KR20230108116A - Functionally reinforced Artificial Turf - Google Patents
Functionally reinforced Artificial Turf Download PDFInfo
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- KR20230108116A KR20230108116A KR1020220003509A KR20220003509A KR20230108116A KR 20230108116 A KR20230108116 A KR 20230108116A KR 1020220003509 A KR1020220003509 A KR 1020220003509A KR 20220003509 A KR20220003509 A KR 20220003509A KR 20230108116 A KR20230108116 A KR 20230108116A
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- artificial turf
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- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 21
- 239000011707 mineral Substances 0.000 claims abstract description 21
- 239000011159 matrix material Substances 0.000 claims abstract description 15
- 229920000642 polymer Polymers 0.000 claims abstract description 15
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 14
- 229910010293 ceramic material Inorganic materials 0.000 claims abstract description 10
- 239000000654 additive Substances 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims description 23
- 239000000126 substance Substances 0.000 claims description 13
- 239000002028 Biomass Substances 0.000 claims description 12
- 239000004698 Polyethylene Substances 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 229920000573 polyethylene Polymers 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- 229920000098 polyolefin Polymers 0.000 claims description 7
- 229920006124 polyolefin elastomer Polymers 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 claims description 6
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000395 magnesium oxide Substances 0.000 claims description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 6
- -1 polyethylene Polymers 0.000 claims description 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 6
- 229910001583 allophane Inorganic materials 0.000 claims description 5
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 5
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 5
- 229910001562 pearlite Inorganic materials 0.000 claims description 5
- 239000005995 Aluminium silicate Substances 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 4
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 3
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 3
- WQNHWIYLCRZRLR-UHFFFAOYSA-N 2-(3-hydroxy-2,5-dioxooxolan-3-yl)acetic acid Chemical compound OC(=O)CC1(O)CC(=O)OC1=O WQNHWIYLCRZRLR-UHFFFAOYSA-N 0.000 claims description 3
- HZLCGUXUOFWCCN-UHFFFAOYSA-N 2-hydroxynonadecane-1,2,3-tricarboxylic acid Chemical compound CCCCCCCCCCCCCCCCC(C(O)=O)C(O)(C(O)=O)CC(O)=O HZLCGUXUOFWCCN-UHFFFAOYSA-N 0.000 claims description 3
- AGULWIQIYWWFBJ-UHFFFAOYSA-N 3,4-dichlorofuran-2,5-dione Chemical compound ClC1=C(Cl)C(=O)OC1=O AGULWIQIYWWFBJ-UHFFFAOYSA-N 0.000 claims description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 3
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 3
- BGRDGMRNKXEXQD-UHFFFAOYSA-N Maleic hydrazide Chemical compound OC1=CC=C(O)N=N1 BGRDGMRNKXEXQD-UHFFFAOYSA-N 0.000 claims description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 3
- 229910006404 SnO 2 Inorganic materials 0.000 claims description 3
- 229940040563 agaric acid Drugs 0.000 claims description 3
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 3
- 239000001099 ammonium carbonate Substances 0.000 claims description 3
- 235000012501 ammonium carbonate Nutrition 0.000 claims description 3
- AQCDIIAORKRFCD-UHFFFAOYSA-N cadmium selenide Chemical compound [Cd]=[Se] AQCDIIAORKRFCD-UHFFFAOYSA-N 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 claims description 3
- 239000001530 fumaric acid Substances 0.000 claims description 3
- HZXMRANICFIONG-UHFFFAOYSA-N gallium phosphide Chemical compound [Ga]#P HZXMRANICFIONG-UHFFFAOYSA-N 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 3
- 239000001095 magnesium carbonate Substances 0.000 claims description 3
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
- 239000011976 maleic acid Substances 0.000 claims description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 3
- 239000001630 malic acid Substances 0.000 claims description 3
- 235000011090 malic acid Nutrition 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 3
- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 claims description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 3
- 229910001887 tin oxide Inorganic materials 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 3
- 244000025254 Cannabis sativa Species 0.000 claims 1
- 229910000514 dolomite Inorganic materials 0.000 claims 1
- 239000010459 dolomite Substances 0.000 claims 1
- 239000000428 dust Substances 0.000 abstract description 12
- 230000001603 reducing effect Effects 0.000 abstract description 6
- 230000000996 additive effect Effects 0.000 abstract description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 12
- 230000035699 permeability Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 4
- 239000012855 volatile organic compound Substances 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 2
- HHSPVTKDOHQBKF-UHFFFAOYSA-J calcium;magnesium;dicarbonate Chemical compound [Mg+2].[Ca+2].[O-]C([O-])=O.[O-]C([O-])=O HHSPVTKDOHQBKF-UHFFFAOYSA-J 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 229910052622 kaolinite Inorganic materials 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 229940099514 low-density polyethylene Drugs 0.000 description 2
- 229920001179 medium density polyethylene Polymers 0.000 description 2
- 239000004701 medium-density polyethylene Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000005349 anion exchange Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229910052729 chemical element Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000010353 genetic engineering Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 231100000075 skin burn Toxicity 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C13/00—Pavings or foundations specially adapted for playgrounds or sports grounds; Drainage, irrigation or heating of sports grounds
- E01C13/08—Surfaces simulating grass ; Grass-grown sports grounds
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/75—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
- G01N21/77—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
- G01N21/78—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator producing a change of colour
- G01N21/81—Indicating humidity
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Structural Engineering (AREA)
- Civil Engineering (AREA)
- Plasma & Fusion (AREA)
- Life Sciences & Earth Sciences (AREA)
- Architecture (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Road Paving Structures (AREA)
Abstract
Description
본 발명은 기능성 인조잔디에 관한 것으로서, 고분자 매트릭스, 미네랄 마스터배치, 세라믹 소재를 포함하여 난연성, 습윤조절 및 통기성을 향상시키고 공기 중의 유해물질은 포름알데히드와 휘말성 유기화합물을 흡착 및 분해하여 미세먼지를 저감시키는 기능성 인조잔디에 관한 것이다.The present invention relates to a functional artificial turf, which includes a polymer matrix, a mineral masterbatch, and a ceramic material to improve flame retardancy, moisture control, and breathability, and harmful substances in the air adsorb and decompose formaldehyde and volatile organic compounds to reduce fine dust. It relates to a functional artificial turf that reduces
일반적으로 인조잔디는 천연잔디에 비해 생육이나 환경 등의 조건이 까다롭지 않으면서 시공 후 유지관리가 상대적으로 용이하고 날씨 및 계절에 상관없이 이용할 수 있으므로 주로 운동장이나 각종 경기장 등의 조성에 사용되고 있다.In general, artificial turf is relatively easy to maintain after construction and can be used regardless of weather and season without demanding conditions such as growth or environment compared to natural turf, so it is mainly used for the construction of playgrounds or various stadiums.
이러한 장점이 있기에 사용과 관리의 편리성과 시공의 다양성 등으로 인조잔디는 점차 사용영역을 늘려가고 있으며 종류도 점차 다양해지고 있다.Because of these advantages, the use area of artificial turf is gradually increasing due to the convenience of use and management and the diversity of construction, and the types are gradually diversifying.
일반적으로 인조잔디는 합성수지를 기포지에 파일사 형태로 심어 제작하는 것으로, 소재의 특성 상 피부 화상을 입을 확률이 높으며, 태양열의 축적이 용이하여 하절기에는 사용이 어려울 정도로 온도가 높아져 부상의 위험이 더욱 높아지는 문제점이 있다.In general, artificial turf is manufactured by planting synthetic resin in the form of pile yarn on foam paper. Due to the nature of the material, there is a high probability of skin burns, and because it is easy to accumulate solar heat, the temperature rises to the point where it is difficult to use it in the summer season, increasing the risk of injury. There is a growing problem.
또한 종래의 인조잔디는 원사 제조과정에서 이산화탄소를 배출하는 문제가 있고, 사용과정에서 유해물질이 배출되기도 하며, 난연 성능의 구현이 어려워 난연성, 내구성 및 내후성이 떨어지는 문제점이 있다.In addition, the conventional artificial turf has problems in that carbon dioxide is emitted during the yarn manufacturing process, harmful substances are emitted during the process of use, and flame retardancy, durability and weatherability are poor due to difficulty in implementing flame retardant performance.
최근에는 미세먼지나 온도차이로 인해 실내스포츠 시설들이 늘어남에 따라 실내에서의 인조잔디의 수요가 더욱 확대되면서, 통기성 향상과 미세먼지 저감, 유해물질 배출의 저감을 위한 소재에 대한 연구가 더욱 필요한 실정이다.Recently, as the number of indoor sports facilities increases due to fine dust or temperature differences, the demand for indoor artificial turf is further expanding, and more research is needed on materials for improving air permeability, reducing fine dust, and reducing harmful substance emissions. am.
본 발명은 고분자 매트릭스, 미네랄 마스터배치, 세라믹 소재를 포함하여 난연성, 습윤조절 및 통기성을 향상시키고 공기 중의 유해물질은 포름알데히드와 휘말성 유기화합물을 흡착 및 분해하여 미세먼지를 저감시키는 기능성 인조잔디의 제공을 그 목적으로 한다.The present invention includes a polymer matrix, a mineral masterbatch, and a ceramic material to improve flame retardancy, moisture control, and air permeability, and harmful substances in the air adsorb and decompose formaldehyde and volatile organic compounds to reduce fine dust. provided for that purpose.
상기 목적을 달성하기 위한 본 발명은, 고분자 매트릭스 85~95 중량부, 미네랄 마스터배치 0.1~5 중량부, 세라믹 소재 0.01~3 중량부, 상용화제 0.1~5 중량부 및 첨가제 3~5 중량부를 포함하는 기능성 인조잔디를 기술적 요지로 한다.The present invention for achieving the above object includes 85 to 95 parts by weight of a polymer matrix, 0.1 to 5 parts by weight of a mineral masterbatch, 0.01 to 3 parts by weight of a ceramic material, 0.1 to 5 parts by weight of a compatibilizer, and 3 to 5 parts by weight of an additive. functional artificial turf as the technical point.
또한, 상기 고분자 매트릭스는, 폴리에틸렌(Polyethylene, PE), 폴리올레핀(Polyolefin, PO) 및 POE(Polyolefin Elastomer) 중 어느 하나 이상을 포함하는 것이 바람직하다.In addition, the polymer matrix preferably includes at least one of polyethylene (PE), polyolefin (PO), and polyolefin elastomer (POE).
또한, 상기 고분자 매트릭스는, 바이오매스(Biomass)를 포함하는 것이 바람직하다.In addition, the polymer matrix preferably includes biomass.
또한, 상기 미네랄 마스터배치는, 펄라이트(Pearlite) 파우더, 알로펜(Allophane) 파우더, 고령토 파우더, 겔라이트 파우더, 미네랄 파우더 중 어느 하나 이상을 포함하는 것이 바람직하다.In addition, the mineral masterbatch preferably includes at least one of pearlite powder, allophane powder, kaolin powder, gelite powder, and mineral powder.
또한, 상기 미네랄 파우더는, 탄산마그네슘(Mg2(OH)2CO3), 산화알루미늄(Al2O3), 황화구리(CuS), 탄산암모늄((NH4)2CO3), 카드뮴셀레나이드(CdSe), 산화세륨(CeO), 질산암모늄(H4N2O3), 탄화규소(SiC), 인화갈륨(GaP), 티탄산스트론튬(SrTiO3), 산화주석(SnO2), 탄산칼슘(CaCO3), 돌로마이트(CaMg(CO3)2) 및 산화마그네슘(MgO) 중 어느 하나 이상을 포함하는 것이 바람직하다.In addition, the mineral powder may include magnesium carbonate (Mg 2 (OH) 2 CO 3 ), aluminum oxide (Al 2 O 3 ), copper sulfide (CuS), ammonium carbonate ((NH 4 ) 2 CO 3 ), cadmium selenide (CdSe), cerium oxide (CeO), ammonium nitrate (H 4 N 2 O 3 ), silicon carbide (SiC), gallium phosphide (GaP), strontium titanate (SrTiO 3 ), tin oxide (SnO 2 ), calcium carbonate ( It is preferable to include at least one of CaCO 3 ), dolomite (CaMg(CO 3 ) 2 ) and magnesium oxide (MgO).
또한, 상기 세라믹 소재는, 이산화티타늄, 산화 지르코늄, 산화 아연, 산화철 및 산화망간 중 어느 하나 이상을 포함하는 것이 바람직하다.In addition, the ceramic material preferably includes at least one of titanium dioxide, zirconium oxide, zinc oxide, iron oxide, and manganese oxide.
또한, 상기 상용화제는, 말레산, 말레산 무수물, 말레산 하이드라지드, 디클로로 말레산 무수물, 불포화된 디카르복실산, 푸마르산, 시트르산, 시트르산 무수물, 말산 및 아가리신산으로 이루어진 군에서 선택되는 하나 이상인 것이 바람직하다.In addition, the compatibilizing agent is one selected from the group consisting of maleic acid, maleic anhydride, maleic acid hydrazide, dichloro maleic anhydride, unsaturated dicarboxylic acid, fumaric acid, citric acid, citric acid anhydride, malic acid and agaric acid. It is preferable to be more than
또한, 상기 기능성 인조잔디는, 수분 감지 및 유해물질 감지를 위한 센서가 더 포함되는 것이 바람직하다.In addition, the functional artificial turf preferably further includes a sensor for detecting moisture and harmful substances.
본 발명은 고분자 매트릭스, 미네랄 마스터배치, 세라믹 소재 등을 포함하는 기능성 인조잔디에 관한 것으로서, 난연성, 습윤조절 및 통기성을 향상시키고 미세먼지 저감이 가능한 인조잔디 원사를 제공할 수 있는 효과가 있다.The present invention relates to a functional artificial turf comprising a polymer matrix, a mineral masterbatch, a ceramic material, and the like, and has an effect of providing artificial turf yarns capable of improving flame retardancy, moisture control and air permeability and reducing fine dust.
또한, 바이오매스가 포함되어 친환경 소재를 제공하여 탄소를 저감하고, 유해물질의 배출을 억제하면서 미세먼지를 저감하는 기능을 하게 된다In addition, biomass is included to provide eco-friendly materials to reduce carbon and reduce fine dust while suppressing the emission of harmful substances.
또한, 수분 감지 및 유해물질 감지를 위한 센서를 더 포함하여 습윤 조절 및 통기성 조절 및 미세먼지 감지 등 다양한 기능이 발현되도록 하여, 사용자가 쾌적한 환경에서 운동을 즐길 수 있도록 한다.In addition, sensors for detecting moisture and harmful substances are further included so that various functions such as moisture control, air permeability control, and fine dust detection are expressed, so that users can enjoy exercise in a comfortable environment.
본 발명은 기능성 인조잔디에 관한 것으로서, 기능성 인조잔디 전체 조성물 중량부에 대해 고분자 매트릭스 85~95 중량부, 미네랄 마스터배치 0.1~5 중량부, 세라믹 소재 0.01~3 중량부, 상용화제 0.1~5 중량부 및 첨가제 3~5 중량부를 포함하여 난연성, 습윤조절 및 통기성을 향상시키고 공기 중의 유해물질은 포름알데히드와 휘말성 유기화합물을 흡착 및 분해하여 미세먼지를 저감시키는 기능성 인조잔디에 관한 것이다.The present invention relates to a functional artificial turf, and includes 85 to 95 parts by weight of a polymer matrix, 0.1 to 5 parts by weight of a mineral masterbatch, 0.01 to 3 parts by weight of a ceramic material, and 0.1 to 5 parts by weight of a compatibilizer, based on parts by weight of the total composition of the functional artificial turf. It relates to a functional artificial turf that includes 3 to 5 parts by weight of parts and additives to improve flame retardancy, moisture control and air permeability, and to reduce fine dust by adsorbing and decomposing formaldehyde and volatile organic compounds from harmful substances in the air.
상기 고분자 매트릭스는 폴리에틸렌(Polyethylene, PE), 폴리올레핀(Polyolefin, PO) 및 폴리올레핀 엘라스토머(Polyolefin Elastomer, POE) 중 어느 하나 이상을 포함한다.The polymer matrix includes at least one of polyethylene (PE), polyolefin (PO), and polyolefin elastomer (POE).
여기서 폴리에틸렌은 선형 저밀도 폴리에틸렌(linear lowdensity polyethylene, LLDPE), 저밀도 폴리에틸렌(Low Density Polyethylene, LDPE) 및 고밀도 폴리에틸렌(High Density Polyethylene, HDPE) 중 어느 하나 이상을 선택하여 적정량 혼합하여 사용할 수 있다. 단, 고분자 매트릭스는 상술한 단일 고분자 수지를 사용하는 것만으로도 충분하나 경우에 따라 2종 이상을 혼합하여 사용할 수도 있다.Here, polyethylene may be selected from among linear lowdensity polyethylene (LLDPE), low density polyethylene (LDPE), and high density polyethylene (HDPE) and mixed in an appropriate amount. However, as the polymer matrix, it is sufficient to use only the above-mentioned single polymer resin, but in some cases, two or more kinds may be mixed and used.
또한, 상기 고분자 매트릭스는, 바이오매스(Biomass)를 포함할 수 있다.In addition, the polymer matrix may include biomass.
즉, 바이오매스 복합체가 10 ~ 30중량부 포함된 바이오매스 폴리에틸렌, 바이오매스 폴리올레핀, 바이어매스 폴리올레핀 엘라스토머이며, 일실시예로 상기 바이오매스 폴리에틸렌은 선형 저밀도 폴리에틸렌(LLDPE)과 중밀도 폴리에틸렌(MDPE)을 3.5 : 1의 중량부로 사용할 수 있다.That is, biomass polyethylene, biomass polyolefin, and biomass polyolefin elastomer containing 10 to 30 parts by weight of the biomass composite, and in one embodiment, the biomass polyethylene is linear low density polyethylene (LLDPE) and medium density polyethylene (MDPE). It can be used in parts by weight of 3.5:1.
이에 의해 인조잔디에 친환경 소재인 바이오매스가 포함되어 인조잔디에서의 유해물질의 배출을 최소화하게 된다.Accordingly, biomass, which is an eco-friendly material, is included in the artificial turf, thereby minimizing the emission of harmful substances from the artificial turf.
그리고, 상기 미네랄 마스터배치는, 펄라이트(Pearlite) 파우더, 알로펜(Allophane) 파우더, 고령토 파우더, 겔라이트 파우더, 미네랄 파우더 중 어느 하나 이상을 포함하는 것이다.The mineral masterbatch includes at least one of pearlite powder, allophane powder, kaolin powder, gelite powder, and mineral powder.
여기에서, 상기 펄라이트 파우더는 100~2000mesh 크기로, 전체 미네랄 마스터배치 100중량부에 대해 70~90중량부, 상기 알로페인 파우더는 100~2000mesh 크기 로, 전체 미네랄 마스터배치 100중량부에 대해 3-10중량부, 상기 고령토 파우더는 100~2000mesh 크기로, 전체 미네랄 마스터배치 100중량부에 대해 2~10중량부, 상기 겔라이트 파우더는 100~2000mesh 크기로, 전체 미네랄 마스터배치 100중량부에 대해 2~10중량부를 사용한다.Here, the pearlite powder has a size of 100 to 2000 mesh, 70 to 90 parts by weight based on 100 parts by weight of the total mineral masterbatch, and the allophane powder has a size of 100 to 2000 mesh, based on 100 parts by weight of the total mineral masterbatch 3- 10 parts by weight, the kaolin powder has a size of 100 to 2000 mesh, 2 to 10 parts by weight based on 100 parts by weight of the total mineral masterbatch, and the gelite powder has a size of 100 to 2000 mesh, 2 parts by weight based on 100 parts by weight of the total mineral master batch Use ~10 parts by weight.
상기 펄라이트는 보온기능과 배수기능(통기성)이 탁월하며, 난연성을 향상시키고, 상기 알로페인은 음이온 교환능력을 가지고 있어 질소, 인 등의 제거 능력이 우수하여 미세먼지 저감기능에 기여하게 되며, 습윤 조절 기능이 부여하게 된다.The pearlite has excellent warming and drainage functions (breathability) and improves flame retardancy, and the allophane has an anion exchange ability and is excellent in removing nitrogen, phosphorus, etc., contributing to the fine dust reduction function, and wet control function is provided.
또한, 상기 고령토(카올리나이트, Kaolinite)는 높은 비표면적으로 습윤 조절 기능이 부여될 수 있으며, 상기 겔라이트는 원적외선, 음이온 방출 및 탈취기능을 부여될 수 있다. In addition, the kaolinite (kaolinite) can be given a wet control function with a high specific surface, and the gelite can be given a far-infrared ray, anion emission and deodorization function.
여기서, 상기 미네랄 파우더는, 탄산마그네슘(Mg2(OH)2CO3), 산화알루미늄(Al2O3), 황화구리(CuS), 탄산암모늄((NH4)2CO3), 카드뮴셀레나이드(CdSe), 산화세륨(CeO), 질산암모늄(H4N2O3), 탄화규소(SiC), 인화갈륨(GaP), 티탄산스트론튬(SrTiO3), 산화주석(SnO2), 탄산칼슘(CaCO3), 돌로마이트(CaMg(CO3)2) 및 산화마그네슘(MgO) 중 어느 하나 이상을 포함하는 것이다.Here, the mineral powder is magnesium carbonate (Mg 2 (OH) 2 CO 3 ), aluminum oxide (Al 2 O 3 ), copper sulfide (CuS), ammonium carbonate ((NH 4 ) 2 CO 3 ), cadmium selenide (CdSe), cerium oxide (CeO), ammonium nitrate (H 4 N 2 O 3 ), silicon carbide (SiC), gallium phosphide (GaP), strontium titanate (SrTiO 3 ), tin oxide (SnO 2 ), calcium carbonate ( It includes at least one of CaCO 3 ), dolomite (CaMg(CO 3 ) 2 ) and magnesium oxide (MgO).
상기 미네랄 파우더에 의해 온도 저감 효과, 친환경 효과가 있다.The mineral powder has a temperature reducing effect and an eco-friendly effect.
그리고, 상기 세라믹 소재는, 이산화티타늄, 산화 지르코늄, 산화 아연, 산화철 및 산화망간 중 어느 하나 이상을 포함하는 것으로서, 공기 중의 유해물질은 포름알데히드와 휘발성 유기화합물을 흡착 및 분해하여 미세먼지를 저감시키는 기능을 하게 된다.In addition, the ceramic material includes at least one of titanium dioxide, zirconium oxide, zinc oxide, iron oxide, and manganese oxide, and harmful substances in the air adsorb and decompose formaldehyde and volatile organic compounds to reduce fine dust. will function
그리고 상기 상용화제는, 말레산, 말레산 무수물, 말레산 하이드라지드, 디클로로 말레산 무수물, 불포화된 디카르복실산, 푸마르산, 시트르산, 시트르산 무수물, 말산 및 아가리신산으로 이루어진 군에서 선택되는 하나 이상인 것을 포함한다.And the compatibilizing agent is at least one selected from the group consisting of maleic acid, maleic anhydride, maleic acid hydrazide, dichloro maleic anhydride, unsaturated dicarboxylic acid, fumaric acid, citric acid, citric anhydride, malic acid and agaric acid. include that
상기 첨가제로는 첨가제 100중량부에 대해 난연제 1~5중량부, UV 안정제 0.01~3중량부인 것이 바람직하다.As the additive, it is preferable that the flame retardant is 1 to 5 parts by weight and the UV stabilizer is 0.01 to 3 parts by weight based on 100 parts by weight of the additive.
또한 본 발명에 따른 상기 기능성 인조잔디는, 수분 감지 및 유해물질 감지를 위한 센서가 더 포함되는 것이 바람직하다.In addition, the functional artificial turf according to the present invention preferably further includes a sensor for detecting moisture and harmful substances.
상기 센서는 육안으로는 패턴이 보이지는 않지만 주변의 습도 변화에 따라 즉각적으로 색이 변하며 패턴이 드러나도록 설계한 것으로서, 색 시약 및 기능성 색 필터를 기반으로 화학 원소 또는 화합물을 색 변화를 통해 감지하도록 한다.The sensor is designed so that the pattern is not visible to the naked eye, but immediately changes color and reveals the pattern according to the change in ambient humidity, and detects a chemical element or compound through color change based on a color reagent and a functional color filter. do.
상기 센서는 유전자 조작을 통한 선택적 반응성을 조절하여 다양한 유해물질을 감지하도록 한다.The sensor controls selective reactivity through genetic manipulation to detect various harmful substances.
이와 같이 본 발명은 바이오매스를 포함하는 고분자 매트릭스, 광촉매, 펄라이트, 겔라이트 등을 사용하여 난연성, 습윤조절 및 통기성을 향상시키고 미세먼지 저감이 가능한 인조잔디 원사를 제공할 수 있도록 한다.As described above, the present invention provides an artificial turf yarn capable of improving flame retardancy, moisture control and air permeability and reducing fine dust by using a polymer matrix containing biomass, a photocatalyst, perlite, gelite, and the like.
Claims (8)
폴리에틸렌(Polyethylene, PE), 폴리올레핀(Polyolefin, PO) 및 POE(Polyolefin Elastomer) 중 어느 하나 이상을 포함하는 것을 특징으로 하는 기능성 인조잔디.The method of claim 1, wherein the polymer matrix,
A functional artificial turf comprising at least one of polyethylene (PE), polyolefin (PO), and polyolefin elastomer (POE).
바이오매스(Biomass)를 포함하는 것을 특징으로 하는 기능성 인조잔디.The method of claim 2, wherein the polymer matrix,
Functional artificial turf characterized in that it contains biomass (Biomass).
펄라이트(Pearlite) 파우더, 알로펜(Allophane) 파우더, 고령토 파우더, 겔라이트 파우더, 미네랄 파우더 중 어느 하나 이상을 포함하는 것을 특징으로 하는 기능성 인조잔디.The method of claim 1, wherein the mineral masterbatch,
A functional artificial turf comprising at least one of pearlite powder, allophane powder, kaolin powder, gelite powder, and mineral powder.
탄산마그네슘(Mg2(OH)2CO3), 산화알루미늄(Al2O3), 황화구리(CuS), 탄산암모늄((NH4)2CO3), 카드뮴셀레나이드(CdSe), 산화세륨(CeO), 질산암모늄(H4N2O3), 탄화규소(SiC), 인화갈륨(GaP), 티탄산스트론튬(SrTiO3), 산화주석(SnO2), 탄산칼슘(CaCO3), 돌로마이트(CaMg(CO3)2) 및 산화마그네슘(MgO) 중 어느 하나 이상을 포함하는 것을 특징으로 하는 기능성 인조잔디.The method of claim 4, wherein the mineral powder,
Magnesium carbonate (Mg 2 (OH) 2 CO 3 ), aluminum oxide (Al 2 O 3 ), copper sulfide (CuS), ammonium carbonate ((NH 4 ) 2 CO 3 ), cadmium selenide (CdSe), cerium oxide ( CeO), ammonium nitrate (H 4 N 2 O 3 ), silicon carbide (SiC), gallium phosphide (GaP), strontium titanate (SrTiO 3 ), tin oxide (SnO 2 ), calcium carbonate (CaCO 3 ), dolomite (CaMg) (CO 3 ) 2 ) and magnesium oxide (MgO) functional artificial turf characterized in that it comprises any one or more.
이산화티타늄, 산화 지르코늄, 산화 아연, 산화철 및 산화망간 중 어느 하나 이상을 포함하는 것을 특징으로 하는 기능성 인조잔디.The method of claim 1, wherein the ceramic material,
A functional artificial turf comprising at least one of titanium dioxide, zirconium oxide, zinc oxide, iron oxide and manganese oxide.
말레산, 말레산 무수물, 말레산 하이드라지드, 디클로로 말레산 무수물, 불포화된 디카르복실산, 푸마르산, 시트르산, 시트르산 무수물, 말산 및 아가리신산으로 이루어진 군에서 선택되는 하나 이상인 것을 특징으로 하는 기능성 인조잔디.The method of claim 1, wherein the compatibilizer,
Maleic acid, maleic anhydride, maleic acid hydrazide, dichloro maleic anhydride, unsaturated dicarboxylic acid, fumaric acid, citric acid, citric acid anhydride, malic acid and agaric acid, characterized in that at least one selected from the group consisting of functional synthetic grass.
수분 감지 및 유해물질 감지를 위한 센서가 더 포함되는 것을 특징으로 하는 기능성 인조잔디.The method of claim 1, wherein the functional artificial turf,
Functional artificial turf further comprising a sensor for detecting moisture and harmful substances.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR102222628B1 (en) | 2020-09-25 | 2021-03-04 | 주식회사 주목씨지알 | Impact-absorbing pad composition for artificial turf that is easy to reduce carbon and collect fine dust, and shock-absorbing pad made of the composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR102222628B1 (en) | 2020-09-25 | 2021-03-04 | 주식회사 주목씨지알 | Impact-absorbing pad composition for artificial turf that is easy to reduce carbon and collect fine dust, and shock-absorbing pad made of the composition |
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