KR20210000525U - Deodorizing porous ceramic balls of female materials for deodorizing fillings made of deodorizing solutions and metal powders - Google Patents

Abstract

In order to improve the deodorizing power and recycling rate of the existing deodorizing ceramic balls corresponding to various large amounts of odor, the deodorizing solution 31 according to the presence or absence of heat resistance without the use of a curing agent and the metal powder 32 serving as a catalyst are used. By combining the advantages of the deodorizing function with the porous clay powder, the basic particle diameter of about 0.25mm~60mm to continuously regenerate and recycle the odor deodorization and purification functions, and the filter material for cyclic deodorization filling manufactured in a standard higher than that of need. It is a ceramic ball 600 and a manufacturing method, and the above is characterized in that it is manufactured in multiple processes according to the strength corresponding to the odorous substance.

Description

Deodorizing porous ceramic balls of female materials for deodorizing fillings made of deodorizing solutions and metal powders}

The technical field of the present invention combines the characteristics of porous mineral powders including zeolites, deodorizing solutions and metal powder products with a catalytic function, strengthening the deodorization persistence than the existing deodorizing balls, and returning to nature when regenerating, recycling, and discarding the balls. It is a technical field that manufactures deodorizing porous ceramic balls for environmental industry use and materials.

This design does not use a curing agent, and mixes raw materials based on heat-resistant deodorant (31) and metal powder (32) for catalysts (32) with or without heat resistance at high temperature firing around 1000℃, forming ball, coating, drying, firing ball, cooling Deodorizing porous ceramic balls can be manufactured by selecting and reinforcing the strength of deodorizing power by selecting multi-processes 1, 2, and 3 such as impregnating balls. Particle diameter 0.25mm~60mm, which has the advantage of reinforcing cyclical deodorizing power and dissipating power and multiple regeneration, recycling and multi-purpose use of waste, and not clogging the natural pores of porous minerals by mixed raw materials. Deodorizing porous ceramic ball media, materials and manufacturing methods that are manufactured based on the standard are the technology behind the design.

1.Korean Patent Publication No.:1018759080000 (2018.07.02) designation; Manufacturing method of functional ceramic ball for antibacterial and deodorizing 2. Korean Patent Application Publication No.:1020210004743 (2021.01.13) designation; Functional clay ceramic ball made using porous powder and platinum and its manufacturing method 3. Korean Patent Publication No.:1019912610000 (2019.06.14) designation; Antibacterial deodorant with improved antibacterial, sterilizing and deodorizing properties 4. Korean Patent Application Publication No.:1020200129557 (2020.11.18) Name: Zeolite-based antibacterial ceramic ball and its manufacturing method (Reference: Applicant is the prior art of Kyung-Hwan Lee, and uses the same equipment)

1. Research paper at Busan Metropolitan City Environmental Research Institute (2003.10.23) title; A Study on the Malodorous Components of Food Waste Treatment Facility

The tasks to be solved are as follows.

The odor, which is composed of various harmful mixtures such as methanol, ethanol, ammonia, sulfur oxides, heavy metals, etc., which are generated from various ordinary odor substances, water pollution, and air pollution, is harmful to health including lung cancer. As a means to remove it from the whole, odors are deodorized by spraying a highly toxic chemical deodorant or by using a ceramic ball or mesh filter coated with metal oxide, charcoal, and diatomaceous earth absorption power.

The above materials are highly toxic, have good absorbing power, but have low dissipation power, insufficient deodorizing power, or discarded waste caused by frequent replacement of deodorant products, which can lead to natural damage. Reduces the use of chemical deodorants and reduces the use of chemical deodorants based on clay mineral powders, including zeolite, which can be returned to nature, and deodorizing solutions and metal powders that enhance deodorization power, while reducing the deodorizing power, increasing the regeneration and recycling rate, and reducing the use of odor substances. There has been a need to develop porous deodorizing ceramic ball media and materials that enhance the deodorizing function without mixing with it, and finding the above alternative has become a task to be solved.

Hereinafter, the auxiliary material 89 is a clay mineral powder including zeolite, and is described through zeolite powder, the process and the multi-process are in common, and the means to solve the problem is as follows.

1. The deodorizing porous ceramic ball 600 manufacturing facility and purpose of the present invention are to utilize the existing ceramic ball production equipment, and have stronger deodorizing power and lasting power than ordinary organic liquid, microbial deodorant products, and deodorizing ceramic balls. It is to reduce toxicity compared to direct application of deodorant, and to manufacture renewable deodorant filling media and materials.

2. In the manufacture of porous deodorizing ceramic balls, the main elements of the manufacturing and the maximum value of utilization are, the deodorizing solution 31 is a deodorizing solution with or without heat resistance, and the metal powder 32 is a metal powder with a catalytic function, and the fine pores of zeolite (90 ), it is manufactured in a multi-process, reinforcing the cyclical deodorizing function and regenerating and recycling it multiple times, and the deodorizing effect is further strengthened by the artificial air device when used

3. The reason for manufacturing in the above multi-process is:

Commercially available products are used for the above deodorizing solution and metal powder.

Since the above may have different heat resistance to withstand high-temperature sintering, metal powder having a catalytic function is combined according to the heat resistance and strength of the deodorizing power of the deodorizing solution products, and the deodorizing porous ceramic ball 600 is formed in a multi-step process of steps 1, 2, and 3. To manufacture.

4. The use and deodorization method of the deodorizing porous ceramic ball 600 of the present invention,

The deodorizing porous ceramic ball 600 is an adsorption tower that induces complex odors such as organic acids, methanol, ethanol, hydrogen sulfide, ammonia, formaldehyde, amines, and wastewater or atmospheric odors generated from food waste to the outlet. , Adsorption, oxidation, neutralization, decomposition, and filtration of the odor gas emitted by putting the deodorizing porous ceramic ball 600 into an independent space such as odor reduction facility, etc. to the surface of the deodorizing porous ceramic ball 600 and microporous and deodorizing solution. It is used as a deodorant filling filter and material that purifies and removes odor by further strengthening the deodorizing power with the catalytic function of the metal powder (32) and blows it into the atmosphere, and has less dissolution of various harmful components, environmental hormones and phthalates, etc. It is recycled and recycled many times.

5. The structure of the deodorizing porous ceramic ball 600,

The basic particle diameter is about 0.25mm~60mm, and it is manufactured with a higher standard if necessary.It is a high-temperature plastic with an appropriate pH of 6.8~7.2 and a porosity of 20%~35% by weight, and the porosity before processing (%) 35~45, After processing, the porosity (%) is 30 to 40, and each particle is excellent in deodorization, breathability, water retention, drainage, and adsorption, and the color can be controlled by high temperature firing temperature and metal powder (32) at the time of manufacture.

6. The raw materials and types of manufacturing the deodorizing porous ceramic ball 600 are:

Clay mineral powders including zeolite and mica ore powders such as phyllite, sericite, and cumulus mica are used as sub-materials (89), and the main materials (88) are TiO2, MnO2, CuO, CoO, ZnO, which function as catalysts on the market. Metal powder such as Fe2O3 (32) and deodorant solution (31) are selectively used, and commercially available products are used for the deodorization solution (31). The deodorizing solution 31 is divided into a multi-process of'mixing' or'impregnating' the high-temperature firing ball 530, and is manufactured into a deodorizing porous ceramic ball 600 that adsorbs, decomposes, and removes persistent odors or odors.

7. The above deodorizing solution 31 must have heat resistance when it is mixed with a molding ball that undergoes high temperature firing at around 1000°C, and in the case of the deodorizing solution 31 used for impregnation, non-heat resistance is given priority. Heat-resistant deodorizing solutions can also be used. The above selection is selected according to the purpose of manufacture.

8. The composition ratio of the raw material of the present invention is,

Based on 100% by weight of the total amount of raw materials, the quantitative raw material is 80 to 90% by weight of zeolite powder, 10 to 20% by weight of mica ore powder, 15 to 25% by weight of water (30), 15 to 15 to 25% by weight of a deodorant solution diluted with water (31). It is composed of 25% by weight (concentration is determined by the manufacturer), based on 2 to 5% by weight of the catalyst metal powder 32 coating agent.

9. The shape of the ball formed in the process of design is,

Molding ball (water blending ball 330, deodorization blending ball 331, deodorization coating molding ball 332, coating molding ball 333) and firing ball (high temperature firing ball 530, deodorization blending firing ball ( 531) There are deodorizing coated firing balls 532, coated firing balls 533), and firing impregnating balls (plastic deodorizing impregnating balls 534, coated firing deodorizing impregnating balls 535), and non-coating process 1 in multi-process And process 2, and process 3 including coating of catalyst metal powder 32, and forming balls, firing balls, and plastic impregnating balls are prepared.

10. The time required for manufacturing the deodorizing porous ceramic ball is:

The time required for work such as drying, firing, cooling, etc. of design manufacturing varies depending on the environment such as the production volume of the ball, the type of ball, and the size, and is increased or decreased based on about 1 hour. When the total production is less than 10 tons, the following multi-process 1, It can be produced in one day by selecting 2 or 3, and it has the advantage of the above-described speed and the process of reducing the probability of blocking micropores by not using a curing agent and a softening agent.

11. The detailed manufacturing processes of multi-process 1, 2, and 3 according to the purpose of manufacturing the deodorizing porous ceramic ball 600 and the properties and functions of raw materials are as follows. It is a technique that helps to maintain porosity and increase the number of regenerations.

(1) <Multi-process 1>

A heat-resistant deodorant solution (31) with or without heat-resistant deodorization solution (31) that withstands high-temperature firing at around 1000°C without using a curing agent and a heat-resistant deodorization solution (31) from the manufacture of porous deodorizing ceramic balls (600) based on metal powder for catalyst (32). In the mixing step 1,

The focus is on mixing the heat-resistant deodorant solution (31) as the main material (88),

It is prepared by mixing-molding (331)-drying-baking (531)-cooling-finishing (600)-selection and packaging by putting quantitative sub-materials (89) and deodorizing solution (31) into a high-speed mixer. Is the same as

Injecting and high-speed mixing of the sub-material 89 and heat-resistant deodorizing solution 31 of clay mineral powder including zeolite and mica ore powder of a quantity into a high-speed mixer;

Molding the above mixture into a spherical deodorizing blended ball 331 with a molding device;

Dry with heat and wind of 200℃~400℃ to less than 10% moisture content;

Sintering the deodorant mixed ball 331 at high temperature at around 1,000° C. and fired into a deodorizing mixed firing ball 531 having deodorizing power;

Completion of deodorizing porous ceramic ball 600 after air-cooling below 60°C;

Size selection and packaging;

Deodorizing porous ceramic ball, characterized in that it is manufactured by this multi-process 1

(2) <Multi-process 2>

Deodorization porous ceramic ball 600 is manufactured using a deodorizing solution 31 with or without heat resistance and metal powder 32 for catalyst as the main material 88 at high temperature firing around 1000℃, and impregnating the deodorizing solution 31 (534) It is multi-process 2, where doing is the center,

In the manufacturing process, quantitative auxiliary materials (89) and water (30) are added and mixed-molding (330)-first drying-baking (530)-cooling-deodorizing solution (31) impregnation (534)-second drying-cooling -Completed (600)-It is manufactured by selection and packaging, and the detailed description is as follows.

Mixing by adding a quantity of the clay mineral powder including zeolite and the subsidiary material 89 and water 30 of mica ore powder into a high-speed mixer;

Molding the mixture into a spherical water-mixed ball 330 with a molding device;

Primary drying of the water-mixed ball 330 with heat and wind at 200°C to 400°C;

After firing with a high-temperature firing ball 530 at a high temperature of about 1000° C. and cooling by air cooling below 60° C.;

Preparing a plastic deodorizing impregnating ball 534 by impregnating the deodorizing solution 31 in the high temperature firing ball 530;

Secondary drying with heat and wind of about 50℃~150℃;

Completion of deodorizing porous ceramic ball 600 after air-cooling below 60°C;

Size selection and packaging;

Deodorizing and filling filter media deodorizing porous ceramic ball, characterized in that manufactured by this multi-process 2

(3) <Multi-process 3>

Process 3 of manufacturing a porous deodorizing ceramic ball 600 using a deodorizing solution 31 with or without heat resistance and a metal powder for catalyst (32) as the main material 88 at high temperature firing around 1000℃ is as follows. It is manufactured by dividing into multi-process 3-2.

① <Multi-process 3-1>

In step 3-1,

The main focus is on mixing the deodorizing solution 31 that endures high-temperature firing at around 1000°C in the auxiliary material 89 and coating the metal powder 32 serving as a catalyst on the surface of the deodorizing mixed ball 331,

The manufacturing process is mixing-molding (331)-metal powder of catalyst (32) coating (332)-drying-baking (532)-cooling-finishing by adding quantitative sub-materials (89) and deodorizing solution (31) to a high-speed mixer. (600)-It is manufactured through the process of selection and packaging, and the detailed description is as follows.

Injecting and mixing the clay mineral powder including a quantity of zeolite and the subsidiary material 89 of mica ore powder and the heat-resistant deodorizing solution 31 into a high-speed mixer and high-speed mixing;

Molding the above mixture into a spherical deodorizing blended ball 331 with a molding device;

Coating the metal powder 32 having a catalytic function on the surface of the deodorizing mixing ball 331 and coating it with a deodorizing coating molding ball 332;

Dry with heat and wind of 200℃~400℃ to less than 10% moisture content;

After drying, firing at high temperature at around 1,000° C. and firing with deodorizing coated firing balls 532;

Completion of deodorizing porous ceramic ball 600 after air-cooling below 60°C;

Size selection and packaging;

Deodorizing porous ceramic ball for deodorizing filling media, characterized in that manufactured by this multi-process 3-1

② <Multi-process 3-2>

In step 3-2,

The center is coating the metal powder 32 of the catalyst function on the surface of the water-mixed ball 330 and impregnating the deodorizing solution 31 into the coating firing ball 533,

In the manufacturing process, quantitative sub-materials 89 and water 30 are added to a high-speed mixer to mix-molding (330)-metal powder coating (333)-first drying-baking (533)-cooling-deodorizing solution impregnation (535). ) Second drying-cooling-completion (600)-selection and packaging, and detailed descriptions are as follows.

Mixing by adding a quantity of the clay mineral powder including zeolite and the subsidiary material 89 and water 30 of mica ore powder into a high-speed mixer;

A water-mixed ball 330 is formed by mixing the quantitative auxiliary material 89 and water 30 at high speed;

Coating the metal powder 32 having a catalytic function on the surface of the water-mixed ball 330 and coating it with a coating ball 333;

Primary drying with a moisture content of 10% or less with heat and wind of 200℃~400℃;

After drying, firing at high temperature at around 1,000° C. and firing with a coated firing ball 533 having a catalytic function;

Air-cooled cooling below 60°C;

Coated firing deodorization impregnating ball 535) production by impregnating a non-heat-resistant deodorizing solution 31 in the coated firing ball 533;

Secondary drying with heat and wind of about 50℃~150℃;

Completion of deodorizing porous ceramic ball 600 after air-cooling below 60°C;

Size selection and packaging;

Deodorizing porous ceramic ball for deodorizing filling media, characterized in that manufactured by this multi-step 3-2

(4) To further increase the deodorizing strength in the above multi-process, multi-process 1, 2, and 3 are combined.

(5) The deodorizing porous ceramic ball 600 manufactured by Step 1, Step 2, and Step 3 above is artificially injected into the ball field to dilute the air and mix the balls to provide a cyclical deodorization function and It further improves persistence.

12. The deodorizing porous ceramic ball 600 of the present invention is not blocked by the raw material mixed with the original micropores possessed by the porous mineral powder, and the porosity is maintained can be confirmed through the generation of bubbles in FIG. 5.

13. Deodorizing porous ceramic ball 600 is the ball size, color, shape, texture, deodorizing solution, metal powder, high temperature firing time, deodorization solution impregnation time, metal powder catalyst and deodorization solution mixture in the above multi-process. The concentration and ratio, the ratio of the input of the deodorizing porous ceramic ball 600 to the odor material, etc., are selected and adjusted according to the specifications, workload, and properties of the raw materials, and the deodorizing solution and metal powder catalyst are available on the market. Purchase and use products for sale of various properties.

14. The above deodorizing porous ceramic ball 600 is put into an independent space of the odor reduction facility, and the duration of the deodorizing power lasts from 1 to 6 months depending on the odor material and other environments, and when the deodorizing function is deteriorated, it is collected to supplement the deodorizing power. And recycled and recycled several times, or by decomposing or incineration of impurities, civil engineering materials and natural regression are possible, and the input amount of the ball and the replacement period are determined according to the odor material.

15. The deodorizing porous ceramic ball 600 of the present design collects odor and odor in micropores with a large surface area, decomposes and removes it into a deodorizing solution and metal powder, and filters harmful substances because the deodorizing power is continuously and cyclically regenerated. It is used as a filter material and material for deodorizing porous ceramic balls to prevent air pollution of harmful odors as it discharges and deodorizes the purified air to the atmosphere. In addition, the deodorizing porous ceramic ball 600 has moisture absorption and antibacterial functions. The above contents become a means of solving the task.

As an effect of the design,

1. Used as a material for long-term deodorization by putting it into the environment and odor reduction facilities in the workplace

2. The required time varies depending on the environment such as the production volume of the balls, the type of balls, and the size, and the total production of balls can be produced in one day by selecting multi-processes 1, 2, and 3 up to 10 tons, and it does not use hardeners and softeners. It is a manufacturing of deodorizing porous ceramic balls with a low probability of blocking micropores.

3. In the manufacturing process, additional facility costs are reduced because deodorizing porous ceramic balls can be manufactured and regenerated using existing facilities.

4. Ordinary dry deodorant molding balls lose their shape after long-term use, but this design is robust and has a cyclical deodorization function that lasts for several months and is regenerated and recycled many times.

5. Microscopic balls are not blocked by raw materials.

6. Less dissolution of harmful ingredients and environmental hormones and phthalates

7. The toxicity of chemical deodorants is reduced, and the deodorizing function and persistence are strengthened.

8. It is a deodorant filling filter and material that absorbs, decomposes, and deodorizes soot and wastewater odors discharged from large-scale restaurants, waste disposal sites, factories, etc.

9. Air environment is purified

10. Recycling, reducing waste of resources, etc.

11. The above does not deodorize by masking odors with ordinary aromatic substances, spraying or mixing highly toxic chemical deodorants and organic liquids directly to odor wastes, and has a deodorizing solution diluted with water and micropore of porous minerals, and has a catalytic function. Deodorant porous ceramic ball that combines the advantages of metal powder is manufactured, and it is put into a designated space as a filter material and material such as odor reduction facilities, so it is possible to remove a large amount of odors while reducing the abuse and toxicity of chemical deodorants for a long period of time. Becomes.

1 is a process diagram of the deodorizing porous ceramic ball manufacturing process 1 of the present invention
Figure 2 is a process diagram of the deodorizing porous ceramic ball manufacturing process 2 of the present invention
Figure 3 is a process diagram 3-1 and 3-2 of the deodorizing porous ceramic ball manufacturing process 3 of the present invention
Figure 4 is a diagram for each process explaining the production process and the main process of the present invention
5 is an active state diagram of the micropores 90 through the experiment of generating bubbles 130 in the water of the present invention
Figure 6 is an explanatory diagram expressing the diversity of the shape of the deodorizing porous ceramic ball of the present invention
7 is a scanning electron microscope (SEM) photograph of the micropores of the present invention

Detailed contents for implementing the present invention are as follows.

Compared with conventional deodorization and antibacterial ceramic ball manufacturing, the present invention does not mix all of the raw materials in the stirring step or perform high-temperature firing several times, and the deodorization solution 31 serving as the main raw material 88 as shown in Figs. ) Can be manufactured by selecting the deodorizing power and multi-process of the deodorizing porous ceramic ball 600 as appropriate processes 1, 2, and 3 based on the presence or absence of heat resistance and the use of metal powder for the catalyst function.

(Hereinafter, as the auxiliary material (89), clay mineral powder including zeolite and mica ore powder of phyllite, sericite, and cumulus mica are selected.)

Hereinafter, since the manufacturing facility of the present invention recycles the existing equipment, the flow of the process may be similar to the existing one, but the detailed method of combining raw materials to enhance deodorization is different, and the deodorizing solution 31 is used for deodorization and E. coli and other bacteria. It also has antibacterial properties.

The main raw material and multi-process of deodorizing porous ceramic ball are,

The deodorizing solution 31 and the metal powder 32, which are the main raw materials 88 that function as a deodorant, are commercially available products. This is not a design for manufacturing the main raw material 88, but a design for manufacturing the deodorizing porous ceramic ball 600, and since the heat resistance of the commercially available product may be different, it is carried out in a multi-process according to the properties of the product and the purpose of manufacture. .

The composition ratio of the'quantitative raw material' of the present design is,

Based on 100% by weight of the total amount of raw materials, the quantitative raw material is zeolite (88) powder 80 to 90% by weight, mica (89) ore powder 10 to 20% by weight, water (30) 15 to 25% by weight, heat resistance diluted with water To the non-heat-resistant deodorant solution 31, 15 to 25% by weight, and 10 to 20% by weight of the metal powder 32 serving as a catalyst and color development, depending on the presence or absence of heat resistance of the deodorization solution 31, Step 1, Step 2, Step Select 3 to manufacture the deodorizing porous ceramic ball 600 in a multi-process, and the time required for manufacturing varies according to the ball production volume, standard, and process, so it is adjusted according to each manufacturing situation. Tone available)

Through the process of forming molded balls, plastic balls, and plastic impregnated balls that can be manufactured in a spherical or non-spherical shape according to the process of the present invention, it is completed into a deodorizing porous ceramic ball 600, and an environment that deodorizes large and small amounts of odors and odors. It is used as an industrial deodorant filter and material.

Hereinafter, the working time required for mixing, drying, firing, and impregnation between the raw materials of each process is added or subtracted according to the manufacturing environment such as the amount of raw materials, the ball standard, and the type of equipment, based on about 1 hour, and facilities and equipment utilize existing facilities. Can reduce the cost of new facilities.

Multi-process 1, 2, and 3 manufacturing of deodorizing porous ceramic balls 600 mainly based on deodorizing solution 31 with or without heat resistance and metal powder for catalyst (32) at high temperature firing around 1000℃. In,

<Multi-process 1>

In step 1 of mixing the heat-resistant deodorant solution (31),

The focus is on mixing the deodorant solution (31) that has heat resistance at high temperature firing around 1000℃

The manufacturing process is prepared by mixing-molding (331)-drying-baking (531)-cooling-finishing (600)-selection and packaging by adding quantitative auxiliary materials (89) and deodorizing solution (31). Is the same as

① Ingredient input and mixing:

In a high-speed mixer, 200-300RPM of water and dilute heat-resistant deodorization solution (31) are added to a quantitative amount of zeolite powder and sub-material (89) of mica ore powder and about 15 to 25% by weight of water based on 100% by weight of the total amount of raw material Mix at high speed at a speed.

② Deodorization mixed ball (331) molding:

The above mixture is rotated and spherically molded at a speed of 40 to 60 RPM using a molding device P-Pan to prepare a deodorizing mixed-type ball 331.

③ Drying:

Using a Tunnel Dryer (stainless mesh conveyor), dry the moisture content of the deodorant mixed ball 331 to 10% or less with heat and wind of 200 to 400°C.

④ Firing:

Completely firing the deodorant mixed ball 331 in a rotary kiln [around 1,000°C], and at this time, maintaining a speed of about 1Ton/Hr, and manufacturing a deodorizing mixed firing ball 531.

⑤ Completion after cooling:

The product of the deodorizing mixed firing ball 531 fired at high temperature is cooled in an air-cooled manner below 60°C using a cooling rotary kiln equipped with an air blower to complete the deodorizing porous ceramic ball 600.

⑥ Sorting and packaging:

The finished deodorizing porous ceramic ball 600 is selected and packaged in size according to the purpose.

<Multi-process 2>

In step 2 of impregnating the deodorizing solution 31,

The center is to impregnate (534) the deodorizing solution (31),

In the manufacturing process, quantitative auxiliary materials (89) and water (30) are added and mixed-molding (330)-first drying-baking (530)-cooling-deodorizing solution (31) impregnation (534)-second drying-cooling -Completed (600)-It is manufactured by selection and packaging, and the detailed description is as follows.

① Ingredient input and mixing:

A quantity of zeolite powder and a sub-material 89 of mica ore powder, and about 15 to 25% by weight of water 30 based on 100% by weight of the total amount of the raw material are added to a high-speed mixer and mixed at a high speed of 200 to 300 RPM.

② Water mixing ball (330) molding:

The above mixture is rotated at a speed of 40 to 60 RPM using a molding device P-Pan, and molded into a water-mixed ball 330 in a spherical shape.

③ 1st drying:

Using a Tunnel Dryer (stainless mesh conveyor), dry the water-mixed ball 330 to a moisture content of 10% or less with heat and wind at 200~400℃.

④ Firing:

While maintaining a speed of about 1Ton/Hr in a rotary kiln, the water-mixed ball 330 is completely fired [around 1,000°C] to be fired into a high-temperature firing ball 530.

⑤ Cooling:

The fired high-temperature firing ball 530 is cooled by air cooling of 60°C or less using a cooling rotary kiln equipped with an air blower.

⑥ Impregnation:

The cooled high-temperature firing ball 530 is immersed in a deodorizing solution 31 of about 15 to 25% by weight, and the'non-heat-resistant deodorizing solution 31 diluted with water' is placed in the micropores of the high-temperature firing ball 530. The plastic deodorization impregnating ball 534 is manufactured by impregnating it to sufficiently permeate. (Note, the deodorizing solution 31 can be used in both heat-resistant and non-heat-resistant deodorizing solution 31 in the case of the impregnation process, and the manufacturer selects it. )

⑦ Secondary drying and cooling:

Using Tunnel Dryer (stainless mesh conveyor), dry the solution of the plastic deodorant impregnating ball 534 with heat and wind at 50~150℃ to about 10~12% and cool it to complete the deodorizing porous ceramic ball 600. do.

⑧ Sorting and packing:

Select and package the size suitable for the purpose.

<Multi-process 3 (including metal powder (32) coating)>

Process 3 of manufacturing a deodorizing porous ceramic ball 600 mainly consisting of a deodorizing solution 31 with or without heat resistance at high temperature firing around 1000°C and a metal powder for catalyst 32 is as follows: Multi-Step 3-1 and Multi-Step 3 Separate with -2.

①<Multi-process 3-1>

In step 3-1,

The main focus is to mix the'deodorant solution 31 that endures high temperature firing in the sub-material 89' and'coating the metal powder 32 of the catalyst function on the surface of the deodorant mixed ball 331'. , The manufacturing process is mixed-molding (331)-metal powder of the catalyst (32) coating (332)-drying-baking (532)-cooling-finishing (600) by adding a quantitative auxiliary material (89) and a deodorizing solution (31). )-It is manufactured through the process of selection and packaging, and the detailed description is as follows.

① Ingredient input and mixing:

In a high-speed mixer, in a high-speed mixer, add about 15 to 25% by weight of water and dilute heat-resistant deodorization solution (31) with a quantitative amount of zeolite powder and subsidiary material 89 of mica ore powder, and about 15 to 25% by weight of the total amount of raw material. Mix at high speed at a speed.

② Deodorization mixed ball (331) molding:

The above mixture is rotated at a speed of 40 to 60 RPM using a molding device P-Pan, and molded into a spherical shape to produce a deodorizing mixed compound type ball 331 (above, spherical molding is basic, and manufactured by changing the shape of the ball. Possible)

④ Coating:

CoO, MnO2, CuO, or the like, which is a metal powder 32 used as a catalyst, is coated on the surface of the molded undried deodorant mixed ball 331 to form a deodorizing coated ball 332 (using an oxidizing agent such as ozone). In the case of the device, it is to select and coat the metal powder (32) that acts as a catalyst with excellent deodorizing effect according to the type of odor, and color expression is also possible.)

In the above-described coating operation, the coating powder is maintained without being peeled even after baking in the post-process and drying of heat and wind.

⑤ Drying:

Using a Tunnel Dryer (stainless mesh conveyor), dry the deodorizing coating molding ball 332 with a heat and wind of 200~400℃ to a moisture content of 10% or less.

⑥ Firing:

The deodorizing coating molding ball 332 is completely fired [around 1,000°C] in a rotary kiln, and at this time, it is manufactured as a deodorizing coated firing ball 532 having a deodorizing power and a specific color while maintaining a speed of about 1Ton/Hr.

⑦ Completion after cooling:

The deodorizing coated firing ball 532 fired at high temperature is cooled by air cooling below 60℃ using a 12M×1,200Ø cooling rotary kiln equipped with an air blower to complete the deodorizing porous ceramic ball 600.

⑧ Sorting and packing:

The finished deodorizing porous ceramic ball 600 is selected and packaged according to the size required.

<Multi-process 3-2>

In step 3-2,

The process of coating the metal powder 32 serving as a catalyst on the surface of the water-mixed ball 330 and impregnating the deodorizing solution 31 into the coating firing ball 533 is the center, and the manufacturing process is a quantitative sub-material (89). ) And water (30) to mix-molding (330)-metal powder coating (333)-1st drying-baking (533)-cooling-deodorizing solution impregnation (535)-2nd drying-cooling-finishing (600) )-It is manufactured by selection and packaging, and the detailed description is as follows.

① Ingredient input and mixing:

A quantity of zeolite powder and a sub-material 89 of mica ore powder, and about 15 to 25% by weight of water 30 based on 100% by weight of the total amount of the raw material are added to a high-speed mixer and mixed at a high speed of 200 to 300 RPM.

(Among the features of zeolite minerals, when the external environment is dry, they emit moisture, and when the external environment is high in humidity, the balance between absorption and dissipation is better than diatomaceous earth. Diatomaceous earth has high hygroscopic power but low emission rate. Therefore, zeolite is chosen as an auxiliary material that absorbs and absorbs odors and discharges purified air.)

② Water mixing ball (330) molding:

The above mixture is rotated at a speed of 40 to 60 RPM using a molding device P-Pan, and molded into a water-mixed ball 330 in a spherical shape.

③ Coating:

The surface of the undried water-mixed ball 330 is coated with MnO2 or CuO, which is a metal powder 32 used as a catalyst, and color is applied to the coated ball 333. (An oxidizing agent such as ozone is used. In the case of the device, the metal powder 32, which acts as a catalyst that has excellent deodorizing effect, is selected and coated according to the type of odor. That is, it is coated to further enhance the deodorizing function of the deodorizing solution.)

④ 1st drying:

Using a Tunnel Dryer (stainless mesh conveyor), dry the coating molding ball 333 to a moisture content of 10% or less with heat and wind at 200~400℃.

⑤ Firing:

The coating molding ball 333 is completely fired [around 1,000°C] in a rotary kiln, and at this time, a speed of about 1Ton/Hr is maintained and fired with the coated firing ball 533. The coating firing ball can be colored according to the firing time and metal powder selection.

⑥ Cooling:

The fired coated firing ball 533 is cooled in an air-cooled manner of 60°C or less using a cooling rotary kiln equipped with an air blower.

⑦ Impregnation:

The cooled coating firing ball 533 is immersed in a non-heat-resistant deodorizing solution 31 diluted with water of about 15 to 25% by weight, and the deodorizing solution 31 is placed on the surface and micropores of the coated firing ball 533. ) Is impregnated to sufficiently permeate to prepare a coated plastic deodorant impregnating ball 535).

⑧ The above deodorant solution 31 can be used in both heat-resistant and non-heat-resistant deodorant solutions for processes that do not undergo high-temperature firing, and the manufacturer selects it according to the purpose of manufacture, and in this description, non-heat resistance is given priority for understanding. Explained.

⑨ Secondary drying and cooling:

Using Tunnel Dryer (Stainless Mesh Conveyor), heat and wind of 50~150℃ The moisture content in the solution is dried to about 10 to 12%, and then cooled by air cooling at 60° C. or lower to complete the deodorizing porous ceramic ball 600.

⑩ Sorting and packing:

Select and package the size suitable for the purpose.

Mixing and impregnating the deodorant solution is easier to supplement the deodorant power than the deodorant powder and is a method of increasing the regeneration rate, and the present invention can be manufactured without using a reinforcing agent or a softening agent.

In the above manufacturing process, the coating of the metal powder 32,

Almost no discoloration and peeling off the surface of the ball, and the various ball shapes according to the process and the completed shape of the deodorizing porous ceramic ball 600 can be confirmed in FIG. 6, and also through the plane and side photographs of FIG. It can be confirmed through the generation of air bubbles 130 that the smooth function of the micropores 90 is maintained. Since the micropores 90 are also involved in maintaining the continuous and cyclical deodorizing power, the pores may be clogged due to the mixing ratio of raw materials and the use of a large amount of hardener during ball manufacturing, which causes deodorization and adsorption power and other functions to be deteriorated. .

The deodorizing porous ceramic ball 600 manufactured by the above-described subdivided process includes standard, color, shape, texture, deodorizing solutions, metal powders, selection of main and sub-materials, time required for each process, metal powder and deodorizing solution. The mixing ratio, volume and specification of the deodorant porous ceramic ball 600 may vary depending on the manufacturing purpose and multi-process of the manufacturer of the deodorizing porous ceramic ball 600, and the ratio composition of the raw material may be based on Example 4, drying, firing, cooling. The time required for etc. is increased or decreased based on about 1 hour, and the advantage of reducing the probability of blocking micropores is the rapidity of producing 10 tons per day by selecting the following multi-processes 1, 2, and 3, and the use of hardeners and softeners. have.

As described above, the required time varies depending on the production volume of the ball, the type of the ball, and the standard, etc., and the deodorizing solution 31 and metal powder 32 with and without heat resistance can be purchased by purchasing products manufactured and sold by related companies in the market. use.

The deodorizing porous ceramic ball 600 is put into an input site such as an odor reduction facility, so that the duration of the deodorizing power lasts from 1 to 6 months depending on the odor material and other environments.When the function is deteriorated, it is collected to supplement and regenerate the deodorizing power. It recycles several times or decomposes or incinerates impurities and recycles or returns them naturally as civil engineering materials, and determines the ball size, input amount, ball type, usage period, and replacement period according to the polluted environment.

Examples 1 to 15 above capture, adsorption and decompose the outflow of various large and small odors such as manure, food, livestock waste, etc. with a deodorizing porous ceramic ball 600, and respond to artificial ball stimulation and cyclical deodorization. As a function, it becomes an alternative to the development of deodorizing porous ceramic ball deodorizing filter material that continuously converts to clean air for several months or more, and it is a detailed content for implementing the design.

The industrial applicability of the present invention is to remove various odors mixed with multi-component organic compounds including ammonia generated from manure, food, livestock waste, incineration plants, etc., by collecting, adsorbing and decomposing them with a deodorizing porous ceramic ball. As it can be used as a filter material and material for cyclic deodorization and filling, it can be applied to various facilities and environmental industries beyond the daily life field to deodorize harmful odors and purify the air.

Main raw material (88): deodorization solution (31) with or without heat resistance and metal powder for catalyst (32)
Sub-materials (89): Select clay mineral powder including zeolite and mica ore powder of phyllite, sericite, and red mica.
90: microscopic ball
130: bubbles (bubbles generated through microscopic pores)
30: water
31: Deodorant solution (collectively, heat-resistant and non-heat-resistant deodorant solution products on the market)
32: Metal powder (common name for metal oxides (MnO2, CuO, CoO, TiO2, ZnO, Fe2O3, etc.) that act as catalysts)
330: water-mixed ball
(Forming ball mixed with sub-material (89) powder and water (30))
331: deodorant mixed ball
(Forming ball in which the auxiliary material (89) powder and the heat-resistant deodorizing solution (31) are mixed)
332: deodorizing coating molding ball
(Molded ball coated with metal powder 32 on deodorant mixed ball 331)
333: coating molding ball
(Molding ball coated with metal powder 32 on water-mixed ball 330)
530: high temperature plastic ball
(Firing ball obtained by firing water-mixed ball 330 at high temperature)
531: deodorization mixed firing ball
(Firing ball obtained by firing deodorant mixed ball 331 at high temperature)
532: deodorization coated firing ball
(Firing ball obtained by firing deodorant coating molding ball (332) at high temperature)
533: coated firing ball
(Coated ball 333 is fired at high temperature)
534: plastic deodorization impregnation ball
(Firing impregnation ball impregnated with deodorizing solution (31) in high temperature firing ball (530))
535: coating plastic deodorization impregnation ball
(Coated firing ball 533 impregnated with deodorizing solution 31)
Multi-process 1, multi-process 2: uncoated
Multi-process 3: Coating process (including areas that overlap with uncoated processes)
600: deodorizing porous ceramic ball (final finished ball of each multi-process 1, 2, 3)

Claims (7)

In the multi-steps 1, 2, and 3 of strengthening deodorizing power, mainly consisting of a heat-resistant deodorant solution (31) and catalyst metal powder (32) that endures high temperature firing without using a curing agent.
Multi-step 1 is,
Injecting the auxiliary material 89 of zeolite clay powder and mica ore powder;
(a1) a high-speed mixing step of a heat-resistant deodorant solution (31) obtained by diluting a fixed amount of auxiliary material (89) and water;
Forming the mixture into a spherical deodorizing compound ball 331;
Drying step to less than 10% moisture content with heat and wind of 200 ℃ ~ 400 ℃;
(a2) firing step of deodorizing mixed firing ball 531 having enhanced deodorizing power by firing at high temperature around 1,000° C.;
Completion step of multi-process deodorizing porous ceramic ball 600 after air-cooling below 60°C;
Deodorizing porous ceramic ball for deodorizing filling, characterized in that is a multi-process manufacturing method The method according to claim 1 of steps (a1) to (a2)
Multi-process 2,
(a1) high-speed mixing of a fixed amount of auxiliary material 89 and water 30;
Molding the mixture into a spherical water mixing ball 330;
200℃~400℃ Primary drying with heat and wind;
After firing the high-temperature firing ball 530 at around 1000° C., air-cooled cooling below 60° C.;
Manufacture of a plastic deodorization chamber needle ball 534 by impregnating a non-heat-resistant deodorizing solution 31 diluted with water in a high-temperature baking ball 530;
(a2) secondary drying with heat and wind of about 50℃~150℃; The method according to claim 1 of steps (a1) to (a2)
In multi-step 3, 3-1,
(a1) high-speed mixing of a heat-resistant deodorizing solution 31 obtained by diluting water with a fixed amount of auxiliary material 89;
Molded into a spherical deodorant blended ball 331;
Coating the deodorizing coating molding ball 332 with the catalyst metal powder 32 on the surface of the deodorizing mixed ball 331;
Dry with heat and wind of 200℃~400℃ to less than 10% moisture content;
(a2) firing the deodorizing coating firing ball 532 by firing at high temperature around 1,000°C; The method according to claim 1 of steps (a1) to (a2)
In multi-process 3, 3-2,
(a1) high-speed mixing of a fixed amount of auxiliary material 89 and water 30;
Molded into a spherical water-mixed ball 330;
Coating the coating molding ball 333 with the metal powder 32 having a catalytic function on the surface of the water-mixed ball 330;
Primary drying with a moisture content of 10% or less with heat and wind of 200℃~400℃;
Baking at high temperature around 1,000°C and firing with coated firing balls 533;
Air-cooled cooling below 60°C;
The coating and firing ball 533 is impregnated with a non-heat-resistant deodorizing solution 31 diluted with water to prepare a coated firing deodorizing impregnating ball 535;
(a2) secondary drying with heat and wind of about 50℃~150℃; Deodorizing porous ceramic ball for deodorizing filling, characterized in that manufacturing a deodorizing porous ceramic ball 600 by the method of any one of claims 1 to 4 The method according to claim 1 to 4,
The composition ratio of the raw material of the deodorizing porous ceramic ball 600 is based on 100% by weight of the total amount of the raw material, 80 to 90% by weight of zeolite (88) powder, 10 to 20% by weight of mica (89) ore powder, and 15 to 25 of water (30) Weight%, heat-resistant to non-heat-resistant deodorant solution 31 diluted with water (31) 15 to 25% by weight, catalyst metal powder (32) 10 to 20% by weight, and multi-process manufacturing with a standard particle diameter of 0.25mm to 60mm or more Deodorizing porous ceramic ball for deodorizing filling, characterized in that The method according to claim 1 to 4,
The deodorizing porous ceramic ball 600 forms molded balls, plastic balls, and impregnated balls based on porous mineral powder, deodorizing solution 31, and catalyst metal powder 32 without using a curing agent. Filter media deodorizing porous ceramic ball for deodorization filling, characterized in that it is manufactured in multiple processes with filter media and materials for cyclical deodorization and filling that are collected, absorbed, decomposed, purified, regenerated and recycled.

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