KR20210146653A - Coated steel sheets with high pitting corrosion resistance and the method of the same - Google Patents
Coated steel sheets with high pitting corrosion resistance and the method of the same Download PDFInfo
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 110
- 239000010959 steel Substances 0.000 title claims abstract description 110
- 238000000034 method Methods 0.000 title claims description 22
- 230000007797 corrosion Effects 0.000 title abstract description 12
- 238000005260 corrosion Methods 0.000 title abstract description 12
- 238000007747 plating Methods 0.000 claims abstract description 83
- 239000010410 layer Substances 0.000 claims abstract description 66
- 230000007547 defect Effects 0.000 claims abstract description 52
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 18
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 18
- 239000002344 surface layer Substances 0.000 claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 claims abstract description 14
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 10
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 9
- 239000012535 impurity Substances 0.000 claims abstract description 8
- 238000005096 rolling process Methods 0.000 claims description 46
- 239000011347 resin Substances 0.000 abstract description 5
- 229920005989 resin Polymers 0.000 abstract description 5
- 239000011148 porous material Substances 0.000 description 18
- 239000011701 zinc Substances 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 7
- 238000001816 cooling Methods 0.000 description 7
- 239000011777 magnesium Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 238000012937 correction Methods 0.000 description 3
- 238000005242 forging Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- -1 hydroxide ions Chemical class 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/38—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling sheets of limited length, e.g. folded sheets, superimposed sheets, pack rolling
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/06—Zinc or cadmium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/12—Aluminium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
- C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
- C23C2/40—Plates; Strips
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/38—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling sheets of limited length, e.g. folded sheets, superimposed sheets, pack rolling
- B21B2001/383—Cladded or coated products
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- Mechanical Engineering (AREA)
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- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Thermal Sciences (AREA)
- Metal Rolling (AREA)
- Coating With Molten Metal (AREA)
Abstract
Description
본 발명은 도금강판의 제조에 관한 것으로, 보다 상세하게는 내공식성이 우수한 도금강판 및 그 제조방법에 관한 것이다.The present invention relates to the manufacture of a plated steel sheet, and more particularly, to a plated steel sheet having excellent pitting resistance and a method for manufacturing the same.
용융 도금법으로 제조되는 도금강판은 우수한 내식성 및 경제성을 바탕으로 건축 내외장재, 가전 및 자동차용 강판으로 주로 사용되고 있다.Coated steel sheets manufactured by hot-dip plating are mainly used as steel sheets for interior and exterior building materials, home appliances and automobiles based on their excellent corrosion resistance and economic feasibility.
특히, 도금층에 아연, 알루미늄 및 마그네슘을 포함하는 고내식 도금강판은 해양구조물 및 농축산업용 건자재와 같이 가혹한 부식환경에서 내식성이 요구되는 용도로 그 사용량이 증가되고 있는 추세이다.In particular, the use of highly corrosion-resistant plated steel sheets containing zinc, aluminum and magnesium in the plating layer is increasing for applications requiring corrosion resistance in harsh corrosive environments, such as marine structures and construction materials for agricultural and livestock industries.
그러나 일반 도금강판 3배 이상의 내식성을 가진 고내식 도금강판도 그 제조과정에서 용융 금속이 응고됨에 따라 필연적으로 발생하는 수축 현상에 의해 미세한 핀홀(Pin Hole), 기공(Prosity), 딤플(Dimple) 등의 결함이 도금층 표면에 잔존하며, 이러한 결함은 공식(Pitting Corrosion)을 유발하여 제품 수명 저하의 주요 원인으로 작용한다.However, even with high corrosion-resistance plated steel sheet having
이러한 종래기술의 문제점을 해결하기 위한 기술로서 특허문헌 1 및 특허문헌 2에 기재된 발명을 들 수 있다. 상기 특허문헌 1-2에서는 도금강판 표면에 유기계 또는 무기계 수지를 도포하여 내식성 및 내흑변성을 향상시키는 방법을 개시하고 있으나 공식의 개선효과는 미약하며, 용접성이 저하하고, 수지의 탈락에 의한 환경오염, 금형오염 및 제조 원가 상승의 단점이 있다.As a technique for solving the problems of the prior art, the invention described in
따라서 본 발명의 일측면은 종래기술과는 달리 도금강판 표면에 별도의 유기계 또는 무기계 수지를 도포하지 않고도 내공식성이 우수한 도금강판을 제공하는 것을 목적으로 한다.Accordingly, one aspect of the present invention aims to provide a plated steel sheet having excellent pitting resistance without applying a separate organic or inorganic resin to the surface of the plated steel sheet, unlike the prior art.
또한 본 발명의 다른 측면은 도금강판 표면에 별도의 유기계 또는 무기계 수지를 도포하지 않고도 내공식성이 우수한 도금강판 제조할 수 있는 방법을 제공하는 것을 목적으로 한다.Another aspect of the present invention is to provide a method for manufacturing a coated steel sheet having excellent pitting resistance without applying a separate organic or inorganic resin to the surface of the coated steel sheet.
또한 본 발명에서 이루고자 하는 기술적 과제들은 이상에서 언급한 기술적 과제들에 한정되지 않으며, 언급하지 않은 또 다른 기술적 과제들은 아래의 기재로부터 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자에게 명확하게 이해될 수 있을 것이다.In addition, the technical problems to be achieved in the present invention are not limited to the technical problems mentioned above, and other technical problems not mentioned above are clearly understood by those of ordinary skill in the art to which the present invention belongs from the description below. it could be
본 발명의 일측은, 소지 강판의 일면 또는 양면에 도금층이 형성되어 있는 도금강판에 있어서, 상기 도금층은 Al, Zn, Mg, Si, 및 잔여 불가피한 불순물을 포함하고, Al과 Zn의 합이 도금층 자체 중량%로 60% 이상이며, 상기 도금층의 표층부에, 깊이 2㎛ 이상, 직경 30㎛ 이상의 표면 결함이 면적비 10% 이하로 존재하는 것을 특징으로 하는 내공식성이 우수한 도금강판에 관한 것이다.In one aspect of the present invention, in a plated steel sheet in which a plating layer is formed on one or both surfaces of a base steel sheet, the plating layer includes Al, Zn, Mg, Si, and residual unavoidable impurities, and the sum of Al and Zn is the plating layer itself It is 60% or more by weight, and it relates to a plated steel sheet having excellent pitting resistance, characterized in that surface defects of 2 μm or more and 30 μm or more in diameter are present in an area ratio of 10% or less in the surface layer portion of the plating layer.
본 발명의 다른 측면은, Another aspect of the present invention is
소지 강판을 도금 욕조에 장입하여 그 표면을 도금하는 공정; 및charging the base steel sheet into a plating bath and plating the surface thereof; and
그 표면에 도금층이 형성된 상기 도금 강판을 조질압연하는 공정;을 포함하고, 상기 조질압연 공정에서 도금강판을 20~300℃의 온도 범위에서 3,000~50,000㎫의 압력으로 2회 이상의 다단 조질압연을 실시하는 것을 특징으로 하는 내공식성이 우수한 도금강판의 제조방법에 관한 것이다.A step of temper rolling the plated steel sheet having a plating layer formed on its surface; and, in the temper rolling process, performing multi-stage temper rolling of the plated steel sheet at a temperature of 20 to 300° C. at a pressure of 3,000 to 50,000 MPa. It relates to a method for manufacturing a plated steel sheet excellent in pitting resistance, characterized in that.
상기 도금층은 Al, Zn, Mg, Si, 및 잔여 불가피한 불순물을 포함하고, Al과 Zn의 합이 도금층 자체 중량%로 60% 이상인 것이 바람직하다.The plating layer contains Al, Zn, Mg, Si, and residual unavoidable impurities, and the sum of Al and Zn is preferably 60% or more by weight of the plating layer itself.
상기 소지 강판을 용융 도금 욕조에 침지하여 그 표면에 용융 도금층을 형성하는 것이 바람직하다.It is preferable to immerse the base steel sheet in a hot-dip bath to form a hot-dip plated layer on the surface thereof.
상기 도금층은 소지강판의 일면 또는 양면에 형성될 수 있으며, 편면당 두께를 2~100㎛로 제어함이 바람직하다.The plating layer may be formed on one side or both sides of the base steel sheet, and it is preferable to control the thickness per side to 2 to 100 μm.
상술한 구성의 본 발명에 따르면, 도금강판의 도금층 표층부에, 깊이 2㎛ 이상, 직경 30㎛ 이상의 핀홀, 기공, 딤플 등의 표면결함이 10% 이하의 면적비로 형성되는 내공식성이 우수한 도금강판을 효과적으로 제공할 수 있다.According to the present invention of the above configuration, in the surface layer of the plating layer of the plated steel sheet, surface defects such as pinholes, pores, and dimples with a depth of 2 μm or more and a diameter of 30 μm are formed in an area ratio of 10% or less. can be provided effectively.
도 1은 도금강판의 단면을 나타내는 그림으로서, (a)는 종래 통상적인 조질압연을 거친 도금강판의 도금층 표층부에 조대한 핀홀, 기공, 딤플 등의 표면결함이 잔류하는 경우를, (b)는 본 발명에 따른 다단 조질압연을 거친 도금강판의 도금층 표층부에 그 크기나 분율이 감소한 표면결함이 잔류하는 경우을 나타낸다.
도 2는 도금강판의 실제 표면 사진으로서, (a)는 종래 통상적인 조질압연을 거친 도금강판의 표면결함(d) 사진을, (b)는 본 발명에 따른 다단 조질압연을 거친 도금강판의 표면결함(d) 사진을 나타낸다.
도 3은 복합 부식시험을 거친 도금강판의 실제 표면 사진으로서, (a)는 종래 통상적인 조질압연을 거친 도금강판의 표면공식(p) 발생 사진을, (b)는 본 발명에 따른 다단 조질압연을 거친 도금강판의 표면공식(p) 발생 사진을 나타낸다.1 is a diagram showing a cross-section of a plated steel sheet, (a) is a case in which surface defects such as coarse pinholes, pores, dimples, etc. remain in the surface layer of the plated layer of a plated steel sheet that has undergone conventional temper rolling, (b) is It shows a case in which surface defects with reduced size or fraction remain in the surface layer of the plating layer of the plated steel sheet subjected to multi-stage temper rolling according to the present invention.
2 is a photograph of the actual surface of a plated steel sheet, (a) is a photograph of surface defects (d) of a plated steel sheet subjected to conventional temper rolling, (b) is a surface of a plated steel sheet subjected to multi-stage temper rolling according to the present invention. Defect (d) shows a picture.
3 is a photograph of the actual surface of a plated steel sheet that has undergone a complex corrosion test, (a) is a photograph of surface pitting (p) of a plated steel sheet that has undergone conventional temper rolling, (b) is a multi-stage temper rolling according to the present invention; The photo shows the surface pitting (p) occurrence of the plated steel sheet that has been subjected to
이하, 본 발명을 설명한다.Hereinafter, the present invention will be described.
종래 도금강판의 경우, 그 제조과정에서 용융 금속이 응고됨에 따라 필연적으로 발생하는 수축 현상에 의해 미세한 핀홀, 기공, 딤플 등의 결함이 도금층 표면에 잔존하며, 이러한 결함이 공식을 유발하는 문제가 발생함은 전술한 바와 같다. 따라서 본 발명자들은 이러한 종래기술의 문제점을 해소하기 위하여, 연구를 거듭하였으며, 그 결과, 도금강판을 도금층 형성 직후에 조질압연하는 단계에서 2회 이상 다단 조질압연하여, 도금층 표층부의 핀홀, 기공, 딤플 등의 결함을 제거함으로써 가혹한 부식환경에서도 내공식성이 우수한 도금강판을 제조할 수 있음을 확인하고 본 발명을 제시하는 것이다.In the case of conventional plated steel sheets, defects such as fine pinholes, pores, and dimples remain on the surface of the plating layer due to the shrinkage phenomenon that inevitably occurs as the molten metal solidifies during the manufacturing process, and these defects cause pitting. Ham is the same as described above. Therefore, the present inventors repeated research in order to solve the problems of the prior art, and as a result, in the step of temper rolling the plated steel sheet immediately after forming the plating layer, multi-stage temper rolling was performed twice or more, and pinholes, pores, and dimples in the surface layer of the plating layer The present invention is presented by confirming that a plated steel sheet having excellent pitting resistance can be manufactured even in a severe corrosive environment by removing defects such as.
따라서 본 발명의 내공식성이 우수한 도금강판은, 소지 강판의 일면 또는 양면에 도금층이 형성되어 있는 도금강판에 있어서, 상기 도금층은 Al, Zn, Mg, Si, 및 잔여 불가피한 불순물을 포함하고, Al과 Zn의 합이 도금층 자체 중량%로 60% 이상이며, 상기 도금층의 표층부에, 깊이 2㎛ 이상, 직경 30㎛ 이상의 표면 결함이 면적비 10% 이하로 존재하는 것을 특징으로 한다.Therefore, in the plated steel sheet having excellent pitting resistance of the present invention, in the plated steel sheet having a plating layer formed on one or both sides of the base steel sheet, the plating layer contains Al, Zn, Mg, Si, and residual unavoidable impurities, Al and The sum of Zn is 60% or more by weight% of the plating layer itself, and surface defects of 2 μm or more and 30 μm or more in diameter are present in the surface layer of the plating layer in an area ratio of 10% or less.
이하, 첨부도면을 참조하여 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.
도 1은 도금강판의 단면을 나타내는 그림으로서, (a)는 종래 통상적인 조질압연을 거친 도금강판의 도금층 표층부에 조대한 핀홀, 기공, 딤플 등의 표면결함이 잔류하는 경우를, (b)는 본 발명에 따른 다단 조질압연을 거친 도금강판의 도금층 표층부에 그 크기나 분율이 감소한 표면결함이 잔류하는 경우을 나타낸다.1 is a diagram showing a cross-section of a plated steel sheet, (a) is a case in which surface defects such as coarse pinholes, pores, dimples, etc. remain in the surface layer of the plated layer of a plated steel sheet that has undergone conventional temper rolling, (b) is It shows a case where surface defects with reduced size or fraction remain in the surface layer of the plating layer of the plated steel sheet subjected to multi-stage temper rolling according to the present invention.
도 1(a)에 나타난 바와 같이, 종래의 도금강판의 경우, 소지강판(1)과 도금층(5) 사이에 경질의 합금층(3)을 포함하고, 상기 도금층(5) 표층부에 조대한 핀홀, 기공, 딤플 등의 표면결함(7)이 형성되어 있는 구조로 되어 있다. 이러한 표면 결함(7)은 도금공정에서 용융 금속이 응고됨에 따라 필연적으로 발생하는 수축 현상에 의해 형성되어 진다. As shown in Fig. 1 (a), in the case of a conventional plated steel sheet, a
이에 반하여, 본 발명의 다단 조질압연을 이용하는 도금강판의 경우, 도 1(b)와 같이, 표층부 결함(17)의 크기가 작고 분율이 낮게 형성되어 있다. 구체적으로, 본 발명의 도금강판의 구조를 살펴보면 다음과 같다.In contrast, in the case of the plated steel sheet using the multi-stage temper rolling of the present invention, as shown in FIG. 1( b ), the size of the surface layer defects 17 is small and the fraction is formed low. Specifically, looking at the structure of the plated steel sheet of the present invention is as follows.
먼저, 본 발명의 도금강판은 소지강판(11)을 포함한다. 본 발명에서 상기 소지강판(11)으로 탄소강 등을 이용함이 바람직하나 이에 제한되지 않으며 다양한 성분조성을 갖는 소재를 이용할 수 있다.First, the plated steel sheet of the present invention includes a base steel sheet (11). In the present invention, it is preferable to use carbon steel or the like as the
또한 본 발명의 도금강판은, 상기 소지강판(11)과 도금층(15) 사이에 형성된 경질의 합금층(13)을 포함한다. 이러한 경질의 합금층(13)은 도금층을 이루는 성분 금속과 소지 철 성분과의 반응 등에 의해 형성되는 금속간화합물로 이루어져 있다. In addition, the plated steel sheet of the present invention includes a hard alloy layer (13) formed between the base steel sheet (11) and the plating layer (15). The
한편 본 발명에서 상기 도금층(15)는 상기 소지강판(11)의 일면 또는 양면에 형성될 수 있으며, 편면당 2~100㎛의 두께를 가질 수 있다. 또한 상기 도금층(15)은 Al, Zn, Mg, Si, 및 잔여 불가피한 불순물을 포함하고, Al과 Zn의 합이 도금층 자체 중량%로 60% 이상으로 조성되어 있음이 바람직하다. Meanwhile, in the present invention, the
그리고 발명에서는 도 1(b)와 같이, 상기 도금층(15)의 표층부는 표면결함(17)을 가질 수 있다. And in the present invention, as shown in Figure 1 (b), the surface layer portion of the
전술한 바와 같이, 종래 통상적인 조질압연을 거친 도금강판의 경우, 도금층(5) 표층부에 조대한 핀홀, 기공, 딤플 등의 결함(7)이 형성되어 있다. 이에 대하여, 본원발명은 도금강판의 표면에 2회 이상의 다단 조질압연을 실시함으로써 표면결함(17)의 크기 및 분율이 현저히 감소된 도금강판을 제공함을 특징으로 한다. 이러한 다단 조질압연을 통하여 상기 표면결함(17)의 크기 및 분율이 감소되어, 부식을 유발하는 이온이 상기 표면결함(17)부위에 농화되는 것을 방지함으로써 내공식성을 향상시키는 작용을 할 수 있는 것이다. As described above, in the case of a plated steel sheet that has undergone conventional temper rolling, defects 7 such as coarse pinholes, pores, and dimples are formed in the surface layer portion of the
구체적으로, 본 발명에서는 상기 도금층(15)의 표층부에, 깊이 2.0㎛ 이상, 직경 30㎛ 이상의 표면 결함이 면적비 10% 이하로 존재하는 것이 바람직하며, 보다 더 바람직하게는 5% 이하, 가장 바람직하게는, 1% 이하의 면적비를 가지도록 하는 것이다. . Specifically, in the present invention, in the surface layer portion of the
도 2는 도금강판의 실제 표면 사진으로서, (a)는 종래 통상적인 조질압연을 거친 도금강판의 표면결함(d) 사진을, (b)는 본 발명에 따른 다단 조질압연을 거친 도금강판의 표면결함(d) 사진을 나타낸다. 구체적으로, 도 2(a)는 그 깊이가 2㎛ 이상이고 직경이 30㎛이상인 핀홀, 기공, 딤플 등과 같은 표면결함(d)을 10%를 초과하는 면적비로 포함하는 경우인 통상적인 조질압연을 거친 도금강판의 표면결함(d) 사진을 나타내며, 도 2(b)는 그 깊이가 2㎛ 미만, 직경 30㎛ 미만인 핀홀, 기공, 딤플 등과 같은 표면결함(d)을 10% 이하의 면적비로 제어된 경우인 본 발명에 따른 다단조질압연을 거친 도금강판의 표면결함(d) 사진을 나타낸다2 is a photograph of the actual surface of a plated steel sheet, (a) is a photograph of surface defects (d) of a plated steel sheet subjected to conventional temper rolling, (b) is a surface of a plated steel sheet subjected to multi-stage temper rolling according to the present invention. Defect (d) shows a picture. Specifically, FIG. 2(a) shows a typical temper rolling that includes surface defects (d), such as pinholes, pores, dimples, etc. having a depth of 2 μm or more and a diameter of 30 μm or more, in an area ratio exceeding 10%. A photograph of surface defects (d) of a rough plated steel sheet is shown, and FIG. 2(b) is control of surface defects (d) such as pinholes, pores, dimples, etc. with a depth of less than 2 μm and a diameter of less than 30 μm with an area ratio of 10% or less. A photograph of surface defects (d) of a plated steel sheet subjected to multi-forging temper rolling according to the present invention is shown.
한편 도 3은 복합 부식시험을 거친 도금강판의 실제 표면 사진으로서, (a)는 종래 통상적인 조질압연을 거친 도금강판의 표면공식(p) 발생 사진을, (b)는 본 발명에 따른 다단 조질압연을 거친 도금강판의 표면공식(p) 발생 사진을 나타낸다. 도 3(a)에 나타난 바와 같이, 그 깊이가 2㎛ 이상이고 직경이 30㎛이상인 핀홀, 기공, 딤플 등과 같은 표면결함을 10%를 초과하는 면적비로 포함하는 경우로서, 부식환경에서 수산화이온(OH-), 염화이온(Cl-) 등이 쉽게 결함 부위에 농화되어 공식(p)을 유발함을 알 수 있으며, 이는 본 발명에 따른 다단 조질압연을 거친 도금강판의 표면공식(p) 발생 사진을 나타내는 도 3(b)와 대비된다. Meanwhile, FIG. 3 is a photograph of the actual surface of a plated steel sheet that has undergone a complex corrosion test, (a) is a photograph of surface pitting (p) of a plated steel sheet that has undergone conventional temper rolling, and (b) is a multi-stage tempering according to the present invention. The photo shows the surface pitting (p) occurrence of the plated steel sheet that has undergone rolling. As shown in Fig. 3(a), in the case of including surface defects such as pinholes, pores, dimples, etc. having a depth of 2 μm or more and a diameter of 30 μm or more in an area ratio exceeding 10%, hydroxide ions ( It can be seen that OH - ), chloride ions (Cl - ), etc. are easily concentrated in the defect site to cause pitting (p), which is a photo of surface pitting (p) occurrence of plated steel sheet subjected to multi-stage temper rolling according to the present invention Contrasted with Figure 3 (b) showing.
다음으로, 본 발명의 일실시예에 따른 내공식성이 우수한 도금강판 제조방법을 설명한다.Next, a method for manufacturing a plated steel sheet having excellent pitting resistance according to an embodiment of the present invention will be described.
본 발명의 도금강판 제조방법은, 소지 강판을 도금 욕조에 장입하여 그 표면을 도금하는 공정; 및 그 표면에 도금층이 형성된 상기 도금 강판을 조질압연하는 공정;을 포함하고, 상기 조질압연 공정에서 도금강판을 20~300℃의 온도 범위에서 3,000~50,000㎫의 압력으로 2회 이상의 다단 조질압연을 실시하는 것을 특징으로 하다. The method for manufacturing a plated steel sheet of the present invention comprises the steps of charging a base steel sheet into a plating bath and plating the surface; and a step of temper rolling the plated steel sheet having a plating layer formed on the surface thereof; in the temper rolling process, the plated steel sheet is subjected to multi-stage temper rolling at a temperature of 20 to 300° C. at a pressure of 3,000 to 50,000 MPa. It is characterized in that it is carried out.
본 발명의 일실시예에 따른 용융도금법을 이용한 도금강판 제조공정은 대략, 소지강판의 전처리, 열처리, 도금, 다단조질압연, 형상교정, 후처리 등의 과정을 거칠 수 있다.The plated steel sheet manufacturing process using the hot-dip plating method according to an embodiment of the present invention can roughly undergo processes such as pre-treatment, heat treatment, plating, multi-forging tempering rolling, shape correction, post-treatment of the base steel sheet.
본 발명에서는 소지강판을 도금조에 침지하여 도금을 행하기 전에, 필요에 따라 소지강판의 표면을 세척하는 전처리 공정을 거칠 수도 있으며, 이는 화학적, 물리적 또는 전기화학적 방법을 사용할 수 있다.In the present invention, before plating by immersing the base steel sheet in a plating bath, if necessary, a pretreatment process of washing the surface of the base steel sheet may be performed, which may be chemical, physical or electrochemical method.
그리고 상기 전처리된 소지 강판을 필요에 따라 가열하는 열처리공정을 행할 수도 있으며, 이는 강판에 사용 목적에 적합한 기계적 성질을 부여함과 아울러, 후속하는 용융도금공정에 용융상태의 도금물질과 동일한 온도를 유지하여 균일한 도금이 가능하게 하기 위함이다.In addition, a heat treatment process of heating the pre-treated base steel sheet may be performed as needed, which imparts mechanical properties suitable for the purpose of use to the steel sheet, and maintains the same temperature as the plating material in the molten state in the subsequent hot-dip plating process This is to enable uniform plating.
이어, 본 발명에서는 상기 전처리 등이 된 소지강판을 도금조 등에 침지하여 소지 강판의 표면을 코팅함으로써 소지 강판의 표면에 도금층을 형성한다.Next, in the present invention, a plating layer is formed on the surface of the base steel plate by coating the surface of the base steel plate by immersing the base steel sheet subjected to the pretreatment, etc. in a plating bath.
본 발명에서는 상기 도금하는 방법으로 용융도금법을 이용할 수 있다. .In the present invention, a hot-dip plating method may be used as the plating method. .
상기 도금을 통하여 형성된 도금층은 Al, Zn, Mg, Si, 및 잔여 불가피한 불순물을 포함하고, Al과 Zn의 합이 도금층 자체 중량%로 60% 이상인 것이 바람직하다. 왜냐하면, Al과 Zn는 도금층의 주성분으로 그 합이 60% 미만이면 Al의 부동태피막과 Zn의 희생방식에 의한 내식성을 충분히 확보할 수 없기 때문이다.The plating layer formed through the plating includes Al, Zn, Mg, Si, and residual unavoidable impurities, and the sum of Al and Zn is preferably 60% or more by weight% of the plating layer itself. This is because Al and Zn are the main components of the plating layer, and if the sum is less than 60%, it is not possible to sufficiently secure the corrosion resistance by the passivation film of Al and the sacrificial method of Zn.
이후, 본 발명에서는 상기 도금층이 형성된 도금강판을 다단 조질압연한다.Then, in the present invention, the plated steel sheet on which the plating layer is formed is subjected to multi-stage temper rolling.
종래에는 도금조로부터 배출된 도금강판의 도금층의 표면사상 조정과 항복점연신을 제거하기 위하여 상온에서 1회 조질압연을 실시하였으나, 본 발명에서는 상기 목적에 더하여 핀홀, 기공, 딤플 등의 결함을 물리적으로 제거하기 위하여 조질압연장치에 압연롤을 추가하여 고압으로 2회 이상 조질압연하는 것을 특징으로 한다.Conventionally, temper rolling was performed once at room temperature to adjust the surface finish of the plating layer of the plated steel sheet discharged from the plating bath and remove the yield point elongation, but in the present invention, in addition to the above object, defects such as pinholes, pores, and dimples are physically eliminated It is characterized in that by adding a rolling roll to the temper rolling device to remove it, the temper rolling is performed at high pressure twice or more.
구체적으로, 본 발명에서는 상기 다단 조질압연 온도 범위를 20~300℃로 제어하는 것이 바람직하다. 만일 다단 조질압연 온도가 20℃미만이면, 냉간 취성의 증가로 핀홀, 기공, 딤플 등의 결함을 충분히 제거할 수 없으며, 300℃를 초과하면 도금층이 합금화되어 취성이 증가하는 현상이 나타날 수 있다.Specifically, in the present invention, it is preferable to control the multi-stage temper rolling temperature range to 20 ~ 300 ℃. If the multi-stage temper rolling temperature is less than 20 ° C, defects such as pinholes, pores, and dimples cannot be sufficiently removed due to an increase in cold brittleness, and if it exceeds 300 ° C, the plating layer is alloyed and brittleness increases.
한편, 본 발명에서는 상기 온도 범위를 유지하기 위하여 수냉장치를 이용하여 냉각하였으나 냉각방법으로서 수냉 또는 공냉방식 등을 모두 이용할 수 있으며, 특정한 냉각방법에 제한되지 않는다.Meanwhile, in the present invention, in order to maintain the above temperature range, cooling is performed using a water cooling device, but water cooling or air cooling may be used as a cooling method, and the cooling method is not limited to a specific cooling method.
또한, 본 발명에서는 상기 다단 조질압연 압력을 3,000~50,000㎫로 제어함이 바람직하다. 만일 상기 다단 조질압연 압력이 3,000㎫ 미만이면, 표면사상과 항복점연신을 제어할 수 없고, 핀홀, 기공, 딤플 등의 결함을 충분히 제거할 수 없으며, 50,000㎫을 초과하면 가공경화가 발생하여 요구사양에 적합한 기계적성질을 확보하기 어려울 수 있다.In addition, in the present invention, it is preferable to control the multi-stage temper rolling pressure to 3,000 ~ 50,000 MPa. If the multi-stage temper rolling pressure is less than 3,000 MPa, surface finish and yield point elongation cannot be controlled, and defects such as pinholes, pores, and dimples cannot be sufficiently removed. It may be difficult to secure suitable mechanical properties for
또한 상기 다단 조질압연된 도금강판의 도금층 표층부에는, 핀홀, 기공, 딤플 등의 표면결함이 존재할 수 있으며, 상기 표면결함은 2㎛ 이상의 깊이와 30㎛ 이상의 직경을 가진 것들도 존재할 수 있다. In addition, surface defects such as pinholes, pores, and dimples may exist in the surface layer portion of the plating layer of the multi-stage temper rolling plated steel sheet, and the surface defects may have a depth of 2 μm or more and a diameter of 30 μm or more.
본 발명에서 2㎛ 이상의 깊이와 30㎛ 이상의 직경을 가진 표면결함이 10% 이하의 면적비를 갖도록 제어하는 것이 보다 바람직하며, 보다 더 바람직하게는 5% 이하, 가장 바람직하게는, 1% 이하의 면적비를 가지는 것이다.In the present invention, it is more preferable to control so that surface defects having a depth of 2 μm or more and a diameter of 30 μm or more have an area ratio of 10% or less, even more preferably 5% or less, and most preferably, an area ratio of 1% or less will have
후속하여, 본 발명에서는 필요에 따라 형상교정기를 이용하여 도금강판의 반곡 등의 결함을 교정하는 형상교정 공정을 거칠 수도 있다. Subsequently, in the present invention, if necessary, a shape correction process of correcting defects such as curvature of the plated steel sheet using a shape corrector may be performed.
나아가 상기 형상교정 공정 이후, 필요에 따라 도금 강판상에 일시방청제 등을 요구 사양에 맞게 도포할 수도 있으며, 이어, 운반 및 취급이 용이하도록 생산된 도금강판 제품을 포장할 수 있다.Furthermore, after the shape correction process, if necessary, a temporary rust preventive agent may be applied on the plated steel sheet according to the required specifications, and then, the plated steel sheet product produced may be packaged for easy transport and handling.
이하, 실시예를 통하여 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail through examples.
(실시예)(Example)
용융 도금 모사장치를 이용하여 두께가 1.0mm인 판재 형태의 강판을 각각 마련하였다. 상기와 같이 마련된 강판들을, Al, Zn, Mg 및 Si를 포함하고, Al+Zn의 자체 중량비(%)가 하기 표 1같이 제어된 용융도금조에 침지한 후, 꺼내어 그 표면에 용융도금층이 형성된 도금강판을 제조하였다.A plate-shaped steel plate having a thickness of 1.0 mm was prepared using a hot-dip plating simulation device, respectively. The steel sheets prepared as described above, containing Al, Zn, Mg and Si, were immersed in a hot-dip plating bath in which the Al+Zn own weight ratio (%) is controlled as shown in Table 1 below, and then taken out and a hot-dip plating layer is formed on the surface. A steel plate was prepared.
이후, 상기와 같이 제조된 각각의 도금강판을 하기 표 1과 같은 조건으로 다단 조질압연하여 도금층 표층부에 핀홀, 기공, 딤플 등의 표면결함이 감소한 도금강판을 얻었다.Thereafter, each of the plated steel sheets prepared as described above was subjected to multi-stage temper rolling under the conditions shown in Table 1 to obtain a plated steel sheet having reduced surface defects such as pinholes, pores, and dimples in the surface layer of the plating layer.
이렇게 얻어진 도금강판의 내공식성을 평가하기 위하여 핀홀, 기공, 딤플 등의 표면결함을 주사전자현미경을 이용하여 촬영하고 표면결함의 깊이, 직경 및 면적비를 화상 분석기를 이용하여 측정하였다.To evaluate the pitting resistance of the plated steel sheet thus obtained, surface defects such as pinholes, pores, and dimples were photographed using a scanning electron microscope, and the depth, diameter, and area ratio of the surface defects were measured using an image analyzer.
또한, 결함의 감소에 따른 내공식성을 평가하기 위하여 KS D 9502 시험표준에 의거 중성염수분무시험을 240시간 동안 실시하고 화상분석기를 이용하여 공식 부위 면적을 측정하였으며, 그 평가 결과를 하기 표 2에 나타내었다.In addition, in order to evaluate the pitting resistance according to the reduction of defects, a neutral salt spray test was conducted for 240 hours according to the KS D 9502 test standard, and the area of the pitting area was measured using an image analyzer, and the evaluation results are shown in Table 2 below. indicated.
상기 표 1 및 표 2에 나타난 바와 같이, 도금층 성분과 다단 조질압연 조건이 본 발명의 범위를 만족하는 발명예 1-2는 도금층 표층부에 소정의 면적비와 크기를 갖는 표면결함이 형성되어 내공식성이 우수함을 알 수 있다.As shown in Tables 1 and 2, in Inventive Example 1-2, in which the plating layer components and the multi-stage temper rolling conditions satisfy the scope of the present invention, surface defects having a predetermined area ratio and size are formed in the surface layer of the plating layer, so that pitting resistance is reduced. can be seen to be excellent.
즉, 본 발명예에서 깊이 2㎛ 이상, 직경 30㎛ 이상의 핀홀, 기공, 딤플 등의 표면결함의 면적비가 10% 이하로 종래예 대비 1/8로 감소함에 따라 공식 면적도 1/5로 감소되어 종래예 대비 우수한 내공식성을 가짐을 알 수 있다.That is, in the example of the present invention, as the area ratio of surface defects such as pinholes, pores, and dimples with a depth of 2 μm or more and a diameter of 30 μm or more was reduced to 1/8 compared to the conventional example by 10% or less, the pit area was also reduced to 1/5. It can be seen that it has excellent pitting resistance compared to the conventional example.
이에 반하여, 종래예와 동일한 방법으로 도금하면 도금층의 Al, Zn의 합이 중량비 60% 이상인 경우에도 공식 현상을 유발하는 표면결함이 도금층 표면에 다수 잔존함을 확인할 수 있다.On the other hand, when plating is performed in the same manner as in the prior art, it can be confirmed that many surface defects that cause pitting remain on the surface of the plating layer even when the sum of Al and Zn in the plating layer is 60% or more by weight.
또한 비교예 1 내지 비교예 3에서는 도금층 성분, 다단조질압연 조건이 본 발명의 범위를 벗어나 결함이 충분히 제거되지 않았으며, 내공식성도 열위함을 확인할 수 있다.In addition, in Comparative Examples 1 to 3, it can be seen that the plating layer component and the multi-forging temper rolling condition were not sufficiently removed, and defects were not sufficiently removed outside the scope of the present invention, and the pitting resistance was also inferior.
이상에서 설명한 바와 같이, 본 발명의 상세한 설명에서는 본 발명의 바람직한 실시 예에 관하여 설명하였으나, 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자라면 본 발명의 범주에서 벗어나지 않는 한도 내에서 여러 가지 변형이 가능함은 물론이다. 따라서 본 발명의 권리 범위는 설명된 실시 예에 국한되어 정해져서는 안 되며, 후술하는 청구범위뿐만 아니라, 이와 균등한 것들에 의해 정해져야 한다.As described above, in the detailed description of the present invention, preferred embodiments of the present invention have been described, but those of ordinary skill in the art to which the present invention pertains may make various modifications without departing from the scope of the present invention. Of course, this is possible. Therefore, the scope of the present invention should not be limited to the described embodiments, but should be defined by the claims to be described later as well as equivalents thereof.
Claims (8)
상기 도금층은 Al, Zn, Mg, Si, 및 잔여 불가피한 불순물을 포함하고, Al과 Zn의 합이 도금층 자체 중량%로 60% 이상이며, 상기 도금층의 표층부에, 깊이 2㎛ 이상, 직경 30㎛ 이상의 표면결함이 면적비 10% 이하로 존재하는 것을 특징으로 하는 내공식성이 우수한 도금강판.
In a plated steel sheet having a plating layer formed on one or both sides of the base steel sheet,
The plating layer contains Al, Zn, Mg, Si, and residual unavoidable impurities, and the sum of Al and Zn is 60% or more by weight of the plating layer itself. A plated steel sheet with excellent pitting resistance, characterized in that surface defects exist in an area ratio of 10% or less.
The plated steel sheet having excellent pitting resistance according to claim 1, wherein the plating layer may be formed on one side or both sides of the base steel sheet, and the thickness per side is controlled to be 2 to 100 µm.
The plated steel sheet having excellent pitting resistance according to claim 1, wherein the plated steel sheet is a hot-dip plated steel sheet.
그 표면에 도금층이 형성된 상기 도금 강판을 조질압연하는 공정;을 포함하고, 상기 조질압연 공정에서 도금강판을 20~300℃의 온도 범위에서 3,000~50,000㎫의 압력으로 2회 이상의 다단 조질압연을 실시하는 것을 특징으로 하는 내공식성이 우수한 도금강판의 제조방법.
charging the base steel sheet into a plating bath and plating the surface thereof; and
A step of temper rolling the plated steel sheet having a plating layer formed on its surface; and, in the temper rolling process, the plated steel sheet is subjected to multi-stage temper rolling twice or more at a temperature of 20 to 300° C. and at a pressure of 3,000 to 50,000 MPa. A method of manufacturing a plated steel sheet having excellent pitting resistance, characterized in that
[Claim 5] The plated steel sheet having excellent pitting resistance according to claim 4, wherein the plating layer contains Al, Zn, Mg, Si, and residual unavoidable impurities, and the sum of Al and Zn is 60% or more by weight% of the plating layer itself. manufacturing method.
[Claim 5] The method of claim 4, wherein the base steel sheet is immersed in a hot-dip bath to form a hot-dip plated layer on the surface thereof.
[Claim 5] The method of claim 4, wherein the plating layer may be formed on one side or both sides of the base steel sheet, and the thickness per side is controlled to be 2 to 100 µm.
[Claim 5] The plating with excellent pitting resistance according to claim 4, wherein, in the multi-stage temper rolling plated steel sheet, surface defects having a depth of 2 μm or more and a diameter of 30 μm or more are formed in an area ratio of 10% or less in the surface layer of the plating layer. A method for manufacturing a steel plate.
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| KR20020040437A (en) * | 2000-11-24 | 2002-05-30 | 이구택 | method of manufacturing a hot-rolled galvanized steel sheets with excellent surfaceappearance |
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| KR101560947B1 (en) | 2013-12-24 | 2015-10-15 | 주식회사 포스코 | SURFACE TREATMENT COMPOSITION HAVING EXCELLENT CORROSION RESISTANCE AND BLACKENING RESISTANCE AND METHOD FOR PREPARING SURFACE TREATED Zn-Al-Mg ALLOY PLATED STEEL SHEET USING THE SAME |
| KR20190032364A (en) * | 2016-07-20 | 2019-03-27 | 타타 스틸 이즈무이덴 베.뷔. | Method and coating for providing a Zn-Al-Mg coating |
| KR20200012938A (en) | 2017-06-01 | 2020-02-05 | 닛테츠 닛신 세이코 가부시키가이샤 | High strength Zn-Al-Mg surface coated steel sheet and manufacturing method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR20020040437A (en) * | 2000-11-24 | 2002-05-30 | 이구택 | method of manufacturing a hot-rolled galvanized steel sheets with excellent surfaceappearance |
| KR20080109935A (en) * | 2006-05-15 | 2008-12-17 | 티센크루프 스틸 악티엔게젤샤프트 | Process for producing a sheet steel product coated with an anticorrosion system |
| KR101560947B1 (en) | 2013-12-24 | 2015-10-15 | 주식회사 포스코 | SURFACE TREATMENT COMPOSITION HAVING EXCELLENT CORROSION RESISTANCE AND BLACKENING RESISTANCE AND METHOD FOR PREPARING SURFACE TREATED Zn-Al-Mg ALLOY PLATED STEEL SHEET USING THE SAME |
| KR20190032364A (en) * | 2016-07-20 | 2019-03-27 | 타타 스틸 이즈무이덴 베.뷔. | Method and coating for providing a Zn-Al-Mg coating |
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