KR20210058106A - Purification method of hydrogen produced through hydroelectrolysis using palladium-containing hydrogen separation membrane - Google Patents

Abstract

The present invention provides a method for producing hydrogen, which comprises: a first step of decomposing water to produce hydrogen; a second step of injecting an inert gas into the hydrogen and oxygen-containing by-product gas produced in the first step; and a third step of separating a mixed gas containing hydrogen and oxygen with a palladium-based hydrogen separation membrane and purifying the mixed gas into high-purity hydrogen, wherein the hydrogen concentration of residual gas that has not passed through the separation membrane is set to be lower than a hydrogen explosion concentration by controlling the inert gas injected in the second step. The method of the present invention, when supplying electrolyzed hydrogen to a separation membrane purifier, supplies the inert gas to prevent the risk of explosion.

Description

Purification method of hydrogen produced through hydroelectrolysis using palladium-containing hydrogen separation membrane

The present invention relates to a method for purifying water electrolytic hydrogen using a hydrogen separation membrane containing palladium.

Hydrogen is attracting attention as a major energy source in the future that can replace existing energy, because it is lightweight, abundant, and excellent in terms of the environment. H ₂ is used as a raw material for chemical synthesis, as a reducing gas in the semiconductor manufacturing process, and as a fuel cell fuel.

Water is an ideal source of hydrogen with reproducibility that can be used repeatedly as hydrogen and oxygen.

Water decomposition hydrogen production technology includes a photochemical method using a photocatalyst, a biological method using microorganisms, etc., a solar thermal chemistry and an electrolysis method. Among them, there is a water electrolysis method that uses renewable energy sources such as solar and wind energy, or uses existing nuclear energy to generate power, and uses this power and late-night power to decompose water to produce hydrogen.

The technology for producing hydrogen from pure water using electric energy is divided into alkaline water electrolysis, solid polymer electrolyte (PEM) water electrolysis, and high-temperature steam electrolysis technology using solid oxides. Alkaline water electrolysis technology is a technology that uses an alkaline aqueous solution (KOH, etc.) as an electrolyte and a separate membrane to separate hydrogen/oxygen, and is characterized by having an operating condition of 100°C or less, and is characterized by having a solid polymer electrolyte (PEM). The water electrolysis technology is a technology that uses a solid polymer electrolyte (PEM) membrane as an electrolyte and a separator, and is characterized by having an operating condition of 200°C or less depending on the stability of the polymer membrane. In addition, the high-temperature steam electrolysis technology using a solid oxide is a technology that uses an oxide film having hydrogen or oxygen ion conductivity as an electrolyte and a separator, and is characterized by having a high temperature operating condition of 700 to 900°C. However, among the low-temperature water electrolysis methods, alkaline electrolysis is inexpensive, but because it operates at a low current density (the device is 10 times larger than PEM), it is expected to be more disadvantageous than PEM in the future price and performance competition. This is being done.

The cost of producing hydrogen by water electrolysis is determined by the price of the electrolyzer and the power cost. Electrolyzed hydrogen is three times more expensive than the cost of producing hydrogen using fossil fuels, and this difference cannot be overcome only by improving the efficiency of the electrolyzer, and can be overcome by lowering the cost of electricity supplied to electrolysis.

As the hydrogen market expands to the field of distributed power using fuel for fuel cell vehicles and renewable power, the electrolyzer field will play a huge role in the hydrogen economy. In the hydrogen market as a fuel for automobiles, water electrolysis competes with a reforming method that produces hydrogen by reforming inexpensive hydrocarbons, but it is advantageous in competition because it produces hydrogen with low carbon traces in the presence or absence of a carbon-footprint. Although the electric energy supplied to water electrolysis has carbon traces, water electrolysis can produce hydrogen with low carbon traces because it can be linked with renewable power or nuclear power. Hydrogen will be the primary route for producing low-carbon hydrogen, and if hydrogen functions as a transport fuel, it will be the core of a low-carbon economy. Since renewable power is intermittent energy, it will cause many problems in the existing power grid, and it is difficult to actively respond to changes in the load of customers. Hydrogen by water electrolysis can be applied as a means to solve this problem.

On the other hand, the need for an electrochemical treatment method, which is an advanced oxidation treatment method for removing TOC (total organic carbon), which is a biologically difficult to treat, is increasing due to the recent reinforcement of environmental regulations. The advanced wastewater treatment method using the water electrolysis method has the advantage of not only removing hardly decomposable organic substances but also producing by-product hydrogen, but requires a technology that can separate oxygen and hydrogen, which are by-product gases, and purify it into 99% or more high-purity hydrogen. Do.

Hydrogen concentration produced by water electrolysis reaction is within about 70%, and to produce high-purity hydrogen, it must go through a hydrogen purification device. Currently, the most commercialized technology is PSA, which uses activated carbon and molecular sieve as adsorbents. (Pressure Swing Absorption) method is being used.

In the PSA method, a mixed gas containing hydrogen is selectively collected as an adsorbent in a pressurized state of 5 bar to 20 bar in a container filled with an adsorbent, and the rest of the gas remains inside the container. Afterwards, high-purity hydrogen gas is produced by lowering it to normal pressure and discharging it to remove residual gas other than the collected hydrogen.

If the by-product gas generated in the water electrolysis system is produced with high purity hydrogen using this method, the hydrogen concentration of the residual gas inside the container during the PSA reaction falls within the range of 4% to 74%, which is the hydrogen explosion concentration, and there is a risk of explosion. do. In particular, since the by-product gases generated in the water electrolysis system are hydrogen and oxygen, there is a need for a more stable hydrogen purification method because the risk of explosion is higher than that of other hydrogen production methods.

Water electrolytic hydrogen contains 0.1 to 10% oxygen that is not completely separated from the electrolytic stack. It has been found that when hydrogen containing oxygen is used or compressed in a fuel cell, friction between the oxygen molecules and the hydrogen molecules increases, thereby increasing the risk of explosion, and the present invention is based on this.

The first aspect of the present invention

A first step of producing hydrogen by decomposing water;

A second step of injecting an inert gas into the hydrogen and oxygen-containing by-product gas produced in the first step; And

The hydrogen and oxygen-containing mixed gas of the second step is separated by a palladium-based hydrogen separation membrane and purified into high-purity hydrogen, but the hydrogen concentration of the residual gas that has not passed through the separation membrane is more than the hydrogen explosion concentration through the control of the inert gas injected in the second step. The third stage of low operation

It provides a hydrogen production method comprising a.

The first step may be performed using a water electrolysis method, a photochemical method using a photocatalyst, a biological method using microorganisms, and/or a solar thermochemical and electrolysis method.

The first step may be to electrolyze the water. For example, the first step may be performed using alkaline water electrolysis, solid polymer electrolyte (PEM) water electrolysis, or high-temperature steam electrolysis technology using a solid oxide. In the first step, electric energy for water electrolysis can be supplied as renewable energy or late-night power.

In the first step, the subject of hydrolysis may be wastewater, and non-degradable organic substances may be removed by an electrochemical treatment method.

The recovery rate of hydrogen recovered through the third step may be 80 to 90% relative to the hydrogen produced in the first step.

In the third step, it can be purified with 99% or more high purity hydrogen.

In the third step, the palladium-based hydrogen separation membrane may operate at 100 to 500°C.

The second aspect of the present invention

Step a of injecting an inert gas into by-product gas containing hydrogen and oxygen produced through water electrolysis; And

The hydrogen and oxygen-containing gas mixture in step a is separated by a palladium-based hydrogen separation membrane and purified into high purity hydrogen, but the hydrogen concentration of the residual gas that has not passed through the separation membrane is controlled by the inert gas injected in step a to determine the hydrogen explosion concentration. Step b to operate low

It provides a water electrolyzed hydrogen purification method comprising a.

Hereinafter, the present invention will be described.

In order to solve the problem of high risk of explosion due to increased friction between oxygen molecules and hydrogen molecules when hydrogen containing oxygen is used in a fuel cell or compressed, a dense metal film containing palladium is used as a hydrogen separation membrane. It is possible to completely remove 0.1~10% of oxygen that is not separated in, but since the separation membrane must be heated to 100 ~ 500℃ to operate the metal film, there is a risk of explosion due to the reaction of hydrogen and oxygen due to palladium acting as a combustion catalyst. . Accordingly, it is a feature of the present invention to prevent an explosion hazard by supplying an inert gas (eg, nitrogen, helium, argon, etc.) when supplying electrolyzed hydrogen to a separator purifier.

The method of purifying by-product gas generated in a water electrolysis system using a palladium-based hydrogen separation membrane into high-purity hydrogen has the advantage of being able to produce high-concentration hydrogen using a separation membrane as soon as it occurs through a water electrolysis reaction. As it is concentrated, the risk of explosion can be eliminated. In addition, there is no risk of explosion as the residual gas that has not passed through the separation membrane is discharged below the hydrogen explosion concentration.

The hydrogen purification method using a hydrogen separation membrane has the advantage of being able to produce the purity of hydrogen in the range of 99% to 99.9995% according to the purpose of use, whereas the hydrogen recovery rate of the hydrogen separation membrane system is within 80 to 90%. May be present and fall within the explosive concentration range.

Accordingly, the separation membrane system according to the present invention seeks to solve this problem by configuring the system in a manner of purifying hydrogen while injecting an inert gas such as nitrogen into the separation membrane reactor in order to operate more safely. When the separation membrane system is configured in this way, the residual gas can be discharged while operating the system with the hydrogen concentration of the residual gas that has not passed through the separation membrane significantly lower than the hydrogen explosion concentration, thereby almost eliminating the risk of explosion.

The present invention is applicable to all water electrolysis technologies, and is also applicable to advanced wastewater treatment methods using a water electrolysis method. Accordingly, the present invention can produce by-product hydrogen without risk of explosion as well as removal of hardly decomposable organic substances.

Since hydrogen obtained from a resource containing hydrogen such as water contains impurities such as oxygen, it is necessary to separate and purify it at a stage prior to use.

The hydrogen separation method using a separation membrane has advantages such as more energy saving compared to other hydrogen separation methods such as deep cooling separation and adsorption, simple operation, and miniaturization of the equipment used.

The palladium based metal separation membrane has high hydrogen permeability and excellent hydrogen separation. In addition, 　The hydrogen separation membrane using a palladium-based metal separation membrane can produce pure hydrogen usefully for fuel cells or other processes that consume hydrogen, and can be used in hydrogenation or dehydrogenation reaction processes to improve the quantity of target products. It can be applied in various ways.

Looking at the process of hydrogen separation in the palladium-based metal membrane, hydrogen molecules (H ₂ ) diffuse to the surface of the Pd metal membrane, and then the hydrogen molecules adsorb to the surface of the Pd metal membrane, and the adsorbed hydrogen molecules dissociate, and the Pd metal. After the dissociated hydrogen atoms (H) diffuse in the membrane lattice, hydrogen molecules are regenerated, and when the hydrogen molecules are regenerated, hydrogen molecules are desorbed from the surface of the Pd metal film, and hydrogen molecules are diffused. Is separated. Typically, the operating temperature of the hydrogen separation membrane is 300 ~ 500 ℃.

의 관계에 있다. 상기 식 중 A는 금속막의 종류나 조작 조건 등에 따라 달라진다.In the palladium-based metal separation membrane, the hydrogen permeation amount is mainly the hydrogen partial pressure P1 on the raw material side, the hydrogen partial pressure P2 on the purification side, the film thickness t of the palladium-based metal separation membrane, and the membrane area of the metal separation membrane. That is, the amount of hydrogen permeation Q per unit area is

Is in a relationship. In the above formula, A varies depending on the type of the metal film or operating conditions.

As can be seen from the above equation, in order to improve the performance of the hydrogen permeable membrane, that is, to improve the amount of hydrogen permeation per unit area, I. Develop an alloy having a large integer A different according to the alloy type, or Ⅱ. Thinning the film thickness of the hydrogen permeable membrane, or Ⅲ. It is conceivable to increase the difference in partial pressure of hydrogen. In a hydrogen permeable membrane based on a palladium alloy, a method of improving the hydrogen permeability is mainly considered by reducing the thickness of the membrane. However, when the film thickness is made thin, the mechanical strength is weakened. Since the amount of hydrogen permeation is affected by the difference in partial pressure of hydrogen, it is required to achieve both thinning and strength. Therefore, a palladium alloy having a thin film thickness is used in combination with a porous support to supplement the mechanical strength. In order to facilitate the module and to form a thin separation layer, it is preferable to use a porous support for the palladium-based metal separation membrane. For example, a porous support; It may be in the form of having a hydrogen separation membrane located on one or both sides of the porous support.

The porous support may be tubular or flat.

Metal or ceramic materials may be used as the porous support. As the material of the porous metal, stainless steel, nickel, Inconel, or the like may be used. As a material of the porous ceramic, oxides based on Al, Ti, Zr, Si, etc. may be used.

In order to control the surface roughness of the porous support, a surface treatment process may be performed. As a surface treatment method, a polishing process such as CMP (Chemical Mechanical Polishing) or a process using plasma may be used.

It is preferable that the size of the surface pores formed in the porous support is not too large or too small. For example, when the size of the surface pores of the porous support is less than 0.001 µm, the permeability of the porous support itself is low, making it difficult to function as a porous support. On the other hand, when the size of the surface pores exceeds 10 µm, the pore diameter becomes too large, so that the thickness of the hydrogen separation layer must be formed thick. Therefore, it is preferable to form the porous support so that the size of the surface pores is 0.001 to 10 μm.

Optionally, the porous shielding layer, which may be formed on the porous metal support, is capable of passing hydrogen through the pores/gap to prevent diffusion that may occur between the palladium constituting the separator layer and the metal support. It can be formed as Non-limiting examples of the shielding layer include oxide-based, nitride-based, and carbide-based ceramics including one of Ti, Zr, Al, Si, Ce, La, Sr, Cr, V, Nb, Ga, Ta, W, and Mo. have. Preferably, there is _{an oxide-based ceramic material such as TiO y} , ZrO _y , and Al ₂ O _z (1<y≤2 or 2<z≤3). The shielding layer may be formed of metal oxide powder by a dry spray method, a wet spray method, or a sol-gel method.

The thickness of the shielding layer may be determined in consideration of manufacturing conditions and conditions of use of the hydrogen separation membrane. For example, when considering the use condition of 400° C., when forming TiOy as a shielding layer, it may be formed to a thickness of 100 to 200 nm. When ZrOy is formed as a shielding layer, it may be formed to a thickness of 500 to 800 nm.

On the other hand, it is preferable to introduce a spray coating method that is easy to mass-produce in order to construct the diffusion barrier layer on the surface of the support. The spray coating method can solve the problem of forming a support defect that may occur in the shielding layer coating, and it is easy to coat a large area.

It is preferable to coat a dense 　 palladium 　-containing layer as a catalyst layer for hydrogen separation on the outside or inside the support.

In the present invention, the 　Pd　-containing layer may be a 　 palladium 　 or a palladium 　 alloy. The palladium 　 alloy may be an alloy of 　Pd and one or more metals selected from the group consisting of Au, Ag, Cu, Ni, Ru, and Rh. It is also within the scope of the present invention that the Pd?-containing layer further includes layers such as 　Pd/Cu, 　Pd/Au, 　Pd/Ag, 　Pd/Pt, etc. in a multi-layered structure.

The Pd　-containing layer can be formed to a thickness of 0.1 to 20 µm. If the thickness is less than 0.1 μm, it is good because the hydrogen permeability is further improved, but it is difficult to manufacture the metal separation membrane densely, and thus, there is a problem that the life of the metal separation membrane is shortened. When the thickness is greater than 20 µm, the hydrogen permeability may be relatively low while it can be formed densely. In addition, there is a problem in that the overall manufacturing cost of the hydrogen separation membrane increases due to the metal separation membrane formed thicker than 20 μm using palladium, which is expensive. Preferably, considering the life characteristics of the metal separation membrane, hydrogen permeability, etc., it is preferable to form a thickness of 1 to 10 μm.

The hydrogen permeability through the separation membrane is also characteristic of the thinner, the higher the hydrogen permeability. Therefore, it is preferable that the thickness of the 　Pd　-containing layer as a metal separation membrane is as thin as possible. By preparing the 　Pd　-containing layer through sputtering, polishing, and electroless plating using a plating solution, it is possible to form a metal dense film without defects such as pinholes as well as increase the mechanical strength of the thin film while reducing the layer thickness.

By using a general sputtering method, a general polishing method, and a general electroless plating method, a layer of 　Pd　 or 　Pd　 alloy can be formed, but it is not limited to the use conditions and materials of each sputtering method, polishing method, and electroless plating method.

Among the separation membrane coating methods, the electroless plating method is a technology capable of coating a large area regardless of the shape of the support. Since contamination of the separator by carbon may be a problem, it is desirable to completely exclude the carbon source. On the other hand, plating is performed at room temperature, which not only has excellent high-temperature durability, but also has a simple facility and a very economical manufacturing process.

Meanwhile, as a low-temperature water electrolysis technology, Polymer Electrolyte Membrane Electrolysis (PEM Electrolysis) is an ion exchange membrane (electrolyte function) that separates the anode, cathode, and generated hydrogen and oxygen gas, and allows hydrogen ions to move from the anode to the cathode. ). Similar to the PEM fuel cell, PEM electrolysis uses a noble metal catalyst (Pt, Id, Ru) and a fluorocarbon-based ionomer as a polymer solid electrolyte. Each electrode reaction in PEM electrolysis is as follows.

Positive electrode _{(anode): 2H 2 O →} 4H + + 4e - + O 2

A negative electrode ^{(cathode): 4H + + 4e} - → 2 H 2

The advantage of PEM electrolysis is that it is possible to operate at a high current density, so the device is compact, the structure of the electrolysis cell and system is simple, and there is no corrosiveness, so a long life can be secured.

The core technology of PEM electrolysis is a technology related to an oxygen generating anode catalyst that accounts for more than 50% of the electrolysis voltage loss (overvoltage) generated during water electrolysis and directly affects the durability of the water electrolysis device. As the electrode catalyst used in PEM electrolysis, since the ion exchange membrane is a strong acid electrolyte with a pH of 2 to 4, an acid-resistant platinum-based catalyst is used. As for the oxygen generating catalyst, iridium metal has the best durability, but ruthenium metal has the best efficiency. Hydrogen-related catalysts include gold and palladium, platinum and bismuth alloy electrocatalysts. Hydrocarbon-based PEMs are being developed instead of fluorine-based PEMs for the purpose of reducing the manufacturing cost of water electrolysis devices.

The connection method with renewable energy is a method of connecting the renewable energy and the electrolysis system, such as direct connection, and the method of adjusting and optimizing the power suitable for receiving and electrolysis of the renewable power source.

The typical technology of high-temperature water electrolysis is a solid oxide fuel cell (SOFC) technology that operates at 700~1000℃, and is called a solid oxide electrolyzer cell (SOEC). That is, a method of electrolyzing water vapor at a high temperature of 750°C or higher using stabilized zirconia (Zr) or the like as an electrolyte for an oxygen ion conductor. The electrode reaction is as follows.

A negative electrode _{(cathode): H 2 O +} 2e - → H 2 + O 2-

Positive electrode ^{(anode): O 2- → 1/2} O 2 + 2e -

The main components of high-temperature water electrolysis are composed of a dense ion conductive electrolyte and two porous electrodes, and the basic operating mechanism is when high-temperature water flows into the porous cathode and an electrical potential difference occurs at the anode, as shown in FIG. Water molecules react and separate into hydrogen and oxygen.

After that, hydrogen gas diffuses to the cathode surface and oxygen ions move to the anode through the electrolyte. The transferred oxygen ions are oxidized to become oxygen and come out to the anode.

As the operating temperature increases, the amount of electric energy required decreases and the thermal energy increases, so that the total energy becomes insensitive to the operating temperature. Therefore, operation at high temperatures is an advantage and has many opportunities to produce hydrogen using industrial waste heat.

Among the constituents of high-temperature water electrolysis, the most important electrolyte must be chemically stable, have low electronic conductivity, and have good ionic conductivity. In addition, the electrolyte should be dense to prevent gas penetration to prevent hydrogen and oxygen from recombining, and should be as thin as possible to minimize resistance and voltage.

_{Electrolyte materials that can be used for SOEC include ZrO 2} based electrolytes such as YSZ (yttria stabilized sirconia) and ScSZ (Scandia stabilized zirconia), and _{CeO 2} based electrolytes such as GDC (Gd-doped ceria) and YDC (Y-doped ceria), LSGM. LaGaO ₃ based electrolytes such as ((La,Sr)(Ga, Mg)O _{3) are typical.} ZrO ₂ and CeO ₂ have flurotie structures, and oxygen ions form octahedral, and oxygen ions diffuse relatively quickly due to structural voids. In particular, while CeO ₂ has high ionic conductivity and excellent chemical stability with the cathode material, it has a disadvantage that it is difficult to use as an electrolyte due to its high electronic conductivity in a high-temperature reducing atmosphere.

The electrode must be chemically stable under oxidation/reduction conditions and must have high electronic conductivity. In addition, the electrode should have an appropriate porosity and pore size in order to maintain gas movement between the electrode surface and the electrode-electrolyte interface and to provide a sufficient three-phase boundary of the electrolyte-electrode-gas.

One of the key technologies that are important for manufacturing the electrolytic stack is the development of connectors. In the HTES cell, the connector electrically connects the cell and the neighboring cell inside the stack, and blocks the movement of gas between the anode and the neighboring cathode physically. These connecting materials must have high electrical and thermal conductivity, and must be chemically stable in high temperature oxidation and reduction atmospheres. It should also have high mechanical strength, have similar thermal expansion coefficients with other components, and should not react with each other.

A solid oxide electrolysis cell for high temperature water electrolysis has the same structure as a solid oxide fuel cell and a stack structure. The structure of a solid oxide fuel cell (SOFC) is largely divided into a flat plate type and a tube type, and the tube type is further classified into a cylindrical type and a flat tube type to be made flat to facilitate stacking of cells. In order to increase the power density of the SOFC cell, reducing the resistance of the cell by applying a thin film of electrolyte on the electrode support is a method commonly used to manufacture flat and tube cells.

In the case of a flat SOFC cell, since it uses a metal or ceramic connecting plate, it is easy to stack and collect, but it is difficult to make a large-area flat cell, and a sealing material for separating the flow of fuel and air above and below the cell is required. On the other hand, since the tubular cell has excellent mechanical strength and seals only both ends or one end of the tube, the sealing portion is smaller than that of the flat cell, making it easier to control the flow of gas inside and outside. To connect the fluid passage to the tubular SOFC cell, a metal manifold and the cell are connected by brazing or a ceramic paste containing glass is applied.

The separation membrane system according to the present invention comprises a system in which hydrogen is purified while injecting an inert gas such as nitrogen into the separation membrane reactor in order to operate more safely, so that the hydrogen concentration of the residual gas that has not passed through the separation membrane is significantly more than the hydrogen explosion concentration. The residual gas can be discharged while operating the system at a low level, virtually eliminating the risk of explosion.

1 is a schematic diagram of a hydrogen purification system for purifying a water electrolysis reaction gas.
2 is a conceptual diagram of SOEC hydrogen production.

Hereinafter, the present invention will be described in more detail through examples. However, the following examples are intended to clearly illustrate the technical features of the present invention, and do not limit the scope of the present invention.

Example 1 : Hydrogen purification of by-product gas of a water electrolysis system for removing hardly decomposable TOC

As a treatment device for separating oxygen and hydrogen, which are by-product gases generated in a water electrolysis system for advanced wastewater treatment, the applicability evaluation of a hydrogen purifier using a palladium membrane was performed.

Using the hydrogen purification system of FIG. 1 to which three palladium membranes having a diameter of 1 inch and a length of 45 cm were applied, a hydrogen purification reaction in the water electrolysis by-product gas was performed.

As a result of carrying out hydrogen purification performance evaluation on the by-product gas generated from the pilot scale electrolyzer for sewage discharge water treatment, the hydrogen concentration of the by-product gas generated by the water electrolysis reaction was 66%, and it was a hydrogen purification system using a palladium membrane. High purity hydrogen was produced at 150L/min with a purity of 99% or more. At this time, the hydrogen concentration of the residual gas discharged was less than 1%.

Claims (10)

A first step of producing hydrogen by decomposing water;
A second step of injecting an inert gas into the hydrogen and oxygen-containing by-product gas produced in the first step; And
The hydrogen and oxygen-containing mixed gas of the second step is separated by a palladium-based hydrogen separation membrane and purified into high-purity hydrogen, but the hydrogen concentration of the residual gas that has not passed through the separation membrane is more than the hydrogen explosion concentration through the control of the inert gas injected in the second step. The third stage of low operation
Hydrogen production method comprising a. The method of claim 1, wherein the first step is to electrolyze water. The method of claim 2, wherein the electric energy for water electrolysis in the first step is supplied as renewable energy or late-night power. The method of claim 1, wherein the subject of hydrolysis in the first step is wastewater, and non-decomposable organic substances are also removed by an electrochemical treatment method. The method of claim 1, wherein the recovery rate of hydrogen recovered through the third step is 80 to 90% relative to the hydrogen produced in the first step. The method for producing hydrogen according to claim 1, wherein in the third step, purification is performed with high purity hydrogen of 99% or more. The method of claim 1, wherein in the third step, the palladium-based hydrogen separation membrane is operated at 100 to 500°C. The method of claim 1, wherein the first step is performed using a water electrolysis method, a photochemical method using a photocatalyst, a biological method using microorganisms, and/or a solar thermochemistry and electrolysis method. The method of claim 2, wherein the first step is performed using alkaline water electrolysis, solid polymer electrolyte (PEM) water electrolysis, or high-temperature steam electrolysis using solid oxides. Step a of injecting an inert gas into by-product gas containing hydrogen and oxygen produced through water electrolysis; And
The hydrogen and oxygen-containing gas mixture in step a is separated by a palladium-based hydrogen separation membrane and purified into high purity hydrogen, but the hydrogen concentration of the residual gas that has not passed through the separation membrane is controlled by the inert gas injected in step a to determine the hydrogen explosion concentration. Step b to operate low
Water electrolyzed hydrogen purification method comprising a.

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