KR800000882B1 - Composition meterial of the cement aggregate - Google Patents
Composition meterial of the cement aggregate Download PDFInfo
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- KR800000882B1 KR800000882B1 KR7700904A KR770000904A KR800000882B1 KR 800000882 B1 KR800000882 B1 KR 800000882B1 KR 7700904 A KR7700904 A KR 7700904A KR 770000904 A KR770000904 A KR 770000904A KR 800000882 B1 KR800000882 B1 KR 800000882B1
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Abstract
Description
[발명의 명칭][Name of invention]
시멘트 골재의 조성물Composition of cement aggregate
[발명의 상세한 설명]Detailed description of the invention
본 발명은 화강암이 심층 풍화되어 지표부근의 지층에 매설된 산성암을 분쇄하여서 된 모래(이하 산모래라 한다)에 저급지방산인 개미산의 나트륨염이나 칼슘염을 배합하여서 된 시멘트 골재의 조성물에 관한 것이다.The present invention relates to a composition of a cement aggregate obtained by mixing sodium salt or calcium salt of formic acid, which is a lower fatty acid, with sand (hereinafter referred to as acid sand) obtained by crushing acidic rock embedded in a layer near the surface due to deep weathering of granite. .
본 발명에 사용되는 사용암은 모암인 화강암의 구조와 조직의 특성에 따른 절리(節理)와 할리(割理)등에 의하여 지층에서 심층 풍화되어 비록 세립화 되었으나 입자들이 서로 응결되어 있는 상태로 지층에 매설되어 있는 암석이다.The used rock used in the present invention is deeply weathered in the strata due to the jointing and the Harley according to the characteristics of the structure and texture of the granite, which is the granite. Buried rock.
따라서 이를 산모래로 만들기 위하여는 산성암을 채취하여 분쇄되 약 14% 정도가 200멧쉬이하로 되는 6멧쉬이하의 입자로 분쇄하여야 한다.Therefore, in order to make it into sand, acidic rock should be collected and crushed into particles of 6 mesh or less, about 14% of which is 200 mesh or less.
종래에도 강모래와 시멘트로 된 골재조성물에 고급지방산의 알카리 금속염을 첨가 배합한 예가 있으나, 이 경우는 방수성은 향상되지만 조기강도나 압축강도의 향상은 기대할 수 없었다.Conventionally, there is an example in which an alkali metal salt of a higher fatty acid is added to an aggregate composition made of steel sand and cement, but in this case, waterproofness is improved but early strength or compressive strength cannot be improved.
본 발명자는 산모래를 시멘트와 혼합하여 몰탈을 제조하였을 때 통상적인 시멘트 몰탈에 사용하는 강모래보다 압축강도가 우수함을 알게 되어, 이를 시멘트몰탈용 강모래대용품으로 사용하는 방법을 연구한 결과 산모래에 저급지방산의 알카리 금속염이나 알카리 토금속을 첨가하면 고급 지방산의 알카리금속염을 첨가하는 경우와는 달리 방수성은 크게 향상되지 않지만 조기강도와 압축강도는 현저하게 우수함을 알게 되었다.The present inventors found that when sand mortar was mixed with cement to produce mortar, the compressive strength was superior to that of steel sand normally used for cement mortar. As a result of studying the method of using sand sand substitute for cement mortar, sand sand was found. When alkali metal salts or alkaline earth metals of lower fatty acids are added to the water, the water resistance is not significantly improved, unlike the alkali metal salts of higher fatty acids, but the early strength and the compressive strength are remarkably excellent.
이러한 현상은 산모래가 지표에 노출되어 화학적인 풍화를 받기 전 상태, 즉 지중에 매설되어 물리적인 풍화만을 받은 상태의 산성암을 분쇄 한것이므로 그 표면이 거칠뿐 아니라 표면에 미세한 분말이 묻어 있어서 개미산의 나트륨염이나 칼슘염이 입자표면의 미세한 분말들을 응결시키고 서로 접착되면서 입자간의 공격을 채워주므로서 나타나는 것으로 판단된다.This phenomenon is because the acid sand is crushed before it is exposed to the surface and subjected to chemical weathering, that is, it is buried in the ground and received only physical weathering. Therefore, its surface is not only rough but also has fine powder on the surface. Sodium salts or calcium salts are believed to occur by condensing fine powders on the surface of the particles and adhering to each other to fill the attack between the particles.
본 발명에 사용하는 저급지방산의 금속염은 개미산의 나트륨염과 칼슘염으로서 이들은 산모래중량에 대하여 0.1%내지 20%의 범위내에서 사용할 수 있으나, 특히 0.5%내지 6.0%의 범위내에서 사용하는 것이 우수한 효과를 얻을 수 있다.The metal salts of lower fatty acids used in the present invention are sodium salts and calcium salts of formic acid, which can be used in the range of 0.1% to 20% by weight of acid sand, but in particular in the range of 0.5% to 6.0% Excellent effect can be obtained.
본 발명에 의한 조성물의 일례를 구체적으로 설명하면 지표부근의 지층에 매설되어 있는 산성암을 분쇄하하여 6멧쉬이하의 입도를 갖도록 하되, 200멧쉬 통과분이 약 15-20%정도로 되게하고 여기에 0.1내지 20%의 개미산나트륨이나 개미산 칼슘을 배합하여 제조한다.When explaining an example of the composition according to the present invention in detail, the acid rock embedded in the strata near the ground surface is ground to have a particle size of 6 mesh or less, but the amount of 200 mesh passes is about 15-20%, and 0.1 to 0.1 It is prepared by combining 20% sodium formate or calcium formate.
제조된 조성물은 시멘트와 통상이 강모래 배합비율로 배합하고 물을 가하여 몰탈을 제조하게 된다.The prepared composition is formulated with cement and usually in the ratio of steel sand and water is added to prepare mortar.
본 발명에 의한 조성물은 강모래보다 압축강도가 우수한 산모래를 주성분으로 사용하고 저급지방산의 금속염인 개미산의 나트륨염이나 칼슘염을 배합하므로서 압축 강도가 산모래 단독으로 사용하는 경우보다 우수할뿐 아니라 입자 표면의 미세한 분말들이 개미산의염에 의하여 서로 응결되면서 입자들을 결착시키기게 되므로 조기강도도 우수하게 되는 것이다.The composition according to the present invention has superior compressive strength than the case where acid sand is used alone, by using acid sand having a higher compressive strength than steel sand as a main component and combining sodium salt or calcium salt of formic acid, which is a metal salt of lower fatty acids. The fine powder on the particle surface is condensed with each other by the salt of formic acid, thereby binding the particles, the early strength is also excellent.
[실시예 1]Example 1
지표 부근의 지층에 매설되어 있는 산성암을 채취하여 6멧쉬이하로 되게 분쇄하되, 200멧쉬 통과분이 전체의 15%내지 20%정도 되도록 하고 제조된 산모래 1.990g에 개미산 나트륨 23.88g을 배합한다. 생성된 조성물을 시멘트 900g에 배합한 다음 물 540㏄를 가하고 혼련하여 몰탈을 제조한 다음, 3일과 7일후에 KSF2514호에 의하여 압축 강도를 측정하고 그 결과를 표 1에 기재한다.The acidic rocks buried in the strata near the surface are collected and pulverized to 6 mesh or less, so that the amount of 200 mesh passes is 15% to 20% of the total and 23.88g of sodium formate is added to 1.990g of the produced sand. The resulting composition is blended with 900 g of cement, 540 kPa of water is added and kneaded to prepare mortar. After 3 and 7 days, the compressive strength is measured by KSF2514 and the results are shown in Table 1.
동일한 방법을 이용하되, 개미산 나트륨을 첨가하지 않고 섬진강 모래와 산 모래만을 사용하여 동일한 시험을 하였다.Using the same method, the same test was performed using only summon river sand and acid sand without the addition of sodium formate.
[표 1]TABLE 1
[실시예 2]Example 2
산모래 1㎏에 개미산칼슘 4.0g을 배합하여 시멘트 500g을 혼합하고 물 250㏄를 사용하여 혼련한 다음 7일과 14일후 KSF2514에 의하여 압축강도를 측정한다.500 g of cement is mixed with 1 g of acid sand, 500 g of cement is mixed and kneaded using 250 kPa of water. After 7 and 14 days, compressive strength is measured by KSF2514.
비교용으로 섬진강 모래를 시멘트와 혼합하여 몰타르를 제조하고 그 압축강도를 측정한다.For comparison, summed steel sand is mixed with cement to produce mortar and its compressive strength is measured.
시험 결과는 표 2에 기재한다.The test results are shown in Table 2.
[표 2]TABLE 2
상기 표 1과 표 2의 시험성적표에 의하면 압축강도에 차이가 있으나, 이는 시험한 날자, 산성암 체취지역 및 시료의 크기에 따라 차이를 보이는 것이다.According to the test report table of Table 1 and Table 2, there is a difference in compressive strength, but this shows a difference depending on the date of testing, the acidic odor area and the size of the sample.
그러나, 산모래에 개미산칼슘을 첨가하면 통상 사용하는 강모래나 산모래만을 사용한 몰탈보다 압축강도가 향상되고 있음을 알 수 있다.However, it can be seen that when calcium formate is added to the acid sand, the compressive strength is improved compared to the steel sand or mortar using only acid sand.
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KR7700904A KR800000882B1 (en) | 1977-04-15 | 1977-04-15 | Composition meterial of the cement aggregate |
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KR7700904A KR800000882B1 (en) | 1977-04-15 | 1977-04-15 | Composition meterial of the cement aggregate |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20180044237A1 (en) * | 2016-08-15 | 2018-02-15 | University Of South Carolina | High Strength Reduced Elastic Modulus Concrete |
KR20190092912A (en) * | 2018-01-31 | 2019-08-08 | 강원대학교산학협력단 | A composite of artificial aggregates improved water absorption and specific gravity comprising mine powder with high specific gravity and fluidized-bed boiler ash, and an artificial aggregates manufactured by using the same, and a mehtod for manufacturing it |
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1977
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20180044237A1 (en) * | 2016-08-15 | 2018-02-15 | University Of South Carolina | High Strength Reduced Elastic Modulus Concrete |
US11414348B2 (en) * | 2016-08-15 | 2022-08-16 | University Of South Carolina | High strength reduced elastic modulus concrete |
KR20190092912A (en) * | 2018-01-31 | 2019-08-08 | 강원대학교산학협력단 | A composite of artificial aggregates improved water absorption and specific gravity comprising mine powder with high specific gravity and fluidized-bed boiler ash, and an artificial aggregates manufactured by using the same, and a mehtod for manufacturing it |
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