KR20230086564A - Eco -friendly disinfection and deodorant - Google Patents
Eco -friendly disinfection and deodorant Download PDFInfo
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- KR20230086564A KR20230086564A KR1020220074690A KR20220074690A KR20230086564A KR 20230086564 A KR20230086564 A KR 20230086564A KR 1020220074690 A KR1020220074690 A KR 1020220074690A KR 20220074690 A KR20220074690 A KR 20220074690A KR 20230086564 A KR20230086564 A KR 20230086564A
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- silicate
- composition
- present
- deodorization
- disinfection
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- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 44
- 239000002781 deodorant agent Substances 0.000 title abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 69
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 62
- 238000004332 deodorization Methods 0.000 claims abstract description 41
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 40
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000011593 sulfur Substances 0.000 claims abstract description 32
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 230000002829 reductive effect Effects 0.000 claims abstract description 22
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 claims abstract description 18
- 229910000342 sodium bisulfate Inorganic materials 0.000 claims abstract description 18
- 239000003513 alkali Substances 0.000 claims abstract description 11
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 10
- 241000588724 Escherichia coli Species 0.000 claims description 8
- 241000191967 Staphylococcus aureus Species 0.000 claims description 8
- 241000589517 Pseudomonas aeruginosa Species 0.000 claims description 7
- 206010041925 Staphylococcal infections Diseases 0.000 claims description 6
- 208000015688 methicillin-resistant staphylococcus aureus infectious disease Diseases 0.000 claims description 6
- 239000004115 Sodium Silicate Substances 0.000 claims description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 3
- 239000000378 calcium silicate Substances 0.000 claims description 2
- 229910052918 calcium silicate Inorganic materials 0.000 claims description 2
- 235000012241 calcium silicate Nutrition 0.000 claims description 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims description 2
- 239000012153 distilled water Substances 0.000 claims description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000391 magnesium silicate Substances 0.000 claims description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 claims description 2
- 235000019792 magnesium silicate Nutrition 0.000 claims description 2
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 2
- 235000019794 sodium silicate Nutrition 0.000 claims description 2
- 230000001877 deodorizing effect Effects 0.000 abstract description 11
- 230000001954 sterilising effect Effects 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- 150000001875 compounds Chemical class 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000001988 toxicity Effects 0.000 abstract 1
- 231100000419 toxicity Toxicity 0.000 abstract 1
- 238000000034 method Methods 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 16
- 239000000645 desinfectant Substances 0.000 description 13
- 235000019645 odor Nutrition 0.000 description 13
- 239000000126 substance Substances 0.000 description 11
- 238000003756 stirring Methods 0.000 description 10
- 238000012360 testing method Methods 0.000 description 9
- 244000005700 microbiome Species 0.000 description 7
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 5
- 208000015181 infectious disease Diseases 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 4
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- JXHZRQHZVYDRGX-UHFFFAOYSA-M sodium;hydrogen sulfate;hydrate Chemical compound [OH-].[Na+].OS(O)(=O)=O JXHZRQHZVYDRGX-UHFFFAOYSA-M 0.000 description 4
- 230000009471 action Effects 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- -1 stains Substances 0.000 description 3
- KEZYHIPQRGTUDU-UHFFFAOYSA-N 2-[dithiocarboxy(methyl)amino]acetic acid Chemical compound SC(=S)N(C)CC(O)=O KEZYHIPQRGTUDU-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 208000035473 Communicable disease Diseases 0.000 description 2
- 241000711573 Coronaviridae Species 0.000 description 2
- 241000588747 Klebsiella pneumoniae Species 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 206010035664 Pneumonia Diseases 0.000 description 2
- 241000201788 Staphylococcus aureus subsp. aureus Species 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
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- 230000007613 environmental effect Effects 0.000 description 2
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- 239000007788 liquid Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- FZIPCQLKPTZZIM-UHFFFAOYSA-N 2-oxidanylpropane-1,2,3-tricarboxylic acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O.OC(=O)CC(O)(C(O)=O)CC(O)=O FZIPCQLKPTZZIM-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 208000025721 COVID-19 Diseases 0.000 description 1
- 208000017667 Chronic Disease Diseases 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 206010012735 Diarrhoea Diseases 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241001313207 Gonepteryx rhamni Species 0.000 description 1
- 241000282412 Homo Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 206010020601 Hyperchlorhydria Diseases 0.000 description 1
- 206010061598 Immunodeficiency Diseases 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 208000025370 Middle East respiratory syndrome Diseases 0.000 description 1
- 208000035415 Reinfection Diseases 0.000 description 1
- MXKIASVYJZPUMJ-UHFFFAOYSA-N S.SC Chemical compound S.SC MXKIASVYJZPUMJ-UHFFFAOYSA-N 0.000 description 1
- 201000003176 Severe Acute Respiratory Syndrome Diseases 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000000427 antigen Substances 0.000 description 1
- 102000036639 antigens Human genes 0.000 description 1
- 108091007433 antigens Proteins 0.000 description 1
- 239000002246 antineoplastic agent Substances 0.000 description 1
- 229940041181 antineoplastic drug Drugs 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 241001493065 dsRNA viruses Species 0.000 description 1
- 201000006549 dyspepsia Diseases 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 229960003444 immunosuppressant agent Drugs 0.000 description 1
- 239000003018 immunosuppressive agent Substances 0.000 description 1
- 230000000415 inactivating effect Effects 0.000 description 1
- 206010022000 influenza Diseases 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
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- 239000002994 raw material Substances 0.000 description 1
- 230000008786 sensory perception of smell Effects 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- BMLSLBUURMXNPI-UHFFFAOYSA-M sodium;3-carboxy-3,5-dihydroxy-5-oxopentanoate;sulfuric acid Chemical compound [Na+].OS(O)(=O)=O.OC(=O)CC(O)(C(O)=O)CC([O-])=O BMLSLBUURMXNPI-UHFFFAOYSA-M 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
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- 239000003381 stabilizer Substances 0.000 description 1
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- 239000000454 talc Substances 0.000 description 1
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- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 241000712461 unidentified influenza virus Species 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/18—Liquid substances or solutions comprising solids or dissolved gases
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2101/00—Chemical composition of materials used in disinfecting, sterilising or deodorising
- A61L2101/02—Inorganic materials
- A61L2101/12—Inorganic materials containing silicon
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2101/00—Chemical composition of materials used in disinfecting, sterilising or deodorising
- A61L2101/02—Inorganic materials
- A61L2101/14—Inorganic materials containing sulfur
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2101/00—Chemical composition of materials used in disinfecting, sterilising or deodorising
- A61L2101/32—Organic compounds
- A61L2101/36—Carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/20—Method-related aspects
- A61L2209/21—Use of chemical compounds for treating air or the like
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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- Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
본 발명은 친환경 소독 및 탈취용 조성물과 그 제조방법에 관한 것이다. 구체적으로, 본 발명은 유황, 규산염, 구연산, 황산수소나트륨 및 알칼리 환원수를 포함함으로써 우수한 살균 및 탈취 효과를 나타내며, 인공 화합물을 사용하지 않아 친환경적인 소독 및 탈취용 조성물에 관한 것이다.
구체적으로, 본 발명은 유황, 규산염, 구연산, 황산수소나트륨, 및 알칼리 환원수를 포함하는 조성물이 우수한 항균 및 탈취 활성을 나타냄을 확인한 바, 독성을 유발할 수 있는 화합물의 함량은 줄여 안전하면서도 친환경적인 소독 및 탈취제로 유용하게 활용될 수 있다.The present invention relates to an eco-friendly disinfection and deodorization composition and a manufacturing method thereof. Specifically, the present invention relates to an eco-friendly disinfection and deodorization composition that exhibits excellent sterilization and deodorization effects by including sulfur, silicate, citric acid, sodium hydrogen sulfate and alkali reduced water, and does not use artificial compounds.
Specifically, the present invention has confirmed that the composition containing sulfur, silicate, citric acid, sodium hydrogen sulfate, and alkaline reduced water exhibits excellent antibacterial and deodorizing activity, and safe and environmentally friendly disinfection by reducing the content of compounds that can cause toxicity. And it can be usefully used as a deodorant.
Description
본 발명은 친환경 소독 및 탈취용 조성물과 그 제조방법에 관한 것이다. 구체적으로, 본 발명은 유황, 규산염, 구연산, 황산수소나트륨 및 알칼리 환원수를 포함함으로써 우수한 살균 및 탈취 효과를 나타내며, 인공 화합물을 사용하지 않아 친환경적인 소독 및 탈취용 조성물에 관한 것이다.The present invention relates to an eco-friendly disinfection and deodorization composition and a manufacturing method thereof. Specifically, the present invention relates to an eco-friendly disinfection and deodorization composition that exhibits excellent sterilization and deodorization effects by including sulfur, silicate, citric acid, sodium hydrogen sulfate and alkali reduced water, and does not use artificial compounds.
최근 신종 인플루엔자(신종플루) 및 코로나 바이러스(SARS, MERS, COVID-19 등)가 전 세계에 창궐하면서 그 병증과 확산속도 및 여파에 대한 다양한 분석과 전망 등이 쏟아지고 세계 각국은 방역대책을 세우기에 부심하고 있다. 인플루엔자 바이러스는 RNA 바이러스로서 항원 변이가 상대적으로 쉽기 때문에 감염인구 집단 내에서의 반복적인 재감염이 가능하다. 코로나바이러스의 경우, 여러 변이를 형성하여 인간에게 심각한 전염성 폐렴과 같은 신종 감염병을 유발하고 있다. 이에, 여러 감염증의 확산에 따라 어느 때 보다도 소독의 생활화 및 위생 관리가 필요한 시기이다. 또한, 감염에 취약한 노령 인구의 증가, 만성 질환자의 증가, 항암제 및 면역 억제제의 사용으로 인한 면역부전환자의 증가, 항생제 사용 증가 및 각종 침습적 의료처치의 이용 확대로 인해 감염에 노출될 위험은 점차 증가하고 있다. 그에 따라, 사회적으로 식품위생, 환경위생 및 세균오염 예방이 강조되고 있는 추세이다.As new influenza (swine flu) and corona viruses (SARS, MERS, COVID-19, etc.) have recently spread around the world, various analyzes and prospects on the disease, spread rate, and aftermath are pouring in, and countries around the world are establishing quarantine measures. are concentrating on Influenza virus is an RNA virus, and because it is relatively easy to mutate antigens, repeated reinfection within the infected population is possible. In the case of coronavirus, it is causing new infectious diseases such as severe contagious pneumonia in humans by forming multiple mutations. Accordingly, with the spread of various infectious diseases, it is a time when disinfection and sanitation management are needed more than ever. In addition, the risk of exposure to infection is gradually increasing due to the increase in the elderly population vulnerable to infection, the increase in chronic diseases, the increase in immunocompromised patients due to the use of anticancer drugs and immunosuppressants, the increase in the use of antibiotics, and the expansion of the use of various invasive medical procedures. are doing Accordingly, food hygiene, environmental hygiene, and bacterial contamination prevention are being emphasized socially.
세척, 소독, 살균, 멸균 등은 미생물의 숫자를 감소시키거나 제거하는 과정으로 감염관리의 중요한 방법 중 하나이다. 소독제(disinfectant)는 감염을 일으키는 미생물의 생장을 억제시키거나 사멸시키는 작용을 가진 제제이다. 소독제의 효과를 높이기 위해서는 작업 환경, 살균소독제의 특성, 사용방법 등을 고려하여 소독제를 선택하여 사용해야 한다 (Korean J Clin Microbial 11(2): 117-122, 2008).Cleaning, disinfection, sterilization, sterilization, etc. are processes that reduce or remove the number of microorganisms and are one of the important methods of infection control. A disinfectant is an agent that has the action of inhibiting or killing the growth of microorganisms that cause infection. In order to increase the effectiveness of a disinfectant, it is necessary to select and use a disinfectant in consideration of the working environment, the characteristics of the disinfectant, and the method of use (Korean J Clin Microbial 11(2): 117-122, 2008).
탈취제(deodorant)는 악취를 제거하는데 이용되는 물질이다. 생활수준이 향상되고 경제가 성장함에 따라 악취는 중요한 환경 문제로 인식되고 있다. 악취는 원인이 되는 물질의 종류와 성질이 매우 다양하고, 악취 물질 상호간에 복합적으로 작용하기 때문에 이를 효과적으로 처리하는 것은 어려운 문제 중 하나로 취급되고 있다.A deodorant is a substance used to remove bad odors. As living standards improve and economies grow, odor is recognized as an important environmental problem. Odor is treated as one of the difficult problems to treat effectively because the types and properties of substances that cause odor are very diverse, and the odor substances act complexly with each other.
종래의 탈취제는 인체에 유해한 화학 성분을 포함할 뿐만 아니라, 탈취가 이루어지는 과정에서 유해한 화학 성분이 정화되지 않고 그대로 배수되거나 대기 중으로 배출되므로, 수질과 대기를 오염시키는 등 제2의 환경 오염원이 되는 치명적인 문제점을 안고 있다. 또한, 악취를 제거하기 위해 사용되고 있는 방향제 또는 나프탈렌 등의 경우, 암모니아의 분자 구조를 변화시켜 냄새를 분해 및 제거하지 못하는 바, 악취보다 더 강한 향을 발생시켜 그로 인해 사용자가 암모니아에 의한 악취를 느낄 수 없도록 하는 간접적인 탈취 기능에 지나지 않는다. Conventional deodorizers not only contain chemical components harmful to the human body, but also cause harmful chemical components to be drained or discharged into the atmosphere without being purified during the deodorization process, which is fatal and becomes a second source of environmental pollution such as polluting water and air. have a problem In addition, in the case of aromatics or naphthalene, which are used to remove odors, the molecular structure of ammonia cannot be decomposed and removed, and the odor is stronger than the odor, so that the user can feel the odor caused by ammonia. It is nothing more than an indirect deodorization function that prevents
이러한 배경 하에, 본 발명자들은 유해 물질을 포함하지 않아 친환경적인 소독 및 탈취제를 개발하기 위해 예의 노력한 결과, 유황, 규산염, 구연산, 황산수소나트륨 및 알칼리 환원수를 포함하는 조성물이 우수한 탈취 및 항균 활성을 가지는 것을 확인함으로써 본 발명을 완성하였다.Under this background, the inventors have made diligent efforts to develop an environmentally friendly disinfection and deodorant that does not contain harmful substances, and as a result, a composition containing sulfur, silicate, citric acid, sodium hydrogen sulfate and alkaline reduced water has excellent deodorization and antibacterial activity By confirming that, the present invention was completed.
본 발명의 하나의 목적은 유황, 규산염, 구연산, 황산수소나트륨 및 알칼리 환원수를 포함하는 소독 및 탈취용 조성물을 제공하는 것이다.One object of the present invention is to provide a composition for disinfection and deodorization containing sulfur, silicate, citric acid, sodium hydrogen sulfate and alkaline reduced water.
본 발명의 다른 하나의 목적은 (a) 유황 및 규산염을 교반하는 단계; (b) 구연산 및 황산수소나트륨을 첨가하여 교반하는 단계; 및 (c) 알칼리 환원수를 첨가하여 교반하는 단계;를 포함하는 소독 및 탈취용 조성물의 제조방법을 제공하는 것이다.Another object of the present invention is (a) stirring sulfur and silicate; (b) stirring by adding citric acid and sodium hydrogen sulfate; It is to provide a method for preparing a composition for disinfection and deodorization comprising; and (c) adding alkaline reduced water and stirring.
이를 구체적으로 설명하면 다음과 같다. 한편, 본 발명에서 개시된 각각의 설명 및 실시형태는 각각의 다른 설명 및 실시 형태에도 적용될 수 있다. 즉, 본 발명에서 개시된 다양한 요소들의 모든 조합이 본 발명의 범주에 속한다. 또한, 하기 기술된 구체적인 서술에 의하여 본 발명의 범주가 제한된다고 볼 수 없다.A detailed description of this is as follows. Meanwhile, each description and embodiment disclosed in the present invention may also be applied to each other description and embodiment. That is, all combinations of the various elements disclosed herein fall within the scope of the present invention. In addition, it cannot be seen that the scope of the present invention is limited by the specific descriptions described below.
상기 목적을 달성하기 위한 본 발명의 하나의 양태는, 유황, 규산염, 구연산, 황산수소나트륨 및 알칼리 환원수를 포함하는 소독 및 탈취용 조성물을 제공한다. One aspect of the present invention for achieving the above object provides a composition for disinfection and deodorization containing sulfur, silicate, citric acid, sodium hydrogen sulfate and alkaline reduced water.
본 발명의 용어 "소독"은 물체 등의 표면에 있는 미생물을 사멸 또는 불활성화하여 감염력을 억제하는 조작을 의미하며, 위생 관리, 감염 및 전염병 방지의 목적을 가진다. 본 발명의 용어 "탈취"는 기체상 물질이 사람의 후각을 자극하여 불쾌감과 혐오감을 주는 냄새인 악취를 제거하는 기능을 의미한다.The term "disinfection" of the present invention means an operation to suppress infectivity by killing or inactivating microorganisms on the surface of an object, etc., and has the purpose of hygiene management, infection and epidemic prevention. The term "deodorization" of the present invention refers to a function of removing odor, which is an unpleasant or disgusting smell, by stimulating the human sense of smell by a gaseous substance.
본 발명의 유황(Sulfur, Cas number 7704-34-9)은 분말화 된 유황으로, 침강유황(precipitated sulfur), 승화유황(sublimed sulfur), 또는 콜로이드 유황(colloidal sulfur)을 모두 포함한다. 유황은 친환경 유기농 자재로 이용되며, 살균, 살비 효과가 있을 뿐 아니라, 식물의 생육을 촉진하는 작용을 하는 것으로 알려져 있다. The sulfur (Sulfur, Cas number 7704-34-9) of the present invention is powdered sulfur, and includes all of precipitated sulfur, sublimed sulfur, or colloidal sulfur. Sulfur is used as an eco-friendly organic material, and is known to have sterilization and acaricidal effects, as well as promote plant growth.
본 발명의 조성물에서 상기 유황은 0.06 내지 0.8 중량부 포함될 수 있다. 본 발명의 조성물에서 유황이 상기 범위 미만으로 포함될 경우 유효한 살균 또는 탈취 활성이 발휘되지 않을 수 있으며, 상기 범위를 초과하여 포함될 경우 액체 형태의 조성물에 완전히 용해되지 않을 수 있다.In the composition of the present invention, the sulfur may be included in an amount of 0.06 to 0.8 parts by weight. In the composition of the present invention, when sulfur is included below the above range, effective bactericidal or deodorizing activity may not be exhibited, and when it is included above the above range, it may not be completely dissolved in the composition in liquid form.
본 발명의 규산염(sodium metasilicate pentahydrate, Cas number 10213-79-3)은 규산염 합제라고도 불리며, 물에 용해되어 pH를 높임으로써 알칼리 조건을 유지하게 하며, 농도에 따라 pH 변화가 적다. 친수성 규산의 작용으로 분산성 및 흡착성이 우수하며, 알칼리도를 조정하는 완충 작용을 나타낸다. 규산염 수용액은 강알칼리 특성으로 인해 세정력을 강화하고, 계면 활성력을 촉진하여 미생물에 대한 침투력과 살균 효과를 강화할 수 있다. 본 발명에서 상기 규산염은 규산마그네슘, 규산칼슘, 규산소다, 및 메타규산소다로 이루어진 군으로부터 2 이상을 선택하여 100 내지 150℃에서 가열한 후, 증류수 및 용해제를 첨가한 후 액상화하여 제조된 것일 수 있다.The silicate (sodium metasilicate pentahydrate, Cas number 10213-79-3) of the present invention is also called a silicate mixture, and is dissolved in water to increase the pH to maintain an alkaline condition, and the pH change is small depending on the concentration. It has excellent dispersibility and adsorption due to the action of hydrophilic silicic acid, and shows a buffering action that adjusts alkalinity. The aqueous silicate solution can enhance detergency due to its strong alkalinity and enhance the penetrating power and sterilizing effect on microorganisms by promoting surface activity. In the present invention, the silicate may be prepared by selecting two or more from the group consisting of magnesium silicate, calcium silicate, sodium silicate, and sodium metasilicate, heating at 100 to 150 ° C, adding distilled water and a solubilizing agent, and then liquefying. there is.
본 발명의 조성물에서 상기 규산염은 8 내지 12 중량부 포함될 수 있다. 본 발명의 조성물에서 규산염이 상기 범위 미만으로 포함될 경우 충분한 소독 활성이 발휘되지 않을 수 있으며, 규산염이 상기 범위를 초과하여 포함될 경우 인체에 자극을 줄 수 있다. In the composition of the present invention, the silicate may be included in 8 to 12 parts by weight. In the composition of the present invention, if the silicate is included in the above range, sufficient disinfecting activity may not be exerted, and if the silicate is included in the above range, it may irritate the human body.
본 발명의 구연산(citric acid, Cas number 77-92-9)은 박테리아 및 바이러스에 대한 사멸능 및 피부 개선 효능 등이 알려져 있으며, 얼룩, 석회, 녹과 같은 물질을 제거하는 세제 원료로도 사용된다. 본 발명에서 구연산은 조성물에 포함되어 규산염의 사용으로 인해 조성물의 pH가 과도하게 높아지는 것을 방지할 수 있다.Citric acid (Cas number 77-92-9) of the present invention is known for its ability to kill bacteria and viruses and its skin improving effect, and is also used as a detergent raw material to remove substances such as stains, lime, and rust. . In the present invention, citric acid can be included in the composition to prevent the pH of the composition from being excessively high due to the use of silicate.
본 발명의 황산수소나트륨(sodium bisulfate monohydrate, Cas number 10034-88-5)은 방부제, 보존제, 안정화제, 완충제, 용제, 코팅제, 항산화제, 환원제 등의 화합물 제조에 사용되며, 본 발명의 조성물에 포함되어 pH 조절제의 역할을 할 수 있다.Sodium bisulfate monohydrate (Cas number 10034-88-5) of the present invention is used in the preparation of compounds such as preservatives, preservatives, stabilizers, buffers, solvents, coating agents, antioxidants, and reducing agents, and is used in the composition of the present invention. It can also act as a pH regulator.
본 발명의 알칼리 환원수(alkaline reduced water)는 수소가 풍부하여 환원력이 높은 물로서, 체내 흡수가 빠르고 설사, 소화불량, 위산과다 등의 질병 개선에 도움을 주는 것으로 알려져 있다. 본 발명에서 알칼리 환원수는 조성물에 포함되어 높은 환원력으로 인하여 탈취 활성을 향상시킬 수 있다.The alkaline reduced water of the present invention is hydrogen-rich and has high reducing power, and is known to help improve diseases such as diarrhea, indigestion, and hyperacidity. In the present invention, alkaline reducing water is included in the composition and can improve the deodorizing activity due to its high reducing power.
본 발명에서 상기 유황, 규산염, 구연산, 황산수소나트륨, 및 알칼리 환원수는 직접 합성하거나, 시중에 유통되는 제품을 구입하여 사용할 수 있으며, 유효 성분으로서 조성물에 포함될 수 있다면 그 형태 또는 수득 방법은 제한되지 않는다.In the present invention, the sulfur, silicate, citric acid, sodium hydrogen sulfate, and alkali reduced water may be directly synthesized or purchased and used on the market, and as long as they can be included in the composition as an active ingredient, their form or method of obtaining is not limited. don't
본 발명의 소독 및 탈취용 조성물은 유황 0.06 내지 0.3 중량부, 규산염 8 내지 12 중량부, 구연산 0.1 내지 0.5 중량부, 황산수소나트륨 0.1 내지 0.5 중량부, 및 알칼리 환원수 80 내지 95 중량부를 포함할 수 있다. 본 발명의 소독 및 탈취용 조성물은 유황 0.09 내지 0.18 중량부, 규산염 8 내지 10 중량부, 구연산 0.1 내지 0.3 중량부, 황산수소나트륨 0.1 내지 0.3 중량부, 및 알칼리 환원수 87 내지 95 중량부를 포함할 수 있으며, 더욱 구체적으로, 유황 0.12 중량부, 규산염 9.05 중량부, 구연산 0.18 중량부, 황산수소나트륨 0.18 중량부, 및 알칼리 환원수 90.47 중량부를 포함할 수 있다.The composition for disinfection and deodorization of the present invention may include 0.06 to 0.3 parts by weight of sulfur, 8 to 12 parts by weight of silicate, 0.1 to 0.5 parts by weight of citric acid, 0.1 to 0.5 parts by weight of sodium hydrogen sulfate, and 80 to 95 parts by weight of alkali reduced water. there is. The composition for disinfection and deodorization of the present invention may include 0.09 to 0.18 parts by weight of sulfur, 8 to 10 parts by weight of silicate, 0.1 to 0.3 parts by weight of citric acid, 0.1 to 0.3 parts by weight of sodium hydrogen sulfate, and 87 to 95 parts by weight of alkali reduced water. And, more specifically, it may include 0.12 parts by weight of sulfur, 9.05 parts by weight of silicate, 0.18 parts by weight of citric acid, 0.18 parts by weight of sodium hydrogen sulfate, and 90.47 parts by weight of alkali reduced water.
본 발명의 구체적인 일 구현예에서는, 유황, 규산염, 및 알칼리 환원수의 중량비를 상이하게 포함하는 실시예 및 비교예 조성물을 제조한 결과, 유황을 0.3 중량부를 초과하여 포함하는 비교예 2 조성물은 완전히 용해되지 않은 유황 분말이 존재하는 바, 소독제 또는 탈취제로서 바람직하지 않음을 확인하였다 (제조예 1). 또한, 실시예 1 및 비교예 1, 3, 4 조성물의 탈취 효과를 비교 평가한 결과, 실시예 1 조성물의 탈취율이 가장 높으며, 특히 규산염의 함량이 높은 비교예 4 조성물에 비해서도 그 탈취율이 높은 것을 확인한 바 (실험예 1), 본 발명에서는 가장 우수한 탈취 활성을 나타낼 수 있는 유효성분들의 함량을 구체적인 실험을 통하여 규명하였다. In a specific embodiment of the present invention, as a result of preparing the compositions of Examples and Comparative Examples containing different weight ratios of sulfur, silicate, and alkali reducing water, the composition of Comparative Example 2 containing more than 0.3 parts by weight of sulfur completely dissolved. Since untreated sulfur powder exists, it was confirmed that it is undesirable as a disinfectant or deodorant (Preparation Example 1). In addition, as a result of comparative evaluation of the deodorizing effect of the compositions of Example 1 and Comparative Examples 1, 3, and 4, the deodorization rate of the composition of Example 1 was the highest, especially compared to the composition of Comparative Example 4 having a high silicate content. As confirmed (Experimental Example 1), in the present invention, the contents of active ingredients capable of exhibiting the best deodorizing activity were identified through specific experiments.
본 발명의 소독 및 탈취용 조성물은 항균 및 탈취 효과를 나타내는 것을 특징으로 할 수 있다. 본 발명의 용어 "항균"은 세균 또는 진균의 생육 저해 작용을 의미하며, 구체적으로, 대장균(Escherichia coli), 녹농균(Pseudomonas aeruginosa), 황색포도상구균(Staphylococcus aureus), 폐렴균(Klebsiella pneumoniae) 및 MRSA균(Staphylococcus aureus subsp. aureus)에 대한 항균 활성을 의미할 수 있으나, 이에 제한되지 않는다. 본 발명의 구체적인 일 구현예에서는, 실시예 1 조성물의 상기 각 균주에 대한 저해율을 KCL-FIR-1002: 2018의 시험 기준에 따라 평가한 결과, 대장균, 녹농균, 황색포도상구균, 폐렴균, 및 MRSA균에 대한 유효성 시험에서 99.9% 이상의 효능을 나타낸 것을 확인하였다 (실험예 2). The composition for disinfection and deodorization of the present invention may be characterized by exhibiting antibacterial and deodorizing effects. The term "antibacterial" of the present invention refers to the growth inhibitory action of bacteria or fungi, specifically, Escherichia coli ( Escherichia coli ), Pseudomonas aeruginosa ( Pseudomonas aeruginosa ), Staphylococcus aureus ( Staphylococcus aureus ), pneumonia ( Klebsiella pneumoniae ) and MRSA bacteria ( Staphylococcus aureus subsp. aureus) may mean antibacterial activity, but is not limited thereto. In a specific embodiment of the present invention, as a result of evaluating the inhibition rate of each strain of the composition of Example 1 according to the test criteria of KCL-FIR-1002: 2018, Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, Pneumococcus, and MRSA It was confirmed that an efficacy of 99.9% or more was shown in the efficacy test for (Experimental Example 2).
본 발명의 용어 "탈취"는 바람직하지 않은 냄새를 제거하는 행위를 의미하며, "악취 제거" 또는 "소취"와 혼용하여 사용할 수 있다. 본 발명의 구체적인 일 구현예에서는, 본 발명의 실시예 1 조성물이 악취의 주원인이 되는 황화수소 및 메틸머캅탄 가스의 농도를 현저히 감소시키는 것을 확인한 바, 그 탈취 효과가 우수한 것을 확인하였다 (실험예 1).The term "deodorization" of the present invention refers to an act of removing an undesirable odor, and may be used interchangeably with "elimination of odor" or "deodorization". In a specific embodiment of the present invention, it was confirmed that the composition of Example 1 of the present invention significantly reduced the concentration of hydrogen sulfide and methylmercaptan gas, which are the main causes of odor, and it was confirmed that the deodorizing effect was excellent (Experimental Example 1 ).
또한, 본 발명의 소독 및 탈취용 조성물은 유효성분의 소독 또는 탈취 효과를 저해하지 않는 한, 상기 유효성분 이외에도 목적에 따라 향료, 색소, 방부제, 산화방지제, 소포제, 담체 등이 추가로 포함될 수 있다. 상기 담체의 경우, 점토(예: 카올린, 벤토나이트, 산 점토 등), 활석(예: 활석 분말, 납석 분말 등), 실리카(예: 규조토, 규산 무수물, 운모 분말 등), 알루미나, 황 분말 및 활성탄 중에서 1종 또는 2종 이상이 선택될 수 있으나, 이에 제한되는 것은 아니다.In addition, the composition for disinfection and deodorization of the present invention may further include flavoring agents, coloring agents, preservatives, antioxidants, antifoaming agents, carriers, etc. . In the case of the carrier, clay (eg, kaolin, bentonite, acid clay, etc.), talc (eg, talcum powder, pyrophyllite powder, etc.), silica (eg, diatomaceous earth, silicic anhydride, mica powder, etc.), alumina, sulfur powder, and activated carbon One or two or more may be selected from among, but is not limited thereto.
본 발명의 다른 하나의 양태는, (a) 유황 및 규산염을 교반하는 단계; (b) 구연산 및 황산수소나트륨을 첨가하여 교반하는 단계; 및 (c) 알칼리 환원수를 첨가하여 교반하는 단계;를 포함하는 소독 및 탈취용 조성물의 제조방법을 제공한다. Another aspect of the present invention, (a) stirring sulfur and silicate; (b) stirring by adding citric acid and sodium hydrogen sulfate; And (c) the step of adding alkaline reduced water and stirring; it provides a method for producing a composition for disinfection and deodorization comprising a.
상기 용어 "유황", "규산염", "구연산", "황산수소나트륨", "알칼리 환원수", 및 "소독 및 탈취용 조성물"에 대한 설명은 전술한 바와 같다.The terms "sulfur", "silicate", "citric acid", "sodium hydrogen sulfate", "alkaline reduced water", and "composition for disinfection and deodorization" are explained as described above.
본 발명 소독 및 탈취용 조성물의 제조방법은 구체적으로, 먼저 유황에 규산염을 첨가하여 교반한다. 이때, 교반 직후에는 유황 및 규산염의 혼합물은 불투명한 색을 나타내다가 점차 노란색으로 변화하며, 최종적으로 투명한 색에 도달할 때까지 30 내지 60분 간 교반한다. 다음으로, 상기 혼합물에 분말 형태인 구연산 및 황산수소나트륨을 첨가하여 1 내지 5분 동안 교반한다. 마지막으로, 40 내지 60℃로 가열한 알칼리 환원수를 첨가 후 10 내지 50분 동안 교반하여 완전히 용해시켜 소독 및 탈취용 조성물을 제조할 수 있다.Specifically, in the method for preparing the composition for disinfection and deodorization of the present invention, silicate is first added to sulfur and stirred. At this time, immediately after stirring, the mixture of sulfur and silicate shows an opaque color, then gradually changes to yellow, and is stirred for 30 to 60 minutes until it finally reaches a transparent color. Next, powdered citric acid and sodium hydrogen sulfate are added to the mixture and stirred for 1 to 5 minutes. Finally, a composition for disinfection and deodorization may be prepared by adding alkali reduced water heated to 40 to 60 ° C. and then completely dissolving the mixture by stirring for 10 to 50 minutes.
본 발명의 소독 및 탈취용 조성물 제조방법은, 통상적인 소독 또는 탈취용 조성물을 제조할 때 필요한 과정인 여과 단계, 정제 단계 등을 추가로 포함할 수 있다.The method for preparing a composition for disinfection and deodorization of the present invention may further include a filtration step, a purification step, and the like, which are necessary processes when preparing a conventional disinfection or deodorization composition.
본 발명의 또 다른 하나의 양태는, 상기 소독 및 탈취용 조성물을 이용한 소독 방법을 제공한다.Another aspect of the present invention provides a disinfection method using the disinfection and deodorization composition.
상기 용어 "소독 및 탈취용 조성물"에 대한 설명은 전술한 바와 같다.The description of the term "composition for disinfection and deodorization" is as described above.
본 발명의 소독 방법은, 상기 소독 및 탈취용 조성물을 이용하여 미생물의 활성을 잃게 하여 감염력을 억제하는 모든 행위를 포함한다. 광의의 소독 방법은 물리적 방법을 이용하거나, 화학적 방법을 이용하는 소독 방법을 모두 의미하나, 본 발명의 소독 방법은 소독력이 있는 소독 및 탈취용 조성물을 사용하여 미생물을 제거하는 방법이므로, 화학적 소독 방법인 것이 바람직하다.The disinfection method of the present invention includes all actions of suppressing infectivity by losing the activity of microorganisms using the disinfection and deodorization composition. The disinfection method in a broad sense means both a disinfection method using a physical method or a chemical method, but since the disinfection method of the present invention is a method of removing microorganisms using a disinfectant and deodorizing composition, the chemical disinfection method it is desirable
본 발명의 또 다른 하나의 양태는, 상기 소독 및 탈취용 조성물을 포함하는 액상형 소독제를 제공한다.Another aspect of the present invention provides a liquid type disinfectant comprising the composition for disinfection and deodorization.
상기 용어 "소독 및 탈취용 조성물"에 대한 설명은 전술한 바와 같다.The description of the term "composition for disinfection and deodorization" is as described above.
본 발명의 소독용 조성물은 액체상, 고체상 및 기체상 중 임의의 상으로 제조될 수 있으나, 통상적으로 물에 희석하여 사용하는 점을 고려하면, 액상형인 것이 바람직하다.The disinfectant composition of the present invention may be prepared in any phase of a liquid phase, a solid phase, and a gas phase, but considering that it is usually diluted in water and used, it is preferably a liquid phase.
본 발명의 용어 "소독제"는 생명체가 아닌 물체에 사는 미생물을 억제, 사멸 또는 불활성화 하는데 쓰이는 물질 또는 제품을 의미한다. 상기 소독제는 본 발명의 소독용 조성물을 유효성분으로서 포함할 수 있다면, 그 형태는 제한되지 않으며, 목적에 따라 본 발명 소독 및 탈취용 조성물의 함량은 적절히 선택할 수 있다.As used herein, the term "disinfectant" refers to a substance or product used to inhibit, kill, or inactivate microorganisms living on non-living objects. If the disinfectant can contain the disinfectant composition of the present invention as an active ingredient, the form is not limited, and the content of the disinfectant and deodorant composition of the present invention can be appropriately selected according to the purpose.
본 발명은 유황, 규산염, 구연산, 황산수소나트륨, 및 알칼리 환원수를 포함하는 조성물이 우수한 항균 및 탈취 활성을 나타냄을 확인한 바, 독성을 유발할 수 있는 화합물의 함량은 줄여 안전하면서도 친환경적인 소독 및 탈취제로 유용하게 활용될 수 있다.The present invention has confirmed that the composition containing sulfur, silicate, citric acid, sodium hydrogen sulfate, and alkaline reduced water exhibits excellent antibacterial and deodorizing activity. can be put to good use.
이하 본 발명을 실시예를 통하여 보다 상세하게 설명한다. 그러나 이들 실시예는 본 발명을 예시적으로 설명하기 위한 것으로 본 발명의 범위가 이들 실시예에 국한되는 것은 아니다.Hereinafter, the present invention will be described in more detail through examples. However, these examples are intended to illustrate the present invention by way of example, and the scope of the present invention is not limited to these examples.
제조예 1. 소독 및 탈취용 조성물의 제조Preparation Example 1. Preparation of composition for disinfection and deodorization
본 발명의 소독 및 탈취용 조성물을 제조하기 위하여, 유황(Sulfur, precipitated, sublimed or colloidal. Cas number 7704-34-9), 규산염(sodium metasilicate pentahydrate, Cas number 10213-79-3), 구연산(citric acid, Cas number 77-92-9), 황산수소나트륨(sodium bisulfate monohydrate, Cas number 10034-88-5), 및 알칼리 환원수(alkaline reduced water)를 준비하고, 다음 표 1과 같이 유황, 규산염, 및 알칼리 환원수의 함량을 다르게 혼합하여 실시예 및 비교예 조성물을 제조하였다 (단위: 중량부).In order to prepare the composition for disinfection and deodorization of the present invention, sulfur (Sulfur, precipitated, sublimed or colloidal. Cas number 7704-34-9), silicate (sodium metasilicate pentahydrate, Cas number 10213-79-3), citric acid (citric acid) acid, Cas number 77-92-9), sodium bisulfate monohydrate (Cas number 10034-88-5), and alkaline reduced water were prepared, and sulfur, silicate, and Compositions of Examples and Comparative Examples were prepared by mixing different amounts of alkaline reducing water (unit: parts by weight).
구체적으로, 먼저 유황에 규산염을 첨가하여 교반하는데, 교반 직후에는 불투명한 색을 나타내다가 점차 노란색으로 변화하며, 최종적으로 투명한 색에 도달할 때까지 30 내지 60분 간 교반하여 유황 및 규산염의 혼합물을 제조하였다. 다음으로, 상기 혼합물에 분말 형태인 구연산 및 황산수소나트륨을 첨가하여 1 내지 5분 동안 교반하였다. 마지막으로, 40 내지 60℃로 가열한 알칼리 환원수를 첨가 후 10 내지 50분 동안 교반하여 완전히 용해시켜 소독 및 탈취용 조성물을 제조하였다.제조 결과, 유황의 함량이 상대적으로 높은 비교예 2 조성물의 경우, 완전히 용해되지 않은 유황이 존재하여 소독제 또는 탈취제로서 바람직하지 않음을 확인하였다. Specifically, silicate is first added to sulfur and stirred. Immediately after stirring, it shows an opaque color, then gradually changes to yellow, and is stirred for 30 to 60 minutes until it finally reaches a transparent color to form a mixture of sulfur and silicate. manufactured. Next, citric acid and sodium hydrogen sulfate in powder form were added to the mixture and stirred for 1 to 5 minutes. Finally, after adding alkali reduced water heated to 40 to 60 ° C., the composition was completely dissolved by stirring for 10 to 50 minutes to prepare a composition for disinfection and deodorization. , it was confirmed that incompletely dissolved sulfur was present, making it undesirable as a disinfectant or deodorant.
실험예 1. 조성물의 탈취 활성 평가Experimental Example 1. Evaluation of deodorizing activity of the composition
실시예 및 비교예 조성물의 탈취율을 평가하기 위하여, 탈취 시험조건인 개방 공간에서 황화수소(hydrogen sulfide, H2S) 20ml 및 메틸머캅탄(methyl mercaptan, CH3SH) 20ml를 각각 glass bottle 10L에 넣고, 환경표지 인증기준 EL608: 2017의 시험 규격으로 측정하였다. 시험 중의 온도는 21.5±0.5℃, 습도는 50.0±1.0 %를 유지하였다.In order to evaluate the deodorization rate of the compositions of Examples and Comparative Examples, 20 ml of hydrogen sulfide (H 2 S) and 20 ml of methyl mercaptan (CH 3 SH) were placed in a glass bottle of 10 L, respectively, in an open space, which is a deodorization test condition. , Eco-label certification standard EL608: measured according to the test standard of 2017. During the test, the temperature was maintained at 21.5 ± 0.5 ° C and the humidity was maintained at 50.0 ± 1.0 %.
그 결과 상기 표 2에 나타난 바와 같이, 실시예 1 조성물의 탈취율이 가장 높은 것을 확인하였다. 비교예 4 조성물의 경우 규산염의 함량이 높으나 그에 따라 알칼리 환원수의 함량이 상대적으로 적어짐에 따라 탈취 활성이 실시예 1 조성물에 비하여 낮아졌으며, 비교예 1 및 비교예 3 조성물의 경우 유황 및 규산염의 함량이 유효한 탈취율을 나타내기에는 충분하지 않은 것을 알 수 있었다.As a result, as shown in Table 2, it was confirmed that the composition of Example 1 had the highest deodorization rate. In the case of the composition of Comparative Example 4, the content of silicate was high, but as the content of alkali reducing water was relatively low, the deodorizing activity was lower than that of the composition of Example 1, and in the case of the composition of Comparative Example 1 and Comparative Example 3, the content of sulfur and silicate It turned out that it was not enough to show this effective deodorization rate.
실험예 2. 조성물의 항균 활성 평가Experimental Example 2. Evaluation of antibacterial activity of the composition
실시예 1 조성물의 항균 활성을 평가하기 위하여, KCL-FIR-1002: 2018의 시험 방법에 따라 대장균(Escherichia coli, ATCC 25922), 녹농균(Pseudomonas aeruginosa, ATCC 15442), 황색포도상구균(Staphylococcus aureus, ATCC 6538), 폐렴균(Klebsiella pneumoniae, ATCC 4352), 및 MRSA균(Staphylococcus aureus subsp. Aureus, ATCC 33591)의 감소율을 측정하였다. 시험 환경은 37.0±0.2℃를 유지하였다.Example 1 In order to evaluate the antibacterial activity of the composition, Escherichia coli ( Escherichia coli, ATCC 25922), Pseudomonas aeruginosa ( ATCC 15442), Staphylococcus aureus ( Staphylococcus aureus , ATCC) according to the test method of KCL-FIR-1002: 2018 6538), pneumoniae ( Klebsiella pneumoniae , ATCC 4352), and MRSA ( Staphylococcus aureus subsp. Aureus, ATCC 33591) were measured. The test environment was maintained at 37.0 ± 0.2 ° C.
(CFU/mL)initial concentration
(CFU/mL)
(CFU/mL)Concentration after 1 hour
(CFU/mL)
그 결과 상기 표 3에 나타난 바와 같이, 본 발명 실시예 1 조성물은 대장균, 녹농균, 황색포도상구균, 폐렴균, 및 MRSA균에 대한 유효성 시험에서 99.9% 이상의 효능을 나타낸 것을 확인하였다. As a result, as shown in Table 3, it was confirmed that the composition of Example 1 of the present invention exhibited an efficacy of 99.9% or more in an efficacy test against Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, Pneumococcus, and MRSA.
이상의 설명으로부터, 본 발명이 속하는 기술분야의 당업자는 본 발명이 그 기술적 사상이나 필수적 특징을 변경하지 않고서 다른 구체적인 형태로 실시될 수 있다는 것을 이해할 수 있을 것이다. 이와 관련하여, 이상에서 기술한 실시예들은 모든 면에서 예시적인 것이며 한정적인 것이 아닌 것으로 이해해야만 한다. 본 발명의 범위는 상기 상세한 설명보다는 후술하는 특허 청구범위의 의미 및 범위 그리고 그 등가 개념으로부터 도출되는 모든 변경 또는 변형된 형태가 본 발명의 범위에 포함되는 것으로 해석되어야 한다.From the above description, those skilled in the art to which the present invention pertains will be able to understand that the present invention may be embodied in other specific forms without changing the technical spirit or essential characteristics thereof. In this regard, it should be understood that the embodiments described above are illustrative in all respects and not limiting. The scope of the present invention should be construed as including all changes or modifications derived from the meaning and scope of the claims to be described later and equivalent concepts rather than the detailed description above are included in the scope of the present invention.
Claims (1)
상기 규산염은 규산마그네슘, 규산칼슘, 규산소다, 및 메타규산소다로 이루어진 군으로부터 2 이상을 선택하여 100 내지 150℃에서 가열한 후, 증류수 및 용해제를 첨가하여 액상화된 것이며,
상기 조성물은 유황 0.12 중량부, 규산염 9.05 중량부, 구연산 0.18 중량부, 황산수소나트륨 0.18 중량부, 및 알칼리 환원수 90.47 중량부를 포함하고,
대장균, 녹농균, 황색포도상구균, 폐렴균, 및 MRSA균에 대한 항균 활성을 가지는, 친환경 소독 및 탈취용 조성물.An eco-friendly disinfection and deodorization composition containing sulfur, silicate, citric acid, sodium hydrogen sulfate and alkaline reduced water,
The silicate is selected from the group consisting of magnesium silicate, calcium silicate, sodium silicate, and sodium metasilicate, heated at 100 to 150 ° C., and then liquefied by adding distilled water and a solubilizing agent,
The composition includes 0.12 parts by weight of sulfur, 9.05 parts by weight of silicate, 0.18 parts by weight of citric acid, 0.18 parts by weight of sodium hydrogen sulfate, and 90.47 parts by weight of alkali reduced water,
A composition for eco-friendly disinfection and deodorization having antibacterial activity against Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, Pneumococcus, and MRSA.
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| KR20060014454A (en) * | 2006-01-27 | 2006-02-15 | 윤용주 | The antibacterial mixture |
| KR20090026864A (en) * | 2007-09-11 | 2009-03-16 | 김병철 | Sterilization composition for tableware |
| KR20130002400A (en) * | 2011-06-29 | 2013-01-08 | 인동철 | Deodrant composition for livestock barn and method for deodoring using the same |
| KR20150089327A (en) * | 2014-01-27 | 2015-08-05 | 이기용 | Disinfection and Deodorant Using Mineral and Sulfur |
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| KR20060014454A (en) * | 2006-01-27 | 2006-02-15 | 윤용주 | The antibacterial mixture |
| KR20090026864A (en) * | 2007-09-11 | 2009-03-16 | 김병철 | Sterilization composition for tableware |
| KR20130002400A (en) * | 2011-06-29 | 2013-01-08 | 인동철 | Deodrant composition for livestock barn and method for deodoring using the same |
| KR20150089327A (en) * | 2014-01-27 | 2015-08-05 | 이기용 | Disinfection and Deodorant Using Mineral and Sulfur |
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