KR810000014B1 - Process for preparing rodenticide - Google Patents

Process for preparing rodenticide Download PDF

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Publication number
KR810000014B1
KR810000014B1 KR7903474A KR790003474A KR810000014B1 KR 810000014 B1 KR810000014 B1 KR 810000014B1 KR 7903474 A KR7903474 A KR 7903474A KR 790003474 A KR790003474 A KR 790003474A KR 810000014 B1 KR810000014 B1 KR 810000014B1
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South Korea
Prior art keywords
paraffin wax
coated
ratio
rats
rodenticide
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KR7903474A
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Korean (ko)
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전순표
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전순표
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/26Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/26Phosphorus; Compounds thereof

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Rodenticide having longer storage stability was prepd. Thus, warfarin or zinc phosphide granules were coated with paraffin wax in the ratio of 1: 0.1-5. Coated warfarin or zinc phosphide was then mixed with diets and recoated with paraffin wax at the ratio of 1: 0.2-2. Coagulation procedure was followed afterwards.

Description

살서제의 제조방법Method of preparing the insecticide

본 발명은 살서제에 관한 것으로, 특허 제4,167호의 살서제의 조성방법을 개량한 것이다. 쥐를 구제하는 방법은 여러가지가 있으나 현재까지 살서제를 사용하는 방법 이상의 것만큼 효과를 거둘 수 있는 방법은 발명되지 않고 있다. 살서제로는 수십종이 개발되고 있으나 어느 하나 완벽에 가까운 것은 찾아볼 수 없으며, 특히 쥐만을 치사하고 타동물에는 피해가 없는 선택형이 강한 약제는 거의 찾아볼 수 없다. 그러므로 현 단계로서 선택형이 강하며 쥐의 섭식율이 우수한 살서제를 개발하는 것이 무엇보다도 시급한 과제이다. 쥐의 번식력은 기하급수적으로 증가되므로 일시적이거나 비정기적인 투약으로서는 효과적인 구제가 불가능하다. 따라서 쥐를 효과적으로 구제하기 위하여는 살서제를 쥐의 통로 및 서식처에 계속 투약해 놓으므로서만 가능한 것이다. 그러나 제아무리 살서제라 하더라도 쥐가 살서제를 기피하거나 치사량을 섭식치 않으면 약효를 기대할 수 없다.The present invention relates to a salsaicide, which is an improvement of the composition method of the salsaicide of Patent No. 4,167. There are many ways to rescue rats, but until now, no method has been invented that can be as effective as using a pesticide. There are dozens of species being developed as salsaje, but none of them is close to perfection. Therefore, it is an urgent task to develop a killing agent with a high selection type and a good feeding rate of rats at this stage. As the fertility of rats increases exponentially, effective rescue is not possible with temporary or occasional dosing. Therefore, effective killing of rats can only be achieved by continuously administering a killing agent into the rat's passage and habitat. However, even if you do not eat the flesh, even if the rats do not avoid the killing or feeding the lethal dose can not be expected.

쥐의 식성은 잡식성이지만은 부패되거나 곰팡이가 쓴 먹이는 기피하는 경향이 있으므로 투약된 살서제가 변질되지 않게 하는 것이 무엇보다도 중요하다. 인화아연제나 항혈액 응고제인 왈파린 등은 주성분 함량이 2.5%-0.005%만으로도 쥐를 치사시키므로 살서제의 대부분은 쥐가 잘 먹는 곡물이나 기호성 식품 등의 부재료와 혼합하여 조제하고 있으므로 이들 부재료는 고온 다습한 조건하에서는 2-3일만 지나도 변질되거나 곰팡이가 발생하게 되어 살서제의 섭식율이 떨어져 약효를 거두지 못하게 된다.Rat food is omnivorous, but it tends to rot away from food that is spoiled or moldy, so it is of utmost importance that the drug is not altered. Zinc phosphate or anti-blood coagulant Walparin kills rats with only 2.5% -0.005% of its main ingredient, so most of the killing agents are formulated by mixing them with ingredients such as grains and palatable foods that rats eat well. Under one condition, after 2-3 days, deterioration or mold will occur, and the feeding rate of the insecticide will be lowered and it will not be effective.

특히 우리나라에서 주종을 이루고 있는 시궁쥐(잡쥐)는 그 대부분이 땅의 쥐굴이나 하수도 등에서 서식하므로 이들을 구제하기 위해서는 습기가 높은 하수도나 땅속에 투약하는 것이 가장 효과적이나 위에 언급한 살서제의 변질 때문에 투약하여도 약효를 거두지 못하고 있는 실정이다.In particular, most of the rats (mice) that predominantly in Korea inhabit the rat's den or the sewer of the land, so in order to rescue them, it is most effective to do so in the wet sewer or the ground. The situation is not getting the effect.

특히 본 출원인의 선특허인 특허 제4,167호로 개발된 살서제의 조성방법은 인화아연제의 입자를 파라핀 왁스와 1 : 0.1-5되도록 혼합하여 피복 처리하므로서 쥐의 위내에서의 약효의 분해를 지연시켜 약효가 나타날 때까지 약제의 섭식량을 증가시킨다는 목적과 부재료와의 혼합시에도 주성분이 입자가 피복되어 있으므로 주성분의 분해를 억제하는데 착안하고 있으나 부재료의 부패나 변질을 방지할 수 없어 완제품을 제조 시판하기 위하여 시중에 장기간 보관할 수 없다는 약점이 있었다.In particular, the composition method of the salsaicide developed by the applicant's prior patent No. 4,167 is coated by mixing the zinc phosphate particles with paraffin wax 1: 0.1-5, thereby delaying the degradation of the drug in the stomach of the rat. The purpose is to increase the feeding amount of the drug until it appears, and even when mixing with the subsidiary materials, the main ingredient is coated, so it is focused on suppressing the decomposition of the main ingredient, but it is not possible to prevent the decay and the deterioration of the subsidiary material. The weak point was that it could not be stored for a long time.

본 발명은 이와같은 결함을 시정하기 위하여 살서제인 인화아연제 혹은 왈파린제 등을 일정한 비율로 부재료와 혼합 조제하여 완제품을 만든 후 다시 내습성 물질인 파라핀 왁스와 1 : 0.2-2의 비율로 혼합하여 피복한 후 투약장소에 적합하도록 다양한 모양을 만들어 하수도 및 쥐굴속에 투약하면 살서제의 신선도가 장기간 계속되므로 약효를 높일 수가 있게 된다. 특히 쥐가 많이 서식하는 하수구에 투약하기 위하여서는 살서제를 고형으로 만들어 공간에 매어달 수 있어야 하므로 위의 방법으로 처리하면 소기의 목적을 달성할 수 있게 된다.In order to correct such defects, the present invention is to prepare a finished product by mixing a salicide, a zinc zinc phosphate or a walfarin, etc. with a subsidiary ingredient in a constant ratio, and then mixed with a paraffin wax, which is a moisture resistant substance, in a ratio of 1: 0.2-2. After coating, make various shapes to be suitable for the place of administration and do so in the sewer and rat oyster, so the freshness of the acaricide can be improved for a long time. In particular, in order to administer to the sewer where the rats inhabit a lot, it is necessary to solidify the insecticide and to hang it in the space, so the above method can achieve the desired purpose.

현재까지 인화아연제는 중간제품만이 시판되고 있어 지식이 없는 일반수요자가 적당한 먹이를 선정하여 직접 혼합조제 투약하므로서 주성분 함량의 불정확 및 부재료 선정 및 배합비율의 잘못 등으로 살서효과가 저하되는 경향이 있으나 본 발명으로 다양한 부재료를 선정하여 정확한 처방과 조제법으로 완제품을 제조하여 수요자에게 공급할 수 있게 되므로서 살서효과를 제고시킬 수 있게 된다.To date, zinc phosphate is commercially available only in intermediate products, so the general consumer who has no knowledge selects the appropriate food and directly administers the mixed preparation, and the effectiveness of salsa decreases due to the inaccuracy of the main ingredient content, the selection of subsidiary materials, and the wrong mixing ratio. However, by selecting the various subsidiary materials according to the present invention, it is possible to manufacture the finished product with the correct prescription and preparation method to supply to the consumer while improving the salsa effect.

본 발명에서 사용된 괴복물질은 파라핀 왁스이나 이외에도 비닐수지 및 아크릴 수지 등을 사용할 수 있으나 이들 물질은 쥐가 기피하는 경향이 있어 섭식율이 크게 떨어지므로 약효를 거둘 수 없다.Paraffin wax used in the present invention may be used in addition to paraffin wax or vinyl resins and acrylic resins, but these materials have a tendency to avoid rats, so the feeding rate is greatly reduced, and thus the drug cannot be harvested.

이하 본 발명을 실시예를 들어 설명하나 본 발명을 실시예에 국한시키려는 것은 아니며, 본 발명 청구 범위의 한도내에서 변경 실시할 수 있음은 물론이다.Hereinafter, the present invention will be described with reference to Examples, but the present invention is not intended to be limited to the Examples, and the present invention can be modified within the scope of the claims.

[실시예 1]Example 1

알콜 100㎖에 에틸렌 세루로스 5g을 용해시킨 용액에 인화아연 50g을 투입하여 가열하면서 균등하게 분사시키고, 냉각하면서 피복된 인화아연을 얻는다. 여기서 다시 파라핀 왁스 5g을 녹인 용액에 투입 교반 하고 냉각 응고시켜 분쇄하면 완전 코팅된 인화아연을 얻는다.50 g of zinc phosphide was added to a solution in which 5 g of ethylene cerulose was dissolved in 100 ml of alcohol, sprayed evenly while heating, and coated zinc phosphate was cooled while cooling. Here again, 5 g of paraffin wax was added to the dissolved solution, stirred, cooled and coagulated to obtain fully coated zinc phosphide.

[실시예 2]Example 2

코팅된 인화아연 입자가 1% 함유되도록 싸래기와 기타 부재를 혼합하고 여기에 1:0.2의 비율로 파라핀 왁스를 가하고 교반한 후 3g씩의 정제를 만든 후 이 정제를 다시 파라핀 왁스 용액에 침적시켰다가 응고시키면 완전히 피복된 인화아연제의 정제를 얻는다.The wrapper and other components were mixed to contain 1% of the coated zinc phosphide particles, paraffin wax was added thereto at a ratio of 1: 0.2, stirred, and 3 g of tablets were prepared. The tablets were again immersed in a paraffin wax solution. Coagulation yields a fully coated zinc phosphate tablet.

[실시예 3]Example 3

왈파린제의 분말이 0.025% 들어가겠금 각종 곡물과 첨가물을 혼합한 후 일정한 크기와 모양의 용기에 상기 혼합물과 파라핀 왁스 용액을 1 : 0.3의 비율로 혼합 교반하면서 냉각시켜서 과자모양의 피복된 왈파린제의 살서제를 얻는다.It contains 0.025% of the powder of walfarin. After mixing various grains and additives, the mixture and the paraffin wax solution are mixed and stirred in a ratio of 1: 0.3 in a container of a constant size and shape. Get a flesh

Claims (1)

본문에서 상술하는 바와 같이 왈파린제 또는 인화아연제 입자와 파라핀왁스를 1 : 0.1-5가 되도록 혼합하여 피복한 공지의 피복 왈파린제 또는 피복인화 아연제를 식이와 동시 혼합만 뒤 다시 파리핀 왁스와 1 : 0.2-2의 비율를 혼합함을 특징으로 하여 일정한 모양으로 응고시켜서 되는 살서제의 제조방법.As described above in the text, the known coating walfarin or coated zinc phosphate is coated with a mixture of walfarin or zinc phosphate and paraffin wax to be 1: 0.1-5. A method for producing a fungicide, which is characterized in that the ratio of 1: 0.2-2 is mixed to solidify to a certain shape.
KR7903474A 1979-10-11 1979-10-11 Process for preparing rodenticide KR810000014B1 (en)

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KR7903474A KR810000014B1 (en) 1979-10-11 1979-10-11 Process for preparing rodenticide

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