, 이 성형체에 전리성 방사선을 조사하여 가교하는 제2공정과, 이 가교체를 가열하여 발포시키는 제3공정으로써 됨을 특징으로 하는 가교염화비닐 수지 발포체의 제조방법.A first step of forming a gelled mixture into a desired shape, comprising a vinyl chloride resin, a plasticizer, a stabilizer, a crosslinking aid, and a blowing agent; a second step of irradiating and crosslinking the molded product with ionizing radiation; A method for producing a cross-linked vinyl chloride resin foam, characterized by comprising a third step of heating and foaming a sieve. 전기 제1공정이 염화비닐수지, 가소제, 안정제 및 가교조제를 염화비닐 수지의 겔화는 온도에서 혼합하고 다음에 이와 같이 하여 얻어진 혼합물에 발포제를 그 발포제가 분해하지 않는 온도에서 혼합하고 다음에 이 혼합물을 그 발포제가 분해하지 않는 온도에서 압출기 또는 칼렌더 로울로서 시이트 상으로 성형함을 특징으로 하는 청구의 범위 제1항 기재의 가교염화비닐 수지 발포체의 제조방법.In the first step, the vinyl chloride resin, the plasticizer, the stabilizer and the crosslinking aid are mixed at a temperature for gelling the vinyl chloride resin, and then the blowing agent is mixed at a temperature at which the blowing agent does not decompose and then the mixture is obtained. The method for producing a cross-linked vinyl chloride resin foam according to claim 1, wherein the foaming agent is molded into an sheet as an extruder or a calendar roll at a temperature at which the blowing agent does not decompose. 전기 제1공정이 염화비닐수지, 가소제 및 안정제를 염화비닐수지의 겔화하는 온도에서 혼합하고, 다음에 이와 같이 하여 얻어진 혼합물에 가교조제 및 발포제를 그 발포제가 분해하지 않는 온도에서 혼합하고, 다음에 이 혼합물을 그 발포제가 분해하지 않는 온도에서 압출기 또는 칼렌더 로울로써 시이트상으로 성형함을 특징으로 하는 특허청구의 범위 제1항 기재의 가교염화비닐수지 발포체의 제조방법.In the first step, the vinyl chloride resin, the plasticizer, and the stabilizer are mixed at the temperature at which the vinyl chloride resin is gelled. Then, the crosslinking aid and the blowing agent are mixed in the mixture thus obtained at a temperature at which the blowing agent does not decompose. A method for producing a crosslinked vinyl chloride resin foam according to claim 1, wherein the mixture is molded into a sheet by an extruder or a calendar roll at a temperature at which the blowing agent does not decompose. 전기 제1공정이 염화비닐수지, 2000℃에 있어의 증기압이 1.0mmHg 이하의 가조세, 주석계안정제 0.5PHR 이상, 가교조세 및 발포제로서의 아조디카르본아미드를 그 발포제가 분해하지 않고 또한 염화비닐수지가 겔화하는 온도에서 혼합하고 다음에 발포제가 분해하지 않는 온도에서 압출기 또는 칼렌더 로울로써 시이트상으로 성형함을 특징으로 하는 특허청구의 범위 제1항 기재의 가교염화비닐수지 발포체의 제조방법.In the first step, the vinyl chloride resin, the vapor pressure at 2000 ° C of 1.0 mmHg or less, the crude tax stabilizer 0.5 PHR or more, the crosslinking tax and the azodicarbonamide as the blowing agent are not decomposed by the blowing agent and the vinyl chloride resin. A method for producing a crosslinked vinyl chloride resin foam according to claim 1, characterized in that it is mixed at a temperature at which the gel is gelatinized and then molded into a sheet by an extruder or a calendar roller at a temperature at which the blowing agent does not decompose. 주석계 안정제가 유기주석라우릴레이트, 유기주석말레에이트 및 유기주석멜캅타이도의 군으로부터 선택되는 화합물로써 됨을 특징으로 하는 특허청구의 범위 제4항 기재의 가교염화비닐수지 발포체의 제조방법.A method of producing a crosslinked vinyl chloride resin foam according to claim 4, wherein the tin stabilizer is a compound selected from the group consisting of organotin laurate, organotin maleate and organotin melcaptido. 주석계 안정제와 함게 연계 안정제를 제외한 다른 안정제를 병용함을 특징으로 하는 특허청구의 범위 제4항 기재의 가교염화비닐수지 발포체의 제조방법.A method for producing a crosslinked vinyl chloride resin foam according to claim 4, characterized by using a stabilizer other than a linking stabilizer together with a tin stabilizer. 전기 제1공정이 염화비닐수지, 200℃에 있어의 증기압이 1.0mmHg 이하의 가소제, 연계안정제 0.5PHR 이하, 가교조제 및 발초제로서의 아조디카르본아미드를 그 발포제가 분해하지 않고 또한 염화비닐수지가 겔화하는 온도에서 혼합하고 다음에 발포제가 분해하지 않는 온도에서 압출기 또는 칼렌더 로울로서 시이트상으로 성형함을 특징으로 하는 특허청구의 범위 제1항 기재의 가교염화비닐 수지 발포체의 제조방법.In the first step, the vinyl chloride resin, the plasticizer having a vapor pressure of 200 mm or less at 1.0CHg, the co-stabilizer 0.5PHR or less, the azodicarbonamide as a crosslinking aid and a repellent agent did not decompose the foaming agent, A method for producing a cross-linked vinyl chloride resin foam according to claim 1, characterized in that it is mixed at a temperature for gelation and subsequently molded into a sheet as an extruder or calendar roll at a temperature at which the blowing agent does not decompose. 연계 안정제가 3염기성 황산연, 2염기성 스테아린산연, 스테아린산연, 납, 2염기성 아린산연, 2염기성 프탈산연, 3염기성 말레인산연, 규산연 및 규산실리카겔 공침물의 군으로부터 선택되는 화합물로써 됨을 특징으로 하는 특허청구의 범위 제7항 기재의 가교염화비닐 수지 발포체의 제조방법.The linking stabilizer is a compound selected from the group consisting of tribasic lead sulfate, dibasic stearic acid lead, stearic acid lead, lead, dibasic lead acid arginate, dibasic lead phthalate, tribasic maleic acid lead, lead silicate and silicate silica gel coprecipitation. The manufacturing method of crosslinked vinyl chloride resin foam of Claim 7. 연계 안정제와 함께 다른 안정제를 병용함을 특징으로 하는 특허청구의 범위 제7항 기재의 가교염화비닐 수지 발포체의 제조방법.A method for producing a crosslinked vinyl chloride resin foam according to claim 7, wherein another stabilizer is used in combination with a linkage stabilizer. 염화비닐수지가 염화비닐 호모폴리머 및 염화비닐 50중량% 이상을 함유하는 염화비닐 코 폴리머의 군으로부터 선택되는 수지임을 특징으로 하는 특허청구의 범위 제1항 기재의 가교염화비닐 수지 발포체의 제조방법.A method for producing a cross-linked vinyl chloride resin foam according to claim 1, wherein the vinyl chloride resin is a resin selected from the group of vinyl chloride homopolymer and vinyl chloride copolymer containing 50% by weight or more of vinyl chloride. 가소제로서 프탈산에스테르류, 인산에스테르류, 에폭시화식물유, 니트릴계 합성고무 및 염소화파라핀의 군으로부터 선택되는 화합물 20∼120PHR 사용함을 특징으로 하는 특허청구의 범위 제1항 기재의 가교염화비닐 수지 발포체의 제조방법.As a plasticizer, a compound 20 to 120 PHR selected from the group consisting of phthalic acid esters, phosphate esters, epoxidized vegetable oils, nitrile-based synthetic rubbers and chlorinated paraffins is used. Manufacturing method. 가소제로서 디이소데실 프탈레이트, n-디데실프탈레이트, 디트리데실프탈레이트, 디이소라우릴프탈레이트, 디라우릴프탈레이트, 트리옥틸트리멜리데이트, 트리데실트리멜리데이트, 트리크레딜포스페이트, 에폭시화 대두유 및 분자량 약 1000 이상의 아디핀산 또는 아젤라인산계 폴리에스테르의 군으로부터 선택되는 화합물을 30PHR 이상 사용함을 특징으로 하는 특허청구의 범위 제4항 또는 제7항 기재의 가교염화비닐수지 발포체의 제조방법.As a plasticizer, diisodecyl phthalate, n-didecyl phthalate, ditridecyl phthalate, diisolauryl phthalate, dilauryl phthalate, trioctyl trimellidate, tridecyl trimellidate, tricredil phosphate, epoxidized soybean oil and molecular weight A method for producing a crosslinked vinyl chloride resin foam according to claim 4 or 7, wherein a compound selected from the group of at least about 1000 adipic acid or azelaic acid polyesters is used at least 30 PHR. 내용없음.None. 가교조제로서 트리아릴시이누레이트, 트리아릴이소아누레이트, 트리메티로울프로판트라아크릴레이트, 트리메티로울프로판트리메타크릴레이트, 에틸렌글리콜디메타크릴레이트, 디에틸렌글리콜디메타크릴레이트, 트리에틸렌글리콜디메타크릴레이트 및 폴리에틸렌글리콜디메타크릴레이트의 군으로부터 선택되는 화합물을 0.5∼20PHR 사용함을 특징으로 하는 특허청구의 범위 제1항 기재의 가교염화비닐수지 발포체의 제조방법.As a crosslinking aid, triarylcyanurate, triarylisoanurate, trimethoolol propane triacrylate, trimethoolol propane trimethacrylate, ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, triethylene glycol A method for producing a crosslinked vinyl chloride resin foam according to claim 1, wherein the compound selected from the group consisting of dimethacrylate and polyethylene glycol dimethacrylate is 0.5 to 20 PHR. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019810002255A 1981-06-20 1981-06-20 Method of manufacturing cross linked p v c foam products KR840000566B1 (en)

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Application Number Priority Date Filing Date Title
KR1019810002255A KR840000566B1 (en) 1981-06-20 1981-06-20 Method of manufacturing cross linked p v c foam products

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Application Number Priority Date Filing Date Title
KR1019810002255A KR840000566B1 (en) 1981-06-20 1981-06-20 Method of manufacturing cross linked p v c foam products

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KR830006381A true KR830006381A (en) 1983-09-24
KR840000566B1 KR840000566B1 (en) 1984-04-23

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100325397B1 (en) * 1999-07-14 2002-03-04 송영국 Foaming Product used waste synthetic resin and their manufacturing method
KR100345299B1 (en) * 1999-09-08 2002-07-25 재단법인 포항산업과학연구원 A Plastic Foam Composition containing Used Agricultural Film and A Method for Manufacturing Foam Using It

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100325397B1 (en) * 1999-07-14 2002-03-04 송영국 Foaming Product used waste synthetic resin and their manufacturing method
KR100345299B1 (en) * 1999-09-08 2002-07-25 재단법인 포항산업과학연구원 A Plastic Foam Composition containing Used Agricultural Film and A Method for Manufacturing Foam Using It

Also Published As

Publication number Publication date
KR840000566B1 (en) 1984-04-23

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