KR20200097488A - Ball Type Cleaner for Toilet Bowl - Google Patents
Ball Type Cleaner for Toilet Bowl Download PDFInfo
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- KR20200097488A KR20200097488A KR1020190014925A KR20190014925A KR20200097488A KR 20200097488 A KR20200097488 A KR 20200097488A KR 1020190014925 A KR1020190014925 A KR 1020190014925A KR 20190014925 A KR20190014925 A KR 20190014925A KR 20200097488 A KR20200097488 A KR 20200097488A
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- ball type
- type cleaner
- toilet bowl
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- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000000203 mixture Substances 0.000 claims abstract description 12
- 239000000344 soap Substances 0.000 claims abstract description 9
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 8
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 8
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 8
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 abstract description 13
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 4
- 239000012459 cleaning agent Substances 0.000 description 6
- 239000000975 dye Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- -1 alkylbenzene sulfonate Chemical class 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 230000000249 desinfective effect Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000000017 hydrogel Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 2
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 235000012149 noodles Nutrition 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 230000021148 sequestering of metal ion Effects 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0056—Lavatory cleansing blocks
-
- C11D11/0023—
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
- C11D9/267—Organic compounds, e.g. vitamins containing oxygen containing free fatty acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/44—Perfumes; Colouring materials; Brightening agents ; Bleaching agents
- C11D9/444—Dyes; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
Description
본 발명은 변기용 볼 타입 세정제에 관한 것으로서, 더욱 상세하게는 흐르는 물에 조금씩만 용해되어 사용기간이 제대로 보장되면서도 가공성, 세척력과 소독력이 우수한 변기용 볼 타입 세정제에 관한 것이다.The present invention relates to a bowl-type toilet bowl cleaner, and more particularly, to a bowl-type cleaning agent for a toilet bowl that has excellent processability, cleaning power and disinfection power while being properly dissolved in flowing water to ensure a proper use period.
종래 기술로서 세정성분을 하이드로겔 제형 내에 안정화시킴에 따라 장기간 사용이 가능하면서도 사용기간 동안 균일한 양의 세정성분을 방출할 수 있을 뿐만 아니라 탄성과 연성을 가짐에 따라 변기의 배수구를 막지 않으며 별도의 용기 없이 사용이 가능한 변기 세정제 조성물이 개발된 바 있다.As a conventional technology, by stabilizing the cleaning component in the hydrogel formulation, it is possible to use for a long time, and not only can release the cleaning component in a uniform amount during the period of use, but also has elasticity and ductility, so it does not block the drain of the toilet. A toilet cleaner composition that can be used without a container has been developed.
상기 변기 세정제 조성물은 친수성 폴리머 0.1~10 중량%, 가교제 0.1~2 중량%, 비이온성 계면활성제 1~30 중량%, 표백제 0.1~5 중량% 및 물 55~95 중량%를 포함하는 하이드로겔 제형이다(특허 제1351535호 참조).The toilet cleaner composition is a hydrogel formulation comprising 0.1 to 10% by weight of a hydrophilic polymer, 0.1 to 2% by weight of a crosslinking agent, 1 to 30% by weight of a nonionic surfactant, 0.1 to 5% by weight of a bleach, and 55 to 95% by weight of water. (See Patent No. 1351535).
종래 기술로서 알킬벤젠 술포네이트 및 알파 올레핀 술포네이트의 음이온성 계면활성제와 실리콘 오일을 혼합하여 사용함으로써 세정력이 우수하면서도 때발생 현상이 개선되고 가공성이 용이한 변기 세정제 조성물이 개발된 바 있다(특허공개 제2019-0001774호 참조).As a conventional technique, a toilet cleaner composition has been developed that has excellent cleaning power, improves grime, and facilitates processability by mixing anionic surfactants of alkylbenzene sulfonate and alpha olefin sulfonate with silicone oil. No. 2019-0001774).
한편, 본 발명의 출원인은 플러쉬 밸브 구조의 입수구에 설치하여 사용 기간이 제대로 보장되고 변기 사용시 오물이 묻지 않아서 청결이 유지될 수 있는 양변기 청결 기구를 개발한 바 있다(특허출원 제2017-0149673호 참조).On the other hand, the applicant of the present invention has developed a toilet cleaning device that can be installed at the inlet of a flush valve structure to ensure proper use and maintain cleanliness when using a toilet bowl (see Patent Application No. 2017-0149673). ).
그런데, 상기 양변기 청결 기구에서 레버에 의해 개폐되는 플러쉬 밸브 구조에 세정제를 볼 타입으로 설치할 때 흐르는 물에 의해 녹으면서도 충분한 사용기간이 보장되고 볼 타입으로 가공성이 용이하며 세척력과 소독력이 우수한 세정제 조성물의 개발이 필요하게 되었다.However, when the cleaning agent is installed in the flush valve structure that is opened and closed by the lever in the toilet cleaning device in a ball type, it is melted by flowing water and a sufficient period of use is ensured, and the ball type is easy to process and has excellent cleaning and disinfecting power. Development became necessary.
본 발명은 상기와 같은 종래 기술의 문제점을 해결하기 위하여 제안된 것으로서, 레버에 의해 개폐되는 플러쉬 밸브 구조에 세정제를 볼 타입으로 설치할 때 흐르는 물에 의해 녹으면서도 충분한 사용기간이 보장되고 볼 타입으로 가공성이 용이하며 세척력과 소독력이 우수한 변기용 볼 타입 세정제를 제공하는데 그 목적이 있다.The present invention has been proposed to solve the problems of the prior art as described above, and when a cleaning agent is installed in a ball type in a flush valve structure opened and closed by a lever, a sufficient period of use is ensured while being dissolved by flowing water and processability in a ball type Its purpose is to provide a toilet bowl type cleaner that is easy to clean and has excellent cleaning and disinfecting power.
이와 같은 목적을 달성하기 위한 본 발명의 변기용 볼 타입 세정제는 황산나트륨 35~45 중량%, 에톡시레이트 17~23 중량%, 비누소지 13~17 중량%, 3k 9~11 중량%, 구연산 3 중량% 이내 및 수분을 포함하여 구성된 혼합물을 볼 타입으로 가공하여 흐르는 물에 의해 용해되면서 변기를 세정하는 것을 특징으로 한다.The toilet bowl-type cleaner of the present invention for achieving this purpose is sodium sulfate 35 to 45% by weight, ethoxylate 17 to 23% by weight, soap base 13 to 17% by weight, 3k 9 to 11% by weight, citric acid 3% by weight It is characterized in that the toilet bowl is washed while dissolving by flowing water by processing a mixture composed of water and water into a ball type.
그리고, 염료 8~10 중량%, TCC 0.2 중량% 이내 및 EDTA 0.2 중량% 이내를 더 포함하여 구성되는 것을 특징으로 한다.And, it is characterized in that it is configured to further include 8 to 10% by weight of dye, within 0.2% by weight of TCC and within 0.2% by weight of EDTA.
이와 같이 구성된 본 발명의 변기용 볼 타입 세정제는 레버에 의해 개폐되는 플러쉬 밸브 구조에 세정제를 볼 타입으로 설치할 때 흐르는 물에 조금씩만 용해되어 사용기간이 제대로 보장되면서도 가공성, 세척력과 소독력이 우수한 유용한 효과를 발휘한다.The toilet bowl-type cleaner of the present invention constructed as described above is only slightly dissolved in flowing water when the cleaning agent is installed in a ball-type structure in the flush valve structure opened and closed by a lever, so that the service life is properly guaranteed, but excellent processability, cleaning power and disinfection power are exhibited. do.
이하, 본 발명의 목적이 구체적으로 실현될 수 있는 바람직한 실시예를 상세히 설명한다. 본 실시예를 설명함에 있어서, 동일 구성에 대해서는 동일 명칭이 사용되며 이에 따른 부가적인 설명은 생략하기로 한다.Hereinafter, preferred embodiments in which the object of the present invention can be realized in detail will be described in detail. In the description of the present embodiment, the same name is used for the same configuration, and additional description thereof will be omitted.
본 발명의 변기용 볼 타입 세정제는 황산나트륨, 에톡시레이트, 비누소지, 3k, 구연산 및 수분을 포함하여 구성된 혼합물을 볼 타입(Ball type)으로 가공하여 변기 물내림시 흐르는 물에 의해 용해되면서 변기를 세정하는 것이다.The ball-type cleaning agent for toilet bowl of the present invention cleans the toilet while dissolving by flowing water when the toilet is flushed by processing a mixture consisting of sodium sulfate, ethoxylate, soap, 3k, citric acid, and water into a ball type. Is to do.
구체적으로 본 발명은 황산나트륨(Sodium Sulfate) 35~45 중량%, 에톡시레이트(Ethoxylates) 17~23 중량%, 비누소지 13~17 중량%, 3k(폴리옥시에틸렌라우릴 에테르) 9~11 중량%, 구연산 3 중량% 이내 및 수분(물)을 포함하여 구성된 혼합물을 볼 타입으로 가공한다.Specifically, the present invention is sodium sulfate (Sodium Sulfate) 35 to 45% by weight, ethoxylates (Ethoxylates) 17 to 23% by weight, soap base 13 to 17% by weight, 3k (polyoxyethylene lauryl ether) 9 to 11% by weight , Citric acid within 3% by weight and a mixture comprising moisture (water) is processed into a ball type.
황산나트륨(Sodium Sulfate)은 기본적으로 무독성 개질제로 세정 능력을 배가시키고, (알코올) 에톡시레이트(Ethoxylates)는 계면활성제이며, 구연산은 천연방부제로 금속의 녹을 방지하고 세정액의 pH를 중성화시키며 살균, 소독, 광택 기능을 나타낸다.Sodium Sulfate is basically a non-toxic modifier that doubles the cleaning ability, (Alcohol) Ethoxylates is a surfactant, and citric acid is a natural preservative to prevent metal rust, neutralize the pH of the cleaning solution, sterilize and disinfect. , Indicates gloss function.
비누소지는 소프 누들로도 불리는 고형 비누 제조의 재료로서 지방산과 수산화나트륨의 화학반응으로 생산되는 것이다.Soap base is a material for making solid soap, also called soap noodle, and is produced by the chemical reaction of fatty acids and sodium hydroxide.
3k(폴리옥시에틸렌라우릴 에테르)는 비이온 계면활성제로서 음이온, 양이온 등의 다른 계면활성제와 상용성이 양호하고, 계면활성의 지속성을 향상시킬 뿐만 아니라 산, 알칼리, 염 등이 공존하는 수용액에서도 우수한 계면활성을 나타낸다.3k (polyoxyethylene lauryl ether) is a nonionic surfactant and has good compatibility with other surfactants such as anions and cations, improves the persistence of surfactants, and also in aqueous solutions in which acids, alkalis and salts coexist. It shows excellent surface activity.
더욱 구체적으로 본 발명은 염료 8~10 중량%, TCC(3,4,4-트리클로로카르바닐리드) 0.2 중량% 이내 및 EDTA(테트라소듐이디티에이) 0.2 중량% 이내를 더 포함하여 구성된다.More specifically, the present invention is further comprised of 8 to 10% by weight of a dye, within 0.2% by weight of TCC (3,4,4-trichlorocarvanilide), and within 0.2% by weight of EDTA (tetrasodium EDTA). .
즉 첨가물로서 예를 들어 수용성 타르색소 등과 같은 여러 가지 염료, TCC(3,4,4-트리클로로카르바닐리드) 및 EDTA(테트라소듐이디티에이)를 더 포함하여 구성될 수 있다.That is, as additives, for example, various dyes such as water-soluble tar pigment, TCC (3,4,4-trichlorocarvanilid) and EDTA (tetrasodium EDTA) may be further included.
TCC(3,4,4-트리클로로카르바닐리드)는 항미생물제로 기능하고, EDTA(테트라소듐이디티에이)는 금속이온 봉쇄제로서, 물에 금속 이온이 포함되어 있는 경우에도 거품이 잘 발생되도록 하여 제품의 안정도를 향상시키고 산패를 방지하며 반점 발생이나 변색을 방지하는 것으로, 아래 실시예에서는 EDTA4na(4나트륨 염)이 사용되었다.TCC (3,4,4-trichlorocarbanilid) functions as an antimicrobial agent, and EDTA (tetrasodium IDTA) is a metal ion sequestering agent, and foaming occurs well even when water contains metal ions. To improve the stability of the product, prevent rancidity, and prevent spotting or discoloration, EDTA4na (4 sodium salt) was used in the following examples.
상기 표 1(실시예 1)의 성분비로 혼합한 후, 각각 속이 빈 반구 형상의 양쪽 커터를 이용하여 박수가공(혼합 조성물을 양쪽 커터로 박수치듯 찍어서 구 형태로 성형)시켜 볼 타입으로 가공하였다.After mixing in the composition ratio of Table 1 (Example 1), clapping was performed using both cutters of each hollow hemispherical shape (the mixed composition was clapped with both cutters and molded into a spherical shape) and processed into a ball type.
위 성분비로 혼합하였을 경우 가공성이 매우 우수함을 확인할 수 있었다.When mixed with the above component ratio, it was confirmed that the processability is very excellent.
또한, 상기 실시예를 통해 생산된 볼 타입의 세정제를 레버에 의해 개폐되는 플러쉬 밸브 구조(평상시 물에 접촉되지 않다가 변기 레버를 작동시킬 때 흐르는 물에 의해 일부 씻기면서 용해되어 변기로 흘러 들어가는 방식)에 설치하여 테스트한 결과, 흐르는 물에 의해 녹으면서도 충분한 사용기간이 보장되고 세척력과 소독력 등이 우수함을 확인할 수 있었다.In addition, the flush valve structure in which the ball-type cleaning agent produced through the above embodiment is opened and closed by a lever (when it is not normally in contact with water, it is dissolved while being partially washed by flowing water when the toilet lever is operated and flows into the toilet. ) Installed and tested, it was confirmed that a sufficient period of use was ensured even though it was dissolved by flowing water, and the cleaning power and disinfection power were excellent.
이와 같이 본 발명에 따른 바람직한 실시예를 살펴보았으며, 앞서 설명된 실시예 이외에도 본 발명이 그 취지나 범주에서 벗어남이 없이 다른 특정 형태로 구체화될 수 있다는 사실은 해당 기술분야에 있어 통상의 지식을 가진 자에게는 자명한 것이다.As described above, preferred embodiments according to the present invention have been looked at, and the fact that the present invention can be embodied in other specific forms without departing from its spirit or scope in addition to the above-described embodiments is a matter of ordinary knowledge in the relevant technical field. It is self-evident to those who have.
그러므로, 상술된 실시예는 제한적인 것이 아니라 예시적인 것으로 여겨져야 하며, 이에 따라 본 발명은 상술한 설명에 한정되지 않고 첨부된 청구항의 범주 및 그 동등 범위 내에서 변경될 수 있다.Therefore, the above-described embodiments should be regarded as illustrative rather than restrictive, and accordingly, the present invention is not limited to the above description, and may be modified within the scope of the appended claims and equivalents thereof.
Claims (2)
염료 8~10 중량%, TCC 0.2 중량% 이내 및 EDTA 0.2 중량% 이내를 더 포함하여 구성되는 것을 특징으로 하는 변기용 볼 타입 세정제.The method of claim 1,
Dye 8-10% by weight, TCC within 0.2% by weight, and EDTA ball-type cleaner, characterized in that it further comprises within 0.2% by weight.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101351535B1 (en) | 2007-11-14 | 2014-01-15 | 주식회사 엘지생활건강 | Detergent composition for toilet bowel with hydrogel form |
| KR20190000174A (en) | 2017-06-22 | 2019-01-02 | 코오롱인더스트리 주식회사 | Organic photovoltaics |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101351535B1 (en) | 2007-11-14 | 2014-01-15 | 주식회사 엘지생활건강 | Detergent composition for toilet bowel with hydrogel form |
| KR20190000174A (en) | 2017-06-22 | 2019-01-02 | 코오롱인더스트리 주식회사 | Organic photovoltaics |
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