KR20230114098A - A composition of hard coating having high hardness and weather resistance - Google Patents
A composition of hard coating having high hardness and weather resistance Download PDFInfo
- Publication number
- KR20230114098A KR20230114098A KR1020220010233A KR20220010233A KR20230114098A KR 20230114098 A KR20230114098 A KR 20230114098A KR 1020220010233 A KR1020220010233 A KR 1020220010233A KR 20220010233 A KR20220010233 A KR 20220010233A KR 20230114098 A KR20230114098 A KR 20230114098A
- Authority
- KR
- South Korea
- Prior art keywords
- meth
- acrylate
- diisocyanate
- hard coating
- coating composition
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims description 16
- 238000000576 coating method Methods 0.000 title description 24
- 239000011248 coating agent Substances 0.000 title description 22
- -1 acrylic polyol Chemical class 0.000 claims abstract description 52
- 239000011347 resin Substances 0.000 claims abstract description 31
- 229920005989 resin Polymers 0.000 claims abstract description 31
- 239000008199 coating composition Substances 0.000 claims abstract description 26
- 229910000077 silane Inorganic materials 0.000 claims abstract description 25
- 239000000945 filler Substances 0.000 claims abstract description 20
- 229920005862 polyol Polymers 0.000 claims abstract description 20
- 239000003960 organic solvent Substances 0.000 claims abstract description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 47
- 239000000178 monomer Substances 0.000 claims description 15
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 12
- 125000005442 diisocyanate group Chemical group 0.000 claims description 10
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 239000000049 pigment Substances 0.000 claims description 9
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 7
- 239000002518 antifoaming agent Substances 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 6
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 5
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 5
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 claims description 5
- 239000005056 polyisocyanate Substances 0.000 claims description 5
- 229920001228 polyisocyanate Polymers 0.000 claims description 5
- 239000000395 magnesium oxide Substances 0.000 claims description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 4
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 claims description 3
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 3
- NKQIMNKPSDEDMO-UHFFFAOYSA-L barium bromide Chemical compound [Br-].[Br-].[Ba+2] NKQIMNKPSDEDMO-UHFFFAOYSA-L 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 3
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 3
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 3
- OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 claims description 3
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- BYOIQYHAYWYSCZ-UHFFFAOYSA-N prop-2-enoxysilane Chemical compound [SiH3]OCC=C BYOIQYHAYWYSCZ-UHFFFAOYSA-N 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 3
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 claims description 3
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 claims description 3
- 239000001993 wax Substances 0.000 claims description 3
- DCQBZYNUSLHVJC-UHFFFAOYSA-N 3-triethoxysilylpropane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CCCS DCQBZYNUSLHVJC-UHFFFAOYSA-N 0.000 claims description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 2
- 239000004267 EU approved acidity regulator Substances 0.000 claims description 2
- 229910001620 barium bromide Inorganic materials 0.000 claims description 2
- 229910001634 calcium fluoride Inorganic materials 0.000 claims description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000292 calcium oxide Substances 0.000 claims description 2
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 2
- 229910001947 lithium oxide Inorganic materials 0.000 claims description 2
- 229910001623 magnesium bromide Inorganic materials 0.000 claims description 2
- 229910001635 magnesium fluoride Inorganic materials 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims description 2
- 229910001950 potassium oxide Inorganic materials 0.000 claims description 2
- 230000003449 preventive effect Effects 0.000 claims description 2
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 2
- LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 claims 1
- 239000011247 coating layer Substances 0.000 abstract description 18
- 239000000758 substrate Substances 0.000 abstract description 14
- 229910052751 metal Inorganic materials 0.000 abstract description 10
- 239000002184 metal Substances 0.000 abstract description 10
- 239000000463 material Substances 0.000 abstract description 6
- 230000015572 biosynthetic process Effects 0.000 abstract description 4
- 239000004566 building material Substances 0.000 abstract description 4
- 238000011109 contamination Methods 0.000 abstract description 3
- 238000005034 decoration Methods 0.000 abstract description 3
- 239000002023 wood Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 description 20
- 239000003999 initiator Substances 0.000 description 12
- 239000002245 particle Substances 0.000 description 9
- 230000000704 physical effect Effects 0.000 description 9
- 239000002904 solvent Substances 0.000 description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
- 150000002736 metal compounds Chemical class 0.000 description 6
- 230000002265 prevention Effects 0.000 description 6
- 239000002270 dispersing agent Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- XJHCXCQVJFPJIK-UHFFFAOYSA-M caesium fluoride Chemical compound [F-].[Cs+] XJHCXCQVJFPJIK-UHFFFAOYSA-M 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 239000012948 isocyanate Substances 0.000 description 4
- 150000002513 isocyanates Chemical class 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- LFYJSSARVMHQJB-QIXNEVBVSA-N bakuchiol Chemical compound CC(C)=CCC[C@@](C)(C=C)\C=C\C1=CC=C(O)C=C1 LFYJSSARVMHQJB-QIXNEVBVSA-N 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 239000002360 explosive Substances 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- 238000004383 yellowing Methods 0.000 description 3
- PFCHFHIRKBAQGU-UHFFFAOYSA-N 3-hexanone Chemical compound CCCC(=O)CC PFCHFHIRKBAQGU-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
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- 238000000691 measurement method Methods 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 2
- 229920002492 poly(sulfone) Polymers 0.000 description 2
- 229920000734 polysilsesquioxane polymer Polymers 0.000 description 2
- YKYONYBAUNKHLG-UHFFFAOYSA-N propyl acetate Chemical compound CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 1
- MUTGBJKUEZFXGO-OLQVQODUSA-N (3as,7ar)-3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione Chemical compound C1CCC[C@@H]2C(=O)OC(=O)[C@@H]21 MUTGBJKUEZFXGO-OLQVQODUSA-N 0.000 description 1
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 1
- JFRQLKNEDLLXOQ-UHFFFAOYSA-N 1,3-diisocyanato-2,4-dimethylbenzene Chemical compound CC1=CC=C(N=C=O)C(C)=C1N=C=O JFRQLKNEDLLXOQ-UHFFFAOYSA-N 0.000 description 1
- CDMDQYCEEKCBGR-UHFFFAOYSA-N 1,4-diisocyanatocyclohexane Chemical compound O=C=NC1CCC(N=C=O)CC1 CDMDQYCEEKCBGR-UHFFFAOYSA-N 0.000 description 1
- SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 description 1
- SZBXTBGNJLZMHB-UHFFFAOYSA-N 1-chloro-2,4-diisocyanatobenzene Chemical compound ClC1=CC=C(N=C=O)C=C1N=C=O SZBXTBGNJLZMHB-UHFFFAOYSA-N 0.000 description 1
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 1
- BTJPUDCSZVCXFQ-UHFFFAOYSA-N 2,4-diethylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC(CC)=C3SC2=C1 BTJPUDCSZVCXFQ-UHFFFAOYSA-N 0.000 description 1
- DZDVHNPXFWWDRM-UHFFFAOYSA-N 2,4-diisocyanato-1-methoxybenzene Chemical compound COC1=CC=C(N=C=O)C=C1N=C=O DZDVHNPXFWWDRM-UHFFFAOYSA-N 0.000 description 1
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 1
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 1
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- WNXTZVMMNCCZTP-UHFFFAOYSA-N 2-hydroxyethyl 2-methylprop-2-enoate 5-hydroxy-2-methylpent-2-enoic acid Chemical compound OCCC=C(C(=O)O)C.C(C(=C)C)(=O)OCCO WNXTZVMMNCCZTP-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
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- TVWBTVJBDFTVOW-UHFFFAOYSA-N 2-methyl-1-(2-methylpropylperoxy)propane Chemical compound CC(C)COOCC(C)C TVWBTVJBDFTVOW-UHFFFAOYSA-N 0.000 description 1
- OBOSXEWFRARQPU-UHFFFAOYSA-N 2-n,2-n-dimethylpyridine-2,5-diamine Chemical compound CN(C)C1=CC=C(N)C=N1 OBOSXEWFRARQPU-UHFFFAOYSA-N 0.000 description 1
- YAXXOCZAXKLLCV-UHFFFAOYSA-N 3-dodecyloxolane-2,5-dione Chemical compound CCCCCCCCCCCCC1CC(=O)OC1=O YAXXOCZAXKLLCV-UHFFFAOYSA-N 0.000 description 1
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- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
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- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- SGUXGJPBTNFBAD-UHFFFAOYSA-L barium iodide Chemical compound [I-].[I-].[Ba+2] SGUXGJPBTNFBAD-UHFFFAOYSA-L 0.000 description 1
- OOULUYZFLXDWDQ-UHFFFAOYSA-L barium perchlorate Chemical compound [Ba+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O OOULUYZFLXDWDQ-UHFFFAOYSA-L 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 229910001622 calcium bromide Inorganic materials 0.000 description 1
- WGEFECGEFUFIQW-UHFFFAOYSA-L calcium dibromide Chemical compound [Ca+2].[Br-].[Br-] WGEFECGEFUFIQW-UHFFFAOYSA-L 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229940072282 cardura Drugs 0.000 description 1
- MOOUSOJAOQPDEH-UHFFFAOYSA-K cerium(iii) bromide Chemical compound [Br-].[Br-].[Br-].[Ce+3] MOOUSOJAOQPDEH-UHFFFAOYSA-K 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- SCQOZUUUCTYPPY-UHFFFAOYSA-N dimethyl-[(prop-2-enoylamino)methyl]-propylazanium;chloride Chemical compound [Cl-].CCC[N+](C)(C)CNC(=O)C=C SCQOZUUUCTYPPY-UHFFFAOYSA-N 0.000 description 1
- FZFYOUJTOSBFPQ-UHFFFAOYSA-M dipotassium;hydroxide Chemical compound [OH-].[K+].[K+] FZFYOUJTOSBFPQ-UHFFFAOYSA-M 0.000 description 1
- RUZYUOTYCVRMRZ-UHFFFAOYSA-N doxazosin Chemical compound C1OC2=CC=CC=C2OC1C(=O)N(CC1)CCN1C1=NC(N)=C(C=C(C(OC)=C2)OC)C2=N1 RUZYUOTYCVRMRZ-UHFFFAOYSA-N 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- UHKJHMOIRYZSTH-UHFFFAOYSA-N ethyl 2-ethoxypropanoate Chemical compound CCOC(C)C(=O)OCC UHKJHMOIRYZSTH-UHFFFAOYSA-N 0.000 description 1
- 229910000373 gallium sulfate Inorganic materials 0.000 description 1
- SBDRYJMIQMDXRH-UHFFFAOYSA-N gallium;sulfuric acid Chemical compound [Ga].OS(O)(=O)=O SBDRYJMIQMDXRH-UHFFFAOYSA-N 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 1
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- BLQJIBCZHWBKSL-UHFFFAOYSA-L magnesium iodide Chemical compound [Mg+2].[I-].[I-] BLQJIBCZHWBKSL-UHFFFAOYSA-L 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000011817 metal compound particle Substances 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- VYKXQOYUCMREIS-UHFFFAOYSA-N methylhexahydrophthalic anhydride Chemical compound C1CCCC2C(=O)OC(=O)C21C VYKXQOYUCMREIS-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- AOLPZAHRYHXPLR-UHFFFAOYSA-I pentafluoroniobium Chemical compound F[Nb](F)(F)(F)F AOLPZAHRYHXPLR-UHFFFAOYSA-I 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 239000011856 silicon-based particle Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910001631 strontium chloride Inorganic materials 0.000 description 1
- AHBGXTDRMVNFER-UHFFFAOYSA-L strontium dichloride Chemical compound [Cl-].[Cl-].[Sr+2] AHBGXTDRMVNFER-UHFFFAOYSA-L 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- YRGLXIVYESZPLQ-UHFFFAOYSA-I tantalum pentafluoride Chemical compound F[Ta](F)(F)(F)F YRGLXIVYESZPLQ-UHFFFAOYSA-I 0.000 description 1
- KXYJPVZMZBJJBZ-UHFFFAOYSA-N tert-butyl 2-ethylbutaneperoxoate Chemical group CCC(CC)C(=O)OOC(C)(C)C KXYJPVZMZBJJBZ-UHFFFAOYSA-N 0.000 description 1
- PFBLRDXPNUJYJM-UHFFFAOYSA-N tert-butyl 2-methylpropaneperoxoate Chemical group CC(C)C(=O)OOC(C)(C)C PFBLRDXPNUJYJM-UHFFFAOYSA-N 0.000 description 1
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 150000003573 thiols Chemical group 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- HDUMBHAAKGUHAR-UHFFFAOYSA-J titanium(4+);disulfate Chemical compound [Ti+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O HDUMBHAAKGUHAR-UHFFFAOYSA-J 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- ZOYIPGHJSALYPY-UHFFFAOYSA-K vanadium(iii) bromide Chemical compound [V+3].[Br-].[Br-].[Br-] ZOYIPGHJSALYPY-UHFFFAOYSA-K 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
Abstract
본 발명에 따른 고경도 내후성 하드코팅 조성물은 아크릴 폴리올 수지, 실란 화합물, 충전재 및 유기용제를 포함함에 따라 기재, 특히 금속기재와의 부착성이 뛰어나고, 우수한 표면의 경도, 내스크래치성을 확보할 수 있다. 여기에 금속기재의 녹슬음을 방지하고 오염 및 변형 방지 등의 고기능성을 발현함으로써 표면 보호를 위해 하드코팅층의 형성이 필요한 목재, 건축자재, 가구, 장식, 자동차내외장재, 패널 등에 폭넓게 사용 가능하다.The high-hardness, weather-resistant hard coating composition according to the present invention includes an acrylic polyol resin, a silane compound, a filler, and an organic solvent, so that it has excellent adhesion to substrates, especially metal substrates, and can secure excellent surface hardness and scratch resistance. there is. Here, it can be widely used in wood, building materials, furniture, decoration, automobile interior and exterior materials, and panels that require the formation of a hard coating layer for surface protection by expressing high functionality such as preventing rusting of metal substrates and preventing contamination and deformation.
Description
본 발명은 고경도 내후성 하드코팅 조성물에 관한 것으로, 상세하게는 금속 자재에 부여되는 코팅층을 통하여 표면의 경도를 높임과 동시에 내화학성, 내오염성, 내마모성, 내황변성 및 방청성 등의 고기능성을 부여할 수 있는 고경도 내후성 하드코팅 조성물에 관한 것이다.The present invention relates to a high-hardness, weather-resistant hard coating composition, and in detail, through a coating layer applied to a metal material, to increase the hardness of the surface and at the same time to impart high functionality such as chemical resistance, stain resistance, abrasion resistance, yellowing resistance and rust prevention. It relates to a high hardness weather resistant hard coating composition.
락카는 건축물, 가구, 전선 등의 물체 표면에 칠해져 고체막을 형성함으로써 물체의 표면에 방오, 방청, 방염, 방수성 등의 기능과 광택 및 컬러로 인한 심미성을 부여하기 위하여 사용되는 것으로, 일반적으로 용매에 수지를 희석하여 제조되며, 여기에 사용되는 수지와 용매의 종류는 매우 다양하다.Lacquer is applied to the surface of objects such as buildings, furniture, and wires to form a solid film, which is used to impart functions such as antifouling, rust prevention, flame resistance, and waterproofness to the surface of objects and aesthetics due to gloss and color. It is prepared by diluting the resin, and the types of resins and solvents used here are very diverse.
수지로는 아크릴 수지, 염화비닐 수지, 폴리 에틸렌 수지 및 폴리 아미드 이미드 수지 등의 열가소성 수지와 에폭시 수지, 우레탄 수지, 폴리 설폰 수지 및 페놀 수지 등의 열경화성 수지를 모두 사용할 수 있다.As the resin, thermoplastic resins such as acrylic resins, vinyl chloride resins, polyethylene resins, and polyamide imide resins, and thermosetting resins such as epoxy resins, urethane resins, polysulfone resins, and phenol resins may be used.
이때, 폴리 에틸렌과 같은 열가소성 수지는 다양한 용매에 용해가 가능하여 뛰어난 가공성을 갖는 반면, 용매가 휘발된 후 기질의 표면에서 상대적으로 낮은 물성을 나타내 도료로서의 성능이 저하되는 문제가 있고, 폴리 설폰 수지는 용매가 휘발된 후 우수한 물성을 가지는 반면 용해력이 높은 고성능 용매에서만 용해되므로 폴리 설폰 수지를 용해하기 위해 사용되는 용매의 종류에 제한이 있다.At this time, while thermoplastic resins such as polyethylene can be dissolved in various solvents and have excellent processability, there is a problem that the performance as a paint is deteriorated by showing relatively low physical properties on the surface of the substrate after the solvent is volatilized. has excellent physical properties after the solvent is volatilized, but dissolves only in high-performance solvents with high solubility, so there is a limit to the type of solvent used to dissolve the polysulfone resin.
특히 가장 대중적인 코팅 방법으로는 열가소성 수지 등의 유기화합물 원료를 사용하는 도료도포를 들 수 있으나, 내열성이 낮고 코팅 피막 형성 후 시간이 지남에 따라 변질, 변색, 탈색 등이 나타나 유지보수 및 관리가 필요하다.In particular, the most popular coating method is the application of paints using organic compound raw materials such as thermoplastic resins, but the heat resistance is low and deterioration, discoloration, and discoloration appear over time after the formation of the coating film, making maintenance and management difficult. need.
따라서 실생활에 사용되는 다양한 제품군에 내용제성, 내화학성, 내오염성, 내마모성, 고광택, 내황변성과 같은 고기능성을 모두 부여하는 코팅층에 대한 연구가 시급한 실정이다.Therefore, there is an urgent need to research a coating layer that imparts high functionality such as solvent resistance, chemical resistance, stain resistance, abrasion resistance, high gloss, and yellowing resistance to various product groups used in real life.
본 발명은 상기와 같은 문제를 해결하기 위해 안출된 것으로, 상세하게는 금속 자재에 부여되는 코팅층을 통하여 표면의 경도를 높임과 동시에 내화학성, 내오염성, 내마모성, 내황변성 및 방청성 등의 고기능성을 부여할 수 있는 고경도 내후성 하드코팅 조성물의 제공을 목적으로 한다.The present invention has been made to solve the above problems, and in detail, through a coating layer applied to a metal material to increase the hardness of the surface, and at the same time, high functionality such as chemical resistance, stain resistance, abrasion resistance, yellowing resistance and rust prevention It is an object of the present invention to provide a high hardness weather resistant hard coating composition that can be imparted.
본 발명은 고경도 내후성 하드코팅 조성물에 관한 것이다.The present invention relates to a high-hardness, weather-resistant hard coating composition.
본 발명의 일 양태는 아크릴 폴리올 수지, 실란 화합물, 충전재 및 유기용제를 포함하는 것을 특징으로 하는 고경도 내후성 하드코팅 조성물에 관한 것이다.One aspect of the present invention relates to a high-hardness, weather-resistant hard coating composition comprising an acrylic polyol resin, a silane compound, a filler, and an organic solvent.
본 발명에서 상기 아크릴 폴리올 수지는 메틸(메타)아크릴레이트, 에틸(메타)아크릴레이트, 이소부틸(메타)아크릴레이트, 노말부틸(메타)아크릴레이트, 터셔리부틸(메타)아크릴레이트, 노말헥실메타크릴에이트, 2-에틸헥실(메타)아크릴레이트, 이소노닐(메타)아크릴레이트, 시클로헥실(메타)아크릴레이트, 프로필(메타)아크릴레이트, 노말옥틸(메타)아크릴레이트, 노닐(메타)아크릴레이트, 데실(메타)아크릴레이트, 도데실(메타)아크릴레이트에서 선택되는 어느 하나 또는 복수의 비닐기 함유 단량체를 포함할 수 있으며,In the present invention, the acrylic polyol resin is methyl (meth) acrylate, ethyl (meth) acrylate, isobutyl (meth) acrylate, normal butyl (meth) acrylate, tert-butyl (meth) acrylate, normal hexyl meth Crelate, 2-ethylhexyl (meth)acrylate, isononyl (meth)acrylate, cyclohexyl (meth)acrylate, propyl (meth)acrylate, normaloctyl (meth)acrylate, nonyl (meth)acrylate , It may include any one or a plurality of vinyl group-containing monomers selected from decyl (meth) acrylate and dodecyl (meth) acrylate,
상기 실란 화합물은 비닐메톡시 실란, 비닐트리메톡시 실란, 비닐트리에폭시 실란, 3-아미노프로필트리에폭시 실란, 3-글리시독시프로필트리메톡시 실란, 3-메타글리옥시프로필트리메톡시 실란, 3-메르캅토프로필트리메톡시 실란, N-(b-아미노에틸)-g-아미노프로필트리메톡시실란, g-글리시독시프로필트리에톡시실란, g-글리시독시트리메틸디메톡시실란, 2-(3,4-에폭시시클로헥실)에틸트리메톡시실란, g-메타크릴옥시프로필트리메톡시실란, g-메타크릴옥시프로필트리에톡시실란, g-메르캅토프로필트리메톡시실란 및 g-메르캅토프로필트리에톡시실란에서 선택되는 어느 하나 또는 복수를 포함할 수 있으며,The silane compound is vinylmethoxy silane, vinyltrimethoxy silane, vinyltriepoxy silane, 3-aminopropyltriepoxy silane, 3-glycidoxypropyltrimethoxy silane, 3-metaglycoxypropyltrimethoxy silane, 3-Mercaptopropyltrimethoxysilane, N-(b-aminoethyl)-g-aminopropyltrimethoxysilane, g-glycidoxypropyltriethoxysilane, g-glycidoxytrimethyldimethoxysilane, 2 -(3,4-epoxycyclohexyl)ethyltrimethoxysilane, g-methacryloxypropyltrimethoxysilane, g-methacryloxypropyltriethoxysilane, g-mercaptopropyltrimethoxysilane and g- It may include any one or plurality selected from mercaptopropyltriethoxysilane,
상기 충전재는 산화리튬, 산화나트륨, 산화칼륨, 산화바륨, 산화칼슘, 산화마그네슘, 탄산칼슘, 탄산나트륨, 불화칼슘, 불화리튬, 불화마그네슘, 브롬화마그네슘, 브롬화바륨 및 요오드화칼륨에서 선택되는 어느 하나 또는 복수를 포함할 수 있다.The filler is any one or more selected from lithium oxide, sodium oxide, potassium oxide, barium oxide, calcium oxide, magnesium oxide, calcium carbonate, sodium carbonate, calcium fluoride, lithium fluoride, magnesium fluoride, magnesium bromide, barium bromide and potassium iodide. can include
또한 상기 고경도 내후성 하드코팅 조성물은 아크릴 폴리올 수지 100 중량부에 대하여 실란 화합물 10 내지 50 중량부 충전재 1 내지 10 중량부 및 유기용제 10 내지 500 중량부를 포함할 수 있다.In addition, the high-hardness weather-resistant hard coating composition may include 10 to 50 parts by weight of a silane compound, 1 to 10 parts by weight of a filler, and 10 to 500 parts by weight of an organic solvent based on 100 parts by weight of the acrylic polyol resin.
또한 상기 고경도 내후성 하드코팅 조성물은 디페닐메탄디이소시아네이트, 1.6-헥사메틸렌디이소시아네이트. 1.6-헥사메틸렌디이소시아네이트의 중합체, 2.4-트릴렌디이소시아네이트화 브렌츠카테킨의 부가물, 트릴렌디이소시아네이트, 1-클로로페닐디이소시아네이트, 1.5-나프틸렌디이소시아네이트, 티오디프로필디이소시아네이트, 에틸벤젠-α-2-디이소시아네이트, 2.4-트릴렌디이소시아네이트 이량체 및 4,4',4"-트리페닐메탄트리이소시아네이트에서 선택되는 어느 하나 또는 복수의 유기폴리이소시아네이트나 안료, 침강방지제, 왁스, 산도조절제, 방청제, 수분산 수지, 소포제 및 레벨링제에서 선택되는 어느 하나 또는 복수의 첨가제를 더 포함할 수 있다.In addition, the high hardness weather resistant hard coating composition is diphenylmethane diisocyanate, 1.6-hexamethylene diisocyanate. Polymer of 1.6-hexamethylene diisocyanate, adduct of 2.4-trylene diisocyanate brentscatechin, torylene diisocyanate, 1-chlorophenyl diisocyanate, 1.5-naphthylene diisocyanate, thiodipropyl diisocyanate, ethylbenzene-α - Any one or more organic polyisocyanates selected from 2-diisocyanate, 2.4-tylene diisocyanate dimer, and 4,4',4"-triphenylmethane triisocyanate, pigment, anti-settling agent, wax, acidity regulator, rust preventive , It may further include any one or a plurality of additives selected from a water dispersion resin, an antifoaming agent and a leveling agent.
본 발명에 따른 고경도 내후성 하드코팅 조성물은 아크릴 폴리올 수지, 실란 화합물, 충전재 및 유기용제를 포함함에 따라 기재, 특히 금속기재와의 부착성이 뛰어나고, 우수한 표면의 경도, 내스크래치성을 확보할 수 있다. 여기에 금속기재의 녹슬음을 방지하고 오염 및 변형 방지 등의 고기능성을 발현함으로써 표면 보호를 위해 하드코팅층의 형성이 필요한 목재, 건축자재, 가구, 장식, 자동차내외장재, 패널 등에 폭넓게 사용 가능하다.The high-hardness, weather-resistant hard coating composition according to the present invention includes an acrylic polyol resin, a silane compound, a filler, and an organic solvent, so that it has excellent adhesion to substrates, especially metal substrates, and can secure excellent surface hardness and scratch resistance. there is. Here, it can be widely used in wood, building materials, furniture, decoration, automobile interior and exterior materials, and panels that require the formation of a hard coating layer for surface protection by expressing high functionality such as preventing rusting of metal substrates and preventing contamination and deformation.
이하 구체예 또는 실시예를 통해 본 발명에 따른 고경도 내후성 하드코팅 조성물을 더욱 상세히 설명한다. 다만 하기 구체예 또는 실시예는 본 발명을 상세히 설명하기 위한 하나의 참조일 뿐 본 발명이 이에 한정되는 것은 아니며, 여러 형태로 구현될 수 있다. Hereinafter, the high-hardness and weather-resistant hard coating composition according to the present invention will be described in more detail through specific examples or examples. However, the following specific examples or examples are only one reference for explaining the present invention in detail, but the present invention is not limited thereto, and may be implemented in various forms.
또한 달리 정의되지 않은 한, 모든 기술적 용어 및 과학적 용어는 본 발명이 속하는 당업자 중 하나에 의해 일반적으로 이해되는 의미와 동일한 의미를 갖는다. 본원에서 설명에 사용되는 용어는 단지 특정 구체예를 효과적으로 기술하기 위함이고 본 발명을 제한하는 것으로 의도되지 않는다.Also, unless defined otherwise, all technical and scientific terms have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used herein in description is merely to effectively describe a particular embodiment and is not intended to limit the invention.
또한 명세서 및 첨부된 특허청구범위에서 사용되는 단수 형태는 문맥에서 특별한 지시가 없는 한 복수 형태도 포함하는 것으로 의도할 수 있다.Also, the singular forms used in the specification and appended claims may be intended to include the plural forms as well, unless the context dictates otherwise.
본 발명에 따른 고경도 내후성 하드코팅 조성물은 코팅 대상의 표면에 코팅되어 코팅 대상을 외부의 환경이나 충격으로부터 보호하고 부식 등을 방지하기 위한 조성물로, 상기 코팅 대상은 알루미늄, 철, 니켈, 크롬, 구리 또는 이들의 합금 등의 금속기재를 포함할 수 있다.The high-hardness, weather-resistant hard coating composition according to the present invention is a composition for coating the surface of a coating target to protect the coating target from external environment or impact and to prevent corrosion, etc., the coating target includes aluminum, iron, nickel, chromium, It may include a metal substrate such as copper or an alloy thereof.
본 발명에 따른 고경도 내후성 하드코팅 조성물은 아크릴 폴리올 수지, 실란 화합물, 충전재 및 유기용제를 포함할 수 있다.The high-hardness, weather-resistant hard coating composition according to the present invention may include an acrylic polyol resin, a silane compound, a filler, and an organic solvent.
본 발명에서 상기 아크릴 폴리올 수지는 코팅층을 형성하기 위한 베이스 수지로, 다른 성분과의 혼화성이 높아 코팅층의 내후성을 균질하게 발현하도록 할 수 있다.In the present invention, the acrylic polyol resin is a base resin for forming a coating layer, and has high miscibility with other components, so that the weather resistance of the coating layer can be uniformly expressed.
본 발명에서 상기 아크릴 폴리올 수지는 기본적으로 비닐기를 가지는 단량체와 히드록시기를 가지는 단량체 중 어느 하나, 바람직하게는 이들 모두를 포함하는 것으로, 비닐기와 히드록시기를 모두 가짐에 따라 각 관능기 간의 결합, 가교를 통해 코팅층의 기계적 물성을 크게 높일 수 있다.In the present invention, the acrylic polyol resin basically includes any one of a monomer having a vinyl group and a monomer having a hydroxyl group, preferably both of them. mechanical properties can be greatly improved.
구체적으로 상기 비닐기 함유 단량체는 아크릴레이트계 단량체로 스티렌 및 이의 유도체, 부타디엔 및 탄소수 1 내지 12의 아크릴/메타크릴산 에스테르 중에서 선택된 1종 이상을 사용할 수 있으며, 바람직하게는 메틸(메타)아크릴레이트, 에틸(메타)아크릴레이트, 이소부틸(메타)아크릴레이트, 노말부틸(메타)아크릴레이트, 터셔리부틸(메타)아크릴레이트, 노말헥실메타크릴에이트, 2-에틸헥실(메타)아크릴레이트, 이소노닐(메타)아크릴레이트, 시클로헥실(메타)아크릴레이트, 프로필(메타)아크릴레이트, 노말옥틸(메타)아크릴레이트, 노닐(메타)아크릴레이트, 데실(메타)아크릴레이트, 도데실(메타)아크릴레이트에서 선택되는 어느 하나 또는 복수일 수 있다.Specifically, the vinyl group-containing monomer may use at least one selected from styrene and derivatives thereof, butadiene, and acrylic/methacrylic acid esters having 1 to 12 carbon atoms as an acrylate monomer, preferably methyl (meth)acrylate , ethyl (meth) acrylate, isobutyl (meth) acrylate, normal butyl (meth) acrylate, tert-butyl (meth) acrylate, normalhexyl methacrylate, 2-ethylhexyl (meth) acrylate, iso Nonyl(meth)acrylate, cyclohexyl(meth)acrylate, propyl(meth)acrylate, normaloctyl(meth)acrylate, nonyl(meth)acrylate, decyl(meth)acrylate, dodecyl(meth)acrylate It may be any one or multiple selected from the rate.
상기 히드록시기 함유 단량체는 상기 비닐기 함유 단량체와 중합되어 도막을 형성하고, 도막의 기계적 물성을 향상시키는 역할을 하는 것으로, 본 발명에서는 종류를 한정하는 것은 아니나, 탄소수 1 내지 24의 지방족, 지환족 및 방향족 산무수물을 사용할 수 있고, 예를 들어 숙신산 무수물, 말레인산 무수물, 도데실숙신산 무수물, 옥틸숙신산 무수물, 프탈산 무수물, 헥사히드로프탈산 무수물, 메틸헥사히드로프탈산 무수물, 테트라히드로프탈산 무수물에서 선택되는 1종 이상을 포함할 수 있다. The hydroxy group-containing monomer is polymerized with the vinyl group-containing monomer to form a coating film and serves to improve the mechanical properties of the coating film. In the present invention, the type is not limited, but aliphatic, alicyclic and Aromatic acid anhydrides may be used, for example, at least one selected from succinic anhydride, maleic anhydride, dodecylsuccinic anhydride, octylsuccinic anhydride, phthalic anhydride, hexahydrophthalic anhydride, methylhexahydrophthalic anhydride, and tetrahydrophthalic anhydride. can include
또한 상기 히드록시기 함유 단량체는 상기 무수물 이외에도 2-하이드록시에틸(메타)아크릴레이트, 2-하이드록시프로필(메타)아크릴레이트, 카두라(메타)아크릴레이트, 카프로락톤(메타)아크릴레이트, 2,3-디하이드록시프로필(메타)아크릴레이트, 폴리프로필렌변성 (메타)아크릴레이트, 4-하이드록시메틸시크로헥실-메틸(메타)아크릴레이트, 모노카르복실산(예를 들어, (메트)아크릴산)과 같은 에틸렌성 불포화 모노머를 더 포함할 수 있으나, 이에 한정하는 것은 아니다.In addition to the anhydride, the hydroxyl group-containing monomer is 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, cardura (meth) acrylate, caprolactone (meth) acrylate, 2,3- Dihydroxypropyl (meth)acrylate, polypropylene-modified (meth)acrylate, 4-hydroxymethylcyclohexyl-methyl (meth)acrylate, monocarboxylic acids (e.g., (meth)acrylic acid) and It may further include the same ethylenically unsaturated monomer, but is not limited thereto.
상기 아크릴 폴리올 수지는 비닐기 함유 단량체 100 중량부 대비 히드록시기 함유 단량체 1 내지 50 중량부 포함할 수 있다. 히드록시기 함유 단량체가 상기 범우 미만인 경우 중합이 제대로 진행되지 않으며, 경화 후 코팅층의 가교밀도가 저하되어 내약품성과 내후성이 저하될 수 있고, 상기 범위를 초과하는 경우 수산기가 과다하여 방청성이 떨어질 수 있다.The acrylic polyol resin may include 1 to 50 parts by weight of a hydroxy group-containing monomer based on 100 parts by weight of a vinyl group-containing monomer. If the hydroxy group-containing monomer is less than the above range, polymerization does not proceed properly, and the crosslinking density of the coating layer after curing may decrease, resulting in deterioration in chemical resistance and weather resistance.
본 발명에서 상기 실란 화합물은 소재와의 부착성을 높임과 동시에 표면 접촉각을 높여 내오염성을 강화하기 위해 첨가하는 것으로, 아미노기나 에폭시기, 또는 이들 모두를 포함하는 실란 화합물을 포함하는 것이 바람직하다.In the present invention, the silane compound is added to enhance adhesion to the material and at the same time increase the surface contact angle to enhance stain resistance, and it is preferable to include a silane compound containing an amino group, an epoxy group, or both.
상기 실란 화합물로 예를 들면 테트라(메톡시에톡시 실란), 비닐메톡시 실란, 비닐트리메톡시 실란, 비닐트리에폭시실란, 3-아미노프로필트리에폭시 실란, 3-글리시독시프로필트리메톡시 실란, 3-메타글리옥시프로필트리메톡시실란, 3-메르캅토프로필트리메톡시 실란, N-(b-아미노에틸)-g-아미노프로필트리메톡시실란, g-글리시독시프로필트리에톡시실란, g-글리시독시트리메틸디메톡시실란, 2-(3,4-에폭시시클로헥실)에틸트리메톡시실란, g-메타크릴옥시프로필트리메톡시실란, g-메타크릴옥시프로필트리에톡시실란, g-메르캅토프로필트리메톡시실란 및 g-메르캅토프로필트리에톡시실란에서 선택되는 어느 하나 또는 복수를 포함할 수 있다.Examples of the silane compound include tetra(methoxyethoxysilane), vinylmethoxysilane, vinyltrimethoxysilane, vinyltriepoxysilane, 3-aminopropyltriepoxysilane, 3-glycidoxypropyltrimethoxysilane , 3-metaglycoxypropyltrimethoxysilane, 3-mercaptopropyltrimethoxysilane, N-(b-aminoethyl)-g-aminopropyltrimethoxysilane, g-glycidoxypropyltriethoxysilane , g-glycidoxytrimethyldimethoxysilane, 2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane, g-methacryloxypropyltrimethoxysilane, g-methacryloxypropyltriethoxysilane, It may include any one or plurality selected from g-mercaptopropyltrimethoxysilane and g-mercaptopropyltriethoxysilane.
상기 실란 화합물은 상기 아크릴 폴리올 수지 100 중량부 대비 10 내지 50 중량부 포함하는 것이 바람직하다. 실란 화합물이 상기 범위 미만 첨가되는 경우 내부식성 및 부착성 증대 효과가 미비하며, 상기 범위 초과 첨가하는 경우 조성물의 혼화성이 하락하고 코팅 후 기포 등이 잔존할 수 있다.The silane compound is preferably included in an amount of 10 to 50 parts by weight based on 100 parts by weight of the acrylic polyol resin. When the silane compound is added below the above range, the corrosion resistance and adhesion enhancement effect is insufficient, and when the silane compound is added above the above range, the miscibility of the composition is lowered and air bubbles or the like may remain after coating.
본 발명에 상기 충전재는 코팅층의 경도를 증가시키고 내부식성을 향상시키기 위해 첨가하는 것으로, 종류를 한정하는 것은 아니나 평균입경 100㎚ 이하, 더욱 바람직하게는 10 내지 30㎚ 이하의 금속화합물이나 실리콘계 입자를 포함하는 것이 바람직하다. In the present invention, the filler is added to increase the hardness of the coating layer and improve corrosion resistance, and the type is not limited, but a metal compound or silicon-based particle having an average particle diameter of 100 nm or less, more preferably 10 to 30 nm or less It is preferable to include
이러한 충전재로 예를 들면 산화리튬(Li2O), 산화나트륨(Na2O), 산화칼륨(K2O), 산화바륨(BaO), 산화칼슘(CaO), 산화마그네슘(MgO), 탄산칼슘(CaCO3), 탄산나트륨(NaCO3), 불화칼슘(CaF2), 불화리튬(LiF), 불화마그네슘(MgF2), 브롬화마그네슘(MgBr2), 브롬화바륨(BaBr2) 및 요오드화칼륨(KI) 등이 있으며, 이외에도 황산리튬(Li2SO4), 황산나트륨(Na2SO4), 황산칼슘(CaSO4), 황산마그네슘(MgSO4), 황산코발트(CoSO4), 황산갈륨(Ga2(SO4)3), 황산티탄(Ti(SO4)2), 황산니켈(NiSO4), 염화칼슘(CaCl2), 염화마그네슘(MgCl2), 염화스토론튬(SrCl2), 염화이트륨(YCl2), 염화구리(CuCl2), 불화세슘(CsF), 불화탄탈륨(TaF5), 불화니오븀(NbF5), 브롬화리튬(LiBr), 브롬화칼슘(CaBr3), 브롬화세륨(CeBr4), 브롬화셀레늄(SeBr2), 브롬화바나듐(VBr2), 요오드화바륨(BaI2), 요오드화마그네슘(MgI2), 과염소산바륨(Ba(ClO4)2) 및 과염소산 마그네슘(Mg(ClO4)2) 등의 금속화합물 또는 폴리실세스퀴옥산을 사용하여도 좋다. 또한 이들은 단독으로 또는 둘 이상 혼합하여 사용하여도 무방하다.Examples of such fillers include lithium oxide (Li 2 O), sodium oxide (Na 2 O), potassium oxide (K 2 O), barium oxide (BaO), calcium oxide (CaO), magnesium oxide (MgO), and calcium carbonate. (CaCO 3 ), sodium carbonate (NaCO 3 ), calcium fluoride (CaF 2 ), lithium fluoride (LiF), magnesium fluoride (MgF 2 ), magnesium bromide (MgBr 2 ), barium bromide (BaBr 2 ) and potassium iodide (KI) In addition, lithium sulfate (Li 2 SO4), sodium sulfate (Na 2 SO 4 ), calcium sulfate (CaSO 4 ), magnesium sulfate (MgSO 4 ), cobalt sulfate (CoSO 4 ), gallium sulfate (Ga 2 (SO 4) ) 3 ), titanium sulfate (Ti(SO 4 ) 2 ), nickel sulfate (NiSO 4 ), calcium chloride (CaCl 2 ), magnesium chloride (MgCl 2 ), strontium chloride (SrCl 2 ), yttrium chloride (YCl 2 ) , copper chloride (CuCl 2 ), cesium fluoride (CsF), tantalum fluoride (TaF 5 ), niobium fluoride (NbF 5 ), lithium bromide (LiBr), calcium bromide (CaBr 3 ), cerium bromide (CeBr 4 ), selenium bromide Metals such as (SeBr 2 ), vanadium bromide (VBr 2 ), barium iodide (BaI 2 ), magnesium iodide (MgI 2 ), barium perchlorate (Ba(ClO 4 ) 2 ) and magnesium perchlorate (Mg(ClO 4 ) 2 ) A compound or polysilsesquioxane may be used. In addition, these may be used alone or in combination of two or more.
또한 상기 충전재는 상기와 같은 금속화합물 이외에 유기성분이 코팅된 무기입자를 더 포함하는 것이 좋다. 상기 유기성분이 코팅된 무기입자는 일종의 유무기 하이브리드 입자로, 표면에 다수의 관능기를 갖기 때문에 상술한 일반 금속화합물과 혼합 시 코팅층의 기계적 물성과 화학적 물성, 예를 들어 내스크래치성, 접착성, 내오염성 및 방청성을 모두 향상시킬 수 있다. In addition, the filler preferably further includes inorganic particles coated with an organic component in addition to the metal compound as described above. Since the inorganic particles coated with the organic component are a kind of organic-inorganic hybrid particle and have a plurality of functional groups on the surface, the mechanical and chemical properties of the coating layer when mixed with the general metal compound described above, such as scratch resistance, adhesiveness, Both stain resistance and rust prevention can be improved.
상기 유무기 하이브리드 입자는 상술한 금속화합물 충전재 표면에 싸이올기(thiol), 히드록시기(hydroxyl), 에폭시기(epoxyl), 아민기(amine), 실란기(silane) 등의 관능기를 함유하는 중합 가능한 단량체를 중합시켜 코팅하는 것이 바람직하다.The organic-inorganic hybrid particles are polymerizable monomers containing functional groups such as thiol, hydroxyl, epoxyl, amine, and silane on the surface of the above-described metal compound filler. It is preferable to polymerize and coat.
상기 유무기 하이브리드 입자에 사용되는 코어로 바람직하게는 산화지르코늄, 산화티탄 등을 들 수 있으며, 쉘층을 형성하는 상기 관능기를 함유하는 중합 가능한 단량체로 예를 들면 2-하이드록시에틸 메타아크릴레이트(2-hydroxyethyl methacrylate), 2-하이드록시에틸 아크릴레이트(2-hydroxyethyl acrylate), 2-디메틸아미노에틸메타아크릴레이트(2-(dimethylamino)ethyl methacrylate), 2-디에틸아미노에틸메타아크릴레이트(2-(diethylamino)ethyl methacrylate), 테트라-부틸메타아크릴레이트(t-butyl methacrylate), 2-아미노에틸메타아크릴레이트(2-aminoethyl methacrylate), 아크릴아마이도 프로필트리메틸암모늄 클로라이드(acrylamido- propyltrimethylammonium chloride), 피리딘(pyridine), 피롤리돈(pyrrolidone) 등을 들 수 있고, 이들은 단독으로 또는 둘 이상 혼합하여 사용하여도 무방하다.Zirconium oxide, titanium oxide, etc. are preferably used as the core used for the organic-inorganic hybrid particles, and as a polymerizable monomer containing the functional group forming the shell layer, for example, 2-hydroxyethyl methacrylate (2 -hydroxyethyl methacrylate), 2-hydroxyethyl acrylate, 2-dimethylaminoethyl methacrylate (2-(dimethylamino)ethyl methacrylate), 2-diethylaminoethyl methacrylate (2-( diethylamino)ethyl methacrylate), tetra-butyl methacrylate, 2-aminoethyl methacrylate, acrylamido- propyltrimethylammonium chloride, pyridine ), pyrrolidone, and the like, and these may be used alone or in combination of two or more.
상기 유무기 하이브리드 입자는 그 크기를 한정하는 것은 아니나 코어가 10 내지 30㎚, 쉘층은 1 내지 20㎚의 두께를 갖는 것이 바람직하다. 코어와 쉘층의 크기가 상기 범위 미만인 경우 상술한 코팅층의 물성 강화 특성이 발현되기 어려우며, 상기 범위를 초과하는 경우 다른 충전재와의 혼화성이 떨어져 코팅층의 박리가 발생할 수 있다.The size of the organic-inorganic hybrid particle is not limited, but the core preferably has a thickness of 10 to 30 nm and the shell layer has a thickness of 1 to 20 nm. When the size of the core and the shell layer is less than the above range, it is difficult to express the above-mentioned physical property enhancement characteristics of the coating layer, and when it exceeds the above range, miscibility with other fillers is poor, and peeling of the coating layer may occur.
또한 상기 충전재는 금속화합물과 유무기 하이브리드 입자의 조성비를 한정하는 것은 아니나 금속화합물 : 유무기 하이브리드 입자가 1 : 0.3 내지 0.5를 만족하는 것이 바람직하다. 충전재의 혼합비가 상기 범위를 벗어나는 경우 코팅층의 물성 강화가 제대로 이루어지지 않거나 충전재 간의 뭉침이 발생하여 코팅층의 기계적 물성이 하락할 수 있다.In addition, the filler does not limit the composition ratio of the metal compound and the organic-inorganic hybrid particles, but it is preferable that the metal compound:organic-inorganic hybrid particles satisfy 1:0.3 to 0.5. When the mixture ratio of the filler is out of the above range, the physical properties of the coating layer may not be properly reinforced or the mechanical properties of the coating layer may deteriorate due to aggregation between the fillers.
상기 충전재는 상기 아크릴 폴리올 수지 100 중량부 대비 1 내지 10 중량부 포함하는 것이 바람직하다. 실란 화합물이 상기 범위 미만 첨가되는 경우 코팅층의 내스크래치성이 저하되고 경도 향상 효과가 미비하며, 상기 범위를 초과하여 첨가하는 경우 조성물과의 혼화성과 코팅층의 부착성이 하락하며, 코팅층의 투명성이 하락할 수 있다.The filler is preferably included in an amount of 1 to 10 parts by weight based on 100 parts by weight of the acrylic polyol resin. When the silane compound is added below the above range, the scratch resistance of the coating layer is lowered and the hardness improvement effect is insignificant. can
본 발명에서 상기 유기용제는 당 업계에 알려진 통상적인 유기용제라면 제한 없이 사용 가능하다. In the present invention, the organic solvent can be used without limitation as long as it is a conventional organic solvent known in the art.
이러한 유기용제의 예를 들면 톨루엔, 자일렌, 코코솔 #100(Kocosol #100, K-100, SK에너지주식회사), 코코솔 #150(Kocosol #150, K-150, SK에너지주식회사)과 같은 방향족 탄화수소계 용제, 메틸에틸케톤, 메틸프로필케톤, 메틸부틸케톤, 에틸프로필케톤과 같은 케톤계 용제, 메틸아세테이트, 에틸아세테이트, n-프로필아세테이트, n-부틸아세테이트, 에틸에톡시프로피오네이트 등과 같은 에스테르계 용제 등이 있으며, 이들은 단독으로 또는 둘 이상 혼합하여 사용하여도 좋다.Examples of such organic solvents include toluene, xylene, aromatics such as Kocosol #100 (Kocosol #100, K-100, SK Energy Co., Ltd.), Kocosol #150 (Kocosol #150, K-150, SK Energy Co., Ltd.) Hydrocarbon solvents, ketone solvents such as methyl ethyl ketone, methyl propyl ketone, methyl butyl ketone, and ethyl propyl ketone, esters such as methyl acetate, ethyl acetate, n-propyl acetate, n-butyl acetate, and ethyl ethoxypropionate and the like, and these may be used alone or in combination of two or more.
상기 유기용제는 첨가량을 한정하는 것은 아니나, 상기 아크릴 폴리올 수지 100 중량부 대비 10 내지 500 중량부 포함할 수 있다. 유기용제의 함량이 상기 범위를 만족하는 경우 코팅층의 성형성이 개선되고 조성물의 혼화성이 증가하여 우수한 기계적, 화학적 물성을 확보할 수 있다.The amount of the organic solvent added is not limited, but may be included in an amount of 10 to 500 parts by weight based on 100 parts by weight of the acrylic polyol resin. When the content of the organic solvent satisfies the above range, the moldability of the coating layer is improved and the miscibility of the composition is increased, so that excellent mechanical and chemical properties can be secured.
또한 상기 고경도 내후성 하드코팅 조성물은 상술한 성분들 이외에도 본 발명의 목적을 해치지 않는 범위 내에서 다양한 첨가제를 더 포함할 수 있다. 이러한 첨가제로 예를 들면 중합개시제, 분산제, 안료, 침강방지제, 왁스, 산도조절제, 방청제, 수분산 수지, 소포제 및 레벨링제 등이 있다.In addition, the high-hardness weather-resistant hard coating composition may further include various additives in addition to the above-described components within a range that does not impair the object of the present invention. Such additives include, for example, polymerization initiators, dispersants, pigments, antisettling agents, waxes, acidity regulators, rust inhibitors, water dispersion resins, antifoaming agents and leveling agents.
상기 개시제는 아조 타입 또는 퍼옥사이드 타입의 개시제를 포함할 수 있으며, 바람직하게는 디터셔리부틸퍼옥사이드, 디터셔리아밀퍼옥사이드, 디터셔리부틸퍼옥시-2-에틸헥사노에이트, 디터셔리아밀퍼옥시-2-에틸헥사노에이트, 디이소부틸퍼옥사이드, 터셔리아밀퍼옥시에틸헥사노에이트, 터셔리부틸퍼옥시디에틸아세테이트, 터셔리부틸퍼옥시이소부티레이트 등이 있으나, 이에 제한되는 것은 아니다.The initiator may include an azo-type or peroxide-type initiator, and preferably ditertiary butyl peroxide, diterteria mil peroxide, ditertiary butyl peroxy-2-ethylhexanoate, ditertiary mil peroxy. -2-ethylhexanoate, diisobutyl peroxide, tertiary butyl peroxyethyl hexanoate, tert-butyl peroxydiethyl acetate, tert-butyl peroxyisobutyrate, etc., but are not limited thereto.
또한 상기 개시제는 광중합을 유도하기 위한 광중합 개시제를 포함할 수도 있다. 이러한 광중합 개시제로 예를 들면 상품명으로 이르가큐아 184(치바 스페샤리티·케미칼즈 제조), 이르가큐아 149(치바 스페샤리티·케미칼즈 제조), 이르가큐아 651(치바 스페샤리티·케미칼즈 제조), 이르가큐아 907(치바 스페샤리티·케미칼즈 제조), 이르가큐아 754(치바 스페샤리티·케미칼즈 제조), 이르가큐아 819(치바 스페샤리티·케미칼즈 제조), 이르가큐아 500(치바 스페샤리티·케미칼즈 제조), 이르가큐아 1000(치바 스페샤리티·케미칼즈 제조), 이르가큐아 1800(치바 스페샤리티·케미칼즈 제조), 이르가큐아 754(치바 스페샤리티·케미칼즈 제조), 르시린 TPO(BASF 제조), 카야큐아 DETX－S(일본화약 제조), 카야큐아 EPA(일본화약 제조), 카야큐아 DMBI(일본화약 제조) 등을 들 수 있으며, 이들을 단독 또는 2종 이상으로 조합하여 사용할 수 있다. 그 중에서 이르가큐아 184 및 이르가큐아 819가 바람직하다.In addition, the initiator may include a photopolymerization initiator for inducing photopolymerization. Such photopolymerization initiators include, for example, Irgacure 184 (manufactured by Ciba Specialty Chemicals), Irgacua 149 (manufactured by Ciba Specialty Chemicals), and Irgacure 651 (manufactured by Ciba Specialty Chemicals) as trade names. (manufactured by Ciba Specialty Chemicals), Irgacua 907 (manufactured by Ciba Specialty Chemicals), Irgacua 754 (manufactured by Ciba Specialty Chemicals), Irgacure 819 (manufactured by Ciba Specialty Chemicals), Irgacure Gacure 500 (manufactured by Chiba Specialty Chemicals), Irgacua 1000 (manufactured by Chiba Specialty Chemicals), Irgacua 1800 (manufactured by Chiba Specialty Chemicals), Irgacua 754 (Ciba Specialty Chemicals) Speciality Chemicals), Lecilin TPO (manufactured by BASF), Kayakua DETX-S (manufactured by Nippon Explosives), Kayakua EPA (manufactured by Nippon Explosives), Kayakua DMBI (manufactured by Nippon Explosives), etc. , These can be used alone or in combination of two or more. Among them, Irgacua 184 and Irgacua 819 are preferable.
또한 상기 개시제가 광중합 개시제인 경우, 중합을 촉진하기 위해 광증감제나 광촉진재를 더 포함하여도 좋다.In addition, when the initiator is a photopolymerization initiator, a photosensitizer or photoaccelerator may be further included to promote polymerization.
상기 분산제는 조성물을 구성하는 각 재료들을 분산시키고 거리 유지를 통해 재응집을 막아 도막의 균일한 물성을 발현하도록 하는 역할을 한다. 상기 분산제로는 당 분야에 알려진 통상적인 것을 사용할 수 있으며, 일례로, 고분자량의 블록 공중합체 타입의 분산제 등을 사용할 수 있다.The dispersant serves to disperse each material constituting the composition and prevent re-agglomeration by maintaining a distance to express uniform physical properties of the coating film. As the dispersant, a conventional dispersant known in the art may be used, and for example, a block copolymer type dispersant having a high molecular weight may be used.
상기 안료는 조성물에 원하는 색상(유색)을 발현하거나 도막의 강도나 광택을 증가시키기 위해 사용될 수 있다. 이러한 안료로는 통상적으로 사용되는 유기 안료, 무기 안료, 메탈릭 안료, 알루미늄-페이스트(Al-paste), 펄(pearl), 체질 안료 등을 제한 없이 사용할 수 있으며, 이들을 단독으로 사용하거나 2종 이상 혼용할 수 있다. 상기 안료의 비제한적인 예로는 레드 계열, 황색/오렌지 계열, 블루 계열, 블랙 계열, 백색 계열, 펄 및 메탈릭 계열의 안료 등을 사용할 수 있다.The pigment may be used to express a desired color (color) in the composition or to increase the strength or gloss of a coating film. As these pigments, organic pigments, inorganic pigments, metallic pigments, aluminum-paste, pearl, extender pigments, etc., which are commonly used, can be used without limitation, and these can be used alone or in combination of two or more. can do. Non-limiting examples of the pigment include red, yellow/orange, blue, black, white, pearl and metallic pigments.
상기 소포제는 도장 시 발생되는 기포를 억제함으로써 도막의 외관 특성을 향상시키는 역할을 하는 것으로서, 당 분야에 알려진 통상적인 소포제를 제한 없이 사용할 수 있다. 예를 들어, 실리콘계 또는 비실리콘계 소포제를 사용할 수 있고, 일례로 폴리실록산 타입의 소포제를 사용할 수 있다.The antifoaming agent serves to improve the appearance properties of the coating film by suppressing air bubbles generated during painting, and conventional antifoaming agents known in the art may be used without limitation. For example, a silicone-based or non-silicone-based antifoaming agent may be used, and for example, a polysiloxane type antifoaming agent may be used.
상기 레벨링제는 상기 조성물이 평탄하고 매끄럽게 코팅되도록 레벨링함으로써, 조성물 내의 접착력을 증진시키면서 도막의 외관 특성을 향상시키기 위한 것이다. 상기 레벨링제로는 당 분야에 알려진 통상적인 것을 제한 없이 사용할 수 있으며, 일례로, 아크릴계, 실리콘계, 폴리에스테르계, 아민계 레벨링제 등이 있다.The leveling agent is for leveling the composition so that it is coated flatly and smoothly, thereby improving the appearance properties of the coating film while enhancing the adhesion within the composition. As the leveling agent, conventional ones known in the art may be used without limitation, and examples thereof include acrylic, silicone, polyester, and amine leveling agents.
상기 첨가제들은 각각 첨가량을 한정하지 않는다. 일예로 상기 첨가제는 상기 아크릴 폴리올 수지 100 중량부 대비 0.1 내지 10 중량부 포함할 수 있다.The amount of each of the additives is not limited. For example, the additive may be included in an amount of 0.1 to 10 parts by weight based on 100 parts by weight of the acrylic polyol resin.
또한 상기 고경도 내후성 하드코팅 조성물은 코팅 대상과의 접착성을 더욱 높이기 위해 유기폴리이소시아네이트를 더 포함할 수 있다.In addition, the high-hardness weather-resistant hard coating composition may further include organic polyisocyanate to further increase adhesion to a coating target.
상기 유기폴리이소시아네이트는 조성물의 개시제 존재 하에서 상기 유무기 하이브리드 입자, 아크릴 폴리올과 우레탄 반응을 진행하여 중합된다. 중합된 수지는 분자량의 증가와 함께 다량의 관능기를 함유하고 있어 접착 대상과의 접착성을 더욱 증가시킬 수 있다.The organic polyisocyanate is polymerized by proceeding a urethane reaction with the organic-inorganic hybrid particles and acrylic polyol in the presence of an initiator of the composition. Since the polymerized resin contains a large amount of functional groups along with an increase in molecular weight, it can further increase the adhesiveness to an adhesive target.
상기 유기이소시아네이트로는 바람직하게는 4.4′-디페닐메탄디이소시아네이트, 2.6-드릴렌디이소시아네이트, 1.6-헥사메틸렌디이소시아네이트, 이소포론디이소시아네이트, 4.4′-디싸이클로헥실메탄디이소시아네이트, 1.3-크실렌디이소시아네이트, 1,4-테트라메틸렌디이소시아네이트, 1,10-데카메틸렌디이소시아네이트, 1,4-시클로헥산디이소시아네이트, 톨루엔-2,6-디이소시아네이트, 1,5-나프탈렌디이소시아네이트, 4-메톡시-1,3-페닐렌디이소시아네이트, 4-클로로-1,3페닐렌디이소시아네이트, 2,4-디메틸-1,3-페닐렌디이소시아네이트 등을 사용할 수 있으며, 단독 또는 두 가지 이상 혼합하여 사용할 수 있다. 또한, 다관능 폴리이소시아네이트, 예컨대 1몰의 트리메틸올프로판에 3몰의 2.6-트릴렌디이소시아네이트가 부가된 화합물 등도 병용 가능하다.The organic isocyanate is preferably 4.4'-diphenylmethane diisocyanate, 2.6-drillene diisocyanate, 1.6-hexamethylene diisocyanate, isophorone diisocyanate, 4.4'-dicyclohexylmethane diisocyanate, and 1.3-xylene diisocyanate. , 1,4-tetramethylene diisocyanate, 1,10-decamethylene diisocyanate, 1,4-cyclohexane diisocyanate, toluene-2,6-diisocyanate, 1,5-naphthalene diisocyanate, 4-methoxy- 1,3-phenylene diisocyanate, 4-chloro-1,3-phenylene diisocyanate, 2,4-dimethyl-1,3-phenylene diisocyanate, etc. may be used, and may be used alone or in combination of two or more. In addition, a polyfunctional polyisocyanate such as a compound obtained by adding 3 mol of 2.6-trylene diisocyanate to 1 mol of trimethylolpropane can be used in combination.
상기 유기이소시아네이트는 상기 아크릴 폴리올 수지 100 중량부 대비 0.1 내지 10 중량부 포함할 수 있다. 유기이소시아네이트가 상기 범위 미만 첨가되는 경우 상술한 부착성 개선이 미비할 수 있으며, 상기 범위를 초과하는 경우 경화 시 과도한 중합이 발생하여 코팅층의 표면 평활성이 저하되고 기포가 발생하는 등, 표면 상태가 불량해질 수 있다.The organic isocyanate may be included in an amount of 0.1 to 10 parts by weight based on 100 parts by weight of the acrylic polyol resin. If the organic isocyanate is added below the above range, the above-mentioned improvement in adhesion may be insufficient, and when the above range is exceeded, excessive polymerization occurs during curing, resulting in poor surface condition such as deterioration in surface smoothness of the coating layer and generation of bubbles. it can be done
본 발명에 따른 조성물은 적용 방법을 한정하지 않는다. 일예로, 제조된 조성물을 경화한 후의 도막 두께가 1 내지 100㎛ 정도가 되도록 조성물을 코팅 대상에 도포하되, 도포 방법으로 스프레이 도장법, 솔칠법, 롤러 도장법, 커텐 코트법, 플로우 코트법, 침지 칠법 등을 적용할 수 있다. 그리고 개시제에 따라 다르나 일반적인 개시제의 경우 개시제와 다른 성분들이 혼합된 직후에 도포하여 상온에서 경화를 유도하며, 광중합 개시제를 사용하는 경우 자외선, 감마선, 전자선 등의 광을 퓨전 램프, 고압 수은등, 메탈하라이드 램프 등을 이용하여 1 내지 10분간 정도 조사함으로써 하드 코트를 형성할 수 있다.The composition according to the present invention is not limited to the method of application. For example, the composition is applied to the coating target so that the coating film thickness after curing the prepared composition is about 1 to 100 μm, and the coating method is spray coating, brush coating, roller coating, curtain coating, flow coating, and immersion coating. etc. can be applied. And, although it depends on the initiator, general initiators are applied immediately after the initiator and other components are mixed to induce curing at room temperature. When using a photopolymerization initiator, light such as ultraviolet rays, gamma rays, electron beams, etc. A hard coat can be formed by irradiating for about 1 to 10 minutes using a led lamp or the like.
본 발명에 따른 코팅 대상은 재질 등을 특별히 제한하지 않으나 금속기재인 것이 바람직하다. 또한 금속기재의 용도 또한 특별히 제한하지 않으며, 알루미늄 샤시 등의 건축자재나 일반 생활용품, 차량부품 등 다양하게 사용 가능하다. The coating target according to the present invention is not particularly limited in material or the like, but is preferably a metal substrate. In addition, the use of the metal substrate is not particularly limited, and it can be used in various ways, such as building materials such as aluminum chassis, general household items, and vehicle parts.
본 발명에 따른 고경도 내후성 하드코팅 조성물은 아크릴 폴리올 수지, 실란 화합물, 충전재 및 유기용제를 포함함에 따라 기재, 특히 금속기재와의 부착성이 뛰어나고, 우수한 표면의 경도, 내스크래치성을 확보할 수 있다. 여기에 금속기재의 녹슬음을 방지하고 오염 및 변형 방지 등의 고기능성을 발현함으로써 표면 보호를 위해 하드코팅층의 형성이 필요한 목재, 건축자재, 가구, 장식, 자동차내외장재, 패널 등에 폭넓게 사용 가능하다.The high-hardness, weather-resistant hard coating composition according to the present invention includes an acrylic polyol resin, a silane compound, a filler, and an organic solvent, so that it has excellent adhesion to substrates, especially metal substrates, and can secure excellent surface hardness and scratch resistance. there is. Here, it can be widely used in wood, building materials, furniture, decoration, automobile interior and exterior materials, and panels that require the formation of a hard coating layer for surface protection by expressing high functionality such as preventing rusting of metal substrates and preventing contamination and deformation.
이하, 실시예 및 비교예를 들어 본 발명을 더욱 상세히 설명한다. 다만 하기 실시예들은 본 발명을 더욱 상세히 설명하기 위한 하나의 예시일 뿐, 본 발명이 하기 실시예들에 의해 제한되는 것은 아니다.Hereinafter, the present invention will be described in more detail by way of Examples and Comparative Examples. However, the following examples are only one example for explaining the present invention in more detail, and the present invention is not limited by the following examples.
실시예 및 비교예를 통해 제조된 시편의 물성을 다음과 같이 측정하였다.The physical properties of the specimens prepared in Examples and Comparative Examples were measured as follows.
(부착성)(adhesion)
시편의 부착성은 초기 부착성과 내수시험 후 부착성으로 나누어 측정하였으며, 먼저 초기 부착성은 시편에 1mm 폭으로 10×10의 바둑판목 모양으로 칼집을 내고 바둑판목 부분에 셀로판 테이프를 첩착한 후 때어내는 조작을 수행했다. 테이프에 도막이 전혀 부착하지 않는 경우를 ○, 바둑판목의 모퉁이가 근소하게 벗겨지는 경우를 △, 바둑판목이 1개라도 부착되어 박리한 경우에는 ×로 하여 각 시험편에 대한 평가를 수행했다.The adhesion of the specimen was measured by dividing it into initial adhesion and adhesion after water resistance test. First, the initial adhesion was measured by cutting the specimen in the shape of a 10 × 10 checkerboard with a width of 1mm, attaching cellophane tape to the checkerboard, and then removing it. has performed Each test piece was evaluated as ○ when the coating film was not adhered to the tape, △ when the corner of the checker board was slightly peeled off, and × when even one checker board was attached and peeled off.
또한 내수시험 후 부착성은 시편을 40℃의 온수에 480시간 침지한 후, 각각 도막에 1mm 폭으로 10×10의 바둑판목 모양으로 칼집을 내고 바둑판목의 부분에 테이프를 첩착한 후 때어내는 조작을 수행했다. 그리고 초기 부착성과 동일한 측정방법 및 기준에 의해 판정하였다.In addition, the adhesion after the water resistance test is immersed in 40 ℃ hot water for 480 hours, and then cut each coating in the shape of a 10 × 10 checkerboard with a width of 1mm. performed And it was judged by the same measurement method and criteria as initial adhesion.
(방청성)(rust resistance)
카스 시험기(이타바시 사토시 화공업사 제조, SQ－800－CA)를 이용하여 JIS H 8681－2를 기준으로 240시간의 조건으로 방청성 시험을 실시했다. 눈 관측으로 녹이 전혀 확인되지 않는 경우를 ○, 근소하게 확인된 경우를 △, 명확하게 확인된 경우를 ×로 평가하였다. Using a CAS tester (SQ-800-CA manufactured by Itabashi Satoshi Chemical Industry Co., Ltd.), a rust prevention test was conducted under conditions of 240 hours based on JIS H 8681-2. A case where rust was not observed at all by eye observation was evaluated as ○, a case slightly confirmed as △, and a case where rust was clearly confirmed as ×.
(연필경도)(pencil hardness)
ASTM D3502 측정법에 따라 연필경도시험기를 사용하여 750g 하중으로 연필경도를 측정하였다.Pencil hardness was measured with a 750 g load using a pencil hardness tester according to the ASTM D3502 measurement method.
(내스크래치성)(scratch resistance)
Steel Wool Tester 장비를 이용하여 1 kg 하중으로 Steel Wool Grade #00를 사용하여 시편의 표면을 20회 왕복한 후 이물질을 제거한 후 표면의 광택도를 측정하였다. 이때 동일한 시편을 3회 평가하였고 평가 전후로 하여 4 포인트를 측정하여 평균 값을 도출한 뒤 광택도 감소율을 CEN/TS 1661 표준분석 방법에 따라 아래의 식 1과 같이 산출한 뒤 소수점은 반올림하여 정수로 표기하였다.Using the Steel Wool Tester equipment, the surface of the specimen was reciprocated 20 times using Steel Wool Grade #00 with a load of 1 kg, and then the glossiness of the surface was measured after removing foreign substances. At this time, the same specimen was evaluated three times, and 4 points were measured before and after the evaluation to derive an average value, and then the gloss reduction rate was calculated as in Equation 1 below according to the CEN / TS 1661 standard analysis method, and then the decimal point was rounded to an integer marked.
[식 1][Equation 1]
(상기 식 1에서 *R은 광택도 감소율, RI는 초기 광택도, RF는 내스크래치성 평가 후 광택도를 뜻한다.)(In Equation 1, *R is the gloss reduction rate, RI is the initial gloss, and RF is the gloss after scratch resistance evaluation.)
(실시예 1 내지 4 및 비교예 1, 2)(Examples 1 to 4 and Comparative Examples 1 and 2)
하기 표 1의 조성에 따라 각 성분을 혼합하여 액상의 하드코팅 조성물을 각각 제조하였다. 그리고 이 하드코팅 조성물을 경화 후 두께가 30㎛가 되도록 알루미늄 기재의 표면에 분무기로 스프레이 도장하였다. 그리고 이를 80℃에서 3시간 동안 건조하여 용매를 증발시켜 시험편을 완성하였다. 얻어진 시편의 물성을 측정하여 하기 표 2에 기재하였다.According to the composition of Table 1 below, each component was mixed to prepare a liquid hard coating composition. Then, the hard coating composition was spray-coated with a sprayer on the surface of the aluminum substrate to a thickness of 30 μm after curing. And it was dried at 80 ℃ for 3 hours to evaporate the solvent to complete the test piece. The physical properties of the obtained specimens were measured and listed in Table 2 below.
[표 1][Table 1]
(상기 표 1에서 각 성분은 아크릴 폴리올 100 중량부 대비 첨가량(중량부)이다)(In Table 1, each component is added amount (parts by weight) relative to 100 parts by weight of acrylic polyol)
[표 2][Table 2]
상기 표 2와 같이 본 발명에 따라 제조된 고경도 내후성 하드코팅 조성물은 높은 표면 경도를 통해 내스크래치성이 우수하고, 방청성 및 부착성이 확보된 것을 확인할 수 있다. 구체적으로 충전재로 폴리실세스퀴옥산을 사용한 실시예 2는 실시예 1에 비해 부착성과 표면경도가 향상된 것을 확인할 수 있으며, 여기에 유무기 하이브리드 입자와 유기 이소시아네이트를 더 첨가한 실시예 3, 4는 가장 우수한 물성을 보임을 확인할 수 있다.As shown in Table 2, it can be confirmed that the high-hardness, weather-resistant hard coating composition prepared according to the present invention has excellent scratch resistance through high surface hardness, and secures rust prevention and adhesion. Specifically, Example 2 using polysilsesquioxane as a filler can confirm that adhesion and surface hardness are improved compared to Example 1, and Examples 3 and 4 in which organic-inorganic hybrid particles and organic isocyanate are further added are It can be confirmed that it shows the best physical properties.
이와는 대조적으로 실란화합물을 포함하지 않은 비교예 1은 부착성, 연필경도, 내스크래치성 등에서 가장 나쁜 물성을 보이고 있으며, 충전재를 포함하지 않은 비교예 2는 부착성 등은 향상되었으나 실시예 3 등에 크게 미치지 못함을 확인할 수 있다.In contrast, Comparative Example 1, which did not contain a silane compound, showed the worst physical properties in terms of adhesion, pencil hardness, and scratch resistance. I can confirm that it is not reaching.
한편, 본 발명의 상세한 설명에서는 참조되는 바람직한 실시 예를 중심으로 구체적으로 기술되었으나, 본 발명의 범위에서 벗어나지 않는 한도 내에서 여러 가지 변형이 가능함은 물론이다. 그러므로 본 발명의 범위는 설명된 실시 예에 국한되어 정해져서는 안되며, 후술하는 특허청구의 범위뿐 아니라 이 특허청구의 범위와 균등한 것들에 의해서 정해져야 한다.Meanwhile, although the detailed description of the present invention has been specifically described with reference to preferred embodiments, various modifications are possible without departing from the scope of the present invention. Therefore, the scope of the present invention should not be limited to the described embodiments and should not be defined, and should be defined by not only the scope of the claims to be described later, but also those equivalent to the scope of these claims.
Claims (7)
A high hardness weather resistant hard coating composition comprising an acrylic polyol resin, a silane compound, a filler and an organic solvent.
상기 아크릴 폴리올 수지는 메틸(메타)아크릴레이트, 에틸(메타)아크릴레이트, 이소부틸(메타)아크릴레이트, 노말부틸(메타)아크릴레이트, 터셔리부틸(메타)아크릴레이트, 노말헥실메타크릴에이트, 2-에틸헥실(메타)아크릴레이트, 이소노닐(메타)아크릴레이트, 시클로헥실(메타)아크릴레이트, 프로필(메타)아크릴레이트, 노말옥틸(메타)아크릴레이트, 노닐(메타)아크릴레이트, 데실(메타)아크릴레이트 및 도데실(메타)아크릴레이트에서 선택되는 어느 하나 또는 복수의 비닐기 함유 단량체를 포함하는 것을 특징으로 하는 고경도 내후성 하드코팅 조성물.
According to claim 1,
The acrylic polyol resin is methyl (meth) acrylate, ethyl (meth) acrylate, isobutyl (meth) acrylate, normal butyl (meth) acrylate, tertiary butyl (meth) acrylate, normal hexyl methacrylate, 2-ethylhexyl (meth) acrylate, isononyl (meth) acrylate, cyclohexyl (meth) acrylate, propyl (meth) acrylate, normaloctyl (meth) acrylate, nonyl (meth) acrylate, decyl ( A high-hardness, weather-resistant hard coating composition comprising any one or a plurality of vinyl group-containing monomers selected from meth)acrylate and dodecyl (meth)acrylate.
상기 실란 화합물은 비닐메톡시 실란, 비닐트리메톡시 실란, 비닐트리에폭시 실란, 3-아미노프로필트리에폭시 실란, 3-글리시독시프로필트리메톡시 실란, 3-메타글리옥시프로필트리메톡시 실란, 3-메르캅토프로필트리메톡시 실란, N-(b-아미노에틸)-g-아미노프로필트리메톡시실란, g-글리시독시프로필트리에톡시실란, g-글리시독시트리메틸디메톡시실란, 2-(3,4-에폭시시클로헥실)에틸트리메톡시실란, g-메타크릴옥시프로필트리메톡시실란, g-메타크릴옥시프로필트리에톡시실란, g-메르캅토프로필트리메톡시실란 및 g-메르캅토프로필트리에톡시실란에서 선택되는 어느 하나 또는 복수를 포함하는 것을 특징으로 하는 고경도 내후성 하드코팅 조성물.
According to claim 1,
The silane compound is vinylmethoxy silane, vinyltrimethoxy silane, vinyltriepoxy silane, 3-aminopropyltriepoxy silane, 3-glycidoxypropyltrimethoxy silane, 3-metaglycoxypropyltrimethoxy silane, 3-Mercaptopropyltrimethoxysilane, N-(b-aminoethyl)-g-aminopropyltrimethoxysilane, g-glycidoxypropyltriethoxysilane, g-glycidoxytrimethyldimethoxysilane, 2 -(3,4-epoxycyclohexyl)ethyltrimethoxysilane, g-methacryloxypropyltrimethoxysilane, g-methacryloxypropyltriethoxysilane, g-mercaptopropyltrimethoxysilane and g- High hardness weather resistance hard coating composition comprising any one or a plurality selected from mercaptopropyltriethoxysilane.
상기 충전재는 산화리튬, 산화나트륨, 산화칼륨, 산화바륨, 산화칼슘, 산화마그네슘, 탄산칼슘, 탄산나트륨, 불화칼슘, 불화리튬, 불화마그네슘, 브롬화마그네슘, 브롬화바륨 및 요오드화칼륨에서 선택되는 어느 하나 또는 복수를 포함하는 것을 특징으로 하는 고경도 내후성 하드코팅 조성물.
According to claim 1,
The filler is any one or more selected from lithium oxide, sodium oxide, potassium oxide, barium oxide, calcium oxide, magnesium oxide, calcium carbonate, sodium carbonate, calcium fluoride, lithium fluoride, magnesium fluoride, magnesium bromide, barium bromide and potassium iodide. High hardness weather resistance hard coating composition comprising a.
상기 고경도 내후성 하드코팅 조성물은 아크릴 폴리올 수지 100 중량부에 대하여 실란 화합물 10 내지 50 중량부 충전재 1 내지 10 중량부 및 유기용제 10 내지 500 중량부를 포함하는 것을 특징으로 하는 고경도 내후성 하드코팅 조성물.
According to claim 1,
The high-hardness weather-resistant hard coating composition comprises 10 to 50 parts by weight of a silane compound, 1 to 10 parts by weight of a filler, and 10 to 500 parts by weight of an organic solvent based on 100 parts by weight of an acrylic polyol resin.
상기 고경도 내후성 하드코팅 조성물은 디페닐메탄디이소시아네이트, 1.6-헥사메틸렌디이소시아네이트. 1.6-헥사메틸렌디이소시아네이트의 중합체, 2.4-트릴렌디이소시아네이트화 브렌츠카테킨의 부가물, 트릴렌디이소시아네이트, 1-클로로페닐디이소시아네이트, 1.5-나프틸렌디이소시아네이트, 티오디프로필디이소시아네이트, 에틸벤젠-α-2-디이소시아네이트, 2.4-트릴렌디이소시아네이트 이량체 및 4,4',4"-트리페닐메탄트리이소시아네이트에서 선택되는 어느 하나 또는 복수의 유기폴리이소시아네이트를 더 포함하는 것을 특징으로 하는 고경도 내후성 하드코팅 조성물.
According to claim 1,
The high hardness weather resistant hard coating composition is diphenylmethane diisocyanate, 1.6-hexamethylene diisocyanate. Polymer of 1.6-hexamethylene diisocyanate, adduct of 2.4-trylene diisocyanate brentscatechin, torylene diisocyanate, 1-chlorophenyl diisocyanate, 1.5-naphthylene diisocyanate, thiodipropyl diisocyanate, ethylbenzene-α -High hardness weather resistance hard characterized by further comprising any one or a plurality of organic polyisocyanates selected from 2-diisocyanate, 2.4-tylene diisocyanate dimer and 4,4',4"-triphenylmethane triisocyanate coating composition.
상기 고경도 내후성 하드코팅 조성물은 안료, 침강방지제, 왁스, 산도조절제, 방청제, 수분산 수지, 소포제 및 레벨링제에서 선택되는 어느 하나 또는 복수의 첨가제를 더 포함하는 것을 특징으로 하는 고경도 내후성 하드코팅 조성물.According to claim 1,
The high-hardness weather-resistant hard coating composition further comprises any one or a plurality of additives selected from pigments, anti-settling agents, waxes, acidity regulators, rust preventives, water-dispersible resins, antifoaming agents, and leveling agents. composition.
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