KR20220125674A - Moldable composition for solid washing agent and method for molding the same - Google Patents

Abstract

The present specification provides a moldable solid cleaning agent composition and a method for molding the same. The moldable solid cleaning agent composition disclosed in the present specification can be easily stored for a long time at room temperature, and can be molded immediately in a simple way. Therefore, the composition can be applied directly to an on-site manufacturing system, and can meet customer needs by being adjusted to have various shapes, combinations or sizes. In addition, the solid cleaning agent composition disclosed in the present specification has excellent compatibility with water when used.

Description

MOLDABLE COMPOSITION FOR SOLID WASHING AGENT AND METHOD FOR MOLDING THE SAME

Disclosed herein are a moldable solid detergent composition and a molding method thereof.

As customer needs diversify, interest in on-site manufacturing and customized cosmetics is increasing. However, in the case of the existing solid detergent, it was difficult to satisfy both storage and moldability at the same time as it contained a solvent such as water that enhances the reactivity during mixing. Therefore, there is a problem that cannot be applied to a system that can be directly manufactured on site according to customer needs.

Korean Patent Publication No. 10-2011-0037905

In one aspect, an object of the present invention is to provide a solid detergent composition that is easy to store and has excellent moldability and a molded article thereof.

In another aspect, it is an object to provide a solid detergent composition capable of controlling reactivity without water.

In another aspect, an object of the present invention is to provide a solid detergent molding method that can be molded immediately in a simple way according to customer needs.

In one aspect, the present specification provides a moldable solid detergent composition comprising a starch-based polymer and a polyol, wherein the starch-based polymer is included in an amount of greater than 0 to less than 20% by weight based on the total weight of the composition.

In another aspect, the present specification provides a molded article molded from the composition.

In another aspect, the present specification provides a solid detergent molding method comprising the step of molding by applying pressure to the above-described composition.

In one aspect, the solid detergent composition disclosed herein can maintain the formulation without hardening for a long time at room temperature, and thus has excellent storage and moldability. In another aspect, the solid detergent composition disclosed herein can be molded and solidified within a short time by applying a slight pressure at room temperature (25° C.) without adding water.

In another aspect, when the solid detergent composition disclosed herein is added to lukewarm water, the lipophilic component is spread evenly on the surface of the water without agglomeration, so that the compatibility (or dispersibility) is excellent. In addition, since the lipophilic component is evenly dispersed in the water interface, the moisturizing component can be evenly applied to the entire skin of the body.

1 is a result of observing the storability of a composition according to an embodiment of the present specification.
2 is a result of observing the moldability of the composition according to an embodiment of the present specification.
3 is a result of observing the foamability of the composition according to an embodiment of the present specification.
4 is a result of observing the compatibility of the composition according to an embodiment of the present specification.

Hereinafter, embodiments of the present application will be described in more detail with reference to the accompanying drawings. However, the technology disclosed in the present application is not limited to the embodiments described herein and may be embodied in other forms. However, the embodiments introduced herein are provided so that the disclosed content may be thorough and complete, and the spirit of the present application may be sufficiently conveyed to those skilled in the art. Those of ordinary skill in the art will be able to implement the spirit of the present application in various other forms without departing from the technical spirit of the present application.

In this specification, the singular expression includes the plural expression unless the context clearly dictates otherwise. In the present application, terms such as "comprise", "contains" or "have" are intended to designate that a feature, number, step, action, component, or combination thereof described in the specification is present, and one or the It does not exclude the possibility of the existence or addition of other features or numbers, steps, operations, components, or combinations thereof.

Hereinafter, the present disclosure will be described in detail.

In exemplary embodiments of the present disclosure, a moldable solid detergent composition comprising a starch-based polymer and a polyol, wherein the starch-based polymer is included in an amount of greater than 0 to less than 20% by weight based on the total weight of the composition. can provide

One embodiment of the present disclosure is the use of a starch-based polymer and a polyol for the preparation of a moldable solid detergent composition, wherein the composition contains more than 0 to less than 20% by weight of the starch-based polymer based on the total weight of the composition. It can provide a use, including as. One embodiment of the present disclosure provides the use of a starch-based polymer and a polyol for use in a moldable solid detergent composition, wherein the composition contains more than 0 to less than 20% by weight of the starch-based polymer based on the total weight of the composition. It can provide a use, including as. An embodiment of the present disclosure includes adding a starch-based polymer and a polyol to a composition, wherein the composition comprises greater than 0 to less than 20% by weight of the starch-based polymer based on the total weight of the composition. A method for preparing a solid detergent composition may be provided.

The composition according to an embodiment of the present disclosure is a composition that does not contain water, and can maintain a powder (granule) state without solidification for 0 to 12 hours in a dispenser at room temperature, and is stored without further reaction until a customer's order is placed This is possible. In addition, due to the composition, by applying a pressure of 5-100 mbar at room temperature and atmospheric atmosphere without adding water, it is possible to solidify in a simple way within about 3 minutes. Accordingly, as an embodiment of the present disclosure, the composition can be directly manufactured in the field according to customer needs, or can be manufactured by the customer before use. Therefore, according to one embodiment of the present disclosure, when a customer order comes in after storing the composition in the form of granules, the composition can be molded and provided in a shape desired by the customer. Alternatively, as another embodiment, the composition may be molded into a desired shape before use by a customer who purchased the composition.

In one embodiment, the moisture retention of the composition may be less than 1% by weight based on the total weight of the composition, for example, less than 1%, less than 0.1%, less than 0.01%, less than 0.001%, less than 0.0009% by weight, less than 0.0007% by weight, less than 0.0005% by weight, less than 0.0003% by weight, or less than 0.0001% by weight.

In one embodiment, the starch-based polymer may include at least one selected from the group consisting of corn starch, dextrin, hydroxypropyl starch phosphate, and sodium polyacrylate starch. For example, the starch-based polymer may be a mixture of one or more selected from the group consisting of corn starch, dextrin, hydroxypropyl starch phosphate, and sodium polyacrylate starch.

In one embodiment, the content of the starch-based polymer may be greater than 0 to less than 20% by weight based on the total weight of the composition. More specifically, the content of the starch-based polymer may be 0.1 to 15% by weight based on the total weight of the composition. For example, the content of the starch-based polymer is greater than 0 wt%, 0.01 wt% or more, 0.1 wt% or more, 0.5 wt% or more, 1 wt% or more, 2 wt% or more, 3 wt% or more, 4 wt% or more % or more, 5% or more, 6% or more, 7% or more, 8% or more, 9% or more, 10% or more, 11% or more, 12% or more, 13% or more, 14% or more % or more, 15 wt% or more, 16 wt% or more, 17 wt% or more, 18 wt% or more, or 19 wt% or more, and less than 20 wt%, 19 wt% or less, 18 wt% or less, 17 wt% or less, 16% or less, 15% or less, 14% or less, 13% or less, 12% or less, 11% or less, 10% or less, 9% or less, 8% or less, 7% or less, 6% or less, 5% or less, 4% or less, 3% or less, 2% or less, 1% or less, 0.5% or less, 0.4% or less, 0.3% or less, 0.2% or less, or It may be 0.1 wt% or less. If the starch-based polymer is not included, molding may be difficult due to insufficient bonding strength, and if it is 20% by weight or more, storageability and moldability may be affected due to excessively sticky properties.

In one embodiment, the polyol may include at least one selected from the group consisting of glycerin, butylene glycol, propylene glycol, dipropylene glycol, polyethylene glycol, and sorbitol.

In one embodiment, the content of the polyol may be 0.1 to 10% by weight based on the total weight of the composition. For example, the content of the polyol is 0.1 wt% or more, 0.5 wt% or more, 1 wt% or more, 2 wt% or more, 3 wt% or more, 4 wt% or more, 5 wt% or more, 6 wt% or more, 7 wt% or more or more, 8 wt% or more, or 9 wt% or more, and 10 wt% or less, 9 wt% or less, 8 wt% or less, 7 wt% or less, 6 wt% or less, 5 wt% or less, 4 wt% or less, 3 wt% or less, 2 wt% or less, 1 wt% or less, or 0.5 wt% or less. When the content of the polyol is less than 0.1% by weight, it is difficult to form due to insufficient bonding strength, and when the content of the polyol is more than 10% by weight, the bonding strength is excessive, and storage or moldability may be deteriorated.

In one embodiment, the composition may further include a nonionic surfactant. Nonionic surfactants have excellent solubilizing ability of oil components, and can disperse oil particles on the surface of water without agglomeration, which is a characteristic required from the viewpoint of quality such as fragrance and moisture. Therefore, according to one embodiment of the present disclosure, when the foamable solid detergent prepared from the composition is put in lukewarm water, the lipophilic component does not agglomerate on the surface of the water and has excellent compatibility.

In one embodiment, the nonionic surfactant is an alkanolamide-based, amine oxide-based, mono- or poly-saccharide-based, fatty acid ethoxylate-based, PEG-based, polyethylene oxide-polypropylene oxide copolymer, polyethylene oxide- Polypropylene oxide-polyethylene oxide triblock copolymer, polyvinylpyrrolidone, polyoxyethylene alkyl ether (Polyoxyethylene alkyl ether), and may include at least one selected from the group consisting of sorbitan-based.

For example, the nonionic surfactant may be cocamide methyl MEA, alkyl polyglucoside, or polyoxyethylene sorbitan monolaurate.

In one embodiment, the content of the nonionic surfactant may be 0.1 to 5% by weight based on the total weight of the composition, for example, 0.1% by weight or more, 0.3% by weight or more, 0.5% by weight or more, 0.7% by weight or more, 0.9 wt% or more, 1 wt% or more, 2 wt% or more, 3 wt% or more, or 4 wt% or more, and 5 wt% or less, 4 wt% or less, 3 wt% or less, 2 wt% or less, 1.8 wt% % or less, 1.6 wt% or less, 1.4 wt% or less, 1.2 wt% or less, 1 wt% or less, 0.5 wt% or less, or 0.3 wt% or less.

The composition according to an embodiment may further include one or more selected from the group consisting of a pH adjusting agent, an acid, and an oil. When a solid detergent composition comprising a pH adjuster and an acid is added to water, foaming may be exhibited according to a chemical reaction. In view of the above, the composition according to an embodiment may have foamability. In addition, the composition according to an embodiment may further include an oil to provide a moisturizing function. In the present specification, the term 'foaming' means that carbon dioxide gas is generated through a chemical reaction when the composition according to an embodiment of the present disclosure meets water, and the surfactant having a hydrophilic-lipophilic group as a detergent component is water and air It is a concept that is distinct from bubbles or bubbles that are created while being placed at the interface of

In one embodiment, the pH adjusting agent may include sodium bicarbonate.

In one embodiment, the acid may include at least one selected from the group consisting of citric acid, lactic acid, maleic acid, acetic acid, phosphoric acid and tartaric acid.

In one embodiment, the oil is argan oil, olive oil, castor oil, palm oil, avocado oil, almond oil, malt oil, apricot seed oil, colostrum oil, rosehip oil, macadamia nut oil, liquid paraffin, isopropyl myristate, jojoba It may include one or more selected from the group consisting of oil, green tea oil, sunflower seed oil, and grape seed oil.

In one embodiment, the pH adjusting agent includes sodium bicarbonate, and the acid includes at least one selected from the group consisting of citric acid, lactic acid, maleic acid, acetic acid, phosphoric acid and tartaric acid, and the oil is argan oil, olive oil, Castor oil, palm oil, avocado oil, almond oil, malt oil, apricot seed oil, moonflower colostrum oil, rosehip oil, macadamia nut oil, liquid paraffin, isopropyl myristate, jojoba oil, green tea oil, sunflower seed oil, and grape seed oil It may include one or more selected from the group consisting of.

In one embodiment, based on the total weight of the composition, the content of the pH adjusting agent may be 40 to 70% by weight, the content of the acid may be 15 to 45% by weight, and the content of the oil may be 0.01 to 5% by weight can be

For example, the content of the pH adjusting agent may be 40% by weight or more, 45% by weight or more, 50% by weight or more, 55% by weight or more, 60% by weight or more, or 65% by weight or more, 70% by weight or less, 65% by weight or less, 60 wt% or less, 50 wt% or less, 45 wt% or less, 40 wt% or less, or 35 wt% or less.

For example, the content of the acid may be 15 wt% or more, 20 wt% or more, 25 wt% or more, 30 wt% or more, 35 wt% or more, or 40 wt% or more, 45 wt% or less, 40 wt% or less, 35 wt% or less, 30 wt% or less, 25 wt% or less, or 20 wt% or less.

For example, the content of the oil may be 0.01 wt% or more, 0.1 wt% or more, 1 wt% or more, 2 wt% or more, 3 wt% or more, or 4 wt% or more, 5 wt% or less, 4 wt% or less, 3 wt% or less, 2 wt% or less, 1 wt% or less, or 0.1 wt% or less.

In one embodiment, the formulation of the composition may be granular.

In one embodiment, the composition may be composed of particles having a size of 1 μm to 5 mm or more of 90% of the total particles. More specifically, the composition comprises 90% or more, 91% or more, 92% or more, 93% or more, 94% or more, 95% or more, 96% or more, 97% or more, 98% or more, or 99% or more of the total particles. It may be composed of particles having a size of 1 μm to 5 mm. For example, the size of the particles constituting the composition is 1 μm or more, 10 μm or more, 50 μm or more, 100 μm or more, 200 μm or more, 300 μm or more, 400 μm or more, 500 μm or more, 600 μm or more, 700 μm or more, 800 μm or more, 900 μm or more, 1 mm or more, 1.5 mm or more, 2 mm or more, 2.5 mm or more, 3 mm or more, 3.5 mm or more, 4 mm or more, 4.5 mm or more, 4.7 mm or more, or 4.9 mm or more; , 5 mm or less, 4.5 mm or less, 4 mm or less, 3.5 mm or less, 3 mm or less, 2.5 mm or less, 2 mm or less, 1.5 mm or less, 1 mm or less, 900 µm or less, 800 µm or less, 700 µm or less, 600 μm or less, 500 μm or less, 400 μm or less, 300 μm or less, 200 μm or less, 100 μm or less, 50 μm or less, 10 μm or less, or 5 μm or less.

In one embodiment, the composition may be a bathing agent. The bath agent is not limited in size or shape as long as it is a solid formulation. For example, the bath agent may be in a powder form or a lump form. More specifically, the bathing agent may be a bath bomb, bath powder, bubble bomb, bubble bar, or the like.

In the composition according to an embodiment of the present disclosure, if necessary, ingredients included in a general cosmetic composition may be blended. For example, oils and fats, moisturizing agents, emollients, surfactants, organic and inorganic pigments, organic powders, ultraviolet absorbers, preservatives, disinfectants, antioxidants, plant extracts, alcohols, pigments, fragrances, blood circulation promoters, cooling agents, limiting agents (制汗) agents, and the like. In addition, if necessary, functional additives such as water-soluble vitamins, oil-soluble vitamins, polymer peptides, polymer polysaccharides, sphingolipids and seaweed extract may be further included.

In one embodiment, the present disclosure may provide a molded article molded from the moldable solid detergent composition described above. For example, the molded article may be a bath bomb. According to one embodiment, a molded article can be manufactured in a shape or size desired by a customer using the composition. For example, according to customer preference, it can be molded on the spot and manufactured in the same formulation as bath balm, thereby meeting customer needs.

In exemplary embodiments of the present disclosure, there is provided a method for molding a solid detergent, comprising the step of molding by applying pressure to the composition.

As described above, a solid detergent can be molded into a desired shape only by a simple method of applying pressure, so that it can be possible to purchase a solid detergent product that meets the preferences of consumers right on the spot.

In one embodiment, the pressure may be 5 to 100 mbar. For example, the pressure is 5 mbar or more, 7 mbar or more, 10 mbar or more, 13 mbar or more, 16 mbar or more, 19 mbar or more, 22 mbar or more, 25 mbar or more, 28 mbar or more, 30 mbar or more, 35 mbar or more, 40 mbar or more, 45 mbar or more, 50 mbar or more, 55 mbar or more, 60 mbar or more, 65 mbar or more, 70 mbar or more, 75 mbar or more, 80 mbar or more, 85 mbar or more, 90 mbar or more, or 95 mbar or more, 100 mbar or less, 95 mbar or less, 90 mbar or less, 85 mbar or less, 80 mbar or less, 75 mbar or less, 70 mbar or less, 65 mbar or less, 60 mbar or less, 55 mbar or less, 50 mbar or less, 45 mbar or less, 40 mbar or less , 35 mbar or less, 30 mbar or less, 27 mbar or less, 24 mbar or less, 21 mbar or less, 18 mbar or less, 15 mbar or less, 12 mbar or less, 10 mbar or less, or 7 mbar or less. When the pressure is out of the above range, molding may not be performed to match the shape of the mold.

In one embodiment, the step of applying the pressure may be performed at room temperature and atmospheric atmosphere.

In one embodiment, the method may be to mold a solid detergent without using water.

Hereinafter, the present disclosure will be described in more detail through the following examples. However, the following examples are provided only for the purpose of illustration to help the understanding of the present disclosure, and the scope and scope of the present disclosure are not limited thereto.

Example

1. Experimental results for starch-based polymer alone and by content

As prescribed in Table 1 below, the composition was prepared and observed for storage, moldability and foamability. Specifically, after mixing the powder raw materials in a mixer, the liquid raw materials were evenly introduced and mixed again so that there was no agglomeration.

For storage evaluation, put 30 g of the contents in a viscosity bottle and check whether the contents flowed down in a powder state when the viscosity bottle was tilted 45° immediately after preparation / 6 hours / 12 hours at room temperature conditions (n = 6 persons, 1) For the results of dogs, 6 people judged). (See Fig. 1).

Formability evaluation was visually confirmed whether the circular mold was filled with 30 g of the contents and molded at a pressure of 5-100 mbar, without crumbling and maintaining the original shape well (n=6 persons). (See Fig. 2)

For evaluation of foamability, when the molded contents were placed in a transparent container containing lukewarm water, it was visually confirmed whether bubbles were continuously generated as the contents were dissolved (n=6 persons). (See Fig. 3)

Prescription (wt%) 1-1 1-2 1-3 1-4 1-5 1-6 1-7 1-8 1-9 1-10 Sodium Bicarbonate to 100 to 100 Citric acid 30 - Glycerin 5 5 Cocamide Methyl MEA One One Fragrance One One HYDROXYPROPYL STARCH PHOSPHATE 0 5 - - - - 0.1 15 20 5 SODIUM POLYACRYLATE STARCH - - 5 - - - - - - - VP/VA COPOLYMER - - - 5 - - - - - - HYDROXYPROPYL METHYLCELLULOSE - - - - 5 - - - - - CELLULOSE GUM - - - - - 5 - - - - storability o o o x o o o o o o formability x o o x x x o o x x effervescent o o o o o o o o o x

In FIG. 1 , when the storage property is not good (storability X), it can be confirmed that the form is hardened without maintaining the powder state as a result of observing the storage properties of prescriptions 1-4. In addition, in the case of good storability in FIG. 1 (storability O), the storability of prescription 1-2 was observed.

Figure 2 is an image example of the moldability, Table 1 shows whether the moldability. In FIG. 2, good moldability (formability O) is the result of prescription 4-1 in Table 4 below, and poor moldability (formability X) in FIG. 2 is the result of prescription 4-4. Referring to this, when the formability is not good, it can be confirmed that the shape is not maintained and crumbled.

In FIG. 3, when the foaming property is not good (foamability X), it can be confirmed that bubbles due to carbon dioxide gas do not occur as a result of observing the foaming property of prescription 1-10. In addition, in FIG. 3, when the foaming property is good (foamability O), the foaming property of prescription 1-2 is observed.

As a result, it was confirmed that when starch-based polymer was included, storage and moldability were simultaneously satisfied compared to other polymers (VP/VA Copolymer, Hydroxypropyl Methylcellulose / Cellulose Gum). In addition, it can be confirmed that the moldability effect is good when it is less than 20 wt% with respect to the starch-based polymer.

2. Polyol alone and content comparison data

As prescribed in Table 2 below, the composition was prepared and observed for storability, moldability and foamability.

Prescription (wt%) 2-1 2-2 2-3 2-4 2-5 2-6 2-7 Sodium Bicarbonate to 100 Citric acid 30 Hydroxypropyl Starch Phosphate 10 Cocamide Methyl MEA One Fragrance One Glycerin - 5 - - 0.1 10 20 1,3-Butylene Glycol - - 5 - - - - Dipropylene Glycol - - - 5 - - - storability o o o o o o x formability x o o o o o o effervescent o o o o o o o

Referring to Table 2, when 1,3-butylene glycol, dipropylene glycol or glycerin was used in Examples, storage and moldability were excellent, and foamability was also excellent. In one embodiment, when the content of the polyol is 0.1 to 10% by weight, it can be confirmed that the storage and moldability effect is good.

3. Comparison data of surfactant type alone

As prescribed in Table 3 below, the composition was prepared and observed for storage, compatibility and foamability.

For compatibility evaluation, the molded contents were placed in a transparent container containing lukewarm water, and after all the reaction was completed, it was visually checked whether the oil component was agglomerated or uniformly dispersed on the surface of the water (n=6 persons). (See Fig. 4)

Prescription (wt%) 3-1 3-2 3-3 3-4 3-5 Sodium Bicarbonate to 100 Citric acid 30 Hydroxypropyl Starch Phosphate 10 Glycerin 5 Fragrance One COCAMIDE METHYL MEA - One - - - COCAMIDE MEA - - One - - Lauryl Glucoside (LAURYL GLUCOSIDE) - - - One - Nonionic surfactant (DISODIUM LAURYL SULFOSUCCINATE) - - - - One storability o o o o o compatibility x o o o x effervescent o o o o o

4, if compatibility is good (compatibility O) is a composition of 3-2 prescription, and if the compatibility is not good (compatibility X) showing that the oil is separated and agglomerated on the surface, it is a composition of 3-1 prescription to be. As a result of observation, it was confirmed that quality compatibility was good when a nonionic surfactant was used.

4. Comparison data with or without water

As indicated in Table 4 below, the composition was prepared and observed for storability, moldability and foamability.

Prescription (wt%) 4-1 4-2 4-3 4-4 Sodium Bicarbonate to 100 Citric acid 30 Hydroxypropyl Starch Phosphate 10 Glycerin 5 Fragrance One water - 0.5 One 3 storability o o x x formability o o x x effervescent o o o o

As a result of observation, it was confirmed that when water does not enter the composition combination, storage and moldability can be satisfied at the same time.

The present disclosure may provide the following embodiments as an example.

The first embodiment may provide a moldable solid detergent composition comprising a starch-based polymer and a polyol, wherein the starch-based polymer is included in an amount of greater than 0 to less than 20% by weight based on the total weight of the composition. .

A second embodiment may provide the composition according to the first embodiment, wherein the composition has a water retention amount of less than 1% by weight based on the total weight of the composition.

A third embodiment is the first or second embodiment, wherein the starch-based polymer is selected from the group consisting of corn starch, dextrin, hydroxypropyl starch phosphate and sodium polyacrylate starch. It is possible to provide a composition comprising one or more.

The fourth embodiment may provide the composition according to any one of the first to third embodiments, wherein the content of the starch-based polymer is 0.1 to 15% by weight based on the total weight of the composition.

In a fifth embodiment, in any one of the first to fourth embodiments, the polyol is one selected from the group consisting of glycerin, butylene glycol, propylene glycol, dipropylene glycol, polyethylene glycol and sorbitol (Sorbitol) It is possible to provide a composition comprising the above.

A sixth embodiment may provide the composition according to any one of the first to fifth embodiments, wherein the content of the polyol is 0.1 to 10% by weight based on the total weight of the composition.

A seventh embodiment may provide the composition according to any one of the first to sixth embodiments, wherein the composition further comprises a nonionic surfactant.

An eighth embodiment is any one of the first to seventh embodiments, wherein the nonionic surfactant is an alkanolamide-based, amine-oxide-based, mono- or poly-saccharide-based, fatty acid ethoxylate-based, PEG-based, polyethylene oxide-polypropylene oxide copolymer, polyethylene oxide-polypropylene oxide-polyethylene oxide triblock copolymer, polyvinylpyrrolidone, polyoxyethylene alkyl ether-based, and sorbitan-based group It can provide a composition comprising one or more selected from.

A ninth embodiment may provide a composition according to any one of the first to eighth embodiments, wherein the composition further comprises one or more selected from the group consisting of a pH adjuster, an acid, and an oil.

A tenth embodiment is any one of the first to ninth embodiments, wherein the pH adjusting agent comprises sodium bicarbonate, and wherein the acid is selected from the group consisting of citric acid, lactic acid, maleic acid, acetic acid, phosphoric acid and tartaric acid. and wherein the oil is argan oil, olive oil, castor oil, palm oil, avocado oil, almond oil, malt oil, apricot seed oil, moonshine colostrum, rosehip oil, macadamia nut oil, liquid paraffin, iso myristate A composition comprising at least one selected from the group consisting of propyl, jojoba oil, green tea oil, sunflower seed oil, and grape seed oil may be provided.

An eleventh embodiment may provide the composition according to any one of the first to tenth embodiments, wherein the solid detergent has foaming properties.

A twelfth embodiment may provide the composition according to any one of the first to eleventh embodiments, wherein the formulation of the composition is granular.

A thirteenth embodiment provides the composition according to any one of the first to twelfth embodiments, wherein at least 90% of the total particles consist of particles having a size of 1 μm to 5 mm. can

A fourteenth embodiment may provide the composition according to any one of the first to thirteenth embodiments, wherein the composition is a bathing agent.

A fifteenth embodiment may provide a molded article molded from the composition of any one of the first to fourteenth embodiments.

A sixteenth embodiment may provide the molded article according to any one of the first to fifteenth embodiments, wherein the molded article is a bath bomb, bath powder, bubble bomb or bubble bar.

A seventeenth embodiment may provide a method for molding a solid detergent, comprising the step of molding by applying pressure to the composition of any one of the first to fourteenth embodiments.

The eighteenth embodiment may provide a method for molding a solid detergent according to the seventeenth embodiment, wherein the pressure is 5 to 100 mbar.

A nineteenth embodiment may provide a method for molding a solid detergent according to the seventeenth embodiment or the eighteenth embodiment, wherein the step of applying the pressure is performed at room temperature and an atmospheric atmosphere.

A twentieth embodiment can provide the method for molding a solid detergent according to any one of the seventeenth to nineteenth embodiments, wherein the method is for molding a solid detergent without using water.

Claims (20)

Contains starch-based polymers and polyols,
The starch-based polymer is included in an amount of more than 0 to less than 20% by weight based on the total weight of the composition,
A moldable solid detergent composition. According to claim 1,
wherein the composition has a water retention of less than 1% by weight based on the total weight of the composition. According to claim 1,
The starch-based polymer comprises at least one selected from the group consisting of corn starch, dextrin, hydroxypropyl starch phosphate and sodium polyacrylate starch. According to claim 1, wherein the content of the starch-based polymer is 0.1 to 15% by weight based on the total weight of the composition, the composition. According to claim 1,
The polyol comprises at least one selected from the group consisting of glycerin, butylene glycol, propylene glycol, dipropylene glycol, polyethylene glycol and sorbitol (Sorbitol), the composition. According to claim 1,
The content of the polyol is 0.1 to 10% by weight based on the total weight of the composition, the composition. According to claim 1,
The composition further comprises a nonionic surfactant. 8. The method of claim 7,
The nonionic surfactant is an alkanolamide type, amine oxide type, mono- or poly-saccharide type, fatty acid ethoxylate type, PEG type, polyethylene oxide-polypropylene oxide copolymer, polyethylene oxide-polypropylene oxide-polyethylene A composition comprising at least one selected from the group consisting of oxide triblock copolymer, polyvinylpyrrolidone, polyoxyethylene alkyl ether, and sorbitan. According to claim 1,
The composition further comprises one or more selected from the group consisting of a pH adjusting agent, an acid and an oil. 10. The method of claim 9,
The pH adjusting agent comprises sodium bicarbonate,
The acid includes at least one selected from the group consisting of citric acid, lactic acid, maleic acid, acetic acid, phosphoric acid and tartaric acid,
The oils include argan oil, olive oil, castor oil, palm oil, avocado oil, almond oil, malt oil, apricot seed oil, colostrum colostrum, rosehip oil, macadamia nut oil, liquid paraffin, isopropyl myristate, jojoba oil, green tea oil A composition comprising at least one selected from the group consisting of , sunflower seed oil, and grape seed oil. 10. The method of claim 9,
The solid detergent will have foaming properties, the composition. According to claim 1,
The formulation of the composition is granular. According to claim 1,
The composition, wherein at least 90% of the total particles are composed of particles having a size of 1 μm to 5 mm. The composition of claim 1, wherein the composition is a bathing agent. A molded article molded from the composition of any one of claims 1 to 14. The molded article according to claim 15, wherein the molded article is a bath bomb, bath powder, bubble bomb or bubble bar. Claims 1 to 14, comprising the step of molding by applying pressure to the composition of any one of claims 1 to 14, a solid detergent molding method. 18. The method of claim 17,
The pressure is 5 to 100 mbar, solid detergent molding method. 18. The method of claim 17,
The step of applying the pressure is carried out at room temperature and atmospheric atmosphere, solid detergent molding method. 18. The method of claim 17, wherein the method molds a solid detergent without using water.

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