KR20210054832A - transparent nose pack and method for manufacturing the same - Google Patents

transparent nose pack and method for manufacturing the same Download PDF

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KR20210054832A
KR20210054832A KR1020190140976A KR20190140976A KR20210054832A KR 20210054832 A KR20210054832 A KR 20210054832A KR 1020190140976 A KR1020190140976 A KR 1020190140976A KR 20190140976 A KR20190140976 A KR 20190140976A KR 20210054832 A KR20210054832 A KR 20210054832A
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weight
parts
mesh
coating
nose
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KR1020190140976A
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KR102347522B1 (en
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박한욱
안정배
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주식회사 이엠코퍼레이션
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0212Face masks
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/345Alcohols containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/35Ketones, e.g. benzophenone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/67Vitamins
    • A61K8/678Tocopherol, i.e. vitamin E
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8176Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9789Magnoliopsida [dicotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9794Liliopsida [monocotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/26Optical properties
    • A61K2800/262Transparent; Translucent

Abstract

The present invention relates to a transparent nose pack, which is less sticky when used, can form a film in a short time, and is improved for no residue of a film cosmetic material to be left when peeled off from the skin, and specifically, to a transparent nose pack, in which a film composition obtained by dispersing and dissolving polyvinylpyrrolidone with VP/VA copolymer, hydroxyacetophenone with 1,2 hexanediol, dipotassium glycyrrhizate, polysorbate 60 and sorbitan sesquioleate, and an extract of Hamamelis virginiana in denatured alcohol and purified water to be applied to a release film, the composition is covered with a mesh to move at a constant speed, and thus complete drying is performed by passing through a drying furnace while allowing the mesh to naturally settle in the film cosmetic material, and to a manufacturing method thereof.

Description

투명 코 팩과 그 제조방법{transparent nose pack and method for manufacturing the same}Transparent nose pack and method for manufacturing the same

본 발명은 필 오프 타입의 코 팩에 관한 것으로서, 더 상세하게는 팩 시트를 떼어낸 피부에 잔존물이 남지 않으며 부착 후 건조에 소요되는 시간이 짧아 사용하기 편리한 투명 코 팩과 그 제조방법에 관한 것이다. The present invention relates to a peel-off type nose pack, and more particularly, to a transparent nose pack that is convenient to use because no residue remains on the skin from which the pack sheet is removed, and the time required for drying after attachment is short, and to a method for manufacturing the same. .

필 오프 타입의 코 팩은 세안 후 또는 코 주변에 수분을 바르고 팩의 피막화장료를 콧등에 붙인 다음, 소정 시간 방치하여 건조되면 떼어낼 때 모공의 블랙 헤드가 상기 피막화장료에 수렴되어 함께 제거되게 한 것이다.Peel-off type nose pack is designed to remove the pore blackheads after cleansing or around the nose by applying moisture to the nose, and then leaving the pack for a certain period of time to dry when removed. will be.

종래부터 알려져 있는 필 오프 타입의 코 팩은 젤리상, 페이스트상, 분말상의 여러 형태로 제품화되어 있지만, 에멀젼상의 피막화장료를 이형 필름상에 도포하고 두께를 관리하면서 건조하여 층상을 이루게 하고, 다시 그 위로 부직포 등의 기재를 피복하여 일체로 접합한 구조가 널리 채용되고 있다.Conventionally known peel-off type nose packs are commercialized in various forms in the form of jelly, paste, and powder. However, an emulsion-like coating cosmetic is applied on a release film and dried while controlling the thickness to form a layered form. Above, a structure in which a base material such as a nonwoven fabric is covered and integrally bonded is widely adopted.

콧등 피부에 접하는 피막화장료는 콧등에 발라진 화장수에 용해되면서 모공의 블랙 헤드와 그 주변의 피지를 녹여 수렴하게 되고, 이와 동시에 피막화장료의 수분은 부직포를 통하여 증발 건조되기 시작한다.The coating cosmetic that comes in contact with the skin of the nose and the nose is dissolved in the lotion applied to the nose, and the blackheads of the pores and the sebum around them are dissolved and converged.At the same time, the moisture of the coating cosmetic begins to evaporate and dry through the nonwoven fabric.

상기와 같은 건조에 의해 피막화장료는 수축되면서 콧등 피부를 조이게 되고, 이때 피막화장료에서 콧등 피부에 접하는 면이 완전 건조되지 않은 상태일 때 통증 없이 코 팩을 떼어낼 수 있다.By drying as described above, the coating cosmetic contracts and tightens the skin such as the nose, and at this time, the nose pack can be removed without pain when the surface of the coating cosmetic in contact with the skin such as the nose is not completely dry.

여기서 코 팩에 채용된 부직포의 두께가 두꺼우면 건조 소요시간이 길어지고, 이 경우 피막화장료의 수축에 의한 자극도 서서히 가해지게 되어 사용자가 체감하기 어렵게 된다.Here, if the thickness of the nonwoven fabric employed in the nose pack is thick, the drying time is increased, and in this case, stimulation due to contraction of the coating cosmetic is also gradually applied, making it difficult for the user to experience.

코 팩의 피막화장료가 콧등 피부와 접하는 면까지 완전 건조되면, 그 상태에서 코 팩을 떼어낼 때 콧등 피부까지 당겨져서 통증을 느끼게 될 뿐만 아니라 심하면 피부까지 손상되기도 한다.If the coating material of the nose pack is completely dry to the surface of the nose, etc., when the nose pack is removed, it is pulled to the skin of the nose, causing pain as well as severe damage to the skin.

그러므로 코 팩에 요구되는 조건은 피막화장료의 건조가 신속하게 진행되어야 하고, 이 피막화장료를 지지하는 부직포의 두께를 얇게 하여 사용자가 건조에 의한 자극을 느낄 수 있도록 하는 것이다.Therefore, the condition required for the nose pack is that the drying of the coating cosmetics must proceed quickly, and the thickness of the nonwoven fabric supporting the coating cosmetics is made thin so that the user can feel the irritation caused by the drying.

상기와 같은 특성을 얻고자 종래부터 피막화장료와 기재에 관한 연구 개발이 진행되어 왔다.In order to obtain the above characteristics, research and development on coating cosmetics and substrates have been conducted in the past.

필 오프 타입의 코 팩에서 기재로 범용화되어 있는 부직포에 관해서는, 특허문헌 1에 개시된 바와 같이, 피막화장료가 접합 되는 면은 친수층으로 하고 반대쪽은 발수층으로 가공한 2층 구조의 부직포가 공지되어 있다.As for the nonwoven fabric that is widely used as a base material in a peel-off type nose pack, as disclosed in Patent Document 1, a two-layered nonwoven fabric processed with a hydrophilic layer on the side to which the coating cosmetic is bonded and a water repellent layer on the other side is known. Has been.

그런데 발수층과 친수층의 이중 구조로 된 부직포에서 피막화장료는 친수층에만 스며들어 함유되기 때문에 부직포와의 접합력이 약하게 되고, 이 때문에 건조된 코 팩을 콧등에서 떼어낼 때 부직포와 피막화장료 사이가 분리되면서 잔류물이 콧등 피부에 남게 되는 문제를 일으키므로 상기의 2중 구조는 거의 채택하지 않고 있다.However, in the nonwoven fabric with a double structure of the water repellent layer and the hydrophilic layer, the coating cosmetic material permeates and contains only the hydrophilic layer, so the bonding strength with the nonwoven fabric is weakened. For this reason, when the dried nose pack is removed from the nose, there is a gap between the nonwoven fabric and the coating cosmetic material. Since separation causes a problem in that the residue remains on the skin such as the nose, the above double structure is hardly adopted.

부직포는 피막화장료와 일체로 접합하기 용이한 소재이지만, 이것의 두께와 재질에 따라 제품의 품질은 크게 달라진다.Non-woven fabric is a material that is easy to bond integrally with coating cosmetics, but the quality of the product varies greatly depending on its thickness and material.

즉, 두꺼운 부직포는 비교적 자체 복원력이 강한 편이므로 콧등의 윤곽에 어울리도록 붙이더라도 굴곡진 부분에서 밀착되지 않고 분리되는 현상이 생기고 섬유조직의 공간도 좁아서 여기를 통해 증발되는 수분의 통과량이 제한되어 건조 소요시간이 길어지게 된다.In other words, thick nonwoven fabrics have a relatively strong self-resilience, so even if they are attached to match the contours of the nose, they do not adhere to and separate from the curved part, and the space of the fibrous tissue is also narrow, so the amount of moisture evaporated through it is limited and drying. The time required will be longer.

얇은 부직포는 콧등 윤곽에 잘 어울려 밀착될 수 있고 섬유조직의 공간이 넓어서 건조 소요시간이 짧다.The thin nonwoven fabric fits well with the contours of the nose and can be adhered closely, and the time required for drying is short due to the large space of the fibrous tissue.

그렇지만, 얇은 부직포에 피막화장료를 피복하면 섬유조직의 공간을 통해 스며들어 상기 피막화장료의 일부가 이면 측으로 노출되는 문제가 생긴다.However, when the coating cosmetic material is coated on a thin nonwoven fabric, there is a problem that it penetrates through the space of the fibrous tissue and a part of the coating cosmetic material is exposed to the back side.

이렇게 부직포의 이면을 통해 노출된 피막화장료는 보빈에 감기면서 이형필름의 이면 측 이형처리 되지 않은 면과 접촉하게 되고, 시간이 지나면 이형필름과 부직포 사이는 이면 사이의 피막화장료에 의해 일체로 접착되어 사용할 수 없는 불량품으로 되는 경우가 종종 발생한다.The coated cosmetic material exposed through the back side of the nonwoven fabric comes into contact with the unreleased side of the release film while being wound on the bobbin, and after a period of time, the release film and the nonwoven fabric are integrally bonded by the coat cosmetic material between the back side. It often becomes a defective product that cannot be used.

이 때문에 시판되는 코 팩 대부분은, 이형필름에 도포된 피막화장료를 1차 건조하여 반 건조된 표면으로 부직포를 피복하고, 가볍게 눌러 접합한 다음 2차 건조하는 방식으로 제조하고 있다.For this reason, most of the commercially available nose packs are manufactured by first drying the coating cosmetic applied to the release film, covering the nonwoven fabric with a semi-dried surface, pressing lightly, and then drying the secondarily.

그런데 상술한 제조방식에 따르면 부직포의 이면으로 피막화장료가 스며 나올 수 없게 되지만, 2개의 건조로를 갖추어야 하기 때문에 불요 설비의 추가로 인한 낭비문제와 운용상의 번거로움을 겪어야 하는 문제가 있다.However, according to the above-described manufacturing method, coating cosmetics cannot seep out to the back side of the nonwoven fabric, but there is a problem in that there is a problem of waste due to the addition of unnecessary equipment and troubles in operation because two drying furnaces must be provided.

상술한 바와 같이, 종래의 코 팩에서 부직포를 채용하여 겪게 되는 제반 문제점은 망사를 기재로 채용하여 해결할 수 있을 것으로 기대된다.As described above, it is expected that all problems encountered by employing a nonwoven fabric in a conventional nose pack can be solved by employing a mesh as a base material.

망사는 두께가 얇아서 콧등의 굴곡에 어울리도록 쉽게 변형될 수 있고, 오프닝 면적이 넓어서 피막화장료의 건조시간을 단축할 수 있으며, 조직상의 외관적 결함이 내포되어 있어도 눈에 잘 띄지 않으므로 제품 자재로 사용할 수 있다.Because the mesh is thin, it can be easily deformed to match the curves of the nose, and the opening area is wide, so the drying time of the coating material can be shortened. I can.

그런데 코 팩에 망사를 채용하는 경우에, 기존의 제조방식으로 행하면 피막화장료에 함몰되는 망사의 면적이 부직포에 비해 현저하게 좁아지게 되고, 이로 인하여 피막화장료와 망사 사이의 접합력이 상당히 약하게 되어, 콧등에서 떼어낼 때 피막화장료가 완전히 제거되지 않고 일부가 피부에 남게 된다. However, in the case of employing a mesh for the nose pack, the area of the mesh that is depressed in the coating cosmetic becomes significantly narrower than that of the nonwoven fabric when it is carried out by the conventional manufacturing method, and thus the bonding strength between the coating cosmetic and the mesh is considerably weakened. When it is removed from the skin, the cosmetic material is not completely removed, and a part remains on the skin.

그러므로 코 팩의 기재로서 망사를 채용하려면 제조공정이나 재료의 성분 등에 관하여, 상기 망사와 피막화장료 사이의 접합력을 증강할 수 있는 방안이 강구되어야 한다.Therefore, in order to employ a mesh as a base material for a nose pack, a method for enhancing the bonding strength between the mesh and the coating cosmetic must be devised in relation to the manufacturing process or the components of the material.

피막화장료의 구체적인 예로는 특허문헌 2에 기재되어 있듯이, 다가알코올, 다가알코올 지방산 에스테르를 주성분으로 하고 여기에 기타성분으로 스크럽제나 안료를 첨가하고 정제수로 혼합한 조성물로 이루어지는 것과, 특허문헌 3에 기재되어 있듯이 염 생성기를 가진 고분자화합물이나 합성 고분자화합물을 주성분으로 하는 조성물 등이 알려져 있다.Specific examples of coating cosmetics include polyhydric alcohols and polyhydric alcohol fatty acid esters as main components, and a composition obtained by adding a scrub agent or a pigment as other components and mixing with purified water, as described in Patent Document 2, and described in Patent Document 3 As described above, a polymer compound having a salt-generating group or a composition containing a synthetic polymer compound as a main component is known.

시판되는 코 팩은 상기의 조성물에 관련된 원료를 채용하되, 이산화 타이타늄 분말, 산화철 분말 등의 무기 안료를 첨가한 백색 바탕의 피막화장료를 채용하고 있다.A commercially available nose pack employs a raw material related to the above composition, but employs a white-based coating cosmetic to which inorganic pigments such as titanium dioxide powder and iron oxide powder are added.

그런데 코 팩에서 무기안료는 블랙 헤드의 제거와는 관계없이, 제거된 블랙 헤드가 코 팩에서 눈에 띄게 하는 시각적 효과를 제공하는 것일 뿐, 이것은 코 팩을 콧등에서 벗겨내었을 때 무기안료의 일부가 피부에 남아 지저분한 흔적을 남기게 된다.However, the inorganic pigment in the nose pack only provides a visual effect that makes the removed blackhead stand out from the nose pack, regardless of the removal of the blackhead. This is part of the inorganic pigment when the nose pack is peeled off the nose. Remains on the skin, leaving a dirty mark.

한편, 피막화장료는 성분에 따라 물성이 달라지는데, 블랙 헤드의 제거효율을 높인 것은 수분에 과하게 용해되어 사용 시에 끈적거림이 심하여 불쾌감을 주고, 이를 개선하여 끈적거리지 않도록 성분을 조절하면 수분과 만나도 신속하게 용해되지 않아 블랙 헤드의 제거에 소요되는 시간이 길어진다.On the other hand, coating cosmetics have different physical properties depending on the ingredients, but the increase in the removal efficiency of blackheads is excessively dissolved in moisture, which gives a feeling of discomfort due to severe stickiness during use, and if the ingredients are adjusted so that they do not become sticky by improving this, it will quickly meet with moisture. As it does not dissolve properly, the time required to remove the black head becomes longer.

일본국 실용신안등록 제3034427호Japanese Utility Model Registration No. 3034427 일본국 공개특허 제2019-14671호Japanese Patent Laid-Open No. 2019-14671 일본국 공개특허 제1993-221843호Japanese Patent Laid-Open No. 1993-221843

따라서, 본 발명의 목적은 사용 시 끈적임이 덜하고 단시간에 피막이 형성될 수 있으며, 피부에서 벗겨낼 때 피막화장료의 잔존물이 남지 않는 투명 코 팩을 제공함에 있다.Accordingly, it is an object of the present invention to provide a transparent nose pack that is less sticky when used, a film can be formed in a short time, and does not leave a residue of a film cosmetic when peeled off from the skin.

본 발명의 다른 목적은 피막화장료와 얇은 기재 사이가 잘 분리되지 않도록 강고하게 접합될 수 있는 투명 코 팩의 제조방법을 제공함에 있다.Another object of the present invention is to provide a method of manufacturing a transparent nose pack that can be firmly bonded to prevent separation between a coating cosmetic and a thin substrate.

상기의 목적을 구현하는 본 발명은 폴리비닐피로리돈과 VP/VA 코폴리머의 상보작용으로 피막이 형성되게 하고, 여기에 산화방지제로 하이드록시아세토페논과 1,2 헥산다이올, 피부 컨디셔닝제로 다이포타슘글리시리제이트, 유화제로 폴리소르베이트60과 소르비탄세스퀴올리에이트, 및 피부수렴제로 버지니아 풍년화 추출물을 함유하는 피막 조성물로 이루어진 피막화장료에 망사를 접합하여 일체화한 것을 특징으로 한다.The present invention for realizing the above object is to form a film through the complementary action of polyvinylpyrrolidone and VP/VA copolymer, and hydroxyacetophenone and 1,2 hexanediol as an antioxidant, and dipotassium as a skin conditioning agent. It is characterized by bonding a mesh to a coating composition consisting of a coating composition containing glycyrrhizate, polysorbate 60 and sorbitansquioleate as an emulsifying agent, and a Virginia prickly pear extract as a skin astringent.

상술한 피막 조성물에는 보습제로 알로에베라잎 추출물, 토코페릴아세테이트, 기포생성을 억제하는 다이메티콘이 적당량 첨가될 수 있다.An appropriate amount of aloe vera leaf extract, tocopheryl acetate, and dimethicone for suppressing bubble formation may be added to the above-described coating composition as a moisturizing agent.

그리고 피막 조성물의 성분 함량은, 폴리비닐피로리돈 10~35 중량부 바람직하게는 24 중량부, VP/VA 코폴리머 5~25 중량부 바람직하게는 14 중량부, 하이드록시아세토페논 0.1~1.2 중량부 바람직하게는 0.5 중량부, 1,2-헥산다이올 0.1~1.4 중량부 바람직하게는 0.6 중량부, 다이포타슘글리시리제이트 0.01~0.20 중량부 바람직하게는 0.08 중량부, 폴리소르베이트60 0.05~0.50 중량부 바람직하게는 0.21 중량부, 소르비탄세스퀴올리에이트 0.03~0.07 중량부 바람직하게는 0.05 중량부, 버지니아 풍년화 추출물 0.07~0.13 중량부 바람직하게는 0.1 중량부를 적당량의 변성 알코올과 정제수에 분산 용해하여 얻는다.And the component content of the coating composition, polyvinylpyrrolidone 10 to 35 parts by weight, preferably 24 parts by weight, VP/VA copolymer 5 to 25 parts by weight, preferably 14 parts by weight, hydroxyacetophenone 0.1 to 1.2 parts by weight Preferably 0.5 parts by weight, 1,2-hexanediol 0.1 to 1.4 parts by weight, preferably 0.6 parts by weight, dipotassium glycyrrhizate 0.01 to 0.20 parts by weight, preferably 0.08 parts by weight, polysorbate 60 0.05 to 0.50 parts by weight, preferably 0.21 parts by weight, sorbitan sesquioleate 0.03 to 0.07 parts by weight, preferably 0.05 parts by weight, and Virginia Pomegranate extract 0.07 to 0.13 parts by weight, preferably 0.1 parts by weight, dispersed in an appropriate amount of denatured alcohol and purified water It is obtained by dissolving.

또, 피막 조성물에 첨가될 수 있는 보습제는 알로에베라잎 추출물 0.1 중량부, 토코페릴아세테이트 0.01 중량부이고, 피부보호제로 다이메티콘 0.5 중량부를 더 첨가할 수 있다.In addition, a moisturizing agent that may be added to the coating composition is 0.1 parts by weight of aloe vera leaf extract, 0.01 parts by weight of tocopheryl acetate, and 0.5 parts by weight of dimethicone as a skin protectant may be further added.

상술한 성분 물질을 분산 용해하기 위한 변성 알코올은 25~35 중량부, 정제수는 26~37 중량부이다.The modified alcohol for dispersing and dissolving the above-described component substances is 25 to 35 parts by weight, and purified water is 26 to 37 parts by weight.

상술한 망사는 10~15 데니어의 나일론사로 평직 된 오프닝치수 0.84~2.0mm 범위의 것을 채용할 수 있다.The above-described mesh is a nylon yarn of 10 to 15 denier, and an opening dimension in the range of 0.84 to 2.0 mm may be employed.

또한, 본 발명 투명 코 팩의 제조방법은 이형필름의 이형제 처리된 표면으로 피막화장료 조성물을 도포하고, 건조로에 진입하기 전에 상기 피막화장료 조성물의 상면으로 망사를 피복하여 이동 중에 자연 침하 되게 하면서 완전 건조된 것을 투명 코 팩으로 타공하는 공정으로 이루어진다. In addition, the method of manufacturing the transparent nose pack of the present invention is to apply a coating cosmetic composition to the surface treated with the release agent of the release film, and then completely dry it while allowing it to naturally settle while moving by coating a mesh on the top surface of the coating cosmetic composition before entering the drying furnace. It consists of a process of perforating the resulting material with a transparent nose pack.

본 발명의 투명 코 팩은 피막화장료로 되는 피막에 망사를 함몰하여 일체로 접합한 것이므로 얇은 두께를 갖는 코 팩의 성형이 가능하게 된다. 이에 따라 두께가 얇은 코 팩은 무리하지 않고 콧등의 굴곡에 어울리게 변형하여 붙일 수 있기 때문에 블랙 헤드의 제거 효과가 콧등 전체에 걸쳐 나타나게 되는 이점이 있다.Since the transparent nose pack of the present invention is integrally bonded by concave mesh to a film used as a coating cosmetic material, it is possible to form a nose pack having a thin thickness. Accordingly, there is an advantage that the removal effect of the black head appears over the entire nose, since the thin nose pack can be attached by deforming to suit the curve of the nose, without being unreasonable.

그리고 본 발명의 코 팩은 망사를 채용한 것이므로, 콧등에 부착한 후의 피막 건조가 망사의 개구를 통하여 이루어지게 된다.In addition, since the nose pack of the present invention employs a mesh, drying of the film after being attached to the nose or the like is performed through the opening of the mesh.

그러므로 코 팩을 붙이고 건조될 때까지의 시간이 대폭 단축되므로 사용자가 지루함을 느끼지 않게 되는 이점이 있다.Therefore, there is an advantage that the user does not feel bored since the time until drying after applying the nose pack is greatly shortened.

또한, 본 발명의 코 팩에는 안료가 첨가되지 않아서 외관이 투명하고, 망사는 제조과정에서 피막화장료의 내측으로 함몰되기 때문에, 사용 후 콧등에서 팩을 떼어낼 때 망사와 피막화장료가 함께 분리되어 피부에 잔존물이 남지 않게 된다.In addition, since no pigment is added to the nose pack of the present invention, the appearance is transparent, and the mesh is depressed into the inside of the coating cosmetic during the manufacturing process, so when the pack is removed from the nose or the like after use, the mesh and the coating cosmetic are separated together and the skin There will be no remnants left.

게다가 본 발명의 코 팩에 구비되는 피막은 폴리비닐피로리돈과 VP/VA 코폴리머를 피막형성제로 채용하고 있어서 조제가 간편하면서도 2종류 성분의 상보작용으로 저자극성의 탄력 좋은 피막을 얻을 수 있고, 사용 시에는 화장수에 표면이 신속하게 용해되면서도 심하게 끈적이지 않아 감촉이 좋다.In addition, the film provided in the nose pack of the present invention uses polyvinylpyrrolidone and VP/VA copolymer as a film forming agent, so it is easy to prepare, and a hypoallergenic and elastic film can be obtained by the complementary action of the two components. When used, the surface dissolves quickly in the lotion, but it is not very sticky, so the texture is good.

또한, 본 발명의 제조방법에 의하면, 피막화장료 조성물의 상면에서 망사가 자연 침하하면서 건조로를 통과하여 완전 건조되는 것으로, 상기 피막화장료 조성물에 망사 섬유의 일부가 함몰하여 일체로 접합 되기 때문에, 사용 후 코 팩을 벗겨낼 때 망사와 피막화장료가 피부에서 같이 제거되어 후처리가 깨끗하다는 이점과, 설비 규모에서도 하나의 건조로를 필요로 하여 과다 설비문제 및 운용상의 번거로움이 해소될 수 있다.In addition, according to the manufacturing method of the present invention, the net is completely dried by passing through a drying furnace while naturally settling on the top surface of the coating cosmetic composition. When the nose pack is peeled off, the net and the coating cosmetics are removed from the skin together, so the post-treatment is clean, and even at the facility scale, one drying furnace is required, which can eliminate excessive equipment problems and operational hassles.

도 1은 본 발명의 제조방법에 따른 피막형성기의 개략적 구성도.1 is a schematic configuration diagram of a film forming machine according to the manufacturing method of the present invention.

본 발명의 투명 코 팩을 상세히 설명하면 다음과 같다.The transparent nose pack of the present invention will be described in detail as follows.

본 발명의 투명 코 팩은 피막화장료를 이형필름 위로 도포하고 그 위로 망사를 피복하되, 상기 이형필름과 망사를 등속으로 이동시키면서 건조로를 통과하게 함으로써 상기 망사가 피막화장료에 함몰된 채로 완전 건조되어 일체로 접합 되도록 한 것이다.The transparent nose pack of the present invention applies a coating cosmetic on a release film and covers a mesh thereon, but by passing the release film and the mesh through a drying furnace while moving the release film and the mesh at a constant speed, the mesh is completely dried while being immersed in the coating cosmetic. It was made to be joined.

본 발명에서, 망사는 10~15 데니어의 나일론사로 오프닝치수 0.84~2.38mm 범위의 평직된 것을 채용한다. In the present invention, the mesh is a nylon yarn of 10 to 15 denier, and a plain weave having an opening dimension of 0.84 to 2.38 mm is employed.

본 발명의 투명 코 팩에서, 피막화장료에 함유되는 피막형성제로는 폴리피닐피로리돈과 VP/VA 코폴리머가 특히 적합하고, 상기 폴리비닐피로리돈은 10~35 중량부, 바람직하게는 24 중량부이고, 상기 VP/VA 코폴리머는 5~25 중량부, 바람직하게는 14 중량부 첨가된다.In the transparent nose pack of the present invention, polyfinylpyrrolidone and VP/VA copolymer are particularly suitable as the film forming agent contained in the film cosmetic, and the polyvinylpyrrolidone is 10 to 35 parts by weight, preferably 24 parts by weight. And, the VP/VA copolymer is added in an amount of 5 to 25 parts by weight, preferably 14 parts by weight.

폴리비닐피로리돈은 물, 에탄올, 이소프로판올 등에 용해되는 거의 냄새 없는 백색 분말로서, 피막으로 건조되면 접착성과 응집성이 우수한 흡습성의 광택 필름을 형성한다. 이것은 10 중량부 미만이면 피막의 견고도가 떨어지고, 35 중량부를 넘으면 응집성이 과도하게 높아져 코 팩을 떼어낼 때 피부에 손상을 줄 염려가 생긴다.Polyvinylpyrrolidone is an almost odorless white powder that is soluble in water, ethanol, isopropanol, etc., and forms a hygroscopic glossy film with excellent adhesion and cohesiveness when dried as a coating. If it is less than 10 parts by weight, the firmness of the film decreases, and if it exceeds 35 parts by weight, the cohesiveness becomes excessively high, and there is a fear of damaging the skin when the nose pack is removed.

VP/VA 코폴리머는 건조되면 필름화 되는 특성이 있는 백색 분말로서, 폴리비닐피로리돈의 분산 용해를 돕는 겔화제 역할을 하며, 함께 용매에 분산 용해되면 투명한 점액으로 되어 이형필름 상에 잘 도포될 수 있게 한다.VP/VA copolymer is a white powder that has the property of becoming a film when dried. It acts as a gelling agent to help disperse and dissolve polyvinylpyrrolidone. When it is dispersed and dissolved in a solvent, it becomes a transparent mucus and can be applied well on the release film. Make it possible.

본 발명에서, VP/VA 코폴리머가 5 중량부 미만이면 겔 제형이 만족스럽지 않게 나타나고, 25 중량부를 넘으면 폴리비닐피로리돈의 흡습성을 저해하므로 코 팩 사용 시 피막의 용해가 만족스럽지 않게 된다.In the present invention, if the amount of the VP/VA copolymer is less than 5 parts by weight, the gel formulation appears unsatisfactory, and if it exceeds 25 parts by weight, the hygroscopicity of polyvinylpyrrolidone is inhibited, so that the dissolution of the film is not satisfactory when using a nose pack.

하이드록시아세토페논은 변성 알코올에 용해되는 침상 결정체로서, 본 발명에서는 산화방지 역할과 함께 다른 성분의 보습제를 피부에 가두어 놓는 피막을 형성하여 코 팩 제거 후에도 피부를 촉촉하게 유지시켜 준다. 이것은 0.1 중량부 미만이면 보습 피막 형성이 미미하고, 1.2 중량부를 초과하여도 보습 효과는 더 높아지지 않는다.Hydroxyacetophenone is an acicular crystal soluble in denatured alcohol, and in the present invention, it forms a film that traps moisturizers of other ingredients in the skin along with an antioxidant role to keep the skin moist even after removal of the nose pack. If this is less than 0.1 parts by weight, the moisturizing film formation is insignificant, and even if it exceeds 1.2 parts by weight, the moisturizing effect is not further enhanced.

1,2-헥산다이올은 특이한 냄새를 가진 투명 액체로서, 물이나 기름에 잘 용해되고 항균성이 뛰어나며, 이것은 0.1 중량부 미만이면 항균성이 보장되지 않고, 1.4 중량부를 초과하면 분산 용해물의 점도가 저하되어 도포되는 필름의 두께가 균일하게 유지되지 않을 수 있다.1,2-Hexanediol is a transparent liquid with a peculiar odor. It is well soluble in water or oil and has excellent antibacterial properties. If it is less than 0.1 parts by weight, the antibacterial property is not guaranteed, and if it exceeds 1.4 parts by weight, the viscosity of the dispersion The thickness of the film to be applied may be decreased and may not be uniformly maintained.

다이포타슘글리시리제이트는 분자 구조가 테스토스테론과 유사하여 피부 손상 회복 및 피지조절효과를 나타내는 수용성의 백색 분말이며, 0.01 중량부 미만에서는 효과가 낮고, 0.50 중량부를 초과하여도 효과는 더 좋아지지 않는다.Dipotassium glycyrrhizate is a water-soluble white powder whose molecular structure is similar to that of testosterone and exhibits skin damage recovery and sebum control effects, and its effect is low when it is less than 0.01 parts by weight, and the effect is not better even when it exceeds 0.50 parts by weight.

버지니아 풍년화 추출물은 피부에 긴장감을 주는 수렴작용으로 모공 축소와 피지 제거효과를 나타내는 액상물로서, 0.07 중량부 미만에서는 수렴작용이 약하고 0.16 중량부를 초과하면 민감피부에 자극을 줄 염려가 높아진다.Virginia Pung Nyunhwa extract is a liquid that exhibits pore shrinkage and sebum removal effect by astringent action that gives a feeling of tension to the skin.If it is less than 0.07 parts by weight, the astringent action is weak, and if it exceeds 0.16 parts by weight, there is a high fear of irritation to sensitive skin.

알로에베라잎 추출물은 블랙헤드가 제거될 때 손상 입은 피부를 재생 및 진정시키고 각질을 제거하는 효과가 우수한 액체로서, 0.07 중량부 미만이면 피부 진정 효과가 저조하고 0.16 중량부를 초과하면 버지니아 풍년화 추출물의 수렴작용이 저하될 염려가 있다.Aloe vera leaf extract is a liquid that has an excellent effect of regenerating and soothing damaged skin and removing dead skin cells when blackheads are removed.If it is less than 0.07 parts by weight, the skin soothing effect is poor, and if it exceeds 0.16 parts by weight, the Virginia apex extract converges. There is a fear that the function will be reduced.

폴리소르베이트60은 물에 잘 녹고 서로 용해되지 않는 물질을 분산시키는 작용을 하는 황색의 점성 액체로서, 0.05 중량부 미만에서는 분산작용이 약하고, 0.50 중량부를 초과하면 본 발명 코 팩의 투명도를 저해할 염려가 있다.Polysorbate 60 is a yellow viscous liquid that acts to disperse substances that are well soluble in water and insoluble with each other. If it is less than 0.05 parts by weight, the dispersing effect is weak, and if it exceeds 0.50 parts by weight, the transparency of the nose pack of the present invention will be impaired. I have anxiety.

소르비탄세스퀴올리에이트도 서로 섞이기 어려운 성분의 계면을 활성화하여 잘 분산되게 하는 옅은 황색의 액체로서, 0.03 중량부 미만이면 계면활성 효과가 미미하고, 0.07 중량부를 초과하면 본 발명 코 팩의 투명도를 엷은 황색으로 변색하게 된다.Sorbitanes sesquioleate is also a pale yellow liquid that activates and disperses the interface of components that are difficult to mix with each other.If it is less than 0.03 parts by weight, the surfactant effect is insignificant, and if it exceeds 0.07 parts by weight, the transparency of the nose pack of the present invention Becomes pale yellow.

토코페릴아세테이트는 보습과 피부 활성효과를 갖춘 황색의 냄새 없는 점성 액체로서 본 발명의 코 팩에서는 투명도를 해치는 물질이므로 극소량 첨가한다. 이것은 첨가량이 0.008 중량부 미만이어도 무방하지만 0.011 중량부를 초과하면 코 팩이 엷은 황색으로 물들 수 있다.Tocopheryl acetate is a yellow, odorless, viscous liquid with moisturizing and skin-activating effects. Since it is a substance that impairs transparency in the nose pack of the present invention, it is added in a very small amount. This may be less than 0.008 parts by weight, but if it exceeds 0.011 parts by weight, the nose pack may turn pale yellow.

피막 조성물에 유동성을 부여하고 기포 생성을 막아주는 다이메티콘은 냄새 없는 투명한 광물성 오일로서, 적당량 첨가할 수 있으나 과량 투입시는 피부 트러블을 일으킬 염려가 있으므로 제한적으로 채용한다. Dimethicone, which imparts fluidity to the coating composition and prevents bubble formation, is a transparent mineral oil without odor, and can be added in an appropriate amount.

본 발명에서 변성 알코올은 친유성 물질의 분산을 위하여, 또한 정제수는 친수성 물질의 분산을 위하여 적당량 첨가된다. In the present invention, a denatured alcohol is added in an appropriate amount for dispersion of a lipophilic substance and purified water for dispersion of a hydrophilic substance.

상술한 성분 물질은 다음의 공정을 통하여 분산 용해되어 피막 조성물로 제조되고, 이 피막 조성물은 이형필름상에 도포 건조되면서 피막을 형성함과 동시에 반건조상태에서 표면에 망사를 눌러 붙여 일체화하는 것으로 본 발명의 투명 코 팩을 얻는다.The above-described component materials are dispersed and dissolved through the following process to form a film composition, and this film composition is applied on a release film and dried to form a film, and at the same time, it is considered to be integrated by pressing a mesh on the surface in a semi-dry state. To get the transparent nose pack of the invention.

상술한 피막 형성용 조성물의 각 성분물질을 변성 알코올 및 정제수에 투입하고 분산 용해할 때의 믹싱 시간은 특히 정해지는 것은 아니고, 육안으로 뭉침이 없이 분산 용해된 것이 확인되면 족하며, 믹싱 속도도 특히 정해지는 것은 아니지만, 예를 들면 저속 20 rpm, 중속 1500 rpm, 고속 2500 rpm, 최고속 3500 rpm으로 구분하여 행할 수 있다.The mixing time when each component material of the above-described film-forming composition is added to denatured alcohol and purified water and dispersed and dissolved is not particularly determined, and it is sufficient if it is confirmed that it is dispersed and dissolved without agglomeration with the naked eye, and the mixing speed is also particularly Although not determined, for example, it can be performed by dividing into a low speed of 20 rpm, a medium speed of 1500 rpm, a high speed of 2500 rpm, and a maximum speed of 3500 rpm.

분산 용해는 먼저, 정제수에 다이포타슘글리시리제이트를 투입하고 중속으로 믹싱 하면서 분산 용해하고, 뭉침 없이 용해되면 계속해서 폴리비닐피로리돈을 투입하고 같은 속도로 분산 용해하여 서브용액을 준비하여 놓는다. Disperse and dissolve first, dipotassium glycyrrhizate is added to purified water and dispersed and dissolved while mixing at medium speed, and when dissolved without clumping, polyvinylpyrrolidone is continuously added and dispersed and dissolved at the same rate to prepare a sub-solution.

상기와는 별도로 하이드록시아세토페논과 VP/VA 코폴리머를 변성 알코올에 투입하고 저속으로 믹싱하여, 어느 정도 분산되면 중속으로 믹싱하여 뭉침 없이 분산 용해하여 메인용액을 얻는다.Separately from the above, hydroxyacetophenone and VP/VA copolymer are added to denatured alcohol and mixed at a low speed, and when dispersed to a certain extent, the mixture is mixed at medium speed to disperse and dissolve without clumping to obtain a main solution.

상기 메인용액에 폴리비닐피로리돈을 투입하면서 저속으로 믹싱하여 어느 정도 분산 용해되면 고속으로 믹싱하여 완전히 뭉침 없이 분산 용해한다.When polyvinylpyrrolidone is added to the main solution, mixing at a low speed and dispersing to some extent is mixed at a high speed to disperse and dissolve completely without agglomeration.

다음에 계속해서 상기 서브용액을 투입하고 저속으로 믹싱하여 뭉침 없이 분산되면 최고속으로 믹싱하여 완전히 분산 용해한다.Then, the sub-solution is continuously added and mixed at a low speed to disperse without agglomeration, then the sub-solution is mixed at the highest speed to completely disperse and dissolve.

상기 성분 물질이 분산 용해된 메인용액에 폴리소르베이트60과 소르비탄세스퀴올리에이트, 토코페릴아세테이트, 다이메티콘, 1,2-헥산다이올, 버지니아 풍년화 추출물, 알로에베라잎 추출물을 투입하고, 저속 믹싱하여 뭉침 없이 분산되면 최고속으로 믹싱하여 완전히 분산 용해하고 탈포해서 피막 조성물을 얻는다.Polysorbate 60 and sorbitan sesquioleate, tocopheryl acetate, dimethicone, 1,2-hexanediol, Virginia fern extract, and aloe vera leaf extract were added to the main solution in which the above ingredient substances were dispersed and dissolved, When mixing at a low speed and dispersing without agglomeration, mixing at the highest speed to completely disperse and dissolve and defoaming to obtain a coating composition.

얻어진 피막 조성물은 도 1로 나타낸 통상의 피막형성기로 공급하여 코 팩용 시트재로 제조한다.The obtained film composition is supplied to a conventional film forming machine shown in Fig. 1 to produce a sheet material for a nose pack.

즉, 한쪽 면에 이형제 처리된 이형필름(2)을 피막화장료 조성물이 담긴 저장조(4)로 통과시켜서 상면에 일정 두께의 피막화장료층(6)으로 도포되게 하고, 건조로(8)를 향해 주행할 때 망사(10)를 상기 피막화장료층(6)의 상면으로 공급한다.In other words, the release film (2) treated with the release agent on one side is passed through the storage tank (4) containing the film cosmetic composition to be applied with a film cosmetic layer (6) of a certain thickness on the upper surface, and run toward the drying furnace (8). When doing so, the mesh 10 is supplied to the upper surface of the coating cosmetic layer 6.

피막화장료층(6)의 상면으로 공급되는 망사(10)는 이형필름(2)의 진행속도에 등속으로 공급되면 자연스럽게 상기 피막화장료층(6)으로 침하하게 된다.When the mesh 10 supplied to the upper surface of the coating cosmetic layer 6 is supplied at a constant speed at the moving speed of the release film 2, it naturally subsides into the coating cosmetic layer 6.

이와 같이 등속으로 이동하는 이형필름(2)과 망사(10)는 함께 건조로(8)로 진입하고 완전 건조상태의 시트재로 회수된다.In this way, the release film 2 and the mesh 10 moving at a constant speed enter the drying furnace 8 together and are recovered as a sheet material in a completely dry state.

망사(10)는 피막화장료층(6)의 상면으로 공급되면 자연 침하하지만 건조로(8)를 통과하면서 피막화장료층(6)이 경화됨에 따라 그 침하는 피막화장료층(6)의 상면 부근에서 멈추게 되어, 상기 피막화장료층(6)과 망사(10)의 합체는 코 팩에 알맞은 양상으로 이루어지게 된다.When the mesh 10 is supplied to the top surface of the coating cosmetic layer 6, it naturally subsides, but as it passes through the drying furnace 8 and the coating cosmetic layer 6 is cured, the settling is in the vicinity of the top surface of the coating cosmetic layer 6. When stopped, the combination of the coating cosmetic layer 6 and the mesh 10 is made in a manner suitable for the nose pack.

상술한 바와 같이, 망사(10)와 합체되고 완전 건조된 피막화장료층(6)의 함수율은 5 중량% 이하이다.As described above, the moisture content of the coated cosmetic layer 6 incorporated with the mesh 10 and completely dried is 5% by weight or less.

망사(10)가 피복되고 완전 건조된 피막화장료층(6)은 이후 공정에서 타공하여 소망의 코 팩으로 성형된다.The coating cosmetic layer 6 covered with the mesh 10 and completely dried is punched in a subsequent process and formed into a desired nose pack.

폴리비닐피로리돈 10 중량부, VP/VA 코폴리머 5 중량부, 하이드록시아세토페논 0.1 중량부, 1,2-헥산다이올 0.1 중량부, 다이포타슘글리시리제이트 0.01 중량부, 버지니아 풍년화 추출물 0.07 중량부, 알로에베라잎 추출물 0.07 중량부, 토코페릴아세테이트 0.008 중량부, 다이메티콘 0.3 중량부, 폴리소르베이트60 0.05 중량부, 소르비탄세스퀴올리에이트 0.03 중량부, 변성 알코올 25 중량부, 정제수 28 중량부를 상술한 공정에 따라 분산 용해하여 얻은 조성물을 이형필름에 도포하고 건조하면서 망사를 피복하여 피막화장료와 일체로 접합 된 투명 코 팩을 제조하였다.10 parts by weight of polyvinylpyrrolidone, 5 parts by weight of VP/VA copolymer, 0.1 parts by weight of hydroxyacetophenone, 0.1 parts by weight of 1,2-hexanediol, 0.01 parts by weight of dipotassium glycyrrhizate, 0.07 parts by weight of virginia prickly pear extract Parts by weight, 0.07 parts by weight of aloe vera leaf extract, 0.008 parts by weight of tocopheryl acetate, 0.3 parts by weight of dimethicone, 0.05 parts by weight of polysorbate 60, 0.03 parts by weight of sorbitan sesquioleate, 25 parts by weight of denatured alcohol, purified water 28 parts by weight of the composition obtained by dispersing and dissolving according to the above-described process was applied to a release film, and dried while covering a mesh to prepare a transparent nose pack integrally bonded with the coating cosmetic.

망사는 시판되고 있는 메시넘버 20의 나일론망사로, 굵기 405㎛, 오프닝치수 0.84mm를 사용하였다.The mesh was a commercially available nylon mesh with mesh number 20, a thickness of 405 μm and an opening dimension of 0.84 mm.

폴리비닐피로리돈 17 중량부, VP/VA 코폴리머 10 중량부, 하이드록시아세토페논 0.3 중량부, 1,2-헥산다이올 0.3 중량부, 다이포타슘글리시리제이트 0.04 중량부, 버지니아 풍년화 추출물 0.08 중량부, 알로에베라잎 추출물 0.08 중량부, 토코페릴아세테이트 0.0085 중량부, 다이메티콘 0.35 중량부, 폴리소르베이트60 0.12, 소르비탄세스퀴올리에이트 0.035 중량부, 변성 알코올 26 중량부, 정제수 29 중량부를 상술한 공정에 따라 분산 용해하여 얻은 조성물을 이형필름에 도포하고 건조하면서 망사를 피복하여 피막화장료와 일체로 접합 된 투명 코 팩을 제조하였다.17 parts by weight of polyvinylpyrrolidone, 10 parts by weight of VP/VA copolymer, 0.3 parts by weight of hydroxyacetophenone, 0.3 parts by weight of 1,2-hexanediol, 0.04 parts by weight of dipotassium glycyrrhizate, 0.08 parts by weight of virginia prickly pear extract Parts by weight, 0.08 parts by weight of aloe vera leaf extract, 0.0085 parts by weight of tocopheryl acetate, 0.35 parts by weight of dimethicone, 0.12 parts by weight of polysorbate, 0.035 parts by weight of sorbitan sesquioleate, 26 parts by weight of denatured alcohol, 29 parts by weight of purified water The composition obtained by dispersing and dissolving the portion according to the above-described process was applied to a release film, and dried while covering a mesh to prepare a transparent nose pack integrally bonded with the coating cosmetic.

망사는 시판되고 있는 메시넘버 18의 나일론망사로, 굵기 515㎛, 오프닝치수 1.0mm를 사용하였다.The mesh was a commercially available nylon mesh with mesh number 18, a thickness of 515 μm and an opening dimension of 1.0 mm.

폴리비닐피로리돈 24 중량부, VP/VA 코폴리머 14 중량부, 하이드록시아세토페논 0.5 중량부, 1,2-헥산다이올 0.6 중량부, 다이포타슘글리시리제이트 0.08 중량부, 버지니아 풍년화 추출물 0.09 중량부, 알로에베라잎 추출물 0.09 중량부, 토코페릴아세테이트 0.009, 다이메티콘 0.4 중량부, 폴리소르베이트60 0.21 중량부, 소르비탄세스퀴올리에이트 0.04 중량부, 변성 알코올 27 중량부, 정제수 30 중량부를 상술한 공정에 따라 분산 용해하여 얻은 조성물을 이형필름에 도포하고 건조하면서 망사를 피복하여 피막화장료와 일체로 접합 된 투명 코 팩을 제조하였다.24 parts by weight of polyvinylpyrrolidone, 14 parts by weight of VP/VA copolymer, 0.5 parts by weight of hydroxyacetophenone, 0.6 parts by weight of 1,2-hexanediol, 0.08 parts by weight of dipotassium glycyrrhizate, 0.09 parts by weight of virginia prickly pear extract Parts by weight, 0.09 parts by weight of aloe vera leaf extract, 0.009 parts by weight of tocopheryl acetate, 0.4 parts by weight of dimethicone, 0.21 parts by weight of polysorbate 60, 0.04 parts by weight of sorbitan sesquioleate, 27 parts by weight of denatured alcohol, 30 parts by weight of purified water The composition obtained by dispersing and dissolving the portion according to the above-described process was applied to a release film, and dried while covering a mesh to prepare a transparent nose pack integrally bonded with the coating cosmetic.

망사는 시판되고 있는 메시넘버 16의 나일론망사로, 굵기 555㎛, 오프닝치수 1.19mm를 사용하였다.The mesh was a commercially available nylon mesh with mesh number 16, a thickness of 555 μm and an opening dimension of 1.19 mm.

폴리비닐피로리돈 28 중량부, VP/VA 코폴리머 17 중량부, 하이드록시아세토페논 0.7 중량부, 1,2-헥산다이올 0.9 중량부, 다이포타슘글리시리제이트 0.12 중량부, 버지니아 풍년화 추출물 0.1 중량부, 알로에베라잎 추출물 0.1 중량부, 토코페릴아세테이트 0.01 중량부, 다이메티콘 0.5 중량부, 폴리소르베이트60 0.30 중량부, 소르비탄세스퀴올리에이트 0.05 중량부, 변성 알코올 28 중량부, 정제수 31 중량부를 상술한 공정에 따라 분산 용해하여 얻은 조성물을 이형필름에 도포하고 건조하면서 망사를 피복하여 피막화장료와 일체로 접합 된 투명 코 팩을 제조하였다.28 parts by weight of polyvinylpyrrolidone, 17 parts by weight of VP/VA copolymer, 0.7 parts by weight of hydroxyacetophenone, 0.9 parts by weight of 1,2-hexanediol, 0.12 parts by weight of dipotassium glycyrrhizate, 0.1 Parts by weight, 0.1 parts by weight of aloe vera leaf extract, 0.01 parts by weight of tocopheryl acetate, 0.5 parts by weight of dimethicone, 0.30 parts by weight of polysorbate 60, 0.05 parts by weight of sorbitan sesquioleate, 28 parts by weight of denatured alcohol, purified water 31 parts by weight of the composition obtained by dispersing and dissolving according to the above-described process was applied to a release film, dried, and coated with a mesh to prepare a transparent nose pack integrally bonded with the coating cosmetic.

망사는 시판되고 있는 메시넘버 14의 나일론망사로, 굵기 610㎛, 오프닝치수 1.41mm를 사용하였다.The mesh was a commercially available nylon mesh with mesh number 14, a thickness of 610 μm and an opening dimension of 1.41 mm.

폴리비닐피로리돈 31 중량부, VP/VA 코폴리머 19 중량부, 하이드록시아세토페논 0.8 중량부, 1,2-헥산다이올 1.1 중량부, 다이포타슘글리시리제이트 0.16 중량부, 버지니아 풍년화 추출물 0.11 중량부, 알로에베라잎 추출물 0.11 중량부, 토코페릴아세테이트 0.011 중량부, 다이메티콘 0.55 중량부, 폴리소르베이트60 0.38 중량부, 소르비탄세스퀴올리에이트 0.055, 변성 알코올 29 중량부, 정제수 32 중량부를 상술한 공정에 따라 분산 용해하여 얻은 조성물을 이형필름에 도포하고 건조하면서 망사를 피복하여 피막화장료와 일체로 접합 된 투명 코 팩을 제조하였다.31 parts by weight of polyvinylpyrrolidone, 19 parts by weight of VP/VA copolymer, 0.8 parts by weight of hydroxyacetophenone, 1.1 parts by weight of 1,2-hexanediol, 0.16 parts by weight of dipotassium glycyrrhizate, 0.11 parts by weight of virginia prickly pear extract Parts by weight, 0.11 parts by weight of aloe vera leaf extract, 0.011 parts by weight of tocopheryl acetate, 0.55 parts by weight of dimethicone, 0.38 parts by weight of polysorbate 60, sorbitan sesquioleate 0.055, 29 parts by weight of denatured alcohol, 32 parts by weight of purified water The composition obtained by dispersing and dissolving the portion according to the above-described process was applied to a release film, and dried while covering a mesh to prepare a transparent nose pack integrally bonded with the coating cosmetic.

망사는 시판되고 있는 메시넘버 12의 나일론망사로, 굵기 695㎛, 오프닝치수 1.68mm를 사용하였다.The mesh was a commercially available nylon mesh with mesh number 12, a thickness of 695 μm and an opening dimension of 1.68 mm.

폴리비닐피로리돈 33 중량부, VP/VA 코폴리머 22 중량부, 하이드록시아세토페논 1.0 중량부, 1,2-헥산다이올 1.2 중량부, 다이포타슘글리시리제이트 0.18 중량부, 버지니아 풍년화 추출물 0.12 중량부, 알로에베라잎 추출물 0.12 중량부, 토코페릴아세테이트 0.012 중량부, 다이메티콘 0.6 중량부, 폴리소르베이트60 0.44 중량부, 소르비탄세스퀴올리에이트 0.06 중량부, 변성 알코올 29 중량부, 정제수 33 중량부를 상술한 공정에 따라 분산 용해하여 얻은 조성물을 이형필름에 도포하고 건조하면서 망사를 피복하여 피막화장료와 일체로 접합 된 투명 코 팩을 제조하였다.33 parts by weight of polyvinylpyrrolidone, 22 parts by weight of VP/VA copolymer, 1.0 parts by weight of hydroxyacetophenone, 1.2 parts by weight of 1,2-hexanediol, 0.18 parts by weight of dipotassium glycyrrhizate, 0.12 parts by weight of virginia prickly pear extract Parts by weight, 0.12 parts by weight of aloe vera leaf extract, 0.012 parts by weight of tocopheryl acetate, 0.6 parts by weight of dimethicone, 0.44 parts by weight of polysorbate 60, 0.06 parts by weight of sorbitan sesquioleate, 29 parts by weight of denatured alcohol, purified water 33 parts by weight of the composition obtained by dispersing and dissolving in accordance with the above-described process was applied to a release film, dried, and coated with a mesh to prepare a transparent nose pack integrally bonded with the coating cosmetic.

망사는 시판되고 있는 메시넘버 10의 나일론망사로, 굵기 750㎛, 오프닝치수 2.0mm를 사용하였다.The mesh was a commercially available nylon mesh with mesh number 10, a thickness of 750 μm, and an opening dimension of 2.0 mm.

폴리비닐피로리돈 35 중량부, VP/VA 코폴리머 25 중량부, 하이드록시아세토페논 1.2 중량부, 1,2-헥산다이올 1.4 중량부, 다이포타슘글리시리제이트 0.20 중량부, 버지니아 풍년화 추출물 0.13 중량부, 알로에베라잎 추출물 0.13 중량부, 토코페릴아세테이트 0.012 중량부, 다이메티콘 0.7 중량부, 폴리소르베이트60 0.50 중량부, 소르비탄세스퀴올리에이트 0.07 중량부, 변성 알코올 30 중량부, 정제수 34 중량부를 상술한 공정에 따라 분산 용해하여 얻은 조성물을 이형필름에 도포하고 건조하면서 망사를 피복하여 피막화장료와 일체로 접합 된 투명 코 팩을 제조하였다.35 parts by weight of polyvinylpyrrolidone, 25 parts by weight of VP/VA copolymer, 1.2 parts by weight of hydroxyacetophenone, 1.4 parts by weight of 1,2-hexanediol, 0.20 parts by weight of dipotassium glycyrrhizate, 0.13 parts by weight of virginia pomegranate extract Parts by weight, 0.13 parts by weight of aloe vera leaf extract, 0.012 parts by weight of tocopheryl acetate, 0.7 parts by weight of dimethicone, 0.50 parts by weight of polysorbate 60, 0.07 parts by weight of sorbitan sesquioleate, 30 parts by weight of denatured alcohol, purified water 34 parts by weight of the composition obtained by dispersing and dissolving according to the above-described process was applied to a release film, and dried while covering a mesh to prepare a transparent nose pack integrally bonded with the coating cosmetic.

망사는 시판되고 있는 메시넘버 8의 나일론망사로, 굵기 850㎛, 오프닝치수 2.38mm를 사용하였다.The mesh was a commercially available nylon mesh with mesh number 8, a thickness of 850 μm and an opening dimension of 2.38 mm.

상술한 실시예 1~7에서 얻어진 투명 코 팩을 관능시험에 제공하여 평가 항목별로 얻어진 결과를 표 1로 나타낸다.Table 1 shows the results obtained for each evaluation item by providing the transparent nose packs obtained in Examples 1 to 7 described above for a sensory test.

평가방식은 자원자의 코에 화장수를 바르고 상기 실시예 1~7에서 얻어진 투명 코 팩을 붙일 때 피막화장료가 수분에 용해되어 끈적이는 느낌과, 콧등의 굴곡에 따라 변형되면서 밀착되고 건조될 때까지 그 밀착상태가 유지되는지를 검사하고, 피막화장료의 건조현상으로 피부에 긴장감이 느껴질 때까지를 건조소요시간으로 측정하며, 코 팩을 벗겨낼 때 피막화장료의 일부가 피부에 남게 되는지를 잔류물 유무로 평가하고, 또한 피부에서 망사가 떨어져 나올 때 피막화장료의 일부 또는 전체가 망사와 분리되는가를 접합상태의 유지 또는 일부 분리로 평가한다.The evaluation method is that when applying lotion to the nose of the volunteer and attaching the transparent nose pack obtained in Examples 1 to 7 above, the coating cosmetic dissolves in water and feels sticky, and it adheres and adheres to it while being deformed according to the bend of the nose, etc. Inspect whether the condition is maintained, measure the drying time until the skin feels tense due to the drying phenomenon of the coat cosmetic, and evaluate whether a part of the coat cosmetic remains on the skin when the nose pack is peeled off by the presence or absence of residues. In addition, it is evaluated whether part or all of the film cosmetic material is separated from the mesh when the mesh is separated from the skin as maintenance of the bonded state or partial separation.

항목Item 실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 실시예 4Example 4 실시예 5Example 5 실시예 6Example 6 실시예 7Example 7 감촉Texture 미끈함Slippery 미끈함Slippery 끈끈함pastiness 끈끈함pastiness 끈끈함pastiness 끈적함Stickiness 끈적함Stickiness 밀착상태Tightness 양호Good 양호Good 최량Best 최량Best 최량Best 최량Best 최량Best 건조시간Drying time 10분10 minutes 9분9 minutes 7분7 minutes 7분7 minutes 6분6 minutes 5분5 minutes 5분5 minutes 잔류물Residue ×× ×× ×× ×× ×× 접합상태Bonding state 유지maintain 유지maintain 유지maintain 유지maintain 유지maintain 일부분리Partly 일부분리Partly

* 감촉등급: 끈적함 > 끈끈함 > 미끈함* Texture grade: sticky> sticky> slippery

끈적함 = 손가락에 피막화장료가 묻어나오는 정도 Stickiness = The degree to which the film is applied to the finger

끈끈함 = 손가락이 피막화장료에 달라붙는 정도 Stickiness = The degree to which fingers stick to the coating cosmetics

미끈함 = 피막화장료 표면이 미끈미끈한 정도 Smoothness = The degree to which the surface of the coating cosmetic is smooth

* 최량: 코 팩이 건조될 때까지 콧등 굴곡에 완전히 밀착 유지됨* Best: Keeps completely close to the curves of the nose until the nose pack is dry

* 양호: 코 팩이 건조되면서 콧등 굴곡에서 일부 박리됨* Good: As the nose pack dries, some peeling off at the curves of the nose

* ×: 잔류물 없음 △: 잔류물 있음* ×: No residue △: No residue

[평가] [evaluation]

실시예 3~7의 코 팩 모두 표면이 끈적거렸으나 시술을 곤란하게 할 정도는 아니었으며, 실시예 1, 2의 경우는 코 팩을 콧등에 부착하고 30초 내지 1분 정도 눌러주어야 접착되는 경향을 보였으며, 이것은 피막화장료가 체온에 녹은 후부터 접착이 촉진되는 현상으로 추측된다.Both of the nose packs of Examples 3 to 7 had sticky surfaces, but not to the extent that it would make the procedure difficult, and in Examples 1 and 2, the tendency to adhere only when the nose pack was attached to the nose and pressed for about 30 seconds to 1 minute. This is presumed to be a phenomenon in which adhesion is promoted after the coating cosmetic is dissolved at body temperature.

콧등에 붙인 다음 건조되면서 실시예 6과 실시예 7의 코 팩에서 콧방울부위의 굴곡진 부분이 일부 박리 되는 경향을 보였다. 일부 박리의 원인은 채용한 망사의 나일론사가 콧등의 굴곡에 따라 변형될 때 자체 복원력이 접착력보다 약하여 피부로 밀착된 다음, 마르면서 접착력이 약화함에 따라 어느 시기에 자체 복원력이 접착력보다 강해져서 부분 박리되는 것에 있다고 추측된다.The nose packs of Examples 6 and 7 showed a tendency to partially peel off the curved part of the nose area while being attached to the nose and then dried. The cause of some peeling is that when the nylon yarn of the adopted mesh is deformed according to the bend of the nose, the self-restoring force is weaker than the adhesive force and adheres to the skin. I guess there is something to be done.

따라서 망사의 데니어는 10~15 범위의 것이 적합하다.Therefore, the denier of the mesh is suitable in the range of 10 to 15.

코 팩의 접착 후 건조시간은 오프닝치수가 클수록 단축되었다. The drying time after adhesion of the nose pack was shortened as the opening dimension increased.

실시예 6과 7에서 코 팩을 떼어 낼 때, 망사와 피막화장료 사이의 일부가 분리되는 양상을 보였으며, 이것은 망사의 오프닝치수는 크고 이에 비해 피막화장료와 망사 사이의 접합 면적은 상대적으로 좁아서 나타나는 문제로 판단되므로 망사의 오프닝치수는 2mm 이내로 채택하는 것이 바람직하다.When removing the nose pack in Examples 6 and 7, a part between the mesh and the coating material was separated, and this was due to the large opening dimension of the mesh and the bonding area between the coating material and the mesh was relatively narrow. Since it is judged as a problem, it is desirable to adopt the opening dimension of the mesh within 2mm.

이상과 같이 본 발명의 투명 코 팩은 피막형성제로서 폴리비닐피로리돈과 VP/VA 코폴리머를 채용함에 따라 저자극성의 탄력 좋고 감촉이 우수한 필름상의 피막화장료를 얻을 수 있다.As described above, the transparent nose pack of the present invention employs polyvinylpyrrolidone and a VP/VA copolymer as a film forming agent, so that a film-like cosmetic material having low irritation and elasticity and excellent touch can be obtained.

또 피막화장료를 망사에 일체로 접합하여 막 형태가 유지되게 한 것이므로, 코 팩의 전체 두께를 대폭 줄일 수 있어서 콧등의 굴곡진 부분까지 완전하게 밀착하게 붙일 수 있다.In addition, since the film shape is maintained by integrally bonding the film cosmetic to the mesh, the overall thickness of the nose pack can be greatly reduced, so that it can be completely adhered to the curved part of the nose.

그리고 본 발명의 투명 코 팩에서는 피막화장료의 건조가 망사의 오프닝을 통하여 행해지기 때문에 종래의 부직포를 채용한 코 팩에 비하여 건조에 소요되는 시간이 짧다.In addition, in the transparent nose pack of the present invention, since drying of the coating material is performed through the opening of the mesh, the time required for drying is shorter than that of a nose pack employing a conventional nonwoven fabric.

게다가 본 발명의 제조방법은, 이형필름에 도포된 피막화장료가 건조로에 진입하기 전에 그 상면으로 망사를 피복하여 자연 침하하면서 건조로를 통과하여 완전 건조되게 하는 것이므로, 망사와 피막화장료 사이는 양호하게 접합 되고, 하나의 건조로만 필요로 하기 때문에 설비과다가 발생하지 않고 건조로의 운용도 간결하게 된다. In addition, the manufacturing method of the present invention is to completely dry by passing through the drying furnace while naturally submerging by covering the top surface of the coating cosmetic material applied to the release film before entering the drying furnace. In addition, since only one drying furnace is required, there is no excess of facilities, and the operation of the drying furnace is also simplified.

2: 이형필름 4: 저장조
6: 피막화장료층 8: 건조로
10: 망사
2: release film 4: storage tank
6: coating cosmetic layer 8: drying furnace
10: mesh

Claims (6)

폴리비닐피로리돈과 VP/VA 코폴리머, 하이드록시아세토페논과 1,2 헥산다이올, 다이포타슘글리시리제이트, 폴리소르베이트60과 소르비탄세스퀴올리에이트, 및 버지니아 풍년화 추출물이 변성 알코올과 정제수에 분산 용해된 피막 조성물을 이형필름에 도포하고 반 건조하여 형성되는 피막화장료에 망사를 접합하여 일체화한 것을 특징으로 하는 투명 코 팩.
Polyvinylpyrrolidone and VP/VA copolymer, hydroxyacetophenone and 1,2 hexanediol, dipotassium glycyrrhizate, polysorbate 60 and sorbitan sesquioleate, and virginia nutrient extract were mixed with denatured alcohol. A transparent nose pack, characterized in that a coating composition dispersed and dissolved in purified water is applied to a release film, and a net is bonded to a coating cosmetic formed by semi-drying.
제1항에 있어서,
상기 피막 조성물에는 보습제로 알로에베라잎 추출물, 토코페릴아세테이트, 피부보호제로 다이메티콘이 더 첨가됨을 특징으로 하는 투명 코 팩.
The method of claim 1,
A transparent nose pack, characterized in that aloe vera leaf extract, tocopheryl acetate, and dimethicone as a skin protectant are further added to the coating composition as a moisturizing agent.
제1항에 있어서,
상기 피막 조성물은, 폴리비닐피로리돈 10~35 중량부, VP/VA 코폴리머 5~25 중량부, 하이드록시아세토페논 0.1~1.2 중량부, 1,2-헥산다이올 0.1~1.4 중량부, 다이포타슘글리시리제이트 0.01~0.50 중량부, 폴리소르베이트60 0.1~0.50 중량부, 소르비탄세스퀴올리에이트 0.03~0.07 중량부, 버지니아 풍년화 추출물 0.07~0.13 중량부를 함유하고 있는 것을 특징으로 하는 투명 코 팩.
The method of claim 1,
The coating composition is polyvinylpyrrolidone 10 to 35 parts by weight, VP/VA copolymer 5 to 25 parts by weight, hydroxyacetophenone 0.1 to 1.2 parts by weight, 1,2-hexanediol 0.1 to 1.4 parts by weight, die A transparent nose, characterized in that it contains 0.01 to 0.50 parts by weight of potassium glycyrrhizate, 0.1 to 0.50 parts by weight of polysorbate 60, 0.03 to 0.07 parts by weight of sorbitan sesquioleate, and 0.07 to 0.13 parts by weight of virginia nutrient extract. pack.
제2항에 있어서,
상기 보습제는 알로에베라잎 추출물 0.1 중량부, 토코페릴아세테이트 0.01 중량부이고, 피부보호제는 다이메티콘 0.5 중량부로 첨가됨을 특징으로 하는 투명 코 팩.
The method of claim 2,
The moisturizer is 0.1 parts by weight of aloe vera leaf extract, 0.01 parts by weight of tocopheryl acetate, and the skin protectant is added in 0.5 parts by weight of dimethicone.
제1항에 있어서,
상기 망사는 10~15 데니어의 나일론사로 평직 된 오프닝치수 0.84~2.00mm 범위의 것임을 특징으로 하는 투명 코 팩.
The method of claim 1,
The mesh is a transparent nose pack, characterized in that the opening dimension is in the range of 0.84 ~ 2.00mm plain weave of 10 ~ 15 denier nylon yarn.
이형필름의 이형제 처리된 표면으로 피막화장료 조성물을 도포하고 상기 피막화장료 조성물의 상면으로 망사를 피복하되, 이형필름과 망사를 등속으로 이동시켜서 상기 망사가 피막화장료의 표면에서 자연 침하 되면서 건조로를 통과하여 완전 건조됨으로써 상기 망사가 피막화장료에 일체로 접합 되도록 하는 것을 특징으로 하는 투명 코 팩의 제조방법. Apply the coating cosmetic composition to the surface treated with the release agent of the release film, and coat the mesh with the top surface of the coating cosmetic composition, but move the release film and the mesh at a constant velocity so that the mesh naturally settles on the surface of the coating cosmetic and passes through the drying furnace The method of manufacturing a transparent nose pack, characterized in that by being completely dried, the mesh is integrally bonded to the coating cosmetic.
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05221843A (en) 1992-02-12 1993-08-31 Kao Corp Keratinous plug remover
US20090068255A1 (en) * 2007-04-30 2009-03-12 Betty Yu Use of matrix metalloproteinase inhibitors in skin care
KR20170045613A (en) * 2015-10-19 2017-04-27 송하정 Mask pack and the process of manufacture
JP2019014671A (en) 2017-07-05 2019-01-31 三粧化研株式会社 Horny plug removal cosmetics
KR101962337B1 (en) * 2018-07-02 2019-03-26 주식회사 블리스팩 Porous Freeze-dried Patch and Method For Manufacturing The same
KR20190106713A (en) * 2018-03-06 2019-09-18 주식회사 이엠코퍼레이션 A composition for beauty pack having rapidly water-melting and method for mixing thereof, and beauty pack using the same

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05221843A (en) 1992-02-12 1993-08-31 Kao Corp Keratinous plug remover
US20090068255A1 (en) * 2007-04-30 2009-03-12 Betty Yu Use of matrix metalloproteinase inhibitors in skin care
KR20170045613A (en) * 2015-10-19 2017-04-27 송하정 Mask pack and the process of manufacture
JP2019014671A (en) 2017-07-05 2019-01-31 三粧化研株式会社 Horny plug removal cosmetics
KR20190106713A (en) * 2018-03-06 2019-09-18 주식회사 이엠코퍼레이션 A composition for beauty pack having rapidly water-melting and method for mixing thereof, and beauty pack using the same
KR101962337B1 (en) * 2018-07-02 2019-03-26 주식회사 블리스팩 Porous Freeze-dried Patch and Method For Manufacturing The same

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