KR830001094B1 - How to reduce the dust in the exhaust gas of rotary kilns - Google Patents

How to reduce the dust in the exhaust gas of rotary kilns Download PDF

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KR830001094B1
KR830001094B1 KR1019790002503A KR790002503A KR830001094B1 KR 830001094 B1 KR830001094 B1 KR 830001094B1 KR 1019790002503 A KR1019790002503 A KR 1019790002503A KR 790002503 A KR790002503 A KR 790002503A KR 830001094 B1 KR830001094 B1 KR 830001094B1
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dust
exhaust gas
solid fuel
reduce
rotary kiln
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KR1019790002503A
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Korean (ko)
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페터슨 엠. 에스씨. 헬게호
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오베닐슨
에프. 엘 스미스 앤드 캄파니
엔. 이. 하스트럽
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00Treating solid fuels to improve their combustion
    • C10L9/10Treating solid fuels to improve their combustion by using additives

Abstract

내용 없음.No content.

Description

로터리킬른의 배기가스에 함유된 분진을 억제시키는 방법How to reduce the dust in the exhaust gas of rotary kilns

본 발명은 로터리킬른에서 분쇄된 광성이 고체 연료로 처리되어질 때 생기는 배기가스를 정전 집진기로 보내는 로터리 킬른 플랜트 조작 방법에 관한 것이다.The present invention relates to a rotary kiln plant operating method for sending exhaust gas generated when the pulverized mineral in the rotary kiln is treated with a solid fuel to an electrostatic precipitator.

로터리 킬른 플랜트로 분진-가스에서 분진을 침전시키는 공정은 매우 어려운 것으로 알려져왔다.The process of depositing dust from dust-gas into rotary kiln plants has been known to be very difficult.

통상적으로 가스의 세척을 위하여 정전집진기를 사용 하며, 가스조절을 위해 여러첨가제를 사용하며, 99%이상의 분진세척효율을 가진 정전 집진기의 기능을 증가시키기 위해서 분진의 고유 저항성을 감소 시킨다. 화학물질이 첨가되거나 되지않는 물 또는 스팀을 주입하여 가스류를 조절하는 것은 잘 알려져 있으며 이러한 결과로 분진의 고유 저항성은 적당한 수준으로 감소된다.In general, electrostatic precipitator is used to clean the gas, and various additives are used to control the gas, and the intrinsic resistance of the dust is reduced to increase the function of the electrostatic precipitator having a dust cleaning efficiency of more than 99%. It is well known to control the gas flow by injecting water or steam with or without chemicals, and as a result, the resistivity of the dust is reduced to an acceptable level.

종래 기술로부터 광석의 연소를 위해 로터리킬른으로부터 배기 가스류를 조절하는 것이 알려져 있으며 특히 조절제로서 하나 또는 다수 수용성 알카리금속 화합물이 집진기를 통과하기전에 가스류에 주입되면 시멘트 원료물질이 시멘트 점결제로 변화한다.It is known from the prior art to regulate the exhaust gas flow from the rotary kiln for the burning of ore, especially when one or more water-soluble alkali metal compounds are injected into the gas stream before passing through the dust collector as a regulator, the cement raw material is converted into cement binder. do.

본 조절은 1010ohm cm 이하로 고유 저항성을 감소 시키는 분진의 고유 저항성에 대해서 효과적이며 필터유동과 집진장치의 효율 증가를 가능케한다.This control is effective for the resistivity of the dust, which reduces the resistivity below 10 10 ohm cm and allows for increased filter flow and efficiency of the dust collector.

로터리 킬른에서 고체연료를 사용할 때 많은 양의 분재가 생성되고 집진기로 배출된다. 배기가스류에서 분진의 입자크기 분포는 입자직경이 10내지 20미크론이다.When using solid fuel in rotary kilns, a large amount of bonsai is produced and discharged to the dust collector. The particle size distribution of dust in the exhaust gas stream has a particle diameter of 10 to 20 microns.

이들 입자는 집진되기가 어렵고 이들 저항력은 가끔 임계치 1010ohm cm 을 초과하며 산화황으로 공기오염을 제거하기 위해서는 저황탄을 사용하는 것이 바람직하다.These particles are difficult to collect and their resistivity sometimes exceeds a threshold of 10 10 ohm cm and low sulfur is preferred to remove air pollution with sulfur oxides.

최근 조사에의하면, Na2O 약 2%의 재에존재하는 나트륨의 암계치 아래인 저황탄에서 분재의 저항력을 감소시킨다.Recent investigations have reduced the resistance of bonsai to low-sulphur coal, which is below the dark threshold of sodium present in the ash of about 2% Na 2 O.

조절제로서 수용성 알카리금속 화합물을 침전기로 통과시키기 전에 배기가스류로 주입시키는 것은 잘 알려져 있으며 본 방법은 배기가스류에서 분재의 저항력을 감소시킨다. 더우기, 배기가스류에 조절제를 주입시키면 조절제가 집진기를 통과하므로 분재입자가 극히작고, 부드럽게 현탁에 잔존하여 첨가제의 분포가 불규칙하게 된다.It is well known to inject the water-soluble alkali metal compound into the exhaust gas stream before passing it through the settler as a regulator and the method reduces the resistance of the bonsai in the exhaust gas stream. In addition, when the regulator is injected into the exhaust gas stream, the regulator passes through the dust collector, so that the bonsai particles are extremely small and remain in suspension, resulting in irregular distribution of additives.

좋은 조절효과를 얻기 위해서는 다단식 주입노즐과 주입챔버를 사용해야하므로 침전기설비가 복잡해진다To achieve good control effect, the multistage injection nozzle and injection chamber must be used, which complicates the settler system.

본 발명에 의하며, 집진기를 가진 로터리킬른 조작방법은 분진-배기가스의 저항력을 감소시키기 위해 로터리 킬른에서 고체연료를 사용하기 전에 알카리-금속화합물을 첨가한 고체연료를 연소 시킨다.According to the present invention, a rotary kiln operating method with a dust collector burns a solid fuel containing an alkali-metal compound before using the solid fuel in a rotary kiln to reduce the resistance of dust-exhaust gas.

고체연료에 첨가된 고체알칼리-금속화합물은 고체연료와 함께 연소 되어 가스류에서 적당하게 분포되 고 분재입자와 반응한다.The solid alkali-metal compound added to the solid fuel is combusted with the solid fuel to be properly distributed in the gas stream and react with the bonsai particles.

고체연료를 분쇄시키기전에 고체연료에 조절제(알칼리-금속화합물, 또는 화합물)를 첨가히키는 것이 바람직하다.It is preferable to add a modifier (alkali-metal compound, or compound) to the solid fuel before grinding the solid fuel.

연료와 조절제를 잘혼합시키면 분재의 화학적 조성은 조절제에 의해서 상기에서 언급한 임계치 이하의 저항력을 갖는다.If the fuel and regulator are mixed well, the chemical composition of the bonsai will have a resistance below the threshold mentioned above by the regulator.

다른 방법에는 고체-연료의 살포에 의해서 고용체 화합물에 의하여 알카리-금속화합물을 첨가시킨다.In another method, the alkali-metal compound is added by a solid solution compound by solid-fuel sparging.

연료에 바다물 또는 물을 함유한 수용성 알칼리-금속화합물을 분사시키면 적당한 조절제가 생긴다.Injecting a water-soluble alkali-metal compound containing sea water or water into the fuel results in a suitable regulator.

조절제는 배기가스에서 분진을 토대로 해서 산출한 Na2O 2%이상의 량과 동일량을 첨가시키는 것이 바람직하다.The regulator is preferably added in an amount equal to or greater than 2% Na 2 O calculated on the basis of dust in the exhaust gas.

바람직한 조절제는 염화나트륨 고체를 Na2O 2%와 동일량의 배기가스의 소듐함량에 상응하는 1 : 200이상의 비로 고체연료에 첨가시킨다.Preferred modifiers are added sodium solids to the solid fuel in a ratio of at least 1: 200 corresponding to the sodium content of the exhaust gas in an amount equal to Na 2 O 2%.

이 방법은 실험결과 대단히 효과가 좋았다.This method worked very well.

석회 연소플란트는 일일 생산량이 260톤이고 고체연료를 분쇄하기전에 고체연료 연소부터(가스온도는 40℃) 상승하는 분진의 양을 토대로 산출한 염화나트륨 3.5%를 첨가시킨 고체연료를 부분적으로 연소시켜 집진기 효율을 99.1% 내지 99.9%로 증진시켰다.Lime combustion plant has a daily output of 260 tons and the dust collector is partially burned by adding solid fuel with 3.5% sodium chloride calculated on the amount of dust rising from solid fuel burning (gas temperature is 40 ℃) before grinding the solid fuel. The efficiency was increased from 99.1% to 99.9%.

Yes

집진기의 진행을 개량하기 위해서 분진의 건조조절이 260ts/24hr인 클린을 1978년 6월에 덴마크 석회 플란트에서 사용하였다. 클린은 40ts/24hr 석탄에 상응하는 40/60% 오일/석탄에 비례해서 오일/석탄 연소 시킨다.To improve the progress of the precipitator, a clean with a dry control of 260ts / 24hr was used in a Danish lime plant in June 1978. Clean fires oil / coal in proportion to 40/60% oil / coal equivalent to 40ts / 24hr coal.

염화나트륨을 석탄 분쇄기에서 분쇄하기 전에 콘베어 벨트를 이동하는 동안 석탄에서 직접 분리시킨다.Sodium chloride is separated directly from the coal while moving the conveyor belt before grinding in a coal mill.

염화나트륨의 함량은 석탄의 0.43%이다.The content of sodium chloride is 0.43% of coal.

집진기에서 집진된분진에서 Na2O의 함량은 0.21% 내지 0.30%이다.The amount of Na 2 O in the dust collected in the dust collector is 0.21% to 0.30%.

결과는 염화나트륨의 분배와 침전기 진행사이에는 밀접한 관계가 있음을 보여준다. 먼지의 비저항력은 3.5×1012ohm×㎝ 내지 1.5×1011ohm×㎝로 감소되며 이러한 결과로 먼지농도는 517㎎/N㎥ 건조가스 내지 64㎎/N㎥ 건조가스로 굴뚝에서 감소한다.The results show a close relationship between the distribution of sodium chloride and the progress of the settler. The resistivity of the dust is reduced from 3.5 × 10 12 ohm × cm to 1.5 × 10 11 ohm × cm, and as a result, the dust concentration is reduced in the stack from 517 mg / Nm 3 dry gas to 64 mg / Nm 3 dry gas.

이송속도는 8.47dm/sec 내지 12.73㎝/sec로 증가된다.The feed rate is increased from 8.47 dm / sec to 12.73 cm / sec.

Claims (1)

정전 집진기를 가진 로터리킬른 플랜트에서 연소공정시 생기는 배기가스의 고유저항을 감소시키는 조절방법에 있어서 고체연료를 로터리킬른 플랜트에서 연소시키기전 염화나트륨을 분쇄된 연료에 대하여 1 : 200의 비로 첨가시키는 것을 특징으로 하는 배기가스의 고유저항력을 감소시켜 분진을 억제하는 방법.In a rotary kiln plant with an electrostatic precipitator, a control method for reducing the specific resistance of the exhaust gases generated during the combustion process is characterized in that sodium chloride is added to the pulverized fuel in a ratio of 1: 200 before the solid fuel is combusted in the rotary kiln plant. A method for reducing dust by reducing the resistivity of exhaust gas.
KR1019790002503A 1979-07-25 1979-07-25 How to reduce the dust in the exhaust gas of rotary kilns KR830001094B1 (en)

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