KR20200024418A - Hydrogen gas producing device - Google Patents

Hydrogen gas producing device Download PDF

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KR20200024418A
KR20200024418A KR1020180101057A KR20180101057A KR20200024418A KR 20200024418 A KR20200024418 A KR 20200024418A KR 1020180101057 A KR1020180101057 A KR 1020180101057A KR 20180101057 A KR20180101057 A KR 20180101057A KR 20200024418 A KR20200024418 A KR 20200024418A
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hydrogen
hydrogen generator
nonwoven fabric
electrode plate
titanium
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KR1020180101057A
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Korean (ko)
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안정오
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안정오
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C25B1/06—
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
    • C25B11/031—Porous electrodes
    • C25B11/035—
    • C25B11/0415—
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/02—Process control or regulation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

The present invention relates to a functional hydrogen generator and, more specifically, to a functional hydrogen generator which is useful to obtain hydrogen conveniently by forming molecules of hydrogen in a small molecule. The hydrogen generator: has a water tank (250) for storing water, a collection unit in an upper part, and an opening and closing valve (260) and a discharge port (270) for discharging to control a discharge; has a nonwoven electrode plate (210) having a perforated electric plate (200) which is formed by attaching platinum and titanium carbon materials on a plastic plate in the water tank sequentially at 0.1 mm or less of width and interval, and front and rear nonwoven fabrics (100, 110) which are formed by bonding platinum wire, titanium wire, and a carbon material to nonwoven fabric by a weaving or high frequency method with the diameter of 0.1 mm at an interval of 0.1 mm; and has a control unit which alternates between electrodes and supplies power.

Description

기능성 수소발생장치{Hydrogen gas producing device}Functional hydrogen producing device

본 발명은 기능성 수소발생장치에 관한 것으로, 더욱 상세하게는 미분자의 수소와 산소를 발생케하여 편리하게 수소와 산소를 얻을 수 있는 유용한 기능성 수소발생장치에 관한 것이다. The present invention relates to a functional hydrogen generator, and more particularly, to a useful functional hydrogen generator capable of generating hydrogen and oxygen of fine molecules to conveniently obtain hydrogen and oxygen.

수소를 연료로 사용하는 하는 연료전지나 기타 수소를 필요로 하는 곳에 수소를 공급하기 위한 방법으로는, 수소를 기체상태로 고압탱크에 저장한 후 감압밸브를 통해 소정압력으로 배출시켜 공급하는 방법과, 수소를 액체상태로 저장하고 저장되어 있는 액체상태의 수소를 필요한 만큼씩 기화시켜 공급하는 방법과, 수소저장합금에 수소를 흡착시킨 후 공급하는 방법 등이 알려져 있다.As a method for supplying hydrogen to a fuel cell or other hydrogen that requires hydrogen as a fuel, a method of storing hydrogen in a high pressure tank in a gaseous state and then discharging it to a predetermined pressure through a pressure reducing valve, There are known a method of storing hydrogen in a liquid state and vaporizing and supplying the stored liquid hydrogen as necessary, a method of adsorbing hydrogen to a hydrogen storage alloy and then supplying the hydrogen.

그러나 상기 첫 번째 방법을 위한 장치는, 120기압 내지 150기압의 고압에서 견딜 수 있는 수소저장 압력용기가 필요하고 또한 압력조절을 위한 부대장치가 필요함은 물론 수소가 소모되었을 경우 압력용기에 상기 압력으로 수소를 재충진하여야 하는 등의 불편이 있어 운영비용이 많이 들고 장치가 전체적으로 크고 복잡하여 이동이 불편하다는 문제가 있다.However, the apparatus for the first method requires a hydrogen storage pressure vessel capable of withstanding high pressures of 120 atm to 150 atm, and also requires an auxiliary device for pressure regulation. There is a problem that the inconvenience of having to recharge hydrogen, such as the operation cost is high and the device is large and complex, the movement is inconvenient.

또한 두 번째 방법을 위한 장치는, 기체상태의 수소를 섭씨 영하 250도 이하로 냉각하여야 하므로 일단 냉각용 장비가 필요하고 액화된 액체수소가 액화된 상태를 유지하도록 단열성이 뛰어난 특수용기 및 액화수소를 기화시키기 위한 별도의In addition, the device for the second method requires the cooling of gaseous hydrogen to below 250 degrees Celsius, so that special cooling equipment and liquefied hydrogen are needed to maintain the liquefied state of liquid liquid hydrogen. Separate to vaporize

기화장치 등이 더 필요하여 장치가 복잡하고 이동이 불가능하며 항시 폭발의 위험에 노출되어 있다.More evaporators are needed, which makes the device complex, inaccessible and always at risk of explosion.

세 번째 장치는 수소저장합금에 대한 수소의 흡착 및 배출이 반복될 경우 수소저장합금에 국부적인 응력이 가해져 변형이 야기되거나 크랙이 발생하여 비정상적인 수소 누출의 염려가 있다는 문제가 있다.The third device has a problem in that when the adsorption and discharge of hydrogen to the hydrogen storage alloy is repeated, local stress is applied to the hydrogen storage alloy, causing deformation or cracking, thereby causing abnormal hydrogen leakage.

한편, 상기 세 가지 장치 이외에 캐미컬하이드라이드를 수소발생촉매에 접촉시켜 수소가스를 얻는 장치도 제안된 바 있다.Meanwhile, in addition to the above three devices, a device for obtaining hydrogen gas by contacting a chemical hydride with a hydrogen generating catalyst has also been proposed.

이 장치는 화학적 이론을 기초로 응용한 것으로서, 캐미컬하이드라이드의 유동장내에 수소발생촉매를 위치시켜 케미컬하이드라이드가 수소발생촉매에 접하도록 구성한 구조를 갖는다.This device is an application based on chemical theory and has a structure in which the chemical hydride is in contact with the hydrogen generating catalyst by placing the hydrogen generating catalyst in the flow field of the chemical hydride.

그러나 상기 캐미컬하이드라이드를 저장하는 연료저장탱크와 반응결과물을 저장하는 저장탱크를 별도로 구비하여야 하므로 효과적인 공간사용의 한계가 있어 보다 콤팩트한 수소발생장치를 원하는 기대에 부응하지 못하고 있다.However, since the fuel storage tank for storing the chemical hydride and the storage tank for storing the reaction results are separately provided, there is a limit of effective space use, and thus, a more compact hydrogen generator does not meet the expectation.

대한민국특허청 특허등록 제5029560호(2005.07.13)Patent registration of Korea Patent Office No. 5029560

본 발명의 해결하고자 하는 과제는 The problem to be solved of the present invention

부직포를 이용하여 미세분자의 수소와 산소을 얻을 수 있는 기능성 수소발생장치를 제공하는 데 있다.The present invention provides a functional hydrogen generator that can obtain hydrogen and oxygen of fine molecules using a nonwoven fabric.

본 발명의 또 다른 목적은 비용이 저렴하고 많은 량을 얻을 수 있는 기능성 수소발생장치를 제공하는 데있다.Still another object of the present invention is to provide a functional hydrogen generator which is inexpensive and obtains a large amount.

본 발명의 해결수단은 The solution of the present invention

천공판기판에 백금, 티타늄, 탄소재질을 0.1 mm이하 선폭과 간격으로 차례로 고착시키거나, 부직포에 백금선, 티타늄선, 탄소재질을 0.1mm 직경을 0.1mm간격으로 봉체 또는 부칙포 고주파 방식 접합하여 원형으로 말아 +극 ,-극에 전원을 공급하고, 물탱크내에 형성한 것을 특징으로 하는 기능성 수소발생장치를 달성하였다. Platinum, titanium, and carbon materials are bonded to the perforated substrate in order of line width and interval of 0.1 mm or less, or platinum, titanium, and carbon materials are bonded to non-woven fabric by 0.1 mm diameter 0.1 mm intervals. A functional hydrogen generator was formed by supplying power to the + pole and the-pole, and forming it in the water tank.

본 발명을 형성하므로 미세분자의 산소를 얻을 수 있으며, 안전하고, 비용을 절감할 수 있는 효과가 았는 매우 유용한 발명인 것이다.Since the present invention forms a fine molecule of oxygen, it is a very useful invention that has the effect of being safe, cost-effective.

도 1은 본 발명의 바람직한 실시예의 기능성 수소발생장치를 도시한 사시도.
도 2는 본 발명의 기능성 수소발생장치의 단면도.
도 3은 본 발명의 기능성 수소발생장치를 도시한 부분사시도.
도 4는 본 발명의 전극의 사시도.
도 5는 본 발명의 부직포전극판 단면도.
도 6은 다른 실시예의 기능성 수소발생장치의 상태도.
도 7은 본 발명의 실시예의 전극판의 상태도.1 is a perspective view showing a functional hydrogen generating device of a preferred embodiment of the present invention.
2 is a cross-sectional view of the functional hydrogen generator of the present invention.
Figure 3 is a partial perspective view showing a functional hydrogen generating device of the present invention.
4 is a perspective view of an electrode of the present invention.
5 is a cross-sectional view of the nonwoven electrode plate of the present invention.
6 is a state diagram of a functional hydrogen generator of another embodiment.
Figure 7 is a state diagram of the electrode plate of the embodiment of the present invention.

본 발명의 이점 및 특징, 그리고 그것들을 달성하는 방법은 첨부되는 도면과 함께 상세하게 후술되어 있는 실시예들을 참조하면 명확해질 것이다. 그러나 본 발명은 이하에서 개시되는 실시예들에 제한되는 것이 아니라 서로 다른 다양한 형태로 구현될 수 있으며, 단지 본 실시예들은 본 발명의 개시가 완전하도록 하고, 본 발명이 속하는 기술 분야의 통상의 기술자에게 본 발명의 범주를 완전하게 알려주기 위해 제공되는 것이며, 본 발명은 청구항의 범주에 의해 정의될 뿐이다. Advantages and features of the present invention, and methods for achieving them will be apparent with reference to the embodiments described below in detail in conjunction with the accompanying drawings. As those skilled in the art would realize, the described embodiments may be modified in various different ways, all without departing from the spirit or scope of the present invention. It is provided to fully inform the scope of the invention to the invention, which is defined only by the scope of the claims.

본 명세서에서 사용된 용어는 실시예들을 설명하기 위한 것이며 본 발명을 제한하고자 하는 것은 아니다. 본 명세서에서, 단수형은 문구에서 특별히 언급하지 않는 한 복수형도 포함한다. 명세서에서 사용되는 "포함한다(comprises)." 및/또는 "포함하는(comprising)"은 언급된 구성요소 외에 하나 이상의 다른 구성요소의 존재 또는 추가를 배제하지 않는다. 명세서 전체에 걸쳐 동일한 도면 부호는 동일한 구성 요소를 지칭하며, "및/또는"은 언급된 구성요소들의 각각 및 하나 이상의 모든 조합을 포함한다. 비록 "제1", "제2" 등이 다양한 구성요소들을 서술하기 위해서 사용되나, 이들 구성요소들은 이들 용어에 의해 제한되지 않음은 물론이다. 이들 용어들은 단지 하나의 구성요소를 다른 구성요소와 구별하기 위하여 사용하는 것이다. 따라서, 이하에서 언급되는 제1 구성요소는 본 발명의 기술적 사상 내에서 제2 구성요소일 수도 있음은 물론이다.The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. In this specification, the singular also includes the plural unless specifically stated otherwise in the phrase. As used in the specification, "comprises." And / or “comprising” does not exclude the presence or addition of one or more other components than the constituent elements mentioned. Like reference numerals refer to like elements throughout, and "and / or" includes each and all combinations of one or more of the mentioned components. Although "first", "second", etc. are used to describe various components, these components are of course not limited by these terms. These terms are only used to distinguish one component from another. Therefore, of course, the first component mentioned below may be the second component within the technical spirit of the present invention.

다른 정의가 없다면, 본 명세서에서 사용되는 모든 용어(기술 및 과학적 용어를 포함)는 본 발명이 속하는 기술분야의 통상의 기술자에게 공통적으로 이해될 수 있는 의미로 사용될 수 있을 것이다. 또한, 일반적으로 사용되는 사전에 정의되어 있는 용어들은 명백하게 특별히 정의되어 있지 않는 한 이상적으로 또는 과도하게 해석되지 않는다.Unless otherwise defined, all terms used in the present specification (including technical and scientific terms) may be used in a sense that can be commonly understood by those skilled in the art. In addition, terms that are defined in a commonly used dictionary are not ideally or excessively interpreted unless they are specifically defined clearly.

도 1 내지 도 7에 도시한 본 발명의; 기능성 수소발생장치는 1 to 7 of the present invention; Functional hydrogen generator

물탱크(250)와, 상기 물탱크내에 플라스틱판에 벽금, 티타늄 탄소재질을 0.1 mm이하 폭과 간격으로 차례로 고착시키 천공전기판(200) 또는 부직포에 백금선, 티타늄선, 탄소재질을 0.1mm 직경을 0.1mm간격으로 직조 또는 고주파 방식으로 접합하여 형성한 전후방부직포(100,110)을 부직포전극판(210)을 형성하고, 전극과 전극을 달리하도록 교번 교차하여 전원을 공급하는 제어부를 형성한 특징이 있다. The water tank 250 and the plastic sheet in the water tank are fixed to the wall plate and titanium carbon material in a width and interval of 0.1 mm or less, and the platinum wire, titanium wire, and carbon material are 0.1 mm in diameter on the perforated electrode 200 or nonwoven fabric. And the front and rear nonwoven fabrics 100 and 110 formed by joining in a weaving or high frequency manner at intervals of 0.1 mm to form a nonwoven electrode plate 210, and have a control unit for supplying power by alternatingly intersecting the electrodes and the electrodes. .

상기 천공판이 형성된 천공전극판(200)에 전원을 공급시에 전기분해방식으로 (+),(-)극에 전원을 공급하되 일정시간 전원을 공급한 후에 다른 극으로 변환하여 전원을 공급하도록 교차하여 공급된 것을 특징으로 한다. When power is supplied to the perforated electrode plate 200 in which the perforated plate is formed, the power is supplied to the (+) and (-) poles by the electrolysis method, but after the power is supplied for a predetermined time, the power is switched to another pole to supply power. It is characterized in that the supplied.

상기 직류전원12v~24v를 1분~5분 간격으로 교번 교차하여 공급하여 발생되는수소와 산소를 모아 사용케 하도록 형성하였다. The DC power supplies 12v to 24v were alternately supplied at intervals of 1 to 5 minutes, and were formed to collect and use hydrogen and oxygen generated.

상기 전방부직포(100)와 후방부직포(110)는 고주파접합(120)으로 가압하여 부착한 부짇포전극판(210)을 형성하였다. The front nonwoven fabric 100 and the rear nonwoven fabric 110 were formed by pressing the high frequency bonding 120 to the sub-electrode electrode plate 210 attached thereto.

상기 부직포전극판(210)을 원형으로 말아서 형성이 가능하고, 부직포면과 같이 일자형태로 펼쳐져서 다열배치가 가능한 특징이 있다. The nonwoven fabric electrode plate 210 can be rolled up in a circular shape, and has a characteristic of being arranged in a straight line like a nonwoven fabric and arranged in multiple rows.

물을 저장하는 물탱크(250)와 상부에는 수집부와 배출을 제어하는 배출위한 개폐밸브(260)와 배출구(270)를 형성하고, The water tank 250 and the upper portion for storing water to form the opening and closing valve 260 and the outlet 270 for controlling the discharge portion and discharge,

상기 물탱크내에는 부직포전극판(210,210',210",210"')을 배열하고 상기 부직포전극판에는 상부로 전극(140)이 돌출되어 전선(160)으로 외부에서 전원이 공급되도록 형성한 특징이 있다. The nonwoven fabric electrode plates 210, 210 ', 210 ", 210"' are arranged in the water tank, and the electrode 140 protrudes upward from the nonwoven fabric electrode plate so that power is supplied from the outside to the wire 160. There is this.

본 발명은 일명브라운 가스 또는 수소수라고하는데 용도는 자동차연료 주입구에 공급연료와 혼합하여 효율증가 20~50% 소각장연소열료에 혼합하여 사용되며, 보일러 연료에 혼합하여 기름을 20~50% 절약하고, 배기까스가 완전연소로 대폭줄어드는 효과가 있다. 또는 단독연료로 사용가능하다. The present invention is known as brown gas or hydrogen water, the use is mixed with the feed fuel in the car fuel inlet is used to increase the efficiency of 20 to 50% incineration combustion fuel, and to save 20 to 50% oil by mixing in the boiler fuel Exhaust cutlet is greatly reduced by the complete combustion. Or as a single fuel.

상기 부직포전극판에 고착되어 고착되는 미세전선은 백금, 탄소, 티타늄 중에 선택하여 형성이 가능하다.The fine wires fixed to the nonwoven fabric electrode plate may be selected from platinum, carbon, and titanium.

100: 전방부직포 110: 후방부직포
120: 고주파접합 130: 관통구
140: 전극 200: 천공판전극
250: 탱크, 260: 개폐밸브
300: 수소발생장치100: front nonwoven fabric 110: rear nonwoven fabric
120: high frequency bonding 130: through hole
140: electrode 200: perforated plate electrode
250: tank, 260: on-off valve
300: hydrogen generator

Claims (3)

수소발생장치에 있어서,
물을 저장하는 물탱크(250)와 상부에는 수집부와 배출을 제어하는 배출위한 개폐밸브(260)와 배출구(270)를 형성하고,
상기 물탱크내에 플라스틱판에 백금, 티타늄 탄소재질을 0.1 mm이하 폭과 간격으로 차례로 고착시거나 천공전기판(200), 부직포에 백금선, 티타늄선, 탄소재질을 0.1mm 직경을 0.1mm간격으로 직조 또는 고주파 방식으로 접합하여 형성한 전후방부직포(100,110)을 부직포전극판(210)을 형성하고,
직류전원 12v~24v를 1분~5분 간격으로 전극과 전극의 극성을 달리하도록 교번교차하여 전원을 공급하는 제어부를 형성한 것을 특징으로 하는 기능성 수소발생장치.
In the hydrogen generator,
The water tank 250 and the upper portion for storing water to form the opening and closing valve 260 and the outlet 270 for controlling the discharge portion and discharge,
Platinum, titanium carbon material in the plastic tank in the water tank in order to be fixed in the width and interval of 0.1 mm or less, or weaving electrical plate 200, nonwoven fabric platinum wire, titanium wire, carbon material weaving 0.1mm diameter 0.1mm interval or A nonwoven fabric electrode plate 210 is formed by front and rear nonwoven fabrics 100 and 110 formed by joining by a high frequency method.
A functional hydrogen generator, comprising: a control unit for supplying power by alternating DC power 12v to 24v at different intervals of 1 to 5 minutes so as to change the polarity of the electrode.
제 1항에 있어서, 상기 전후방부직포(100,110)을 부직포전극판(210)을 형성하여 두루말이식으로 감아 형성한 부직포전극판을 형성한 것을 특징으로 하는 기능성 수소발생장치.The apparatus of claim 1, wherein the front and rear nonwoven fabrics (100, 110) are formed by forming a nonwoven fabric electrode plate (210) to form a nonwoven fabric electrode plate wound by a roll graft. 제1항에 있어서, 상기 천공전극판은
백금, 티타늄, 탄소재질 중에 선택하여 사용한 것을 특징으로 하는 수소발생장치.


The method of claim 1, wherein the perforated electrode plate
Hydrogen generator, characterized in that used by selecting from platinum, titanium, carbon materials.


KR1020180101057A 2018-08-28 2018-08-28 Hydrogen gas producing device KR20200024418A (en)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5029560B2 (en) 2008-10-01 2012-09-19 コニカミノルタビジネステクノロジーズ株式会社 Image processing apparatus, compression method and decompression method

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5029560B2 (en) 2008-10-01 2012-09-19 コニカミノルタビジネステクノロジーズ株式会社 Image processing apparatus, compression method and decompression method

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