KR830000251A - Method for preparing [(3-amino-3-carboxyl)-propyl-1]-methylphosphinic acid derivative - Google Patents

Method for preparing [(3-amino-3-carboxyl)-propyl-1]-methylphosphinic acid derivative Download PDF

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Publication number
KR830000251A
KR830000251A KR1019830000280A KR830000280A KR830000251A KR 830000251 A KR830000251 A KR 830000251A KR 1019830000280 A KR1019830000280 A KR 1019830000280A KR 830000280 A KR830000280 A KR 830000280A KR 830000251 A KR830000251 A KR 830000251A
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South Korea
Prior art keywords
formula
amino
carboxyl
propyl
preparing
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KR1019830000280A
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Korean (ko)
Inventor
루프 발터
핀케 만프레트
비에린거 헤르만
뤼데케 페터란게
크라이너 한스-에르그
Original Assignee
칼 엔데만 한스-유겐슐즈-스테이넨
훽스트 아크티엔 게젤샤프트
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Application filed by 칼 엔데만 한스-유겐슐즈-스테이넨, 훽스트 아크티엔 게젤샤프트 filed Critical 칼 엔데만 한스-유겐슐즈-스테이넨
Priority to KR1019830000280A priority Critical patent/KR830000251A/en
Publication of KR830000251A publication Critical patent/KR830000251A/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)

Abstract

내용 없음No content

Description

[(3-아미노-3-카복실)-프로필-1]-메틸포스핀산 유도체의 제조방법Method for preparing [(3-amino-3-carboxyl)-propyl-1]-methylphosphinic acid derivative

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this content is publicly disclosed, the full text is not included.

Claims (1)

다음 일반식(II)의 화합물을 먼저 시안화수소와 반응시켜 다음 일반식(III)의 상응하는 시아노히드린을 형성시킨 다음, 암모니아, 탄산암모늄 또는 중탄산암모늄과 반응시키고, 생성된 다음 일반식(IVa)의 아미노니트릴 또는 (IVb)의 히단토인을 검화하여, R3가 하이드록시 또는 OM인 일반식(I)화합물의 염을 형성시킨 후, 이 염을 유리산(R2=R3=OH, m=0) 또는 염기로 다른염(R2,R3=OM)으로 또는 알콜을 사용하여 에스테르[R3=(C1-C6)알콕시 또는 (C1-C4) 하이드록시알콕시]로 또는 암모니아, 아닐린 또는 하이드라진을 사용하여 각기 아미드, 아닐리드 또는 하이드라지드(R3=NH2, NHC6H5또는 NHNH2)로 전환시킴을 특징으로 하여 상기 일반식(I) 화합물을 제조하는 방법.Then the compound of formula (II) is first reacted with hydrogen cyanide to form the corresponding cyanohydrin of formula (III), and then reacted with ammonia, ammonium carbonate or ammonium bicarbonate, and then generated to form formula (IVa) ) After saponification of the aminonitrile of (IVb) or hydantoin of (IVb) to form a salt of the compound of general formula (I) wherein R 3 is hydroxy or OM, the salt is free acid (R 2 =R 3 =OH, m=0) or base with other salts (R 2 ,R 3 =OM) or with alcohol to ester [R 3 =(C 1 -C 6 )alkoxy or (C 1 -C 4 ) hydroxyalkoxy] Or ammonia, aniline or hydrazine, respectively, to convert to amide, anilide or hydrazide (R 3 =NH 2 , NHC 6 H 5 or NHNH 2 ), respectively. . 상기 일반식에서In the above formula R2는 -OH 또는 -OM(여기서 M은 등가의 무기 또는 유기 염기이다)을 나타내고R 2 represents -OH or -OM (where M is an equivalent inorganic or organic base) R3는 하이드록시, (C1-C6)알콕시, (C1-C4) 하이드록시알콕시, 아미노, 아닐리노, 하이드라지노 또는 -OM을 나타내고,R 3 represents hydroxy, (C 1 -C 6 )alkoxy, (C 1 -C 4 ) hydroxyalkoxy, amino, anilino, hydrazino or -OM, R5는 수소 또는 메틸을 나타내고,R 5 represents hydrogen or methyl, Y는 해리상수 >10-3인 무기산을 음이온을 나타내고 m은 0,1/2 또는 1이며,Y represents an inorganic acid having a dissociation constant >10 -3 and anion, m is 0, 1/2 or 1, (단, R2및 R3는 OH이고, m은 0이거나 또는 m은 1이고 Y는 염소인 화합물은 제외된다)(However, R 2 and R 3 are OH, m is 0 or m is 1 and Y is chlorine.) ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: Disclosure is based on the original application.
KR1019830000280A 1983-01-25 1983-01-25 Method for preparing [(3-amino-3-carboxyl)-propyl-1]-methylphosphinic acid derivative KR830000251A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019830000280A KR830000251A (en) 1983-01-25 1983-01-25 Method for preparing [(3-amino-3-carboxyl)-propyl-1]-methylphosphinic acid derivative

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019830000280A KR830000251A (en) 1983-01-25 1983-01-25 Method for preparing [(3-amino-3-carboxyl)-propyl-1]-methylphosphinic acid derivative

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
KR1019770001139 Division 1977-05-13

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KR830000251A true KR830000251A (en) 1983-03-30

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KR1019830000280A KR830000251A (en) 1983-01-25 1983-01-25 Method for preparing [(3-amino-3-carboxyl)-propyl-1]-methylphosphinic acid derivative

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