KR20210002289A - Method for manufacturing textile having antibiotic and deodorant - Google Patents

Method for manufacturing textile having antibiotic and deodorant Download PDF

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KR20210002289A
KR20210002289A KR1020190078425A KR20190078425A KR20210002289A KR 20210002289 A KR20210002289 A KR 20210002289A KR 1020190078425 A KR1020190078425 A KR 1020190078425A KR 20190078425 A KR20190078425 A KR 20190078425A KR 20210002289 A KR20210002289 A KR 20210002289A
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fiber
deodorant
antibacterial
fibers
aqueous solution
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KR1020190078425A
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Korean (ko)
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임정혁
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임정혁
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/003Treatment with radio-waves or microwaves
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35Heterocyclic compounds
    • D06M13/352Heterocyclic compounds having five-membered heterocyclic rings
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/13Physical properties anti-allergenic or anti-bacterial
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2509/00Medical; Hygiene

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The present invention relates to a method of preparing antibacterial and deodorant fabrics. The method of preparing antibacterial and deodorant fabrics comprises the steps of: (S1) coating first fibers (F1) with an aqueous solution containing an antibacterial substance; (S2) irradiating a first high frequency to the first fibers (F1) coated with the aqueous solution containing an antibacterial substance so as to fixate the antibacterial substance composed of silver fine particles and isothiazolone onto the surface of the first fibers (F1); (S3) drying the first fibers (F1) to which the antibacterial substance is fixated to complete preparation of antibacterial fibers (F1′); (S4) coating second fibers (21) with an aqueous solution containing a deodorant substance; (S5) irradiating a second high frequency to the second fibers (F2) coated with the aqueous solution containing a deodorant substance so as to fixate the deodorant substance composed of silica powder, titanium oxide and zinc oxide onto a surface of the second fibers (F2); (S6) drying the second fibers (F2) to which the deodorant substance is fixated to complete preparation of deodorant fibers (F2′); and (S7) weaving the antibacterial fibers (F1′) and the deodorant fibers (F2′).

Description

고분자수지를 이용한 항균성 의료용품 및 이의 제조방법{Method for manufacturing textile having antibiotic and deodorant}Antimicrobial medical supplies using polymer resin and method for manufacturing the same{Method for manufacturing textile having antibiotic and deodorant}

본 발명은 원단 제조방법에 관한 것으로서, 더욱 상세하게는 우수한 항균 및 소취 능력은 물론 뛰어난 세탁견뢰도를 가지는 항균 및 소취 원단 제조방법에 관한 것이다.The present invention relates to a fabric manufacturing method, and more particularly, to an antibacterial and deodorant fabric manufacturing method having excellent antibacterial and deodorizing ability as well as excellent washing fastness.

일반 가정에서 사용하는 이불, 패드, 소파, 카펫 등의 섬유제품이나 유아용품, 양말, 속옷 등의 의류제품에는황색포도상구균, 폐렴균 등의 각종 세균이나 집먼지 진드기가 번식하여 각종 질병이나 아토피성 피부염, 알레르기 피부염 등을 유발하고 있다. 이러한 세균 및 진드기는 유아, 어린이 및 노약자에게는 건강에 심각한 위협이될 수 있으며, 특히 집먼지 진드기의 사체나 배설물은 아토피 피부염이나 알레르기 피부염을 유발하는 대표적물질로 알려져 있다.Textile products such as blankets, pads, sofas, carpets, and clothing products such as baby products, socks, and underwear used in general homes have various bacteria and house dust mites such as yellow staphylococcus aureus, pneumonia, and various diseases, atopic dermatitis, etc. It causes allergic dermatitis. These bacteria and mites can pose a serious threat to health to infants, children and the elderly, and in particular, the carcasses and excrement of house dust mites are known as representative substances that cause atopic dermatitis or allergic dermatitis.

한편, 은(銀)은 650여 가지 이상의 세균을 살균하는 강력한 항균성 또는 살균성을 나타내면서도 인체에 해가 없는 금속으로, 오래 전부터 신변품 및 생활용품으로 사용되어 왔다. 그리고 최근에는 나노크기의 은미립자를 제조하는 기술의 발달과 함께 은미립자를 원단에 적용하여 항균성을 가지는 원단을 제조하는 방법이 대한민국 등록번호 10-0688675를 통하여 알려져 있다. On the other hand, silver (銀) is a metal that does not harm the human body while showing strong antibacterial or sterilizing properties that sterilize more than 650 kinds of bacteria, and has been used as a new product and household goods for a long time. And recently, with the development of technology for manufacturing nano-sized fine silver particles, a method of manufacturing a fabric having antimicrobial properties by applying silver fine particles to a fabric is known through Korean Registration No. 10-0688675.

선행기술에 따르면, 은미립자를 원단에 적용하기 위하여, 제직된 상태의 초기 원단을 마련하는 단계와, 상기 마련된 원단에서 불순물을 제거하는 전처리단계와, 상기 불순물이 제거된 원단을 은미립자가 투입된 염료로 염색 According to the prior art, in order to apply the fine silver particles to the fabric, the steps of preparing an initial fabric in a woven state, a pretreatment step of removing impurities from the prepared fabric, and a dye in which the silver fine particles are added to the fabric from which the impurities are removed Dyed with

하는 단계와, 상기 염색된 원단을 수세하고 건조시키는 후처리단계를 수행함으로서 은미립자가 포함된 항균원단을 제조할 수 있었다.The antimicrobial fabric containing silver fine particles could be prepared by performing the step and a post-treatment step of washing and drying the dyed fabric with water.

그런데 상기한 방법에 따르면, 반복적인 세탁을 함에 따라, 염료에서 은미립자가 탈락하는 현상이 발생하였고,이에 따라 원단의 항균효과가 급속히 감소되었다라는 문제점이 있었다. However, according to the method described above, there was a problem that silver fine particles were eliminated from the dye due to repeated washing, and accordingly, the antibacterial effect of the fabric was rapidly reduced.

본 발명은 상기한 문제점을 해결하기 위하여 창출된 것으로서, 반복적인 세탁을 하더라도 초기의 항균 및 소취능력을 유지할 수 있는 항균 및 소취 원단 제조방법을 제공하는 것을 목적으로 한다.The present invention has been created in order to solve the above problems, and an object of the present invention is to provide a method of manufacturing an antibacterial and deodorizing fabric capable of maintaining initial antibacterial and deodorizing ability even if repeatedly washed.

본 발명의 다른 목적은, 강력한 항균성 및 소취성을 유지할 수 있는 항균 및 소취 원단 제조방법을 제공하는 것이다. Another object of the present invention is to provide a method for producing antibacterial and deodorizing fabrics capable of maintaining strong antibacterial and deodorizing properties.

기와 같은 목적을 달성하기 위하여, 본 발명에 따른 항균 및 소취 원단 제조방법은, 제1섬유(F1)를 항균성물질 수용액으로 도포하는 단계(S1); 상기 항균성물질 수용액이 도포된 제1섬유(F1)에 제1고주파를 조사하여, 상기 제1섬유(F1)의 표면에 은미립자와 이소티아졸론으로 구성된 항균성물질을 고착시키는 단계(S2); 상기 항균성물질이 고착된 제1섬유(F1)를 건조시켜 항균섬유(F1')을 완성하는 단계(S3); 제2섬유(21)를 소취성 물질 수용액으로 도포하는 단계(S4); 상기 소취성 물질 수용액이 도포된 제2섬유(F2)에 제2고주파를 조사하여, 상기 제2섬In order to achieve the same object, the antibacterial and deodorant fabric manufacturing method according to the present invention comprises the steps of applying a first fiber (F1) with an aqueous antibacterial substance solution (S1); Irradiating a first high frequency to the first fiber (F1) coated with the antimicrobial material aqueous solution, and fixing the antimicrobial material composed of silver fine particles and isothiazolone on the surface of the first fiber (F1) (S2); Drying the first fiber (F1) to which the antimicrobial material is fixed to complete the antibacterial fiber (F1') (S3); Applying the second fiber 21 with an aqueous deodorant solution (S4); By irradiating a second high frequency to the second fiber (F2) coated with the aqueous deodorant solution, the second island

유(F2)의 표면에 실리카분말, 산화티타늄 및 산화아연으로 구성된 소취성물질을 고착시키는 단계(S5); 상기 소취성 물질이 고착된 제2섬유(F2)를 건조시켜 소취섬유(F2')을 완성하는 단계(S6); 및 상기 항균섬유(F1')와 소Fixing a deodorant material composed of silica powder, titanium oxide, and zinc oxide on the surface of oil (F2) (S5); Drying the second fiber (F2) to which the deodorant material is fixed to complete the deodorizing fiber (F2') (S6); And the antibacterial fiber (F1') and cattle

취섬유(F2')를 제직하는 단계(S7);를 포함하는 것을 특징으로 한다.It characterized in that it comprises a; step (S7) of weaving the fiber (F2').

본 발명에 있어서, 상기 항균성물질 수용액은, 상기 은미립자를 이소티아졸론(Isothiazolones)[0009] 과 혼합하여 항균성물질을 제조하고, 상기 항균성물질을 바인더 수지와 함께 물에 균일하게 분산시켜 제조한다. 이때 상기 항균In the present invention, the antimicrobial material aqueous solution is prepared by mixing the silver fine particles with isothiazolones to prepare an antimicrobial material, and the antimicrobial material is uniformly dispersed in water with a binder resin. At this time, the antibacterial

성물질 수용액은, 상기 은미립자 01 ~ 05%, 이소티아졸론 05 ~ 1% 및 바인더 수지 5 ~ 20% 가, 항균성물질수용액의 총량을 100% 로 하기 위한 나머지량의 물속에 분산 또는 용해되어 제조된다.The aqueous solution of the acid substance is prepared by dispersing or dissolving in the remaining amount of water to make the total amount of the aqueous solution of the antimicrobial substance 100% with the silver fine particles 01 to 05%, isothiazolone 05 to 1%, and 5 to 20% binder resin. do.

본 발명에 있어서, 상기 소취성물질 수용액은, 상기 실리카, 산화티타튬 및 산화아연을 분쇄한 후 혼합하여 소취성물질을 제조하고, 상기 소취성물질을 바인더 수지와 함께 물에 균일하게 분산시켜 제조된다. 이때 상기 소취성물질 수용액은, 상기 실리카 2 ~ 4%, 상기 산화티타늄 03 ~ 08%, 상기 산화아연 03 ~ 1% 및 상기 바인더 수지 5 ~ 20% 가, 소취성물질 수용액의 총량을 100% 로 하기 위한 나머지량의 물속에 분산 또는 용해되어 제조된다. 그리고 상기 실리카 분말은 평균입경이 01 내지 10 ㎛의 다공성 실리카이고; 상기 산화티타늄 분말은평균입경이 10 nm 내지 100nm 이며; 상기 산화아연 분말은 평균입경이 10 nm 내지 100nm 이다. In the present invention, the deodorant aqueous solution is prepared by pulverizing and mixing the silica, titanium oxide, and zinc oxide to prepare a deodorant substance, and the deodorant substance is uniformly dispersed in water with a binder resin. do. At this time, the aqueous solution of the deodorant is 2 to 4% of the silica, 03 to 08% of the titanium oxide, 03 to 1% of the zinc oxide, and 5 to 20% of the binder resin, and the total amount of the aqueous solution of the deodorant is 100%. It is prepared by dispersing or dissolving in the remaining amount of water. And the silica powder is a porous silica having an average particle diameter of 01 to 10 ㎛; The titanium oxide powder has an average particle diameter of 10 nm to 100 nm; The zinc oxide powder has an average particle diameter of 10 nm to 100 nm.

본 발명에 있어서, 상기 단계(S3)는, 제1건조실(30)에서 상기 제1섬유(F1)가 이송되는 동안 제1송풍기(31)40~70℃ 범위의 건조온도를 가지는 열풍을 인가하고, 상기 제1섬유(F1)가 상기 제1건조실(30)에서 체류하는 건조시간을 1 ~ 3초로 하는 단계이고; 상기 단계(S6)는, 제2건조실(60)에서 상기 제2섬유(F2)가 이송되는 동안 제 In the present invention, the step (S3), while the first fiber (F1) is transferred from the first drying chamber (30), the first blower (31) applying hot air having a drying temperature in the range of 40 ~ 70 ℃, , The drying time for the first fiber (F1) to stay in the first drying chamber 30 is 1 to 3 seconds; The step (S6), while the second fiber (F2) is transferred in the second drying chamber (60).

2송풍기(61)가 40~70℃ 범위의 건조온도를 가지는 열풍을 인가하고, 상기 제2섬유(F2)가 상기 제2건조실(60)에서 체류하는 건조시간을 1 ~ 3초로 하는 단계이다.2 This is a step in which the blower 61 applies hot air having a drying temperature in the range of 40 to 70° C., and the drying time for the second fiber F2 to stay in the second drying chamber 60 is set to 1 to 3 seconds.

본 발명에 따르면, 항균성물질 수용액이 도포된 제1섬유에 제1고주파를 조사하여 제1섬유의 표면에 은미립자와이소티아졸론으로 구성된 항균성물질을 고착시키고; 소취성 물질 수용액이 도포된 제2섬유에 제2고주파를 조사하여 제2섬유의 표면에 실리카분말, 산화티타늄 및 산화아연으로 구성된 소취성물질을 고착시킴으로써, 반복적인 세탁에도 항균성 및 소취성을 유지할 수 있는 우수한 세탁견뢰도를 구현할 수 있다.According to the present invention, by irradiating the first high frequency to the first fiber coated with the antimicrobial material aqueous solution to fix the antimicrobial material consisting of silver fine particles and isothiazolone on the surface of the first fiber; By irradiating a second high frequency to the second fiber coated with an aqueous deodorant solution, the deodorant material consisting of silica powder, titanium oxide, and zinc oxide is fixed on the surface of the second fiber, thereby maintaining antibacterial and deodorizing properties even in repeated washing. It can implement excellent washing fastness that can be achieved.

또한 항균성을 유지하는 항균섬유(F1')와, 소취성을 유지하는 소취섬유(F2')를 별도로 제조한 후 제직하여 원단을 구현함으로써, 우수한 향균성 및 소취성을 기대할 수 있다라는 작용, 효과가 있다. In addition, by separately manufacturing the antibacterial fiber (F1') that maintains antibacterial properties and the deodorant fiber (F2') that maintains deodorant properties, and then weaving to implement the fabric, excellent antibacterial and deodorant properties can be expected. There is.

도 1은 본 발명의 항균 및 소취 원단을 제조하기 위한 장치의 개략적 구성도,도 2는 본 발명에 따른 항균섬유 및 소취섬유의 표면을 확대하여 도시한 도면.Figure 1 is a schematic configuration diagram of an apparatus for manufacturing an antibacterial and deodorant fabric of the present invention, Figure 2 is a view showing an enlarged surface of the antibacterial fiber and deodorant fiber according to the present invention.

이하, 본 발명에 따른 항균 및 소취 원단 제조방법을 첨부된 도면을 참조하여 상세히 설명한다.Hereinafter, a method of manufacturing an antibacterial and deodorizing fabric according to the present invention will be described in detail with reference to the accompanying drawings.

도 1은 본 발명의 항균 및 소취 원단을 제조하기 위한 장치의 개략적 구성도이고, 도 2는 본 발명에 따른 항균섬유 및 소취섬유의 표면을 확대하여 도시한 도면이다. 1 is a schematic configuration diagram of an apparatus for manufacturing an antibacterial and deodorizing fabric of the present invention, and FIG. 2 is a view showing an enlarged surface of an antibacterial fiber and a deodorizing fiber according to the present invention.

먼저 본 발명에 따른 항균 및 소취 원단을 제조하는 장치는, 제1섬유(F1)가 롤형태로 권회된 제1섬유롤(P1)과,제1섬유(F1)에 도포되는 항균성 물질 수용액이 담겨진 항균성물질 수용조(10), 항균성물질 수용조(10)에서 항균성 물질이 도포된 제1섬유(F1)에 제1고주파를 조사하는 제1고주파오븐(20)과, 제1고주파오븐(20)을 경유한 제1섬유(F1)를 건조하기 위한 제1건조실(30)과, 제1건조실(30)을 경유하면서 완성된 항균섬유(F1')를 감기위한 제1감기롤(P1')과, 제2섬유(F2)가 롤형태로 권회된 제2섬유롤(P2)과, 제2섬유(F2)에 도포되는 소취성 물질 수용액이 담겨진 소취성물질 수용조(40)와, 소취성물질 수용조(40)에서 소취성 물질이 도포된 제2섬유(F2)에 제2고주파를 제2고주파오븐(50)과, 제2고주파오븐(50)을 경유한 제2섬유(F2)를 건조하기 위한 제2건조실(60)과, 제2건조실(60)을 경유하면서 완성된 소취원단(F2')를 감기위한 제2감기롤(P2')를 포함한다. First, the apparatus for manufacturing an antibacterial and deodorant fabric according to the present invention includes a first fiber roll (P1) in which a first fiber (F1) is wound in a roll form, and an aqueous solution of an antimicrobial substance applied to the first fiber (F1). An antimicrobial material receiving tank 10, a first high frequency oven 20 irradiating a first high frequency to the first fiber F1 coated with an antimicrobial material in the antimicrobial material receiving tank 10, and a first high frequency oven 20 A first drying chamber 30 for drying the first fiber F1 passed through, and a first winding roll P1' for winding the finished antibacterial fiber F1' while passing through the first drying chamber 30, and , A second fiber roll (P2) in which a second fiber (F2) is wound in a roll form, a deodorant material receiving tank 40 containing an aqueous solution of a deodorant material applied to the second fiber (F2), and a deodorant material In the receiving tank 40, the second high frequency is applied to the second fiber F2 coated with the deodorant material, and the second high frequency oven 50 and the second fiber F2 passed through the second high frequency oven 50 are dried. It includes a second drying chamber (60) for winding, and a second winding roll (P2') for winding the finished deodorizing fabric (F2') while passing through the second drying chamber (60).

항균성물질 수용조(10)에는 제1섬유(F1)에 항균성물질 수용액을 도포하기 위한 한쌍의 제1도포롤러(15a)(15b)가설치된다. 제1도포롤러(15a)(15b)중 하나는 항균성물질 수용액에 담겨져 회전됨으로서, 제1도포롤러(15a)(15b)사이를 경유하는 제1섬유(F1)의 표면에 항균성물질 수용액을 도포한다.The antimicrobial material receiving tank 10 is provided with a pair of first coating rollers 15a and 15b for applying the antimicrobial material aqueous solution to the first fiber F1. One of the first coating rollers 15a and 15b is immersed in an aqueous solution of an antimicrobial material and rotated, so that an aqueous solution of an antimicrobial material is applied to the surface of the first fiber F1 passing between the first coating rollers 15a and 15b. .

소취성물질 수용조(40)에는 제2섬유(F2)에 소취성물질 수용액을 도포하기 위한 한쌍의 제2도포롤러(45a)(45b)가설치된다. 제2도포롤러(45a)(45b)중 하나는 소취성물질 수용액에 담겨져 회전됨으로서, 제2도포롤러(45a)(45b) A pair of second coating rollers 45a and 45b for applying an aqueous deodorant solution to the second fiber F2 is installed in the deodorant material receiving tank 40. One of the second coating rollers 45a and 45b is immersed in an aqueous deodorant solution and rotated, so that the second coating rollers 45a and 45b

사이를 경유하는 제2섬유(F2)의 표면에 소취성물질 수용액을 도포한다.A deodorant aqueous solution is applied to the surface of the second fiber (F2) passing through it.

제1고주파오븐(20)은, 상호 이격되고 엇갈리게 고주파발생부(21)(22)가 설치된다. 이에 따라 제1고주파오븐(20)을 경유하는 제1섬유(F1)의 일측면 및 타측면에 제1고주파가 고르게 인가된다.The first high-frequency oven 20 is spaced apart from each other and alternately, high-frequency generation units 21 and 22 are installed. Accordingly, the first high frequency is evenly applied to one side and the other side of the first fiber F1 passing through the first high frequency oven 20.

제2고주파오븐(50)은, 상호 이격되고 엇갈리게 고주파발생부(51)(52)가 설치된다. 이에 따라 제2고주파오븐(50)을 경유하는 제2섬유(F2)의 일측면 및 타측면에 제2고주파가 고르게 인가된다. The second high frequency oven 50 is spaced apart from each other, and the high frequency generators 51 and 52 are installed alternately. Accordingly, the second high frequency is evenly applied to one side and the other side of the second fiber F2 passing through the second high frequency oven 50.

제1,2건조실(30)(60) 각각의 내부에는 제1,2섬유(F1)(F2)를 지지하는 다수개의 롤러(30a)(60a)가 설치되고, 제1,2건조실(30)(60) 각각의 외부에는 건조를 위한 바람을 송풍하는 제1,2송풍기(31)(61)가 설치된다.Inside each of the first and second drying chambers 30 and 60, a plurality of rollers 30a and 60a supporting the first and second fibers F1 and F2 are installed, and the first and second drying chambers 30 (60) First and second blowers 31 and 61 for blowing wind for drying are installed outside each.

상기한 장치에서는 용이한 설명을 위하여, 한가닥의 제1섬유(F1)에 항균처리하고, 한가락의 제2섬유(F2)에 소취처리를 하는 것으로 개시되어 있으나, 여러가닥의 제1섬유 및 제2섬유에 항균 및 소취처리할 수 있음은 물론이다. In the above-described device, for easy explanation, it is disclosed that antibacterial treatment is performed on the first fiber (F1) of one strand and deodorization treatment is performed on the second fiber (F2) of one strand. Of course, it can be antibacterial and deodorant on fibers.

다음, 상기한 항균 및 소취 원단 제조장치에 의하여 수행되는 본 발명에 따른 항균소취 원단 제조방법을 설명한다. Next, an antibacterial and deodorizing fabric manufacturing method according to the present invention performed by the above antibacterial and deodorizing fabric manufacturing apparatus will be described.

[0025] 본 발명에서 사용되는 제1,2섬유(F1)(F2)는 아크릴, 폴리에스테르. 나일론으로 이루어진 군에서 선택되는 어느The first and second fibers used in the present invention (F1) (F2) are acrylic, polyester. Any selected from the group consisting of nylon

하나를 사용한다.Use one

본 발명에 따른 항균 및 소취 원단 제조방법을 수행하기 위하여, 먼저 제1섬유(F1)를 항균성물질 수용액으로 도포하는 단계(S1)를 수행한다. 단계(S1)는 제1섬유(F1)를 제1도포롤러(15a)(15b) 사이를 통과시킴으로써 수행되는데, 이때 항균성 물질은 수용액 상태로 제1섬유(F1)에 도포되므로 제1섬유(F1)의 표면에 고르게 도포된다.In order to perform the antibacterial and deodorant fabric manufacturing method according to the present invention, first, a step (S1) of applying the first fiber (F1) with an aqueous antibacterial material solution is performed. Step (S1) is carried out by passing the first fiber (F1) between the first coating rollers (15a, 15b), at this time, the antimicrobial material is applied to the first fiber (F1) in an aqueous solution state, so the first fiber (F1) ) Is evenly applied to the surface.

항균성물질 수용액은, 은미립자를 이소티아졸론(Isothiazolones)과 혼합하여 항균성물질을 제조하고, 항균성물질을 우레탄 수지, 아크릴 수지, 불소계 수지 및 멜라민 수지로 이루어진 그룹에서 선택된 적어도 어느 하나의바인더 수지와 함께 물에 균일하게 분산시켜 제조한다.The antimicrobial material aqueous solution is mixed with silver fine particles with isothiazolones to prepare an antimicrobial material, and the antimicrobial material is mixed with at least one binder resin selected from the group consisting of urethane resin, acrylic resin, fluorine resin, and melamine resin. It is prepared by uniformly dispersing in water.

이러한 항균성물질 수용액은, 은미립자 01 ~ 05%, 이소티아졸론 05 ~ 1% 및 바인더 수지 5 ~ 20% 가, 항균성물질 수용액의 총량을 100% 로 하기 위한 나머지량의 물속에 분산 또는 용해되어 제조된다. Such an aqueous solution of antimicrobial substances is prepared by dispersing or dissolving in the remaining amount of water to make the total amount of the antimicrobial substance aqueous solution 100%, silver fine particles 01 to 05%, isothiazolone 05 to 1%, and binder resin 5 to 20%. do.

은미립자 및 이소티아졸론의 함량을 상기 범위 미만으로 사용하면 항균 특성이 충분하지 못할 염려가 있고, 상기 범위 이상으로 사용하면 균일하게 분산된 항균성물질을 얻기 어렵다. 또한 바인더 수지의 함량이 상기 범위미만이면, 제1섬유(F1)에 항균성물질을 효과적으로 부착시키기 어렵고, 상기 범위 이상이면 제1섬유(F1)의 촉감이 뻣뻣해지는 등 물성이 나빠지는 문제점이 있다. If the content of silver fine particles and isothiazolone is less than the above range, there is a fear that the antimicrobial properties may not be sufficient, and if the content of the silver fine particles and isothiazolone is less than the above range, it is difficult to obtain a uniformly dispersed antimicrobial material. In addition, if the content of the binder resin is less than the above range, it is difficult to effectively attach the antimicrobial material to the first fiber (F1), and if it is more than the above range, the first fiber (F1) has a problem of deteriorating physical properties such as stiff touch.

상기 은미립자는 평균입경 1 nm 내지 100nm인 것이 바람직하다. 평균입경이 1 nm 미만이면 효과는 우수하나 제품가격이 급격히 상승하여 상업화에 문제점이 있고, 100nm를 초과하면 항균성물질 수용액에서 분산성이 저하되는 문제점이 있다. 은미립자는 그대로 항균성물질에 투입될 수도 있지만, 졸(sol) 상태의 콜로이드 액으로 시판되는 것을 사용할 수도 있고, 이 경우 분산성이 좋아지는 이점이 있다. It is preferable that the silver fine particles have an average particle diameter of 1 nm to 100 nm. If the average particle diameter is less than 1 nm, the effect is excellent, but the product price rises rapidly and there is a problem in commercialization, and if it exceeds 100 nm, there is a problem that the dispersibility in the aqueous solution of the antimicrobial substance decreases. The silver fine particles may be added to the antimicrobial material as they are, but commercially available as colloidal solutions in a sol state may be used, and in this case, there is an advantage of improving dispersibility.

[0031] 은미립자는 입경이 작을수록 살균 및 항균력이 우수하며 지금까지 실험한 자료들을 검토하여 볼 때 대장균, 황색 포도상구균, 살모넬라균, 비브리오균, 이질균, 폐렴균, 장티푸스균 및 내성이 가장 강한 MRSA(메티실린내성황색포도상구균)까지 999% 항균 및 살균한다고 보고된 바 있다. 즉, 은미립자는 10nm의 유해균에 직접 작용하는데, 유해균의 세포막을 녹여서 세포 내의 효소와 작용하여 영양물질 유입 및 배출을 차단하고 유해균의 호흡기능을 막아 세포 내 APT 생성을 막고 유해균의 생육정지 및 재생 능력을 파괴하여 유해균을 단시간 내에 사멸시킨다. 따라서 거의 모든 세균은 은미립자와 5분 이상 접촉하여 살 수 없다는 결과가 보고되어 있다[0031] Silver fine particles are excellent in sterilization and antibacterial activity as the particle size is smaller, and when reviewing the data tested so far, E. coli, Staphylococcus aureus, Salmonella, Vibrio, Shigella, pneumococcal, typhoid and MRSA with the strongest resistance (Methicillin-resistant yellow staphylococcus) has been reported to be 999% antibacterial and sterilizing. In other words, silver fine particles act directly on harmful bacteria of 10 nm, and by melting the cell membrane of harmful bacteria, they act with enzymes in the cell to block the inflow and discharge of nutrients, and block the respiratory function of harmful bacteria to prevent the production of APT in the cell, and to stop and regenerate the growth of harmful bacteria. It destroys the ability to kill harmful bacteria in a short time. Therefore, it is reported that almost all bacteria cannot live in contact with silver fine particles for more than 5 minutes.

이소티아졸론은 분말형태로서 박테리아, 곰팡이, 조류 등의 동ㅇ식물로부터 유래한 많은 유해생물에 대하여 광범위한 살균 활성을 가지는 화합물이다. 이러한 이소티아졸론은 유해 미생물의 생장을 억제하는 용도로 사용된다.Isothiazolone is a compound that has a wide range of bactericidal activity against many harmful organisms derived from animals and plants such as bacteria, fungi, and algae in powder form. This isothiazolone is used to inhibit the growth of harmful microorganisms.

상기한 은미립자와 이소티아졸론으로 구성된 항균성물질은 시너지효과를 발생하여 강력한 항균능력을 발휘한다. The antimicrobial material composed of the silver fine particles and isothiazolone generates a synergistic effect and exerts a strong antibacterial ability.

다음, 이송되어 오는 항균성물질 수용액이 도포된 제1섬유(F1)에 제1고주파를 조사하여, 제1섬유(F1)의 표면에은미립자와 이소티아졸론으로 구성된 항균성물질을 고착시키는 단계(S2)를 수행한다. Next, the step of irradiating the first high frequency to the first fiber (F1) to which the transferred antimicrobial material aqueous solution is applied, and fixing the antimicrobial material composed of silver fine particles and isothiazolone on the surface of the first fiber (F1) (S2) Perform.

단계(S2)는 항균성물질 수용액이 도포된 제1섬유(F1)를 제1고주파오븐(20)을 경유하는 동안에, 제1고주파를 제1 Step (S2), while passing through the first high-frequency oven 20, the first fiber (F1) coated with the antimicrobial material aqueous solution, the first high frequency

섬유(F1)에 조사하여 바인더 수지에 유전가열(dielectric heating) 현상을 유도함으로써 바인더 수지가 항균성물질을 제1섬유(F1)에 견고하게 고착되도록 하는 단계이다.This is a step in which the binder resin is firmly fixed to the first fiber F1 by irradiating the fiber F1 to induce a dielectric heating phenomenon in the binder resin.

제1섬유(F1)를 확대하였을 때, 도 2에 도시된 바와 같이, 제1섬유(F1)의 표면에는 수많은 미세한 홈(F1a)이 형성되어 있는데, 바인더 수지가 제1고주파에 의하여 순간 가열되면서 제1섬유(F1)의 표면에 형성된 미세한 홈F1a)으로 침투되고, 이에 따라 항균성물질(A1)은 제1섬유(F1)의 표면에 견고하게 고착된다. 이러한 단계(S2)를When the first fiber (F1) is enlarged, as shown in FIG. 2, a number of fine grooves (F1a) are formed on the surface of the first fiber (F1). As the binder resin is instantaneously heated by the first high frequency, It penetrates into the fine groove F1a formed on the surface of the first fiber F1, and accordingly, the antimicrobial material A1 is firmly fixed to the surface of the first fiber F1. This step (S2)

통하여, 항균성물질(A2)은 제1섬유(F1)에 견고하게 고착되고, 이에 따라 반복적인 세탁이나 자외선에 노출되더라도 항균성물질(A1)이 제1섬유(F1)로부터 탈락되지 않는다.Through this, the antimicrobial material A2 is firmly fixed to the first fiber F1, and accordingly, the antimicrobial material A1 is not removed from the first fiber F1 even when repeatedly washed or exposed to ultraviolet rays.

이때 제1섬유(F1)로 조사되는 제1고주파의 주파수는 10~40MHz 범위이고, 제1고주파오븐(20)에서의 체류시간은 1 3초이다. 만일 제1고주파의 주파수가 상기 범위 미만일 경우 바인더 수지에 유전가열 현상을 유도하기어렵고, 상기 범위 이상이면 제1섬유(F1) 자체의 물성을 변화되어 촉감이 뻣뻣해질 수 있다. 또 제1고주파오븐At this time, the frequency of the first high frequency irradiated with the first fiber F1 is in the range of 10 to 40 MHz, and the residence time in the first high frequency oven 20 is 13 seconds. If the frequency of the first high frequency is less than the above range, it is difficult to induce a dielectric heating phenomenon in the binder resin, and if it is more than the above range, the physical properties of the first fiber F1 itself may be changed and the touch may become stiff. Also the first high frequency oven

(20)에서의 체류시간이 상기 범위 미만일 경우 바인더 수지가 충분히 가열되지 못하고, 상기 범위 이상이면 제1섬유(F1)에서 유전가열 현상이 진행되어 물성이 변할 수 있다.If the residence time in (20) is less than the above range, the binder resin is not sufficiently heated, and if it is more than the above range, the dielectric heating phenomenon proceeds in the first fiber (F1) and physical properties may change.

다음, 이송되어 오는 항균성 물질이 고착된 제1섬유(F1)를 건조시켜 항균섬유(F1')을 완성하는 단계(S3)를 수행한다. 단계(S3)는 항균성 물질이 고착된 제1섬유(F1)를 제1건조실(30)을 통과시킴으로써 제1섬유(F1)에 잔류하Next, a step (S3) of completing the antibacterial fiber (F1') is performed by drying the first fiber (F1) to which the antimicrobial material to be transferred is fixed. Step (S3) is to remain in the first fiber (F1) by passing the first fiber (F1) to which the antimicrobial substance is fixed through the first drying chamber (30).

는 물을 제거하는 것이다.Is to remove water.

단계(S2)는 빠르게 진행되기 때문에, 제1섬유(F1)에 항균성 물질이 고착되더라도 물이 일부 잔류하는데, 이러한물은 제1건조실(30)을 경유하면서 완전히 제거된다. 제1건조실(30)에서는 제1섬유(F1)가 롤러(30a)를 따라 이송되는 동안 제1송풍기(31)가 40~70℃ 범위의 건조온도를 가지는 열풍을 인가하고, 제1섬유(F1)가 건조실(30)에서체류하는 건조시간을 1 ~ 3초로 한다. Since the step (S2) proceeds rapidly, even if the antimicrobial material is fixed to the first fiber (F1), some water remains, and this material is completely removed while passing through the first drying chamber (30). In the first drying chamber 30, while the first fibers F1 are conveyed along the rollers 30a, the first blower 31 applies hot air having a drying temperature in the range of 40 to 70°C, and the first fibers F1 The drying time that) stays in the drying room 30 is 1 to 3 seconds.

[0040] 만일 건조온도 및 건조시간이 상기 범위 미만일 경우 제1섬유(F1)로부터 물이 완전히 증발되지 못하고, 상기 범위 이상일 경우 제1섬유(F1)의 물성이 변화될 수 있다.If the drying temperature and drying time are less than the above range, water cannot be completely evaporated from the first fiber (F1), and if it is more than the above range, the physical properties of the first fiber (F1) may be changed.

다음, 제2섬유(21)를 소취성 물질 수용액에 함침시켜 그 표면에 상기 소취성 물질 수용액을 도포하는 단계(S4)를 수행한다. 단계(S4)는 제2섬유(F2)를 제2도포롤러(25a)(25b) 사이를 통과시킴으로써 수행되는데, 이때 소취성 물질은 수용액 상태로 제2섬유(F2)에 도포되므로 제2섬유(F2)에 고르게 도포된다. Next, a step (S4) of applying the aqueous solution of the deodorant substance to the surface of the second fiber 21 is impregnated with the aqueous solution of the deodorant substance (S4). Step (S4) is carried out by passing the second fiber (F2) between the second coating rollers (25a, 25b), at this time, the deodorant material is applied to the second fiber (F2) in an aqueous solution state, so the second fiber ( It is evenly applied to F2).

[0042] 소취성물질 수용액은, 실리카, 산화티타튬 및 산화아연을 분쇄한 후 혼합하여 소취성물질을 제조하고, 소취성물질은 우레탄 수지, 아크릴 수지, 불소계 수지 및 멜라민 수지로 이루어진 그룹에서 선택된 적어도 어느 하나의바인더 수지와 함께 물에 균일하게 분산시켜 제조한다.[0042] A deodorant aqueous solution is pulverized and mixed with silica, titanium oxide and zinc oxide to prepare a deodorant material, and the deodorant material is selected from the group consisting of a urethane resin, an acrylic resin, a fluorine resin and a melamine resin. It is prepared by uniformly dispersing in water together with at least one binder resin.

이러한 소취성물질 수용액은, 실리카 2 ~ 4%, 산화티타늄 03 ~ 08%, 산화아연 03 ~ 1% 및 바인더 수지 5 ~20% 가, 소취성물질 수용액의 총량을 100% 로 하기 위한 나머지량의 물속에 분산 또는 용해되어 제조된다.The aqueous solution of such a deodorant substance contains 2 to 4% of silica, 03 to 08% of titanium oxide, 03 to 1% of zinc oxide, and 5 to 20% of the binder resin, and the remaining amount to make the total amount of the aqueous solution of the deodorant 100%. It is prepared by dispersing or dissolving in water.

실리카, 산화티타늄 및 산화아연을 함량을 상기 범위 미만으로 사용하면 소취 특성이 충분하지 못할 염려가 있고, 상기 범위 이상으로 사용하면 균일하게 분산된 소취성물질을 얻기 어렵다. 또한 바인더 수지의 함량이 상기범위 미만이면, 제2섬유(F2)에 소취성물질을 효과적으로 부착시키기 어렵고, 상기 범위 이상이면 제2섬유(F2)의촉감이 뻣뻣해지는 등 물성이 나빠지는 문제점이 있다. If the content of silica, titanium oxide, and zinc oxide is less than the above range, there is a fear that the deodorizing property may not be sufficient, and if it is used above the above range, it is difficult to obtain a uniformly dispersed deodorant material. In addition, when the content of the binder resin is less than the above range, it is difficult to effectively attach the deodorant material to the second fiber (F2), and when the content of the binder resin is above the above range, there is a problem that the physical properties are deteriorated, such as stiff touch of the second fiber (F2) .

실리카 분말은 무색 투명한 고체로 평균입경 01 내지 10 ㎛의 다공성 실리카인 것이 바람직하다. 평균입경이01㎛ 미만이면 표면적 증가로 우수한 효과를 발휘하지만 가격이 상승하는 문제점이 있고, 10 ㎛ 를 초과하면세탁내구성이 저하되는 문제점이 있다. 다공성 실리카 분말은 미세한 다공으로 악취성분을 포집하는 역할을 한The silica powder is a colorless transparent solid and is preferably a porous silica having an average particle diameter of 01 to 10 µm. If the average particle diameter is less than 01 µm, it exhibits excellent effects by increasing the surface area, but there is a problem of increasing the price, and if it exceeds 10 µm, there is a problem that the washing durability is deteriorated. Porous silica powder plays a role in collecting odor components with fine porosity.

다.All.

산화티타늄 분말은 평균입경 10 nm 내지 100nm인 것이 바람직하다. 평균입경이 10 nm 미만이면 효과는 우수하나제품가격이 급격히 상승하여 상업화에 문제점이 있고, 100nm를 초과하면 수용액 제조시 분산성이 저하되는 문제점이 있다. It is preferable that the titanium oxide powder has an average particle diameter of 10 nm to 100 nm. If the average particle diameter is less than 10 nm, the effect is excellent, but the product price rises rapidly and there is a problem in commercialization. If the average particle diameter exceeds 100 nm, there is a problem that the dispersibility is lowered when preparing an aqueous solution.

[0047] 산화아연 분말은 평균입경 10 nm 내지 100nm인 것이 바람직하다. 평균입경이 10 nm 미만이면 효과는 우수하나제품가격이 급격히 상승하여 상업화에 문제점이 있고, 100nm를 초과하면 수용액 제조시 분산성이 저하되는 문제점이 있다.It is preferable that the zinc oxide powder has an average particle diameter of 10 nm to 100 nm. If the average particle diameter is less than 10 nm, the effect is excellent, but the product price rises rapidly and there is a problem in commercialization. If the average particle diameter exceeds 100 nm, there is a problem that the dispersibility is lowered when preparing an aqueous solution.

상기한 산화티타늄 및 산화아연은 광분해 촉매능을 가짐으로써 악취성분을 분해 제거한다. 또한 산화티타늄, 산화아연 및 실리카로 구성된 소취성물질은 시너지효과를 발생하여 강력한 소취능력을 발휘한다.The titanium oxide and zinc oxide described above decompose and remove odor components by having a photodecomposition catalytic ability. In addition, deodorant substances composed of titanium oxide, zinc oxide and silica generate a synergistic effect and exert a strong deodorizing ability.

다음, 이송되어 오는 소취성 물질 수용액이 도포된 제2섬유(F2)에 제2고주파를 조사하여 제2섬유(F2)의 표면에실리카분말, 산화티타늄 및 산화아연으로 구성된 소취성물질을 고착시키는 단계(S5)를 수행한다. Next, by irradiating a second high frequency to the second fiber (F2) coated with the transferred deodorant aqueous solution, the deodorant material consisting of silica powder, titanium oxide, and zinc oxide is fixed on the surface of the second fiber (F2). Step S5 is performed.

단계(S2)는 소취성물질 수용액이 도포된 제2섬유(F2)를 제2고주파오븐(20)을 경유하는 동안에, 제2고주파를 제2섬유(F2)에 조사하여 바인더 수지에 유전가열 현상을 유도함으로써 바인더 수지가 소취성물질을 제2섬유(F2)에견고하게 고착시키는 단계이다.Step (S2) is a dielectric heating phenomenon in the binder resin by irradiating the second high frequency to the second fiber (F2) while passing the second fiber (F2) coated with the deodorant aqueous solution through the second high frequency oven (20). This is a step in which the binder resin firmly adheres the deodorant material to the second fiber (F2) by inducing it.

도 2에 도시된 바와 같이, 제2섬유(F2) 역시 확대하였을 때 그 표면에는 수많은 미세한 홈(A2)이 형성되어 있는데, 바인더 수지가 제2고주파에 의하여 순간 가열되면서 제2섬유(F2)의 표면에 형성된 미세한 홈으로 침투되고,이에 따라 소취성물질(A2)은 제2섬유(F2)의 표면에 견고하게 고착된다. 이러한 단계(S5)를 통하여, 소취성물질(A2)은 제2섬유(F2)에 견고하게 고착되고, 이에 따라 반복적인 세탁이나 자외선에 노출되더라도 소취성물질(A2)이 제2섬유(F2)로부터 탈락되지 않는다. As shown in FIG. 2, when the second fiber F2 is also enlarged, numerous fine grooves A2 are formed on its surface. As the binder resin is instantaneously heated by the second high frequency, the second fiber F2 Penetrates into the fine grooves formed on the surface, and accordingly, the deodorant material A2 is firmly fixed to the surface of the second fiber F2. Through this step (S5), the deodorant material (A2) is firmly fixed to the second fiber (F2), and accordingly, even if repeatedly washed or exposed to ultraviolet rays, the deodorant material (A2) is converted into the second fiber (F2). Is not eliminated from

이때 제2섬유(F2)로 조사되는 제2고주파의 주파수는 10~40MHz 범위이고, 제2고주파오븐(20)에서의 체류시간은 1~ 3초이다. 만일 제1고주파의 주파수가 상기 범위 미만일 경우 바인더 수지에 유전가열 현상을 유도하기어렵고, 상기 범위 이상이면 제2섬유(F2) 자체의 물성을 변화되어 촉감이 뻣뻣해질 수 있다. 또 제2고주파오븐At this time, the frequency of the second high frequency irradiated with the second fiber F2 is in the range of 10 to 40 MHz, and the residence time in the second high frequency oven 20 is 1 to 3 seconds. If the frequency of the first high frequency is less than the above range, it is difficult to induce dielectric heating in the binder resin, and if it is more than the above range, the physical properties of the second fiber F2 itself may be changed and the touch may become stiff. Another 2nd high frequency oven

(50)에서의 체류시간이 상기 범위 미만일 경우 바인더 수지가 충분히 가열되지 못하고, 상기 범위 이상이면 제2섬유(F2)의 물성이 변화될 수 있다.If the residence time in (50) is less than the above range, the binder resin is not sufficiently heated, and if it is more than the above range, the physical properties of the second fiber (F2) may be changed.

다음, 이송되어 오는 소취성 물질이 고착된 제2섬유(F2)를 건조시켜 소취섬유(F2')을 완성하는 단계(S6)를 수행한다. 단계(S6)는 소취성 물질이 고착된 제2섬유(F2)를 제2건조실(60)을 통과시킴으로써, 제1섬유(F1)에 잔류 Next, a step (S6) of completing the deodorant fiber (F2') is performed by drying the second fiber (F2) to which the deodorant material to be transferred is fixed. Step (S6) is by passing the second fiber (F2) to which the deodorant material is fixed through the second drying chamber (60), remaining in the first fiber (F1).

하는 물을 제거하는 것이다.It is to remove the water.

단계(S6)는 빠르게 진행되기 때문에, 제2섬유(F2)에 항균성 물질이 고착되더라도 물이 일부 잔류하는데, 이러한물은 제2건조실(60)을 경유하면서 완전히 제거된다. 제2건조실(60)에서는 제2섬유(F2)가 롤러(60a)를 따라 이송되는 동안 제2송풍기(61)가 40~70℃ 범위의 건조온도를 가지는 열풍을 인가하고, 제2섬유(F2)가 제2건조실(60)에서 체류하는 건조시간을 1 ~ 3초로 한다.Since the step (S6) proceeds quickly, even if the antimicrobial material is fixed to the second fiber (F2), some water remains, and this material is completely removed while passing through the second drying chamber (60). In the second drying chamber 60, while the second fibers F2 are transported along the rollers 60a, the second blower 61 applies hot air having a drying temperature in the range of 40 to 70°C, and the second fibers F2 The drying time that) stays in the second drying chamber 60 is 1 to 3 seconds.

[0055] 만일 건조온도 및 건조시간이 상기 범위 미만일 경우 제2섬유(F2)로부터 물이 완전히 증발되지 못하고, 상기 범위 이상일 경우 제2섬유(F2)의 물성이 변화될 수 있다.If the drying temperature and drying time are less than the above range, water cannot be completely evaporated from the second fiber (F2), and if it is more than the above range, the physical properties of the second fiber (F2) may be changed.

다음, 상기 항균섬유(F1')와 소취섬유(F2')를 제직하는 단계(S7)를 수행한다. 단계(S7)에서, 항균섬유(F1')와소취섬유(F2')를 경사와 위사로 제직(weaving)함으로써, 항균 및 소취 원단이 완성되는 것이다. Next, a step (S7) of weaving the antibacterial fiber (F1') and the deodorizing fiber (F2') is performed. In step (S7), by weaving the antibacterial fiber (F1') and the deodorizing fiber (F2') with warp and weft, the antibacterial and deodorant fabric is completed.

<실시예 1> 항균성물질 수용액의 제조 <Example 1> Preparation of an aqueous solution of an antimicrobial substance

평균입경이 1 nm 내지 100nm 인 은미립자 05%, 이소티아졸론 1%, 우레탄수지 15%와, 물 845% 를 교반하여 항균성물질 수용액을 제조한다. An aqueous solution of an antimicrobial substance was prepared by stirring 05% silver fine particles having an average particle diameter of 1 nm to 100 nm, 1% isothiazolone, 15% urethane resin, and 845% water.

<실시예 2> 소취성물질 수용액의 제조<Example 2> Preparation of aqueous solution of deodorant substance

평균입경이 5 내지 10 ㎛ 인 실리카 분말 3%, 평균입경이 50 nm 내지 100nm인 산화티타늄 분말 05%, 평균입경이 50 nm 내지 100nm인 산화아연 05%, 우레탄수지 15%, 물 81% 를 교반하여 소취성물질 수용액을 제조한다.Stirring 3% silica powder with an average particle diameter of 5 to 10 µm, titanium oxide powder with an average particle diameter of 50 nm to 100 nm, 05% zinc oxide with an average particle diameter of 50 nm to 100 nm, urethane resin 15% and water 81% To prepare a deodorant aqueous solution.

<실시예 3> 항균섬유의 제조폴리에스테르 섬유를 항균성물질 수용액으로 도포한 후, 30MHz의 고주파를 조사하여 항균성물질을 폴리에스테르섬유에 고착키고, 이후 70 ℃로 가열된 바람을 송풍하여 건조시킴으로서, 항균섬유를 완성하였다. <Example 3> Preparation of antibacterial fiber After coating the polyester fiber with an aqueous solution of an antimicrobial material, irradiating a high frequency of 30 MHz to fix the antimicrobial material to the polyester fiber, and then drying by blowing air heated to 70°C, Antimicrobial fibers were completed.

<실시예 4> 소취섬유의 제조 <Example 4> Preparation of deodorant fiber

폴리에스테르 섬유를 소취성물질 수용액으로 도포한 후, 30MHz의 고주파를 조사하여 소취성물질을 폴리에스테르섬유에 고착키고, 이후 70 ℃로 가열된 바람을 송풍하여 건조시킴으로서, 소취섬유를 완성하였다.After the polyester fiber was coated with an aqueous deodorant solution, a high frequency of 30 MHz was irradiated to fix the deodorant material to the polyester fiber, and then dried by blowing wind heated to 70° C. to complete the deodorizing fiber.

<실시예 5> [0065] 항균 및 소취 원단의 섬유의 제조<Example 5> Preparation of fibers of antibacterial and deodorant fabric

실시예 3 및 4에서 제조된 항균섬유와 소취섬유를 공지의 제직기로 제직하여 항균 및 소취 원단을 제조하였다.The antibacterial fibers and deodorant fibers prepared in Examples 3 and 4 were woven with a known loom to prepare antibacterial and deodorant fabrics.

<실험예 1 > 항균성 실험 <Experimental Example 1> Antimicrobial test

항균성 원단에 대한 항균시험을 시험규격 KS K 0693-2008 방법으로 실시하였다. 사용한 균주로는 식중독의 주원인균인 황색포도상구균(Staphylcoccus aureus ATCC 6538) 및 폐렴균인 폐렴막대균(Klebsiella pneumoniae ATCC을 005% 비이온계 계면활성제(Tween 80) 상에 접종하여 37℃에서 24시간 배양한 균을 접종원으로 사용하 Antimicrobial tests for antimicrobial fabrics were conducted by the test standard KS K 0693-2008. As the strains used, Staphylcoccus aureus ATCC 6538, the main cause of food poisoning, and Klebsiella pneumoniae ATCC, were inoculated on 005% nonionic surfactant (Tween 80) and cultured at 37°C for 24 hours. Using one germ as an inoculum

였다. 표준포는 KS K 0905 염색견뢰도용 면소재 백포를 사용하였으며, 상기 항균성 실험 결과를 하기 표에 재하였다.Was. As the standard fabric, a cotton material white fabric for color fastness of KS K 0905 was used, and the results of the antibacterial activity are listed in the table below.

표 1Table 1

시험균조Test balance

(보존번호)(Retention number)

황색포도상구균Staphylococcus aureus

(ATCC 6538)(ATCC 6538)

폐렴막대균Pneumococcal

(ATCC 4352)(ATCC 4352)

MaMa

11 × 1011 × 10

55

12 × 1012 × 10

55

MbMb

49 × 1049 × 10

66

47 × 1047 × 10

77

Mc < 20 < 20Mc <20 <20

정균감소값 54 64Bacteriostatic reduction value 54 64

정균감소율(%) 999 999Bacteriostatic reduction rate (%) 999 999

증식값 : (Mb/Ma = 316 이상일 때 유효)Growth value: (effective when Mb/Ma = 316 or more)

황색포도상구균 -445 Staphylococcus aureus -445

폐렴막대균 -3917 Pneumococcal bacteria -3917

정균감소율 : log Mb - log Mc Bacteriostatic reduction rate: log Mb-log Mc

정균감소율(%) : [(Mb-Mc) × 100]/Mb Bacteriostatic reduction rate (%): [(Mb-Mc) × 100]/Mb

Ma : 대조편의 접종직후 생균수 Ma: Number of viable cells immediately after inoculation of control

Mb : 대조편의 18시간 배양후 생균수 Mb: number of viable cells after 18 hours incubation of the control

Mc : 시료의 18시간 배양후 생균수 Mc: The number of viable cells after 18 hours incubation of the sample

이와 같이, 18시간 경과 후 상기 균주의 수가 현저히 줄어 육안으로는 관찰되지 않았다. 또한, 상기 표에서 보는 바와 같이, 본 항균성 원단의 경우, 초기 균주의 농도를 감소시켜 정균감소율 999%의 우수한 항균성을 보였다. 따라서 강력한 항균력이 보존되는 항균성 원단을 제조하였다. As described above, after 18 hours, the number of strains was significantly reduced and was not observed with the naked eye. In addition, as shown in the table above, in the case of the antimicrobial fabric, the concentration of the initial strain was reduced, thereby showing excellent antibacterial properties of 999% bacteriostatic reduction. Therefore, an antimicrobial fabric was prepared in which strong antibacterial activity was preserved.

<실험예 2 > 소취시험 <Experimental Example 2> Deodorization test

표 2Table 2

경과시간(분) 블랭크 농도(ppm) 암모니아 잔류농도(ppm) 소취율(%)Elapsed time (minutes) Blank concentration (ppm) Ammonia residual concentration (ppm) Deodorization rate (%)

초기 500 500 -Initial 500 500-

30 490 75 8530 490 75 85

60 480 63 8560 480 63 85

90 470 40 9190 470 40 91

120 460 34 95120 460 34 95

항균성 원단의 시험편을 암모니아가스가 들어있는 용기 내에 노출시켜 흡수되고 남은 양을 시간의 경과에 따라측정하였으며, 한국원적외선응용평가연구원 KFIA-FI-1004 시험방법으로 소취시험을 수행하였다. 그 결과를 표 2The test piece of antimicrobial fabric was exposed in a container containing ammonia gas, and the amount remaining after being absorbed was measured over time, and a deodorant test was performed using the KFIA-FI-1004 test method of Korea Far Infrared Application Evaluation Research Institute. Table 2 the results

에 기재하였다. 블랭크농도는 시료를 넣지 않은 상태에서 측정한 것이다.Described in. The blank concentration was measured without adding a sample.

<실험예 3 > 견뢰도 시험 <Experimental Example 3> Fastness test

항균성 원단에 대하여 KS K 0218에 따라 20 시간동안의 일광견뢰도, KS K 0430에 따른 세탁견뢰도 및 KS K 0650에 따른 건습의 조건에서의 마찰견뢰도를 시험하였다. For the antimicrobial fabric, the fastness to sunlight for 20 hours according to KS K 0218, wash fastness according to KS K 0430, and friction fastness under dry and dry conditions according to KS K 0650 were tested.

표 3Table 3

세탁견뢰도 마찰견뢰도 일광견뢰도 Washing fastness, friction fastness, light fastness

나일론 폴리에스테르 아크릴 건 습Nylon Polyester Acrylic Wet and Dry

5 5 5 2 3~4 45 5 5 2 3~4 4

상기 표 3에서 보는 바와 같이, 본 발명의 항균성 원단은 KS K 0430에 따른 세탁견뢰도에 있어 5 등급의견뢰도, KS K 0650에 따른 마찰견뢰도에서는 건습의 조건에서 3 내지 4 등급의 견뢰도 및 KS K 0218에 따른 일광견뢰도에서도 3 내지 4 등급의 견뢰도를 보였다. As shown in Table 3, the antimicrobial fabric of the present invention has a fastness of 5 grades in washing fastness according to KS K 0430, and a fastness of 3 to 4 grades in dry and humid conditions in the friction fastness according to KS K 0650 and KS K 0218. The color fastness of 3 to 4 was also shown in the light fastness according to.

이와 같이, 본 발명의 항균 및 소취 원단 제조방법에 의하여 제조된 원단은, 반복적인 세탁에도 항균성 및 소취성이 유지되는 세탁견뢰성을 가진다. As described above, the fabric manufactured by the method of manufacturing an antibacterial and deodorant fabric of the present invention has washing fastness that maintains antibacterial and deodorant properties even in repeated washing.

또한 독립적으로 제조된 항균섬유(F1')와 소취섬유(F2')를 제직하여 제조되므로, 뛰어난 항균성 및 소취성을 기대할 수 있다. 따라서 본 발명의 항균 및 소취 원단으로 제조된 의류는, 착용시에 잡균의 번식을 막고 땀냄새를방지하여 피부를 항상 건강하고 청결하게 유지시켜준다. 또한 촉감이 부드러워 민감한 피부에도 사용할 수 있는것이다.In addition, since it is manufactured by weaving independently manufactured antibacterial fibers (F1') and deodorizing fibers (F2'), excellent antibacterial properties and deodorizing properties can be expected. Therefore, the clothing made of the antibacterial and deodorizing fabric of the present invention prevents the propagation of various bacteria and prevents the smell of sweat when worn to keep the skin healthy and clean at all times. It is also soft to the touch, so it can be used on sensitive skin.

본 발명은 도면에 도시된 일 실시예를 참고로 설명되었으나 이는 예시적인 것에 불과하며, 본 기술 분야의 통상의 지식을 가진 자라면 이로부터 다양한 변형 및 균등한 타 실시예가 가능하다는 점을 이해할 것이다. Although the present invention has been described with reference to an embodiment shown in the drawings, this is only exemplary, and those of ordinary skill in the art will appreciate that various modifications and other equivalent embodiments are possible therefrom.

10 항균성물질 수용조 15a, 15b 제1도포롤러
20 제1고주파오븐 30 제1건조실
31 제1송풍기 40 소취성물질 수용조
45a, 45b 제2도포롤러 50 제2고주파오븐
60 제2건조실 61 제2송풍기
10 Antimicrobial material receiving tank 15a, 15b 1st coating roller
20 No. 1 High Frequency Oven 30 No. 1 Drying Room
31 1st blower 40 Deodorant material storage tank
45a, 45b 2nd coating roller 50 2nd high frequency oven
60 Second drying room 61 Second blower

Claims (1)

제1섬유(F1)를 항균성물질 수용액으로 도포하는 단계(S1);
상기 항균성물질 수용액이 도포된 제1섬유(F1)에 제1고주파를 조사하여, 상기 제1섬유(F1)의 표면에 은미립자와이소티아졸론으로 구성된 항균성물질을 고착시키는 단계(S2);상기 항균성 물질이 고착된 제1섬유(F1)를 건조시켜 항균섬유(F1')을 완성하는 단계(S3);제2섬유(21)를 소취성 물질 수용액으로 도포하는 단계(S4);
상기 소취성 물질 수용액이 도포된 제2섬유(F2)에 제2고주파를 조사하여, 상기 제2섬유(F2)의 표면에 실리카분말, 산화티타늄 및 산화아연으로 구성된 소취성물질을 고착시키는 단계(S5);상기 소취성 물질이 고착된 제2섬유(F2)를 건조시켜 소취섬유(F2')을 완성하는 단계(S6); 및상기 항균섬유(F1')와 소취섬유(F2')를 제직하는 단계(S7);를 포함하는 것을 특징으로 하는 항균소취 원단 제조방법
Applying the first fiber (F1) with an aqueous antimicrobial material solution (S1);
Irradiating a first high frequency to the first fiber (F1) to which the antimicrobial material aqueous solution is applied, and fixing the antimicrobial material composed of silver fine particles and isothiazolone on the surface of the first fiber (F1) (S2); Drying the first fiber (F1) to which the antimicrobial material is fixed to complete the antibacterial fiber (F1') (S3); Applying the second fiber 21 with an aqueous deodorant solution (S4);
The step of irradiating a second high frequency to the second fiber (F2) coated with the aqueous deodorant solution, and fixing a deodorant material composed of silica powder, titanium oxide, and zinc oxide on the surface of the second fiber (F2) ( S5); Drying the second fiber (F2) to which the deodorant material is fixed to complete the deodorant fiber (F2') (S6); And weaving the antibacterial fiber (F1') and the deodorizing fiber (F2') (S7); an antibacterial deodorant fabric manufacturing method comprising:
KR1020190078425A 2019-06-30 2019-06-30 Method for manufacturing textile having antibiotic and deodorant KR20210002289A (en)

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