KR20190096573A - Deodorant composition for spraying and method for producing the same - Google Patents

Abstract

A liquid deodorant composition according to the present invention is liquid to facilitate spraying, and has the effect of having high deodorizing properties, high antibacterial properties and high antiviral properties even at a low content. The liquid deodorant composition includes minerals, salts of metals, and water.

Description

Deodorant composition for spraying and method for producing the same

The present invention relates to a deodorizing composition for spraying and a method for producing the same.

In general, deodorant and antimicrobial agent refers to a medicament for removing or reducing malodor, and a physical adsorbent using a chemical substance such as calcium chloride, formalin or a substance having an adsorption action such as activated carbon is used.

However, the use of solid activated carbon and aromatic chemicals that are toxic to humans is limited as a raw material for deodorizing agents. Deodorants having natural ingredients as raw materials and harmless to humans have been developed.

Korean Patent Publication No. 10-2015-0019461 discloses an 'environmental deodorant composition for removing formaldehyde and ammonia'. The deodorant composition is characterized in that the oil having a formaldehyde deodorization rate and the oil having ammonia deodorization rate is mixed in a weight ratio of 10 ~ 45:55 ~ 90, because it consists only of natural oils commonly used in fragrance, It is harmless and can effectively remove the smell of formaldehyde and ammonia. In addition, since it contains only natural essential oils, not only the deodorant effect but also the aroma effect can be obtained.

Korean Patent Application Publication No. 10-0337148 discloses natural ingredients including herbal medicines such as oak, redwood, camellia, camellia, organza, elm, plum, donkey, licorice, astragalus, jujube, cheonggung and wormwood as main ingredients. Liquid deodorants using materials have been disclosed.

However, deodorants and deodorants that have been developed to date have limitations on deodorant properties, deodorizing effect should be exhibited within a shorter time, and higher deodorizing effect should be exhibited even when using less content. Furthermore, there is a need for a multi-purpose deodorant / antibacterial agent that combines high antimicrobial and bactericidal properties, but stability is also basically required for the human body to be harmless or substantially ineffective.

However, the spray deodorant composition used as a method of spraying on the deodorizing object is limited in the use of known materials having excellent deodorizing properties as the shape thereof should be liquid to facilitate the spraying. So far, many solid deodorants with excellent antibacterial and bactericidal properties have been studied, but the technology for liquefaction for use as a spray deodorant has not been studied.

Therefore, there is a need for a versatile deodorant / antibacterial agent having both high antibacterial and bactericidal properties as well as antiviral properties, which are harmless to the human body or have substantially no influence, and thus more research is needed.

Korean Patent Publication No. 10-2015-0019461 Korean Registered Patent Publication No. 10-0337148

It is an object of the present invention to provide a liquid deodorizing composition which is liquid in shape so as to be easily sprayed, and which has high deodorizing properties, high antibacterial properties and high antiviral properties even at a lower content.

Liquid deodorizing composition according to the present invention, the mineral component extracted from mineral particles containing any one or two or more minerals selected from sericite, bentonite, zeolite, corallite; Salts of metals comprising any one or two or more selected from copper, iron and zinc; And water;

In one embodiment of the present invention, the mineral component may be derived from an aqueous mineral solution prepared by heat-treating and filtering the mineral mixture including the mineral particles and water.

In one embodiment of the present invention, the mineral particles may comprise two or more of the minerals, the mineral component, a1) each of the mineral mixture comprising the respective mineral particles and water at high temperature heat treatment and filtration each Step of preparing a mineral aqueous solution and a2) may be derived from the aqueous mineral solution prepared by mixing the respective mineral aqueous solution to prepare a mineral aqueous solution.

In one embodiment of the present invention, the salt of the metal may include any one or two or more selected from copper sulfate, iron sulfate and zinc sulfate.

In one embodiment of the present invention, the liquid deodorizing composition may further comprise any one or two or more selected from sodium molybdate, sulfur, calcium carbonate and potassium iodide.

In one embodiment of the present invention, the liquid deodorizing composition may include 1 to 30 parts by weight of the salt of the metal based on 100 parts by weight of the water.

In one embodiment of the present invention, the liquid deodorant composition may be an antiviral liquid deodorant composition.

The present invention also provides a spray deodorant comprising the liquid deodorant composition.

In addition, the present invention comprises the steps of: a) preparing a mineral solution by heat-treating and filtering a mineral mixture including water and mineral particles including any one or two or more minerals selected from sericite, bentonite, zeolite, and corallite and filtering; b) provides a method for producing a liquid deodorant composition comprising any one or two or more selected from copper, iron and zinc in the aqueous mineral solution.

In one embodiment of the present invention, the mineral particles may comprise two or more of the minerals, and step a) comprises: a1) high temperature heat treatment and filtration of each mineral mixture comprising each mineral particle and water; Preparing each aqueous mineral solution and a2) mixing the respective aqueous mineral solutions to prepare a mineral aqueous solution.

In one example of the present invention, any one or two or more selected from sodium molybdate, sulfur, calcium carbonate and potassium iodide may be further mixed with the aqueous mineral solution in step b).

The liquid deodorant composition according to the present invention has the effect of having a high liquid deodorizing properties, high antibacterial properties and high antiviral properties even in a small amount of liquid form to facilitate spraying.

Even if the effects are not explicitly mentioned in the present invention, the effects described in the specification and the inherent effects expected by the technical features of the present invention are treated as described in the specification of the present invention.

Hereinafter will be described in detail a spray deodorant composition and a method for producing the same according to the present invention.

Unless otherwise defined in the technical and scientific terms used in the present invention, those having ordinary skill in the art to which the present invention belongs have the meanings that are commonly understood, and the gist of the present invention is unnecessary in the following description. Descriptions of well-known functions and configurations that may be blurred are omitted.

As used herein, the singular forms “a”, “an” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise.

 The unit of% used without special mention in the present invention means weight% unless otherwise defined.

Liquid deodorizing composition according to the present invention, the mineral component extracted from mineral particles containing any one or two or more minerals selected from sericite (svite), bentonite, zeolite, coralite (coral); Salts of metals comprising any one or two or more selected from copper, iron and zinc; And water;

The mineral component is characterized in that it is derived from an aqueous mineral solution prepared by heat treatment and filtration of the mineral mixture comprising the mineral particles and water, characterized in that the heat treatment is preferably carried out at a high temperature. In particular, the liquid deodorant composition according to the present invention has an effect of remarkably excellent properties such as deodorization, sterilization, antibacterial, antiviral, even if the shape is liquid.

The term 'high temperature heat treatment' refers to a heat treatment near the boiling point of the mineral mixture, and preferably may mean a heat treatment within the boiling point ± 10 ° C. of the mineral mixture. As used herein, the term “boiling point” refers to a boiling point of an object, and in detail, may refer to a boiling point of the mineral mixture.

The mineral particles may be used alone as the above-described minerals, preferably two or more minerals may be used. Where the composition comprises two or more minerals, two or more minerals may be used in a variety of ways, such as each mineral being mixed in water and then used in this state by heat treatment and filtration, but preferably each mineral is It is preferable to use each mineral solution through an independent process. The filtration may be various known filtration methods as long as the mineral particles can be separated and removed from the aqueous mineral solution.

As a preferred example when two or more minerals are included, the mineral component may include a1) heat treating and filtering each mineral mixture including the respective mineral particles and water, and a2) the aqueous solution. It can be derived from the aqueous mineral solution prepared by mixing the respective aqueous mineral solution to prepare a mineral aqueous solution. At this time, the heat treatment temperature is preferably performed at a high temperature as described above, that is, near the boiling point of the mineral mixture.

More preferably, all of the above-mentioned minerals may be used to maximize deodorization, antibacterial and antiviral properties. That is, the mineral particles may include sericite, bentonite, zeolite, and corallite. Specifically, when the mineral particles include sericite, bentonite, zeolite, and corallite, the mineral component is a1-1) heat treating and filtering the first mineral mixture comprising mineral particles and water containing sericite A1-2) preparing a first aqueous mineral solution, a1-2) heat treating and filtering a second mineral mixture including bentonite and water, and preparing a second aqueous mineral solution, a1-3) containing zeolite Heat treating and filtering a third mineral mixture including mineral particles and water to prepare a third mineral aqueous solution, a1-4) heat treating and filtering a fourth mineral mixture including mineral particles and water, including corallite Preparing a fourth mineral aqueous solution by a2) preparing a mineral aqueous solution by mixing the respective mineral aqueous solutions Can.

In the step a1), a1-1) to a1-4), the composition ratio of the mineral particles and water is not limited as long as the above-described effects can be realized, for example, 3 to 90 weight of the mineral particles based on 100 parts by weight of water. Part, preferably 5 to 50 parts by weight. More specifically, the composition ratio may be 3 to 30 parts by weight of sericite, 1 to 15 parts by weight of bentonite, 1 to 15 parts by weight of zeolite, 0.5 to 10 parts by weight of coralite, preferably 5 to 20 parts by weight of sericite. , 2 to 10 parts by weight of bentonite, 2 to 10 parts by weight of zeolite, and 1 to 5 parts by weight of coralite. However, the composition ratio is only a preferable example, of course, the present invention is not limited thereto.

The average particle diameter of the mineral particles is not limited as long as the mineral component of the mineral particles can be extracted with water, preferably, the finer the process time, the extraction efficiency can be improved, a specific example, 0.5 to 500 ㎛ Of course, the present invention is not limited thereto.

The extraction time during the extraction may be as long as the mineral component can be extracted to the extent that the above-described effects can be implemented, for example, 10 to 60 minutes, but this is a matter that can be properly adjusted by those skilled in the art, It is a matter of course that the present invention is not limited.

The term 'derived from the mineral aqueous solution' referred to in the present invention means that the mineral component of the mineral aqueous solution from which the mineral component is extracted from the mineral particles is included in the composition, and various methods such as addition and mixing into the composition may be used. There is no limit.

Liquid deodorizing composition according to a preferred embodiment may further comprise any one or two or more selected from sodium molybdate, sulfur, calcium carbonate and potassium iodide. As a preferred example, when the composition includes sulfur, calcium carbonate and potassium iodide, the deodorizing properties, antibacterial properties and antiviral properties may be further improved, but the present invention is not limited thereto. .

The liquid deodorizing composition according to the present invention is not particularly limited in composition ratio, but preferably 0.1 to 5 parts by weight of the sodium molybdate, 0.1 to 10 parts by weight of sulfur, and 0.1 to calcium carbonate based on 100 parts by weight of water. It may include any one or two or more selected from 10 parts by weight and 0.5 to 15 parts by weight of the potassium iodide, more preferably 0.5 to 3 parts by weight of the sodium molybdate, 1 to 5 parts by weight of the sulfur, It may include any one or two or more selected from 1 to 5 parts by weight of calcium carbonate and 2 to 8 parts by weight of the potassium iodide. However, this is only a preferred example, and the present invention is not limited thereto.

The liquid deodorizing composition according to an embodiment of the present invention may include sodium molybdate, but very preferably sodium molybdate is used in the liquid deodorizing composition when two or more of the above minerals are used as respective mineral aqueous solutions through an independent process. It is good to be included. That is, a very preferred example in which the liquid deodorant composition comprises sodium molybdate, wherein the mineral component, a1) to heat and filter each mineral mixture comprising the respective mineral particles and water to prepare each mineral aqueous solution It is preferable that the liquid deodorant composition derived from the aqueous mineral solution prepared by the step and a2) mixing the respective aqueous mineral solutions to produce a mineral aqueous solution includes sodium molybdate. At this time, the heat treatment temperature is preferably performed at a high temperature, that is, near the boiling point as described above. Synthetic effect of deodorizing, antibacterial, and antiviral properties in case of composition containing mineral components derived from mineral aqueous solution mixed with two or more kinds of mineral particles at the same time through extraction and filtration process, even though sodium molybdate is further included May not appear significantly, but in the case of a composition in which two or more kinds of mineral particles are separately subjected to an extraction and filtration process, and a mineral component derived from the mixed aqueous mineral solution is used, deodorization and antibacterial action are further included. , Synergistic effects of antiviral properties can be significantly improved. This is due to the fact that sodium molybdate may exhibit far-infrared, anion-releasing effect, and antimicrobial and antiviral properties by direct or indirect reaction with components of the composition according to the present invention in a liquid phase. The mineral components in the case where two or more of the minerals are used in each mineral aqueous solution through an independent process are considered to be due to the components that can participate in the reaction can be extracted in a high content by the independent process.

The salt of the metal may be various ones as long as it has deodorizing properties, and preferably may include any one or two or more selected from copper sulfate, iron sulfate, and zinc sulfate. As a preferred example, when the salt of the metal includes all of copper sulfate, iron sulfate and zinc sulfate, the deodorizing property, antibacterial property and antiviral property may be further improved, but the present invention is not limited thereto. Of course.

The use amount of the salt of the metal is not limited as long as it can implement the above-described effects, preferably 1 to 30 parts by weight of the salt of the metal with respect to 100 parts by weight of water. More specifically, the use amount may be 0.5 to 10 parts by weight of salt of copper, 0.1 to 5 parts by weight of salt of iron, 0.5 to 10 parts by weight of salt of zinc, and more preferably of 100 parts by weight of water. 1 to 5 parts by weight of salt, 1 to 3 parts by weight of salt of iron, and 2 to 5 parts by weight of salt of zinc. However, the use content is only a preferred example, of course, the present invention is not limited thereto.

The water may be generally handled, and preferably, pure water prepared through an ion exchange filter or a membrane filter is used, and reacts with the unstable ions in the above-described steps such as undergoing a heat treatment at a high temperature. It is possible to prevent the phenomenon that the composition becomes cloudy or the purity decreases. However, this is only a preferred example, and the present invention is not limited thereto.

The liquid deodorant composition according to the present invention may be an antiviral composition. The virus may also include corona virus, herpes simplex virus, rhinovirus or influenza virus.

Liquid deodorant composition according to the present invention can be used in a variety of fields if the purpose for deodorization, antibacterial, sterilization, virus inactivation, etc., preferably can be used to spray the target object in the field for the purpose.

The liquid deodorizing composition according to the present invention is not limited to the production method, but may be preferably prepared by the following method.

Liquid deodorizing composition according to an embodiment of the present invention, a) mineral mixture containing any one or two or more minerals selected from sericite, bentonite, zeolite, corallite and water mixture and heat treatment at high temperature and filtered Preparing an aqueous mineral solution, and b) mixing a salt of a metal including any one or two or more selected from copper, iron, and zinc with the aqueous mineral solution.

The heat treatment time, that is, the extraction time may be as long as the mineral component can be extracted to the extent that the above-described effects can be realized as described above, and may be, for example, 10 to 60 minutes. As it may be, the present invention is not limited thereto.

In a preferred embodiment, the mineral particles may comprise two or more of the minerals, wherein step a) comprises: a1) treating each mineral mixture comprising the respective mineral particles and water at a high temperature with heat and filtering each mineral; Preparing an aqueous solution and a2) may comprise mixing the respective aqueous mineral solution to prepare a mineral aqueous solution.

As a preferred example, any one or two or more selected from sodium molybdate, sulfur, calcium carbonate and potassium iodide may be further mixed with the aqueous mineral solution in step b).

Hereinafter, the present invention will be described in detail with reference to Examples, but these are for explaining the present invention in more detail, and the scope of the present invention is not limited by the following Examples.

Mineral aqueous solution manufacturing process

12.5 parts by weight of sericite particles having an average particle diameter of 30 μm were added to 100 parts by weight of pure water while maintaining pure water at a temperature of 65 ° C., and stirred for 30 minutes to extract the mineral component of sericite into pure water. A mineral mixture was prepared.

Subsequently, the aqueous solution of minerals was prepared by separating and removing the sericite particles in the mineral mixture using a filtration filter.

Soluble ingredient mixing process

To 100 parts by weight of the aqueous mineral solution, 3 parts by weight of copper sulfate, 2.5 parts by weight of iron sulfate, 2.5 parts by weight of zinc sulfate, and 1.25 parts by weight of sodium molybdate were sequentially added and stirred for 25 minutes to prepare a liquid deodorizing composition.

In the mineral aqueous solution preparation of Example 2, a liquid deodorizing composition was prepared in the same manner as in Example 1, except that pure water having a boiling point (100 ° C.) was used instead of pure water having a temperature of 65 ° C. .

A liquid deodorizing composition was prepared in the same manner as in Example 2, except that bentonite was used instead of sericite in Example 2.

A liquid deodorizing composition was prepared in the same manner as in Example 2, except that zeolite was used instead of sericite in Example 2.

A liquid deodorizing composition was prepared in the same manner as in Example 2, except that coralite was used instead of sericite in Example 2.

In Example 2, a liquid deodorizing composition was prepared in the same manner as in Example 2, except that the aqueous mineral solution using the following mixed extraction process was used instead of the aqueous mineral solution.

Mineral aqueous solution manufacturing process

Pure water is heated to a boiling point, the average particle diameter of 30 parts by weight of pure water in the state of boiling point containing 12.5 parts by weight of sericite, 6.5 parts by weight of bentonite particles, 5 parts by weight of zeolite and 3 parts by weight of corallite Into the mineral particles of μm and stirred for 30 minutes to extract the mineral component of each mineral particles in pure water to prepare a mineral mixture.

Subsequently, mineral particles in the mineral mixture were separated and removed using a filtration filter to prepare an aqueous mineral solution using a mixed extraction process.

In Example 2, a liquid deodorizing composition was prepared in the same manner as in Example 2, except that the aqueous mineral solution using the following separate extraction process was used instead of the aqueous mineral solution.

1st mineral aqueous solution manufacturing process

The first pure water was heated to the boiling point, 12.5 parts by weight of sericite particles having an average particle diameter of 30 μm were added to 100 parts by weight of pure water under the boiling point, and the mineral component of sericite was extracted into the pure water. Stirring for minutes gave the first mineral mixture.

Subsequently, the first mineral aqueous solution was prepared by separating and removing the sericite particles in the first mineral mixture using a filtration filter.

Second mineral aqueous solution manufacturing process

The second pure water is heated to the boiling point, 6.5 parts by weight of bentonite particles having an average particle diameter of 30 μm are added to 100 parts by weight of pure water under boiling point, and the bentonite mineral is extracted in the pure water for 30 minutes. Stirring gave a second mineral mixture.

Subsequently, the second mineral aqueous solution was prepared by separating and removing bentonite particles in the second mineral mixture using a filtration filter.

Third mineral aqueous solution manufacturing process

The third pure water is heated to the boiling point, 5 parts by weight of zeolite particles having an average particle diameter of 30 μm are added to 100 parts by weight of pure water in a boiling state, and 30 minutes so that the mineral component of the zeolite is extracted into the pure water. Stirring gave a third mineral mixture.

Subsequently, the third mineral aqueous solution was prepared by separating and removing the zeolite particles in the third mineral mixture using a filtration filter.

4th mineral aqueous solution manufacturing process

The fourth pure water was heated to the boiling point, and 3 parts by weight of corallite particles having an average particle diameter of 30 μm were added to 100 parts by weight of pure water in the state of maintaining the boiling point so that the mineral component of the corallite was extracted into the pure water. Stirring for minutes gave a fourth mineral mixture.

Subsequently, the fourth mineral aqueous solution was prepared by separating and removing the corallite particles in the fourth mineral mixture using a filtration filter.

And the first to fourth mineral aqueous solution was mixed to prepare a separate aqueous solution of the extraction process.

In the soluble component mixing process of Example 7, except that 1.25 parts by weight of sodium molybdate was further mixed with 100 parts by weight of the mineral aqueous solution was carried out in the same manner as in Example 7 to prepare a liquid deodorizing composition.

In the soluble component mixing process of Example 6, except that 1.25 parts by weight of sodium molybdate was further mixed with 100 parts by weight of the aqueous mineral solution, it was carried out in the same manner as in Example 6 to prepare a liquid deodorizing composition.

In the soluble component mixing step of Example 8, 100 parts by weight of an aqueous mineral solution was added in the same manner as in Example 8 except that 3 parts by weight of sulfur, 3 parts by weight of clam shell (calcium carbonate) powder, and 4.5 parts by weight of potassium iodide were further mixed. To prepare a liquid deodorant composition.

Comparative Example 1

3 parts by weight of copper sulfate, 2.5 parts by weight of iron sulfate, 2.5 parts by weight of zinc sulfate and 1.25 parts by weight of sodium molybdate were sequentially added to 100 parts of pure water, and stirred for 25 minutes to prepare a liquid deodorizing composition. .

Deodorization characteristic test

Each of the liquid deodorant compositions of Examples 1 to 10, Comparative Example 1 and Comparative Example 2 was measured by CT 13-70952 as a sample, and the deodorization characteristics of the ammonia removal rate, the hydrogen sulfide removal rate and the methyl mercapten removal rate were evaluated. .

Deodorization characteristics were also evaluated through sensory evaluation of a total of 50 patients. Specifically, In order to determine the deodorization characteristics of each liquid deodorant composition of Examples 1 to 10, Comparative Example 1 and Comparative Example 2, the sensory evaluation by the five-point method, the results are shown in Table 1 below.

In detail, the experimenter who participated in the sensory evaluation was a total of 30 men and women consisting of adolescents and adults of 12 to 17 years old, repeating the sensory evaluation of the deodorant properties of the liquid deodorant composition three times using a five-point method Was carried out.

As a specific evaluation method thereof, food wastes left at room temperature for 20 days were divided into equal weights and used as samples for deodorization. After each experimenter evaluated the degree of malodor of each sample, the same amount of each liquid deodorant composition was sprayed on the sample at the same distance and after 30 minutes to evaluate the degree of malodor reduction for the treated feed to each experimenter It was made. At this time, the sample before the composition treatment was evaluated as the degree of odor reduction was improved in the order of 2, 3, 4, 5 relative to 1 point.

In Table 2, deodorization characteristics were calculated and applied as the average of each evaluated value, rounded off to two decimal places.

Deodorant properties Control (Before Treatment) One Example 1 2.5 Example 2 3.6 Example 3 3.5 Example 4 3.6 Example 5 3.4 Example 6 3.8 Example 7 4.4 Example 8 4.7 Example 9 4.4 Example 10 4.9 Comparative Example 1 1.4

As a result, in the case of Example 2 using the mineral aqueous solution from which mineral-derived minerals were extracted at the boiling point, the deodorizing characteristics were much better than that of Example 1 performed below the boiling point.

In addition, in the case of Example 6 in which two or more kinds of mineral particles were used, it was confirmed that the deodorization characteristics were slightly improved compared to those of Examples 2 to 4 in which one kind of mineral particles were used.

Particularly, in Example 7, using the mineral aqueous solution in which two or more kinds of mineral particles were separately extracted and filtered, and then mixed. Example 6 using the mineral aqueous solution in which two or more mineral particles were mixed and subjected to the extraction and filtration process at once. Compared with the case, it was confirmed that the deodorizing property is significantly improved.

In addition, in the case of Example 8 using a more aqueous sodium molybdate, and mixed with two or more types of mineral particles separately after the extraction and filtration process, compared with the case of Example 7 in which sodium molybdate is not used Deodorization properties were further improved. On the other hand, in the case of Example 9, in which sodium molybdate is further used, and the mineral aqueous solution obtained by mixing two or more kinds of mineral particles and undergoing the extraction and filtration process at the same time is compared with the case of Example 6 in which sodium molybdate is not used, It was confirmed that the improvement of the deodorization characteristic due to sodium is not substantially seen. Therefore, the sodium molybdate can be confirmed that the effect is shown only when the two or more mineral particles are used in the mixed aqueous mineral solution after the extraction and filtration process separately.

In addition, it was confirmed that the case of Example 10 in which sulfur, calcium carbonate, and potassium iodide was further used, compared to the case of Example 9 which was not, the deodorization property was further improved.

As a specific result of the deodorizing properties of the liquid deodorizing composition of Example 10, the ammonia removal rate was 91.8 to 93.8%, the hydrogen sulfide removal rate was 95.9 to 100%, and the methyl mercapten removal rate was 49.0 to 52.1%.

Antibacterial property test

Each of the liquid deodorant compositions of Examples 1 to 10, Comparative Example 1 and Comparative Example 2 was measured by CT 13-70951 to evaluate the antimicrobial properties of the E. coli removal rate, Staphylococcus aureus removal rate and Salmonella removal rate. It was.

As a result, in the case of Example 2 using the mineral aqueous solution from which mineral-derived minerals were extracted at the boiling point, the antibacterial property was better than that of Example 1 performed below the boiling point.

In addition, in the case of Example 6 in which two or more kinds of mineral particles were used, it was confirmed that the antibacterial properties were improved compared to those of Examples 2 to 4 in which one kind of mineral particles were used.

In addition, in the case of Example 7 using the mixed mineral solution after two or more types of mineral particles, respectively, after the extraction and filtration process separately, Example 6 using the mineral aqueous solution roughly subjected to the extraction and filtration process at the same time Compared with the case, it was confirmed that the antimicrobial properties were significantly improved.

In addition, in the case of Example 8 using a more aqueous sodium molybdate, and mixed with two or more types of mineral particles separately after the extraction and filtration process, compared with the case of Example 7 in which sodium molybdate is not used The antibacterial properties were greatly improved. On the other hand, in the case of Example 9, in which sodium molybdate is further used, and the mineral aqueous solution obtained by mixing two or more kinds of mineral particles and undergoing the extraction and filtration process at the same time is compared with the case of Example 6 in which sodium molybdate is not used, It was confirmed that the improvement of antibacterial properties due to sodium is not substantially seen. Therefore, the sodium molybdate can be confirmed that the effect is shown only when the two or more mineral particles are used in the mixed aqueous mineral solution after the extraction and filtration process separately.

In addition, it was confirmed that the case of Example 10 in which sulfur, calcium carbonate, and potassium iodide was further used, compared to the case of Example 9 which was not, the antibacterial property was further improved.

As a specific result of the antimicrobial properties of the liquid deodorizing composition of Example 10, all of the E. coli removal rate, Staphylococcus aureus removal rate and Salmonella removal rate was more than 99.9%.

Antiviral Characterization Test

Each of the liquid deodorant compositions of Examples 1 to 10, Comparative Example 1 and Comparative Example 2 was measured by a CPE / MTT method as described below, and the coronaviruses, herpes simplex viruses, and rhinoviruses of Table 2 below. Or virus inactivation characteristics against influenza virus.

virus Host cell Feline coronavirus (FCV) (Feline infectious peritionitis virus strain WSU 79-1146) CRFK cells Herpes simplex virus type 1 (HSV1) strain F Vero cell Human Rhinovirus 14 (HRV14) HeLa cell Influenza virus A (Flua): H1N1 PR8 MDCK cells

0.9 ml of the sample was placed in each well of a 48-well plate and 100 µl virus solution was added and mixed.

In addition, the Mock infection method was used to determine whether the sample itself is toxic to cells. Specifically, DME / 2% FBS (for FCV), MEM / 2% FBS (for HSV1), MEM / 2% instead of virus solution. FBS (for HRV14) or MEM / TPCK trypsin (for FluA) was used.

Then, after 0, 15, 30, 60 and 360 minutes, 35 μl of MEM 315 μl was continuously diluted to 1:10. Each dilution was removed from the culture medium of cells cultured on 96-plate and infected with 4 wells at 70 μl per well. In addition, the mock infection method for determining whether the sample itself is toxic to cells was also infected by 4 wells.

Subsequently, the mixture was placed in a carbon dioxide incubator for 1 hour, and then the virus solution was removed and the cells were washed with 100 µl of the culture solution used for dilution.

Add 0.1 ml of culture (DME / 2% FBS (for FCV), MEM / 2% FBS (for HSV1), MEM / 2% FBS (for HRV14) or MEM / TPCK trypsin (for FluA) per well) In the carbon dioxide incubator was incubated for 4 days for FCV, 3 days for HSV1, HRV14 and FluA, respectively. After incubation, the culture medium was removed and cell viability was calculated using MTT staining.

The virus inactivation was calculated by calculating the virus titer and cytotoxicity concentration by the Reed and Muench method.

In addition, as a control, it was measured in the same manner as described above, tap water was used instead of the sample of each Example or Comparative Example.

As a result, in the case of Comparative Example 1 in which the mineral particles were not used, it was confirmed that there was substantially no antiviral effect, and all of the examples were confirmed to have antiviral properties.

Specific results on the antiviral properties of the liquid deodorant composition of Example 10 are as follows.

Feline coronavirus (FCV) T Concent. Virus Virus titer (CCID ₅₀ / well) Virus reduction factor (%) (min) 0 min 60 min 360 min 0 min 60 min 360 min 25 ℃ 0% FCV 7,700 7,700 7,700 0 0 0 Mock <3.2 <3.2 90% FCV <221 <68 0 97.13 99.116 Mock 221 68

Herpes simplex virus type 1 (HSV1) T Concent. Virus Virus titer (CCID ₅₀ / well) Virus reduction factor (%) (min) 0 min 60 min 360 min 0 min 60 min 360 min 25 ℃ 0% FCV 33,000 33,000 33,000 0 0 0 Mock <1 <1 <1 90% FCV 33,000 <157 <51 0 99.5242 99.8455 Mock <1 157 51

Human Rhinovirus 14 (HRV14) T Concent. Virus Virus titer (CCID ₅₀ / well) Virus reduction factor (%) (min) 0 min 15 min 30 min 60 min 0 min 15 min 30 min 60 min 25 ℃ 0% FCV 34,000 34,000 34,000 34,000 0 0 0 0 Mock <1 <1 <1 <1 90% FCV 34,000 240 414 305 0 99.29 99.05 99.10 Mock <1 316 316 316

Influenza virus A (Flua): H1N1 PR8 T Concent. Virus Virus titer (CCID ₅₀ / well) Virus reduction factor (%) (min) 0 min 15 min 30 min 60 min 0 min 15 min 30 min 60 min 25 ℃ 0% FCV 13,500 13,500 13,500 13,500 0 0 0 0 Mock <1 <1 <1 <1 90% FCV 13,500 316 316 316 0 97.66 97.66 97.66 Mock <1 316 256 293

As shown in Table 3 to Table 6, all of the corona virus, herpes simplex virus, rhinovirus and influenza virus all had a virus reduction of more than 97.5% after 15 minutes. Especially for rhinovirus and influenza virus, it can be confirmed that more than 97.5% of the virus is inactivated within 15 minutes, the virus inactivation reaction rate is excellent, it can be seen that can respond quickly to the rapid transmission of the virus.

Claims (11)

Mineral components extracted from mineral particles comprising any one or two or more minerals selected from sericite, bentonite, zeolite and coralite; Salts of metals comprising any one or two or more selected from copper, iron and zinc; And water; liquid deodorant composition comprising a. The method of claim 1,
The mineral component is a liquid deodorant composition derived from an aqueous mineral solution prepared by high temperature heat treatment and filtration of the mineral mixture comprising the mineral particles and water. The method of claim 1,
The mineral particle comprises two or more of the minerals,
The mineral component,
a1) high temperature heat treatment and filtration of each mineral mixture comprising each mineral particle and water to produce respective mineral aqueous solution, and
a2) mixing the respective aqueous mineral solution to prepare a mineral aqueous solution
Liquid deodorant composition derived from the aqueous mineral solution prepared, including. The method of claim 1,
The salt of the metal liquid deodorant composition comprising any one or two or more selected from copper sulfate, iron sulfate and zinc sulfate. The method of claim 1,
The liquid deodorizing composition further comprises any one or two or more selected from sodium molybdate, sulfur, calcium carbonate and potassium iodide. The method of claim 1,
The liquid deodorant composition comprises 1 to 30 parts by weight of the salt of the metal relative to 100 parts by weight of water. The method of claim 1,
The liquid deodorant composition is an antiviral liquid deodorant composition. Spray deodorant comprising a liquid deodorant composition of any one of claims 1 to 7. a) preparing a mineral solution by subjecting the mineral mixture including water and mineral particles comprising any one or two or more minerals selected from sericite, bentonite, zeolite, and corallite to heat treatment and filtering;
b) mixing a salt of a metal including any one or two or more selected from copper, iron, and zinc with the aqueous mineral solution
Method for producing a liquid deodorant composition comprising a. The method of claim 9,
The mineral particle comprises two or more of the minerals,
Step a) is
a1) high temperature heat treatment and filtration of each mineral mixture comprising each mineral particle and water to produce respective mineral aqueous solution, and
a2) mixing the respective aqueous mineral solution to prepare a mineral aqueous solution
Method for producing a liquid deodorant composition comprising a. The method of claim 9,
Method of producing a liquid deodorizing composition of any one or two or more selected from sodium molybdate, sulfur, calcium carbonate and potassium iodide in the aqueous mineral solution in step b).