KR20200062776A - A composition of antibacterial fragrances and antibacterial fragrances material having thereof - Google Patents

Abstract

An antibacterial fragrance composition of the present invention provides wider and better antibacterial, antifungal, and disinfection effects on various kinds of bacteria and fungi than when each of essential oils is solely used, and comprises 100% natural ingredients using essential oils harmless to the human body such that residual toxicity does not exist, thereby being used as eco-friendly antibacterial and antifungal agents. Moreover, the composition of the present invention can be used as antibacterial and antifungal agents combined with fragrance due to unique natural fragrance of each essential oil and can be applied to aromatherapy by using medical effects of each essential oil. Moreover, the composition additionally comprises one or more metal aluminosilicate-based heating agents generating heat by hydration such that activity of molecules of the fragrance composition is increased, thereby providing an effect of quickly diffusing the fragrance.

Description

A composition of antibacterial fragrances and antibacterial fragrances material having thereof

The present invention relates to an antimicrobial composition comprising an essential oil and an antimicrobial fragrance comprising the essential oil, and more specifically, mixing an essential oil having an antibacterial property and a perfume component, and rapidly diffusing it to a user It is about a fragrance that can deliver a refreshing and pleasant feeling.

In general, the fragrance diffuses the fragrance contained in the container outside in a closed space to promote a pleasant environment around it. The use of the above-mentioned fragrances is mainly used for indoors and toilets in indoor houses of vehicles, and in recent years, various fragrances having various functions have been developed and utilized.

Among these fragrances, phytoncide is a term used to refer to all substances having bactericidal properties that plants emit to resist bacteria, insects and fungi, and attack organisms. Different and consequently, the effect is also different, and it is known to have a stress-relieving action, strong antibacterial action, deodorization action, fatigue sedation action, allergy and skin disease improvement action, and immune function enhancement effect. A lot of research is being done to scientifically reveal the effects of. In particular, cypress trees belonging to coniferous trees have a superior emission amount of phytoncide per unit compared to other trees, and various products using cypress extract are manufactured and sold.

On the other hand, despite the fact that Korea is a country that likes incense, the incense consumed because of its incense-making technology is almost entirely dependent on foreign company products. Among them, Japanese products are preferred, and the reason that Japanese flavor is preferred is that it is effectively targeting the middle and upper classes through quality improvement. Natural scents made in Japan are traded at a high price of 10,000 won per bottle, which is somewhat burdensome for the common people, but it is a rather attractive product for middle and upper class people who like quality and foreign products, so it is often purchased personally when traveling in Japan.

Artificial scents are cheaper than natural scents, so you can buy them for 500 to 1,000 won each. It is made of chemicals, which is far from the original purpose of buying incense, but because of its low price, most of these artificial fragrances are used.

However, the problems caused by the use of artificial fragrances that are not natural have become a social issue these days.

According to the related data, studies have shown that fragrances can pose a fatal risk to health. [The Royal College of Physicians and the Royal College of Paediatrics and Child Health report in a joint study report that deodorants such as pesticides as well as fragrances can contaminate the air and pose a fatal hazard. According to the report, it is estimated that 99,000 people die from indoor air pollution in Europe, and the death toll from indoor and outdoor air pollution in the UK is at least 40,000 people a year. Also, in order to maintain the fragrance for a long time, several manufacturers produce it with the addition of phallate, but this component causes endocrine system disorders and is designated as an environmental hormone harmful to the human body.

Problems are occurring not only in fragrance materials, but also in containers containing fragrance. Several press releases have reported that polycarbonate products contain environmental hormones that affect the human body.

According to the media, the researchers conducted experiments on six types of candles: commercially available clean cotton, strawberry, and kiwi flavors. As a result, toxic components such as formaldehyde were detected, and it was found that prolonged exposure may affect the bronchus and cause cancer. Consumers' anxiety is growing due to the toxicity behind the fragrance, as opinions have been suggested that can influence the gene's cancer mutagenesis. The component in question is the formaldehyde (formaldehyde) component contained in the fragrance, and since this ingredient has strong aromaticity, it is used to make excellent commercial properties using cheap raw materials, and the probability of cancer is very high.

On the other hand, the interior of the car is sealed for a considerable time, and indoor air pollution is a problem for reasons such as being parked in a wet underground parking lot. When an antibacterial fragrance is installed inside a vehicle, components harmful to the human body are released together as described above, which may rather threaten the human body.

Therefore, it is necessary to provide an antibacterial fragrance made of only natural materials that can be provided in a car interior and are harmless to the human body.

Patent No. 10-1319479 describes a fragrance composition and a package using phytoncide, but does not show any experimental results for antibacterial properties.

Republic of Korea Registered Patent 10-1319479 (October 11, 2013)

The present invention has been devised to solve the above problems, and is intended to provide a fragrance in a convenient form to be provided while being antibacterial and acting as a natural fragrance that is safe for the human body.

Another object of the present invention is to provide a fragrance capable of delivering a refreshing and pleasant feeling to a user by mixing an essential oil having an antibacterial property and a fragrance component and rapidly diffusing it.

The present invention relates to an antibacterial fragrance composition and an antibacterial fragrance comprising the same.

One aspect of the present invention is any one or a plurality of cypress extract selected from cypress, cypress and flower; Any one or more essential oils selected from lavender, thyme, clove, eucalyptus, peppermint and tea tree; Green flavorings consisting of bergamot, green notes, lemon, rosemary, rose, musette, geranium, hyacinth, musk, iris, vetiver and moss; And Aldehyde C11 Undecylenic, Gamma-Undecalactone, Phenyllacetaldehyde, Helional, Alpha-Damascone, Benzyl Acetate (benzyl Acetate) acetate), Methyl Dihydro Jasmonate, Cis-Jasmone, Hydroxy Citric Acid (HCA), Jasmin Absolute, Hydroxycitronellal, Oranthiol ( Aurantiol, Ylang ylang oil, Benzon Resinoid Light, Rose Oxide, Geranium oil, Phenyl ethyl alcohol, Rosalve ), Rose absolute, Eugenol alcohol, Indolene, Civet Cat Oil, Sandalwood, Ethylene Brassylate and Exaltolide It relates to an antimicrobial fragrance composition comprising; any one or a plurality of floral bouquet fragrances selected from (Exaltolide).

At this time, the antibacterial fragrance composition is characterized in that it comprises 60 to 70% by weight of the cypress composition, 10 to 20% by weight of essential oil, 10 to 20% by weight of the green flavor and 10 to 20% by weight of the floral bouque fragrance.

In addition, the cypress composition, essential oil, green flavor and floral bouque flavor is characterized by having a solid shape.

In the present invention, the antibacterial fragrance composition may further include a metal aluminosilicate-based heating agent, and the heating agent is selected from kaolinite, spentine, talc, pyrophyllite, synthetic mica, montmorillonite, hectorite, smectite, and saponite. It is either one or plural.

In addition, the antimicrobial fragrance composition is an antioxidant, an ozone decomposition agent, an antibacterial agent, a moisturizing agent, a coloring agent, a dye, a pigment, an excipient, an alkalizing agent, a pH buffer, a conditioning agent, a chelant, an auxiliary agent, a surfactant, a non-surfactant suspending agent, an emulsifying agent , Binders, chelating agents, anti-microbial agents, anti-fungal agents, abrasives, adhesives, adsorbents, deodorants, pH adjusting agents, oxidizing agents, reducing agents, pigments and any one or more additives selected from a fragrance solubilizer may be further included.

Another aspect of the present invention is an antimicrobial fragrance comprising the antimicrobial fragrance composition, wherein the fragrance is any one selected from oak, cork, coral sand, activated carbon, diatomaceous earth, ocher, calcium hydrogen phosphate, light calcium carbonate, and heavy calcium carbonate. Or it characterized in that the antimicrobial fragrance composition is supported on a plurality of carriers.

The antibacterial fragrance composition according to the present invention and the antibacterial fragrance containing the same show broader and better antibacterial, antifungal and antiseptic effects against various bacteria and fungi than when each essential oil is used alone, and 100 using essential oils harmless to the human body % As it is composed of natural ingredients and has no residual toxicity, it can be used as an environmentally friendly antibacterial and antifungal agent.

In addition, the composition of the present invention can be used as an antibacterial and antifungal agent combined with a fragrance due to the unique natural fragrance of each essential oil, and can also be applied to aromatherapy using the pharmacological action of each essential oil.

Here, by further including at least one metal aluminosilicate-based heating agent capable of dissipating heat by a hydration reaction, the activity of the fragrance composition molecule is increased to have a more quickly scented effect.

Hereinafter, examples and comparative examples will be described in more detail the antibacterial fragrance composition according to the present invention. The following specific examples are provided as examples in order to sufficiently convey the spirit of the present invention to those skilled in the art.

Therefore, the present invention is not limited to the specific examples presented below, but may be embodied in other forms, and the specific examples presented below are only described to clarify the spirit of the present invention, and the present invention is not limited thereto.

At this time, unless there are other definitions in the technical terms and scientific terms to be used, it has a meaning commonly understood by those skilled in the art to which this invention belongs, and unnecessarily obscures the subject matter of the present invention in the following description. Descriptions of possible known functions and configurations are omitted.

Also, the singular form used in the specification and the appended claims may be intended to include the plural form unless otherwise indicated in the context.

The antimicrobial fragrance composition according to the present invention includes any one or a plurality of cypress extracts selected from cypress, side and white flowers; Any one or more essential oils selected from lavender, thyme, clove, eucalyptus, peppermint and tea tree; Bergamot, green note, lemon, rose marry, rose, muget, geranium, hyacinth, musk, Green-based fragrances consisting of Iris, Vetiver, and Moss; And Aldehyde C11 Undecylenic, Bergamot Oil FFC, gamma-Undecalactone, Phenyllacetaldehyde, Helional, Alpha-Damascon ( alpha-Damascone, benzyl acetate, methyl dihydro Jasmonate, cis-Jasmone, hydroxy citric acid (HCA), Jasmin Absolute, hydroxy sheet Hydroxycitronellal, Aurantiol, Ylang ylang oil, Benzon Resinoid Light, Rose Oxide, Geranium oil, Phenyl ethyl alcohol ( Phenyl ethyl alcohol, Rosalve, Rose absolute, Eugenol alcohol, Indolene, Civet Cat Oil, Sandalwood, Ethylene Brasil Ethylene Brassylate and Exaltolide (Exaltolide) any one or a plurality of floral boutique flavors; may include.

The cypress (Chamaecyparis obtusa), cheukbaek (Platycladus orientalis) and the painter (Chamaecyparis pisifera) are all the species belonging to gymnosperms taxales cheukbaek Araliaceae (Cupressaceae), cheukbaek Araliaceae has in addition to cedar the cypress in (Chamaecyparis) in the present invention ( and the like Cryptomeria), hawthorn juniper (Juniperus), Taxodium (Taxodium), or in Hanbaek (Thujopsis).

In general, the species belonging to the cypress family releases phytoncide, which is a term coined by the combination of'phyton' meaning'plant' and'cide' meaning'kill' in Greek. The phytoncide (Phytoncide) is a natural natural healing ingredient emitted from the plant, which collectively refers to the sterilizing material emitted by the plant.Terpenes with high volatility are mainly composed of other phenolic compounds, alkaloids, glycosides, etc. It is expected that products using phytoncide will be further activated by performing complex effects such as deodorization, insect repellent, antibacterial, anti-inflammatory, and increased immune function.

Specifically, the phytoncide contains terpene, and the'terpene' decomposes and removes odors and purifies the air. In particular, it has an effect of removing ammonia, trimethylamine, etc., which cause odors.

In addition, it relieves the excitement caused by the sympathetic nervous system and gives a sense of stability to the parasympathetic nervous system, thereby generating comfort through potential-accompanied negative fluctuations in the frontal lobe of the brain and enhancing enzyme activity in the liver cells to activate physiological functions. The phytoncide α-pinene promotes fatigue recovery and reduces the stress hormone cortisol.

Here, Staphylococcus aureus and Legionella, antibiotic-resistant Staphylococcus aureus, infectious pathogens Listeria and Candida can be sterilized. In addition, fungi, various pests of the bathroom and pathogens parasitic on the skin of the human body are sterilized, and when placed in a high humidity area, dehumidification is also effective.

The cypress extract is extracted from the young branches and leaves of the cypress ( Chamaecyparis obtusa ), the cypress ( Platycladus orientalis ), and the baekbaek ( Chamaecyparis pisifera ), and can extract the active ingredient through water or an organic solvent containing purified water.

Specifically, the young branches and leaves of the cypress can be extracted through a solvent such as lower alcohol, acetone, chloroform, methylene chloride, ether, ethyl acetate, or hexane. At this time, as the lower alcohol, methanol having 1 to 4 carbon atoms, ethanol, propanol, and butanol may be used, and among them, ethanol is most preferable, and may further include 50 to 80% ethanol.

The cypress extract is prepared by adding young branches and leaves such as cypress per 1 liter of the solvent at a rate of 50 to 100 g and decocting for 1 to 6 hours. In addition, it is extracted by ultrasonic extraction, reflux extraction, hot water extraction, cooling extraction or supercritical extraction, preferably reflux extraction, at a temperature of 50 to 120° C. for 0.5 to 24 hours. After concentration under reduced pressure, an extract of the present invention can be obtained using a drying method such as hot air, spraying, coating, or freeze drying. As the drying method, lyophilization, which can best preserve the active ingredient, is preferred.

In addition, when extracting the side white leaves with an organic solvent, preferably, the side white leaves are subjected to ultrasonic extraction, reflux extraction, hot water extraction, cooling extraction or supercritical extraction, preferably ultrasonic extraction at 50 to 100% ethanol for 3 to 24 hours at room temperature. Can be extracted. After concentration under reduced pressure, an extract of the present invention can be obtained using a drying method such as hot air, spraying, coating, or freeze drying. As the drying method, lyophilization, which can best preserve the active ingredient, is preferred.

In the present invention, the essential oil is a composition that is mixed with the cypress extract to amplify the effect of the cypress tree and at the same time give a psychological stability effect, any one or a plurality selected from lavender, thyme, clove, eucalyptus, peppermint and tea tree It can contain.

The lavender oil is extracted from the natural plant Lavender using steam distillation method, which has been mainly used for thousands of years as a folk remedy in the West, and is used for the purpose of clearing the mind when developing a nervous or hysterical attack in the Middle Ages. I also did. The main ingredients of lavender oil include linalyl acetate, linalol, and rabendulol, which are known to have strong sedative effects, and are known to have effects in alleviating insomnia, fatigue, and stress in humans.

The thyme oil has strong, tonic, expectorant, anthelmintic, mouth-and-mouth, blood pressure, anti-toxicity, antirheumatic, aphrodisiac, sterilization, insecticidal, disinfection, edible enhancement, tuberculosis, diuretic action, activates brain cells and improves memory and concentration It has been known to have an effect.

The clove oil is composed of linalyl acetate, linalool and eugenol as main components, and is known to have anticonvulsant, antidepressant, and strong nervous system soothing effects.

The eucalyptus oil contains cineol, has antiseptic and expectorant properties, has strong antibacterial activity against streptococcus, and is known as the best decongestant by inhaling colds and catarrhal symptoms.

The peppermint oil has menthol and menthone as main components, and is known to have antiseptic, anticonvulsant, and expectorant effects.

The tea tree oil is mainly composed of monoterpene alcohol (monoterpene alcohol) and cineol (cineol), and is known to have antibacterial, antiviral, and immune enhancing effects.

The essential oil may be extracted from the leaves or branches of the lavender, clove, eucalyptus, peppermint, tea tree, etc. Specifically, when steaming the leaves or branches, useful components in the interior of the tree are separated. A method of obtaining and rectifying this again by vacuum fractionation may be used.

In the present invention, the fragrance is obtained from flowers, buds, fruits, leaves, branches, stems, roots, and natural resins of aromatic plants, bergamot, green notes, lemons, rosemary, rose, muget, geranium, hyacinth, musk, Green flavors consisting of iris, vetiver and moss; And Aldehyde C11 Undecylenic, Bergamot Oil FFC, gamma-Undecalactone, Phenyllacetaldehyde, Helional, Alpha-Damascon ( alpha-Damascone, benzyl acetate, methyl dihydro Jasmonate, cis-Jasmone, hydroxy citric acid (HCA), Jasmin Absolute, hydroxy sheet Hydroxycitronellal, Aurantiol, Ylang ylang oil, Benzon Resinoid Light, Rose Oxide, Geranium oil, Phenyl ethyl alcohol ( Phenyl ethyl alcohol, Rosalve, Rose absolute, Eugenol alcohol, Indolene, Civet Cat Oil, Sandalwood, Ethylene Brasil Ethylene Brassylate and Exaltolide (Exaltolide) selected from any one or a plurality of floral bouquet flavors; may include, these are mostly plant-based scents by emitting a unique natural scent according to each component, nervous stability, It provides a skin soothing effect, and provides an excellent effect on sterilizing power, disinfecting power, antibacterial and antiviral action than artificial synthetic ingredients.

In the present invention, the bergamot (Citrus bergamia) is used as a natural mosquito repellent, insect ointment, deodorant, inhalant, and has a sedative effect that acts as a powerful antibacterial agent, analgesic agent, preservative, and anticonvulsant.

In the present invention, the green note refers to the smell of freshly cut flowers, grass, or leaves, and includes extracts extracted from sweet violet leaves, which are generally violets. The green notes include palmone and eugenol, and are highly diffusive and effective in treating insomnia.

In the present invention, the lemon (Natural Lemon) relieves pain such as headaches and migraines, and at the same time, when it is hot or anxious, it has a recovery effect and soothing effect and helps to clear the head.

In the present invention, the rosemary (Rosemary) is used as a drug to relieve pain, relieves menstrual cramps in women, normalizes a small amount of menstruation and has diuretic properties, and is effective in resolving the retention of moisture during menstruation. In addition, it gives vitality to brain cells to clear the brain, and is effective for mental overwork and lethargy, and it has the effect of revitalizing and strengthening when the mind is hungry and tired.

In the present invention, the rose (Rose) is a very good tonic for women's womb to relieve tension before menstruation, promote vaginal secretion and normalize the menstrual cycle. In addition, it shows a relieving effect on feelings such as depression, brightens the mind, relieves nervous tension and stress, and empathizes with positive feelings about herself with feminine enjoyment.

In the present invention, the mujet (Muguet) is the French name for the lily of the valley ( Convallaria majalis ), which is toxic and difficult to extract, but is not well known for its effect, but has the effect of amplifying the fragrance when mixed with other fragrances with a subtle fragrance.

In the present invention, the geranium ( pelargonium graveolens ) normalizes the activity of the hormonal system and helps with premenstrual syndrome, irritability, vaginal discharge or unsatisfactory menstruation, and blocks the infectious disease and stimulates the lymphatic system, which treats wastes well. As a tonic in the nervous system, it relieves anxiety and anxiety, stabilizes the nerve, finds stability in the mind, and acts on the adrenal cortex to reduce stress.

In the present invention, the hyacinth ( Hyacinthus ) is not used as a single component, but is used in combination with other fragrances, and has the effect of amplifying the fragrance.

In the present invention, the musk (Musk) is a fragrance obtained by drying a secretion obtained from a sachet (musk spring) in the abdomen of a male musk roe deer, and since the fragrance itself has low volatility and is heavy, it is used as a base for various perfumes when producing perfume. do.

In the present invention, the iris (Iris, iris) is used as a base for various perfumes when making perfumes because it has a large molecule and a large scent, like musk.

In the present invention, the vetiver ( Vetiveria zizanioides ) emotionally raises mood and exerts effects on stress, tension relief, depression relief, and insomnia. Vetiver, which has an excellent effect on recovery from fatigue of the mind and body, maintains the balance of the central nervous system and promotes blood circulation, helping with arthritis and muscle pain. It is used as a tonic for the reproductive system and is used for general infectious diseases by resolving hormone imbalance and activating the immune system throughout the body. It is also useful for skin infections such as acne in skin care and is effective for dry skin and wounds.

In the present invention, the moss (Moss) is an aroma of moss that occurs on oak or pine, and is used as a base for various perfumes when making perfume.

The green flavor may be prepared by, for example, adding water to the extraction part of the plant in a ratio of 1:1 to 1:100 by weight, or heating it, or passing a pressurized water vapor to drain essential oils together with water vapor. As a method of manufacturing essential oils, all kinds of ordinary methods can be used. For example, steam distillation, which discharges essential oils to a temperature lower than the actual boiling point, and compression method to obtain essential oils by squeezing rinds like citrus fruits, While the raw material is expensive, the content of essential oil is low, and when it is unstable to heat and has a lot of soluble content in water, it is absorbed by a non-volatile solvent such as fat, and it is collected using a volatile solvent such as adsorption, hexane, ethyl alcohol, or benzene. A solvent extraction method for extracting aroma components, an exudation method for collecting sap from a wound on a stem or root of a plant, and a supercritical extraction (CO ₂ extracton) may be used. , But is not limited thereto.

In the present invention, the floral bouquet (Floral Bouquet)-based fragrance is a combination of various types of floral scent, and is generally used as a middle note that is expressed in a stable state after 30 to 60 minutes after the fragrance is expressed.

In the present invention, for example, as the floral bouque fragrance, Aldehyde C11 Undecylenic, gamma-Undecalactone, Phenyllacetaldehyde, Helional, Alpha- Damascon (alpha-Damascone), benzyl acetate, methyl dihydro Jasmonate, cis-Jasmone, hydroxy citric acid (HCA), Jasmin Absolute, Hydroxycitronellal, Aurantiol, Ylang ylang oil, Benzon Resinoid Light, Rose Oxide, Geranium oil, Phenyl Phenyl ethyl alcohol, Rossalve, Rose absolute, Eugenol alcohol, Indolene, Civet Cat Oil, Sandalwood, Ethylene Brassylate and Exaltolide, and the like. These may be used alone or in combination of two or more.

In addition, after suspending the natural extract obtained above in distilled water, hot water extraction or fractional extraction using a non-polar solvent such as dichloromethane, n-hexane, chloroform or ethyl acetate, a non-polar solvent-soluble natural extract suitable for the present invention, Preferably a dichloromethane soluble extract can be obtained.

On the other hand, in the present invention, natural raw materials to be extracted are water, lower alcohols such as methanol, ethanol or propanol, chlorinated hydrocarbons such as dichloromethane or chloroform, hydrocarbons such as n-hexane or heptane, aromatics such as benzene and toluene. The natural extract may be provided by ultrasonic extraction, hot water extraction or fractional extraction in a hydrocarbon or a mixed solvent thereof.

In addition, the natural extract of the present invention may be prepared by an essential oil extraction method by steam distillation, compression, adsorption, leaching, supercritical gas extraction, etc., as described in the vegetable oil section above.

The antibacterial fragrance composition is 60 to 70% by weight of the cypress composition, 10 to 20% by weight of the essential oil, 10 to 20% by weight of the green fragrance, and 10 to 20% by weight of the floral boutique fragrance based on the cypress composition. It can be prepared including. When preparing the composition in the above range, the function of giving a refreshing feeling to the user is expressed through the combination of various scents, and in addition, the pharmacological action of each essential oil can be maximally expressed, and it is more extensive for various bacteria and fungi. It can show excellent antibacterial, antifungal and antiseptic effects.

In addition, it is preferable that the cypress composition, essential oil, green flavor and floral bouque flavor have a solid shape. This is because the metal aluminosilicate-based heating agent, which will be described later, has a characteristic that heat is generated by hydration.

In the present invention, the exothermic agent is any agent capable of releasing heat during hydration of the composition, and exothermics in contact with moisture in the air. When the heating agent is included in the fragrance composition as described above, the motility of the fragrance molecule is improved by heat, and thus the fragrance is further promoted to provide the best flavor to the user, and at the same time, the effect of deodorization, insect repellent, antibacterial, anti-inflammatory, and immune function enhancement. Can increase

In the present invention, it is preferable to use a metal aluminosilicate system so that the heat generating agent can actively undergo a hydration reaction. This is because the metal aluminosilicate-based heat generating agent has a microporous surface, so that the moisture in the gas phase can be easily adsorbed, and the hydration reaction proceeds through the adsorption of moisture, thereby facilitating heat generation.

Examples of the metal aluminosilicate-based heating agent in the present invention include kaolinite, spentin, talc, pyrophyllite, synthetic mica, montmorillonite, hectorite, smectite and saponite, and the like, or two or more. It can be used by mixing.

In addition, the metal aluminosilicate-based heating agent has nano-, nano-, meso- and/or macropores, and has a BET surface of at least 300 m 2 /g, especially 300 to 5,000 m 2 /g It is preferred. Here, nanopores may be understood as pores having a diameter of 0.1 to nm, mesopores may have a diameter of 2 to 50 nm, and macropores at least 50 nm or more, especially 50 to It is good to be 950㎛. Here, the heating agent does not limit the average particle size, but is preferably 0.2 to 200 μm.

The metal aluminosilicate-based heating agent is preferably added in an amount of 0.1 to 5 parts by weight compared to 100 parts by weight of the total fragrance composition. When adding less than 0.1 parts by weight, the directional amplification effect due to heat generation is not properly expressed, and when adding more than 5 parts by weight, a component change in the directional material may occur due to excessive heat generation.

In addition, the antibacterial fragrance composition may further include an isothiocyanate derivative to further improve the fragrance of the fragrance composition to be added.

The isothiocyanate derivative has an effect of increasing the fragrance strength of the composition, and the same or stronger fragrance strength can be achieved even if a smaller amount of fragrance composition is used compared to a conventional fragrance composition that does not use the composition. In addition, since the isothiocyanate derivative does not substantially change the fragrance profile of the fragrance composition, even when mixed with other fragrances, the ingredients of the fragrances are changed or expressed alone, which does not cause the user an unpleasant odor.

The isothiocyanate is generally known as a main component of wasabi (Wasabi japonica Matsumura), and plays an important role in expressing a cheap and irritating taste and aroma. In addition, the isothiocyanate is very effective in contributing to the physiological action of antibacterial, antitumor, and antiplatelet aggregation actions.

Examples of the isothiocyanate derivatives usable in the present invention include sulfolaphane (1-isothiocyanato-4-methylsulfinylbutane), glucorapanin (4-Methylsulfinylbutylglucosinolate), phenethyl isothiocyanate, and glucosi And glucosinolate, 6-(methylsulfinyl)hexyl isothiocyanate (6-(methylsulfinyl)hexyl isothiocyanate), and allyl isothiocyanate (3-isothiocyanato-1-propen). These components are isothiocyanate derivatives naturally present in horseradish, broccoli, and the like, and can be easily obtained through a general extraction method, which is economical.

The isothiocyanate derivative is preferably added in a solid form as in the above composition, and the addition amount is not limited, but is preferably added in an amount of 0.1 to 1 part by weight based on 100 parts by weight of the total perfume composition. When adding less than 0.1 parts by weight, the synergistic effect due to the addition of the isothiocyanate derivative is not properly expressed, and when adding more than 1 part by weight, the amplifying effect of the fragrance becomes too strong and may give the user a sense of olfactory fatigue.

The fragrance composition according to the present invention, if necessary, antioxidants, ozone decomposition agents, antibacterial agents, moisturizers, colorants, dyes, pigments, excipients, alkalizing agents, pH buffering agents, conditioning agents, chelants, adjuvants, surfactants, non-surfactants One or more additives such as suspending agents, emulsifying agents, binders, chelating agents, antimicrobial agents, antifungal agents, abrasives, adhesives, adsorbents, deodorants, pH adjusting agents, oxidizing agents, reducing agents, pigments and fragrance solubilizers can be added. However, these additives are not limited to addition amounts or mixing ratios, but are preferably added in a solid form due to the properties of the composition.

The perfume composition according to the present invention is not limited to the manufacturing method. In one example, the extract, essential oil, fragrance and additives are combined together in a batch or continuous reactor. The reactor is preferably suitable for a mechanism for stirring the fragrance formulation, and a solvent may be further added with an additive to uniformly mix the components. It can also be heated to evaporate the solvent during the mixing process.

In addition, it may be carried out through a combination comprising at least one of a variety of forms, such as melt blending, melt blending, dry blending to prepare the composition. Dry blending includes blending without the use of a solvent, and is generally performed to blend two or more fragrance compositions. Melt blending occurs when the temperature of the blending is carried out above the melting point of some of the components and wet blending is generally performed in the presence of a solvent.

The formulation of the formulation includes the use of shear force, elongation force, compression force, ultrasonic energy, electromagnetic energy, thermal energy or a combination comprising one or more of the above force or energy forms, wherein the above mentioned forces are single screw, multiple screw, cross cavity -Intermeshing co-rotating or counter-rotating screw, non-crossing co-rotating or counter-rotating screw, reciprocating screw, screw with pin, barrel with pin, roll, rams, spiral rotor, or any of the above It is performed in a processing device exerted by a combination comprising one or more.

Formulations using the aforementioned forces are single or multiple screw extruders, Buss kneaders, Henschel, helicones, Ross mixers, Banbury, roll mills. , Molding machines such as injection molding machines, vacuum molding machines, blow molding machines, kettles, kettles with distillation and/or condensation columns, etc., or combinations comprising one or more of the above machines.

The fragrance composition prepared as described above may be provided in a solid form, and is preferably provided in a sealed form before use. This is because when the metal aluminosilicate-based heating agent is further included as described above, unnecessary hydration reaction of the heating agent occurs by contact with moisture. To this end, the fragrance composition can be added to the organic polymer formulation. Examples of the polymer to which the fragrance formulation can be added include polyolefin, polyvinyl acetate, polystyrene cellulose acetate, acrylonitrile butadiene styrene, polyacrylic, polycarbonate, polyamide, polyurethane, epoxide and polyester, and the like. have.

In addition, the fragrance composition may be provided in a form supported on one or more carriers. In this case, the carrier is not limited to the present invention, but is preferably oak, cork, coral sand, activated carbon, diatomaceous earth, ocher, calcium hydrogen phosphate, light calcium carbonate, and heavy calcium carbonate. As described above, when the fragrance composition, in particular, the fragrance component is supported on the carrier, it is preferable that the heating agent is mixed and sealed separately from the carrier on which the fragrance composition is supported, thereby promoting diffusion of the fragrance component due to the hydration reaction.

Hereinafter, the present invention will be described in more detail through examples and comparative examples. However, the following examples and comparative examples are only examples for explaining the present invention in more detail, and the present invention is not limited to the following examples and comparative examples.

The physical properties of the specimens prepared through Examples and Comparative Examples were measured as follows.

(Hyang intensity)

Specimens prepared through Examples and Comparative Examples were added to 20 g of a sampling bag (3 L) and measured using e-nose (Futaba, Made in Japan). At this time, the display of the intensity of incense indicated the value of the intensity on the instrument (A.U.=Arbitrary unit), which is an arbitrary notation, using the odorless air as a control.

(Sensory evaluation)

20g of the specimens prepared through Examples and Comparative Examples were added to the fragrance composition into an open circular cell (3 cm×1 cm), and measured through the sense of smell of 20 trained agents. As the measurement method, the higher the value of the fragrance intensity of the measured sample was, the more the fragrance was proportionally diffused, and the distance to detect the odor with the nose was used. That is, the higher the intensity value of the measured sample, the farther the fragrance spreads and the range (distance + space) that can be sensed by the nose is digitized. The evaluation criteria for each item were based on the following 5-point scale method, but rounded off to the second decimal place.

① Diffusion

The intensity of the scent felt by the sense of smell was evaluated separately from the scent intensity.

1: Odorless

2: It is weak and the fragrance is felt within 30cm.

3: Normal, and the scent is felt at a distance of 30-50 cm

4: It is a little strong, and the fragrance is felt at a distance of 50 to 100 cm.

5: Very strong, the fragrance is felt at a distance of 100 cm or more

② Terms

The degree of deterioration, odor, and harmony of scent felt by the sense of smell were evaluated comprehensively.

1: Strong odor

2: The basic scent is minimal, and the odor is moderate

3: Basic scent (green scent) is normal, and odor is weak

4: The basic fragrance and the added fragrance (floral boutique fragrance) are harmonious, and the odor is minimal.

5: Basic and additive fragrances are harmonious, and there is no odor

③ Persistence of fragrance

1: loss of fragrance

2: Fragrance is kept weak, and odor is present

3: The fragrance remains weak

4: The fragrance is kept normal

5: Fragrance is very strong

④ Skin irritation

1: Strong irritation

5: No irritation

(Examples 1 to 3 and Comparative Examples 1 to 3)

Specimens were prepared according to the specifications in Table 1 below, and the manufacturing process was performed by adding cypress extract, essential oil, green flavor, and floral bouque flavor into the reactor in a liquid form and stirred. Here, an excipient (starch) was further added as an additive and stirring was continued to increase the viscosity. When the fluidity disappeared completely, the mixture was put into a screw extruder and extruded into a sphere having an average diameter of 1 cm.

In addition, when a heating agent was further added, the heating agent had a BET surface area of 1,000 m 2 /g, was kaolinite having a diameter of 100 μm, and when a further isothiocyanate derivative was added, the derivative was sulfolapan.

[Table 1]

[Table 2]

As shown in Table 2, the fragrance composition prepared according to the present invention received excellent scores in comparison with the comparative examples in terms of fragrance strength and sensory evaluation. In particular, in the case of Example 2 further including a heat generating agent, it was found that the activity of the fragrance molecule increased due to the hydration reaction of the heat generating agent, and thus it was found that it was superior to Example 1 in terms of diffusion or fragrance strength of the fragrance, and an isothiocyanate derivative was further added. Example 3 was obtained the best evaluation by improving the palatability and persistence of the fragrance.

(Example 4)

The carrier in which the aroma composition of Example 3 was supported was prepared. Specifically, the cypress extract, essential oil, green flavor, and floral bouquet flavor were added to the reactor in a liquid form and stirred to prepare a liquid composition, and then the carrier was immersed in the composition and left for 24 hours. Then, the carrier was separated from the composition and dried at room temperature to complete the fragrance having the perfume composition.

Next, the antibacterial effect of the prepared fragrance was measured. Specifically, E. coli ( Escherichia coli ), Staphylococcus aureus MRSA ( Staphylococcus aureus MRSA) was used, and 10 μl of sterilized physiological saline was inoculated with 100 μl of the retained strain and sufficiently stirred. After stirring, 1 g of the specimen was added, reacted for 30 minutes, and then inoculated into NA (nutrient agar) medium according to the dilution. Then, the inoculated medium was placed in an incubator set at 37°C and a relative humidity of 88*±2% and cultured for 2 days. After the culture was completed, the growth inhibition of the retained strain in the medium was confirmed, and the results are shown in Table 3 below.

[Table 3]

As shown in Table 3, it can be seen that the fragrance prepared according to the present invention has an excellent antibacterial effect. Specifically, in the control group that did not contain any antibacterial substances, the specimens of Example 4 were respectively 6.3×10 ⁷ , 7.0×10 ⁷ , while 1.3×10 ⁸ , 2.7×10 ⁹ and E. coli strains were identified. And only staphylococcus strains can be confirmed that the growth of these bacteria is inhibited.

As described above, the present invention has been described with reference to preferred embodiments and test examples of the present invention, but those skilled in the art may vary the present invention without departing from the spirit and scope of the present invention as set forth in the claims below. You can understand that it can be modified and changed.

This patent was filed with the support of Hannam University Industry-University Cooperation Foundation.

Claims (7)

Cypress, any one or a plurality of cypress extracts selected from cypresses and flowers;
Any one or more essential oils selected from lavender, thyme, clove, eucalyptus, peppermint and tea tree;
Green flavorings consisting of bergamot, green notes, lemon, rosemary, rose, musette, geranium, hyacinth, musk, iris, vetiver and moss; And
Aldehyde C11 Undecylenic, gamma-Undecalactone, Phenyllacetaldehyde, Helional, Alpha-Damascone, benzyl acetate (benzyl acetate) ), Methyl Dihydro Jasmonate, Cis-Jasmone, Hydroxy Citric Acid (HCA), Jasmin Absolute, Hydroxycitronellal, Orantiol ), Ylang ylang oil, Benzon Resinoid Light, Rose Oxide, Geranium oil, Phenyl ethyl alcohol, Rossalve , Rose absolute, Eugenol alcohol, Indolene, Civet Cat Oil, Sandalwood, Ethylene Brassylate and Exaltolide ( Exaltolide) any one or a plurality of floral bouquet flavors;
Antibacterial fragrance composition comprising a.
According to claim 1,
The antibacterial fragrance composition is 60 to 70% by weight of cypress composition, 10 to 20% by weight of essential oil, 10 to 20% by weight of a green fragrance and 10 to 20% by weight of a floral bouque fragrance fragrance composition .
According to claim 1,
The cypress composition, essential oil, green flavoring and floral bouquetting flavorings are antimicrobial aroma compositions characterized by having a solid shape.
According to claim 1,
The antibacterial fragrance composition further comprises a metal alumino silicate-based heating agent.
According to claim 1,
The metal aluminosilicate-based heating agent is an antimicrobial fragrance composition, characterized in that any one or a plurality selected from kaolinite, spentine, talc, pyrophyllite, synthetic mica, montmorillonite, hectorite, smectite and saponite.
According to claim 1,
The antibacterial fragrance composition is an antioxidant, an ozone decomposition agent, an antibacterial agent, a moisturizing agent, a coloring agent, a dye, a pigment, an excipient, an alkalizing agent, a pH buffering agent, a conditioning agent, a chelant, an auxiliary agent, a surfactant, a non-surfactant suspending agent, an emulsifying agent, Antimicrobial fragrance composition further comprising any one or a plurality of additives selected from binders, chelating agents, antimicrobial agents, antifungal agents, abrasives, adhesives, adsorbents, deodorants, pH adjusters, oxidizing agents, reducing agents, pigments and fragrance solubilizers .
An antimicrobial fragrance comprising an antimicrobial fragrance composition according to any one of claims 1 to 6, wherein the fragrance is oak, cork, coral sand, activated carbon, diatomaceous earth, ocher, calcium monohydrogen phosphate, light calcium carbonate, and An antibacterial fragrance, characterized in that the antibacterial fragrance composition is supported on any one or a plurality of carriers selected from heavy calcium carbonate.