KR20190050118A - Ginger extract candy with Salicornia herbacea L. for Pregnant Women and peparation method threreof - Google Patents

Ginger extract candy with Salicornia herbacea L. for Pregnant Women and peparation method threreof Download PDF

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KR20190050118A
KR20190050118A KR1020170145328A KR20170145328A KR20190050118A KR 20190050118 A KR20190050118 A KR 20190050118A KR 1020170145328 A KR1020170145328 A KR 1020170145328A KR 20170145328 A KR20170145328 A KR 20170145328A KR 20190050118 A KR20190050118 A KR 20190050118A
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ginger
candy
green tea
salt
juice
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KR102049640B1 (en
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주나미
정은경
이희정
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숙명여자대학교산학협력단
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/36Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
    • A23G3/48Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds containing plants or parts thereof, e.g. fruits, seeds, extracts
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/0002Processes of manufacture not relating to composition and compounding ingredients
    • A23G3/0004Processes specially adapted for manufacture or treatment of sweetmeats or confectionery
    • A23G3/0019Shaping of liquid, paste, powder; Manufacture of moulded articles, e.g. modelling, moulding, calendering
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K36/00Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
    • A61K36/18Magnoliophyta (angiosperms)
    • A61K36/88Liliopsida (monocotyledons)
    • A61K36/906Zingiberaceae (Ginger family)
    • A61K36/9068Zingiber, e.g. garden ginger
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2250/00Food ingredients
    • A23V2250/20Natural extracts
    • A23V2250/21Plant extracts
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2300/00Processes
    • A23V2300/24Heat, thermal treatment
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2300/00Processes
    • A23V2300/50Concentrating, enriching or enhancing in functional factors

Abstract

The present invention relates to a ginger Salicornia europaea candy for pregnant women and a method for manufacturing the same, wherein the method for manufacturing the ginger Salicornia europaea candy is an optimum condition confirmed by a central compostie design method. The ginger Salicornia europaea candy according to the manufacturing method can be easily ingested during a morning sickness period of pregnant women. Therefore, it is possible to alleviate nausea and vomiting due to morning sickness and be provided as food for pregnant women and a lactating women, possible to provide nutrition to pregnant women and lactating women in a convenient manner.

Description

임신부용 생강함초캔디 및 이의 제조방법{Ginger extract candy with Salicornia herbacea L. for Pregnant Women and peparation method threreof}(Ginger extract candy with Salicornia herbacea L. for Pregnant women and pepper method threreof)

본 발명은 임신부 및 수유부의 임덧 완화 또는 개선용 생강함초캔디를 제공하는 기술이다.The present invention is a technique for providing a ginger basil candy for mitigation or improvement of pregnancy and lactation.

임신부의 영양은 임신 준비기부터 시작하여 임신과 분만기를 대상으로 하는 영양으로, 건강한 임신과 순산, 태아성장을 위하여 매우 중요하므로 이 시기는 모아의 건강관리에서 적극적으로 중재 가능한 영역의 하나이다. 임신기간 동안의 임신부의 영양 및 건강은 모체 건강뿐만 아니라 태아의 성장과 발육에 직접적인 영향을 준다(Bae HS 2008; Lindsay 등 2012). 그러나 Choi 등(2001)은 임신부의 입덧은 음식섭취의 저하로 영양소 섭취상태와 임신기 체중증가에 부정적인 영향을 주며 구토가 심할수록 임부의 영양소 및 열량섭취량이 저조하였고 저체중아를 출산했다고 보고하였으며, 임신부 대상 연구로는 경기지역 임신부의 건강기능성 식품 섭취 실태 조사(Kim JE 2013)와 수도권거주 임신부의 건강기능식품 섭취 실태 조사(Kim SM 2016) 결과, 임신부를 위한 제품개발 연구는 거의 전무한 실정이다. Nutrition of pregnant women is a nutrition for pregnancy and childbirth starting from prepregnancy period, it is very important for healthy pregnancy, delivery and fetal growth, and this period is one of the areas that can actively mediate in maternal health care. Nutrition and health of pregnant women during pregnancy have a direct impact on maternal health as well as on the growth and development of the fetus (Bae HS 2008; Lindsay et al. 2012). However, Choi et al. (2001) reported that the morning sickness of pregnant women negatively affects the nutrient intake and pregnancy weight gain due to the decrease of food intake, and the lower the nutrient and calorie intake of pregnant women and the lower birth weight, As a result of the survey on the health functional food consumption status (Kim JE 2013) of the pregnant women in the Kyunggi area and Kim SM 2016 in the metropolitan area, there was almost no research on product development for pregnant women.

미국산부인과학회에서는 오랫동안 음료를 섭취하지 못하거나 탈수 증상을 보이는 경우 혈관 내 수액요법을 시행해야 하며, 케톤증이나 비타민 결핍을 교정해야하고 포도당과 비타민, 특히 티아민 투여는 장기간 구토가 있는 경우 보충한다고 발표하였으며, 과학적인 증거가 제한적이나, 임신 중 구역과 구토 시 생강 치료는 효과가 있으며 비약제적 치료중의 하나로 고려될 수 있다고 보고하였다.The American Academy of Obstetrics and Gynecology has announced that intravenous fluid therapy should be administered if there is a long absence of drinking or dehydration, correction of ketosis or vitamin deficiency, and supplementation of glucose and vitamins, especially thiamine, if there is long term vomiting , Although there is limited scientific evidence, gingival therapy during pregnancy and vomiting is considered to be effective and considered as a non-therapeutic treatment.

생강(Zingiber officinale Roscoe)은 생강과에 속하는 다년생 초본식물로 열대 아시아가 원산지이며 생강의 매운맛은 소화흡수와 위액의 분비를 왕성하게 하며, 살균작용에 효과적으로 세계적으로 사용되는 향신료뿐만 아니라 약리적 효능도 인정되어 소화불량 등의 소화보조제, 오심, 감기 한풍, 복통, 요통, 설사, 독초 또는 생선독 해독 등의 치료제 및 살균제로도 이용되고 있다(Kwak JS 2008; Kim & Chun 2001). 이러한 생강은 현재 생강 첨가 사과잼, 생강가루 첨가 양갱, 생강가루 첨가 쿠키, 생강 첨가 샐러드와 생강첨가 배즙 등의 연구 및 개발이 진행중이나 캔디에 대한 연구는 희소하다.Ginger (Zingiber officinale Roscoe) is a perennial herbaceous plant belonging to the ginger family. It is originated in tropical Asia. The hot taste of ginger makes digestion absorption and secretion of gastric juice vigorous, and not only spices used worldwide but also pharmacological effects are recognized effectively. (Kwak JS 2008; Kim & Chun 2001) have been used as an adjuvant for digestion, nausea, cold wind, abdominal pain, back pain, diarrhea, poisoning or fish poisoning. These ginger is currently under research and development of ginger added apple jam, ginger added yam, ginger added cookies, ginger added salad and ginger added juice, but studies on candy are rare.

함초(Salicornia herbacea L.)는 명아주과에 속하는 일년초 식물로 우리나라 섬지방의 해안이나 갯벌 그리고 염전 주위에 무리지어 자생하는 염초(鹽草)로 퉁퉁하고 마디마디 튀어나온 풀이라하여 ‘퉁퉁마디’라하고, 일본에서는 몹시 희귀하고 신령스러운 풀이라 하여 신초(神草)라고 한다(Choi JK 2001). 국내에서는 함초분말을 첨가한 돈육패티(Joo & Choi 2014)와 함초 분말 첨가 제빵연구(Bae 등 2008) 등의 연구가 진행 중이며 주로 소금 대체제로서의 연구가 진행 중이나, 이를 이용한 임산부를 위한 제품 개발 연구는 보고된 바 없다. Salicornia Herbacea L. ) is a perennial plant belonging to the mackerel. It is a grass that grows on the coasts, tidal flats and tidal flats of the islands of Korea, It is called "Shinko" (Choi JK 2001) because it is a rare and divine grass. In Korea, researches such as pork patty (Joo & Choi 2014) added with green tea powder and baking powder with green pepper powder (Bae et al. 2008) are in progress and mainly research as salt substitute is under way. Not reported.

대한민국공개특허 제10-2015-0096990호 (2015.08.26 공개)Korean Patent Publication No. 10-2015-0096990 (published on Aug. 26, 2015)

본 발명은 임산부의 입덧을 완화하고 계속된 구역과 구토로 인해 부족한 당과 염을 보충할 수 있는 생강함초캔디 및 이의 제조방법을 제공하고자 한다.The present invention is to provide a ginger powdery candy which can alleviate morning sickness of pregnant women and supplement deficient saccharides and salts due to continued vomiting and vomiting, and a method for producing the ginger powdery candy.

본 발명은 생강과 물을 함께 분쇄하여 분쇄물을 준비하는 단계; 상기 분쇄물에서 육질과 생강즙을 분리하는 단계; 상기 분리된 생강즙을 냉장보관하여 전분을 제거하는 단계; 상기 전분이 제거된 생강즙을 농축하는 단계; 상기 농축된 생강즙에 설탕, 소금, 함초, 물엿 및 물을 혼합하여 가열하는 단계; 및 상기 가열된 혼합물을 성형틀에 넣어 성형하는 단계를 포함하는 생강함초캔디 제조방법을 제공한다.The present invention relates to a method for preparing a pulverized product by pulverizing together ginger and water to prepare a pulverized product; Separating the meat quality and ginger juice from the pulverized product; Storing the separated ginger juice in a refrigerator to remove starch; Concentrating the ginger juice from which the starch has been removed; Mixing the concentrated ginger juice with sugar, salt, green tea, millet, and water and heating; And molding the heated mixture in a molding mold.

본 발명은 상기 방법에 따라 제조된 입덧 예방 또는 개선용 생강함초캔디를 제공한다.The present invention provides a ginger basil candy for morning sickness prevention or improvement produced according to the above method.

또한, 본 발명은 상기 방법에 따라 제조된 생강함초캔디를 유효성분으로 함유하는 입덧 예방 또는 개선용 식품조성물을 제공한다.In addition, the present invention provides a food composition for preventing or improving morning sickness containing ginger green tea candy prepared according to the above method as an active ingredient.

본 발명의 생강함초캔디 제조방법은 중심합성계획법으로 확인된 최적 조건으로, 상기 제조방법에 따른 생강함초캔디는 임신부의 입덧시기에 쉽게 섭취될 수 있어, 입덧에 의한 구역 및 구토를 완화시킬 수 있으며, 간편한 방법으로 임신부 및 수유부에게 영양공급이 가능한 임신부 및 수유부용 식품으로 제공될 수 있다.The ginger powdery candy according to the present invention can be easily ingested in the morning period of the pregnant woman, thereby alleviating the nausea and vomiting due to morning sickness, , And can be provided as a food for pregnant women and lactating women who can provide nutrition to pregnant women and lactating women in a convenient way.

도 1은 생강즙(A) 및 소금(B) 첨가가 함초 캔디의 이화학적 특성에 미치는 영향을 확인한 중첩등고선도(Perturbation plot) 및 반응표면등고선도(response surface plot) 결과이다.
도 2는 생강즙과 소금이 첨가된 생강함초캔디의 시간경과에 따른 용해도를 확인한 결과이다.
도 3은 생강즙(A) 및 소금(B) 첨가가 함초 캔디의 관능적 특성에 미치는 영향을 확인한 중첩등고선도 및 반응표면등고선도 결과로, 색, 향, 단맛, 짠맛, 매운맛 및 전반적인 기호도를 확인한 결과이다.
도 4는 생강즙(A) 및 소금(B) 첨가가 함초 캔디의 특성에 미치는 영향을 확인한 중첩등고선도 및 반응표면등고선도를 통하여 생강함초캔디 제조를 위한 최적의 조건을 확인한 결과이다.
FIG. 1 shows the result of superposition contour plot and response surface plot of the effect of addition of ginger juice (A) and salt (B) on the physicochemical properties of green tea candy.
FIG. 2 is a result of checking the solubility of ginger powdery candy added with ginger juice and salt over time.
Fig. 3 shows the results of checking the color, flavor, sweetness, salty taste, hot taste and overall acceptability of the ginger juice (A) and salt (B) as a result of the superposed contour diagram and reaction surface contour line, to be.
FIG. 4 shows the result of confirming the optimal condition for the production of ginger green tea candy through the overlapping contour diagram and the reaction surface contour diagram which confirmed the influence of the addition of the ginger juice (A) and the salt (B) on the characteristics of the green tea candy.

이하, 본 발명을 보다 상세하게 설명한다.Hereinafter, the present invention will be described in more detail.

본 발명자들은 임신부 및 수유부용 식품 및 이에 대한 개발이 전무함에 따라, 임산부의 입덧을 완화하고 계속된 구역과 구토로 인해 부족한 당과 염을 채워줄 수 있는 임신부 및 수유부용 식품을 개발하던 중 생강 및 함초를 함유하는 캔디 제조방법을 개발하였으며, 특히 상기 제조방법은 반응표면분석법을 이용하여 관능적으로 최적점을 갖는 생강함초캔디를 제공할 수 있음을 확인함으로써 본 발명을 완성하였다.The present inventors have developed foods for pregnant women and lactating women, which can mitigate morning sickness of pregnant women and can fill deficient saccharides and salts due to continued areas and vomiting, The present inventors have completed the present invention by confirming that it is possible to provide ginger green tea candy having a sensible optimum point by using the reaction surface analysis method.

본 발명은 생강과 물을 함께 분쇄하여 분쇄물을 준비하는 단계; 상기 분쇄물에서 육질과 생강즙을 분리하는 단계; 상기 분리된 생강즙을 냉장보관하여 전분을 제거하는 단계; 상기 전분이 제거된 생강즙을 농축하는 단계; 상기 농축된 생강즙에 설탕, 소금, 함초, 물엿 및 물을 혼합하여 가열하는 단계; 및 상기 가열된 혼합물을 성형틀에 넣어 성형하는 단계를 포함하는 생강함초캔디 제조방법을 제공할 수 있다.The present invention relates to a method for preparing a pulverized product by pulverizing together ginger and water to prepare a pulverized product; Separating the meat quality and ginger juice from the pulverized product; Storing the separated ginger juice in a refrigerator to remove starch; Concentrating the ginger juice from which the starch has been removed; Mixing the concentrated ginger juice with sugar, salt, green tea, millet, and water and heating; And a step of molding the heated mixture into a mold, thereby providing a ginger basil candy manufacturing method.

상기 농축된 생강즙은 1 내지 4% 브릭스(brix)로 농축된 것일 수 있으며, 보다 바람직하게는 4% 브릭스로 농축된 것일 수 있으나, 이에 한정되지 않는다.The concentrated ginger juice may be 1 to 4% brix concentrated, more preferably 4% brix concentrated, but is not limited thereto.

상기 생강함초캔디는 캔디 총 100 중량부에 대하여, 생강즙 5 내지 12 중량부, 설탕 50 내지 80 중량부, 소금 0.3 내지 3 중량부, 함초 0.5 내지 1 중량부, 물엿 14 내지 18 중량부 및 물 5 내지 12 중량부를 포함할 수 있다.The ginger green tea candy is prepared by mixing 5 to 12 parts by weight of ginger juice, 50 to 80 parts by weight of sugar, 0.3 to 3 parts by weight of salt, 0.5 to 1 part by weight of green tea, 14 to 18 parts by weight of starch syrup, To 12 parts by weight.

보다 상세하게는 상기 생강함초캔디는 캔디 총 100 중량부에 대하여, 생강즙과 물을 합한 총 함량이 14 내지 18 중량부이며, 소금의 함량이 1.5 내지 2 중량부일 수 있다.More specifically, the total content of the ginger juice and water may be 14 to 18 parts by weight and the salt content may be 1.5 to 2 parts by weight based on 100 parts by weight of the candy ginger candy.

보다 바람직하게는 생강함초캔디 100g에 대하여, 생강즙 7.65g 및 소금 1.75g이 포함될 수 있다.More preferably, 7.65 g of ginger juice and 1.75 g of salt can be contained in 100 g of ginger green tea candy.

상기 농축된 생강즙에 설탕, 소금, 함초, 물엿 및 물을 혼합하여 가열하는 단계는 서서히 가열하여 120 내지 150℃까지 가열될 수 있으며, 보다 상세하게는 130℃까지 가열될 수 있으나, 이에 한정되는 것은 아니다.The step of mixing and heating the concentrated ginger juice with sugar, salt, green tea, millet, and water may be gradually heated to 120 to 150 ° C, and more specifically, heated to 130 ° C. However, no.

또한, 본 발명은 상기 제조방법에 따라 제조된 입덧 예방 또는 개선용 생강함초캔디를 제공할 수 있다.In addition, the present invention can provide a ginger green tea candy for preventing or improving morning sickness, which is produced according to the above-described method.

또한, 본 발명은 사기 제조방법에 따라 제조된 생강함초캔디를 유효성분으로 함유하는 입덧 예방 또는 개선용 식품조성물을 제공할 수 있다.In addition, the present invention can provide a food composition for preventing or improving morning sickness containing ginger powdery candy prepared according to a scent manufacturing method as an effective ingredient.

본 발명에 있어서, 반응표면분석법(response surface analysis method RSM)은 모든 독립변인의 각 수준들에 대한 요인 설계 실험을 실시하지 않고, 여러 독립변인들의 조합 효과를 추정하여 최적화하는 실험계획법으로 반응값에 영향을 주는 중요한 실험인자를 찾은 다음, 소수의 중요 인자로 실험하여, 최적의 반응값을 찾아내는 분석법이다. 즉, 실험결과의 추정치들이 지나는 선이나 면을 반응표면이라 하고, 실험자의 관심영역에서 최적조건을 찾는 방법이다.In the present invention, the response surface analysis method (RSM) is an experimental design method that estimates and optimizes the combination effect of various independent variables without conducting factor design experiments for each level of all independent variables. It is an analytical method that finds the important experimental factors that affect and then finds the optimal reaction value by experimenting with a few important factors. In other words, the line or plane through which the estimates of the experimental results pass is called the reaction surface, and the optimum condition is found in the area of interest of the experimenter.

반응표면 실험계획법 중 최소의 실험으로 최적의 실험결과를 구하기 위해, 독립변수(실험인자)와 종속변수(반응)의 관계를 보다 세밀하게 분석할 수 있는 곡선회귀모형(2차다항회귀모형)의 회귀계수를 추정할 수 있는 효율적인 실험 설계 중 현재까지 가장 많이 사용되고 있는 것이 중심합성계획법(central composite design CCD)이며, 본 발명은 상기 중심합성계획법으로 확인된 최적의 생강함초캔디 제조방법을 제공하며, 상기 방법에 따른 생강함초캔디를 임신부 및 수유부용 건강기능성 식품으로 제공하는 기술이다.In order to obtain the best experimental results from the least experiments among the reaction surface design methods, a curve regression model (second-order polynomial regression model), which can more finely analyze the relationship between independent variables (experimental factors) and dependent variables Among the efficient experimental designs that can estimate the regression coefficient, the central composite design CCD is the most widely used until now. The present invention provides a method of manufacturing an optimal ginger green tea candy confirmed by the central synthetic planning method, The present invention relates to a method for providing ginger green tea candy according to the above method as a health functional food for pregnant women and lactating women.

이하, 본 발명의 이해를 돕기 위하여 실시예를 들어 상세하게 설명하기로 한다. 다만 하기의 실시예는 본 발명의 내용을 예시하는 것일 뿐 본 발명의 범위가 하기 실시예에 한정되는 것은 아니다. 본 발명의 실시예는 당업계에서 평균적인 지식을 가진 자에게 본 발명을 보다 완전하게 설명하기 위해 제공되는 것이다.BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail with reference to the following examples. However, the following examples are intended to illustrate the contents of the present invention, but the scope of the present invention is not limited to the following examples. Embodiments of the present invention are provided to more fully describe the present invention to those skilled in the art.

<< 실험예Experimental Example 1> 재료 1> Material

생강즙첨가 함초캔디를 제조하기 위해 국내산 생강, 함초(동아수산, 국내산), 설탕(백설, 국내산), 소금(백설, 국내산), 및 물엿(오뚜기, 국내산)을 각각 구입하여 사용하였다.(Ginger, green tea, domestic), salt (snow white, domestic), and starch syrup (ottogi, domestic) were purchased and used.

<< 실험예Experimental Example 2> 중심합성계획법(central composite design) 2> Central composite design

독립변수로는 예비실험을 통해 캔디의 품질에 가장 큰 영향을 주는 생강즙과 소금 두 가지를 요인으로 설정하였으며, 종속변수로는 기계적 검사로 캔디의 명도(L, lightness), 적색도(a, redness) 및 황색도(b, yellowness)의 색도, pH, 염도, Hardness 및 용해도를 측정하였다. 관능 평가 항목은 색(Color), 향(Flavor), 단맛(Sweetness), 짠맛(Saltiness), 매운맛(Hot taste), 전반적 기호도(Overall quality)로 설정하였다.Two independent variables were ginger juice and salt which had the greatest effect on the quality of candy through preliminary experiment. The mechanical parameters were L, lightness, redness (a, redness) ), And yellowness (b, yellowness) were measured for color, pH, salinity, hardness and solubility. Sensory evaluation items were set as Color, Flavor, Sweetness, Saltiness, Hot taste, Overall quality.

중심합성계획법의 실험점은 Center point(0.00)과 ±α점(axial point), ±1 level점(factorial point)으로 이루어지고, 실험점 사이에는 모델설정 및 적합결여 검증을 위하여 2개의 반복점을 포함하여 표 2와 같이 총 10개의 실험점이 설정되었다.Experimental points of the center synthetic program consist of Center point (0.00), ± α point (axial point) and ± 1 level point (factorial point), and two repetition points A total of 10 experimental points were set up, as shown in Table 2.

중심합성계획법에서 측정된 데이터로 2차 회귀모형을 추정하고, 추정된 회귀모형이 반응을 설명하는데 적합한지 판단하기 위해, 회귀계수의 유의성검정, 전체 모델의 유의성검정, 모형의 적합성 검정, 회귀모형의 설명력 등을 통계적 유의성 검정을 실시하여 신뢰성 있는 2차 회귀모형을 구한 후, 최적값을 도출하기 위해 정상점(stationary point) 분석을 진행하였다. 정상점은 반응표면분석에서 반응이 증가하다가 감소하거나, 또는 감소하다가 증가하는 변곡점으로 반응 최대점 또는 반응 최소점이거나 최소점도 최대점도 아닌 안장점(saddle point) 중 하나이다. In order to determine whether the estimated regression model is appropriate to explain the response, we use the significance test of the regression coefficient, the significance test of the whole model, the fitness of the model, the regression model And statistical significance test was performed to obtain a reliable quadratic regression model. Then, a stationary point analysis was conducted to derive the optimal value. The steady-state point is one of the saddle points, which is the reaction maximum point or the reaction minimum point or not the minimum viscosity maximum point as the inflection point which increases or decreases while the reaction increases in the reaction surface analysis.

또한, 정상점 주변의 반응값 탐색을 위한 정준분석(canonical analysis)의 수치최적화(numerical optimization)와 그래프최적화(graphical optimization)를 위해 등고선도(contour plot), 중첩등고선도(perturbation plot), 반응표면등고선도(response surface plot) 분석을 이용하였다.In addition, a contour plot, a nested contour plot, and a response surface for numerical optimization and graphical optimization of a canonical analysis for searching a reaction value around a normal point, Response surface plot analysis was used.

<< 실시예Example 1>  1> 생강함초캔디Ginger Green Tea Candy 제조 Produce

생강함초캔디의 배합 및 제조 방법은 도라지 캔디(Lee 등 2001)와 결정형 캔디(Lee 등 2006) 제조방법을 참고한 예비실험을 거쳐, 생강즙첨가 캔디의 카라멜화 현상이 더 빨리 나타나는 특성과 성형 가능한 온도를 고려하여 130℃를 최종 온도로 설정하였다.The ginger green tea candies were prepared and prepared by preliminary experiments with reference to the preparation methods of blooming candy (Lee et al. 2001) and crystalline candy (Lee et al. 2006) The final temperature was set at 130 캜.

세척하여 껍질을 벗긴 생강 1kg을 물 1kg과 함께 분쇄기(HMF-3100S, Hanil, Seoul, Korea)에서 분쇄하여 육질과 즙을 분리하였다. 원료 생강즙을 6시간 동안 4℃에서 냉장보관하여 전분을 제거 후 1.2% 브릭스(brix)의 생강즙을 중불에 끓인 4% 브릭스의 생강즙으로 농축하여 사용하였다.1 kg of ginger peeled and washed was ground with 1 kg of water in a pulverizer (HMF-3100S, Hanil, Seoul, Korea) to separate the meat and juice. The raw ginger juice was stored in a refrigerator at 4 ° C for 6 hours to remove starch, and the ginger juice of 1.2% brix was concentrated to 4% Briggs ginger juice boiled in medium heat.

설탕, 소금, 함초 및 물엿(맥아당 55%)에 상기 생강즙과 물을 넣어 혼합한 후 서서히 가열하여 디지털 온도계(RT903, Muser Apac Sdn Bhd, Kuala Lumpur, Malaysia)로 최종 온도 130℃까지 도달하면 성형틀에 주입, 성형하고 식힌 후 실험에 사용하였다.The mixture of ginger juice and water was mixed with sugar, salt, green tea and syrup (55% of maltose) and slowly heated to reach a final temperature of 130 ° C with a digital thermometer (RT903, Muser Apac Sdn Bhd, Kuala Lumpur, Malaysia) Injection, molding, cooling and used in the experiment.

캔디 제조조건은 표 1과 같이 예비실험을 거쳐 성형 가능한 최대의 함초량을 설정하고 그 외 짠맛은 소금의 양으로 대치하여 소금 0.5~3g, 생강즙 2~14g으로 설정하였으며 생강즙과 물의 총합은 16g으로 설정하였다.The preparation conditions of the candy were set as 0.5 ~ 3g of salt and 2 ~ 14g of salt, and the sum of ginger juice and water was 16g Respectively.

IngredientsIngredients Weight(g)Weight (g) SugarSugar 66.866.8 Starch syrupStarch syrup 1616 Salicornia herbacea L. Salicornia herbacea L. 0.80.8 Ginger juiceGinger juice 2-142-14 WaterWater 2-142-14 SaltSalt 0.5-30.5-3

<< 실시예Example 2> 이화학적 특성 확인 2> Identification of physicochemical properties

상기 실시예 1과 같이 제조된 생강함초캔디의 용해도, 당도 및 염도를 Lee 등(2006)의 실험방법을 응용하여 확인하였으며 모든 실험은 3회 측정한 후 평균값을 내었다.The solubility, sugar content and salinity of the ginger green tea candy prepared in the same manner as in Example 1 were confirmed by applying the experimental method of Lee et al. (2006).

용해도는 6g(6.01±0.06g)의 캔디와 자석교반기(magnetic Stirrer)를 100ml 증류수에 넣고 Hot palt(Corning PC-420, USA)위에서 3단계로 교반하면서 완전히 용해되는 시간을 당도계(PAL-1, ATAGO, Tokyo, Japan)로 측정하였다. 염도와 당도 및 pH는 염도계(ES-421, ATAGO, Tokyo, Japan), 당도계(PAL-1, ATAGO, Tokyo, Japan), pH meter(F-51, Horiba, Tokyo, Japan)를 이용하여 용해도 측정이 끝난 시료를 측정하였다.The solubility was measured by solubilization (PAL-1, PAL-1, PAL-1, PAL-1, and PAL-1) by dissolving 6 g (6.01 ± 0.06 g) of candy and magnetic stirrer in 100 ml of distilled water, ATAGO, Tokyo, Japan). The salinity, the sugar content and the pH were measured by using a salinity meter (ES-421, ATAGO, Tokyo, Japan), a sugar meter (PAL-1, ATAGO, Tokyo, Japan) and a pH meter (F-51, Horiba, Tokyo, Japan) The finished samples were measured.

그 결과, 표 2와 같이 생강함초캔디의 10개 실험점에 따른 용해도는 캔디가 완전히 용해되어 없어질 때까지 13~15분이 소요되었다. 또한, 표 3과 같이 용해완료 시간은 독립변수간에 독립적 작용이 발생하는 Linear model이 결정되었으며, p-value는 0.0013(R2=0.8503)로 유의적인 차이가 있는 것으로 나타났다.As a result, as shown in Table 2, the solubility of the ginger green tea candy according to 10 test points took 13 to 15 minutes until the candy completely dissolves and disappears. In addition, as shown in Table 3, the dissolution completion time was determined as a linear model in which independent action occurred between independent variables, and the p-value was 0.0013 (R 2 = 0.8503).

또한, 도 1과 같은 중첩등고선도를 참고하면 생강즙(A)의 첨가량이 증가할수록 용해되는 시간이 증가하였으나, 소금(B) 첨가량에는 영향을 받지 않는 것으로 나타났다. 설탕용액을 가열 후 냉각하면 고무질(rubber) 영역을 지나 유리질(glass)이 형성되는 유리전이(glass transition)과정을 거쳐 캔디의 물성이 결정되며(Okuno 등 2003), 이때 잔류 수분 함량 및 제조방법 등이 영향을 주게 된다(Lee 등 2011). 이에 따라, 생강즙의 첨가량이 증가할수록 용해도 시간이 증가하여 생강즙첨가에 의한 잔류 수분함량의 변화와 관련이 있는 것으로 판단된다.Also, referring to the overlapping contour map as shown in FIG. 1, the dissolution time was increased as the addition amount of ginger juice (A) was increased, but it was not affected by the addition amount of salt (B). When the sugar solution is heated and cooled, the properties of the candy are determined through a glass transition process in which a glass is formed through the rubber region (Okuno et al. 2003). At this time, the residual water content and the manufacturing method (Lee et al., 2011). Therefore, it was concluded that the increase of the amount of ginger juice increased the solubility time and was related to the change of residual water content by adding ginger juice.

또한, 캔디의 용해도를 구체적으로 판단하기 위해 분마다 용해도를 측정한 결과, 도 2와 같이 평균 80%(4.33%)까지 캔디가 용해되는 시간은 약 7분 정도의 시간이 소요되었으며, 13분 정도에서는 약 99%가 용해되었다.In order to determine the solubility of the candy in detail, the solubility was measured every minute. As a result, it took about 7 minutes for the candy to dissolve to 80% (4.33%) on average as shown in FIG. About 99% were dissolved.

Lee 등(2006)의 가열조건에 따른 경질형 캔디의 물성 연구 중 최종 가열온도가 170℃인 경우 완전히 녹는 시간이 가장 짧았고, 200℃인 경우 가장 긴 시간이 소요되어 수분함량 낮을수록 당의 용해량이 더 큰 것으로 확인됨에 따라, 본 연구의 최종온도가 130℃인 것을 고려할 때 최종온도가 증가할수록 수분함량이 낮아져 당의 용해시간이 더 길어질 것으로 제안될 수 있다.In the physical properties of hard candy according to the heating conditions of Lee et al. (2006), the melting time was the shortest when the final heating temperature was 170 ° C and the longest time was required at 200 ° C. As the water content was lower, Considering that the final temperature of the present study is 130 ° C, it is suggested that as the final temperature increases, the water content decreases and the dissolution time of the sugar becomes longer.

생강함초캔디의 당도와 염도를 측정한 결과 당도는 5.3~5.4%, 염도는 4.45~4.68%의 범위로 나타났고, 선형 모델(Linear model)이 결정되었으며 생강즙과 소금의 첨가량이 증가할수록 염도가 유의적으로 증가하였으나(p-value=0.0235, R2=0.6574) 본 발명에 사용된 생강즙의 염도는 3.3%로 생강에 함유한 염성분에 의해 염도가 증가한 것으로 판단된다(p-value=0.0235, R2=0.6574). As a result of measuring the sugar content and salinity of ginger green pepper candy, the sugar content was in the range of 5.3 ~ 5.4% and the salinity was in the range of 4.45 ~ 4.68%. Linear model was determined and salinity was increased with increasing ginger juice and salt content. ( P-value = 0.0235, R 2 = 0.6574). The salinity of the ginger juice used in the present invention is 3.3%, which is determined by the salt content of ginger ( p -value = 0.0235, R 2 = 0.6574).

당도는 생강즙의 첨가량이 증가할수록 감소하는 경향을 보였으나 유의적이지 않다(p-value=0.3201, R2=0.2777). Sugar content tended to decrease as the addition of ginger juice increased ( p-value = 0.3201, R 2 = 0.2777).

생강즙에 의해 당도가 감소하는 것으로 판단되며 이는 생강 첨가 사과잼(Lee SM 2014)과 장뇌삼추출액 첨가 캔디(Kim & Kim 2005)에서도 생강 첨가량과 장뇌삼추출액 첨가량이 증가할수록 당도가 감소하여 본 연구와 유사한 것으로 나타났다.The sugar content of apple gum (Lee SM 2014) and ginseng ginseng extract (Kim & Kim 2005) decreased with the addition of ginger and ginseng extract. appear.

생강즙의 pH는 5.72이며, 생강함초캔디의 pH는 6.05~6.40으로 생강즙의 첨가량이 증가할수록 pH가 증가하는 경향을 보였으나 p-value가 0.1161(R2=0.4594)로 유의적인 차이는 아니였으며, 선형 모델이 결정되었다. The pH of ginger juice was 5.72 and the pH of ginger green candy was 6.05 ~ 6.40. The pH value tended to increase with the addition of ginger juice, but the p-value was 0.1161 (R 2 = 0.4594) A linear model was determined.

상기 결과는 생강가루 첨가 양갱(Han & Kim 2011)과 생강가루 첨가 쿠키 연구(Lee 등 2015)에서 생강가루 첨가량이 증가할수록 무첨가군에 비해 pH가 유의적으로 증가하였다는 결과와 유사한 경향을 보였으며, 그 외 생강 첨가 샐러드연구(Jung 등 2013)와 생강첨가 배즙 연구(Lee 등 2009)에서도 대조군에 비해 생강첨가량이 증가할수록 pH값이 높아졌다고 나타나 생강관련 연구와 유사한 결과로 나타났다.The results are similar to those of Han and Kim 2011 and ginger flour added cookies study (Lee et al., 2015), as the addition of ginger powder increased the pH significantly compared to no additives (Jung et al., 2013) and ginger-added pear juice (Lee et al., 2009) showed higher pH values as the ginger content was increased than the control group.

Sample No.Sample No. Variable levelsVariable levels ResponsesResponses Ginger juice
(g)
Ginger juice
(g)
water
(g)
water
(g)
Salt
(g)
Salt
(g)
Time of stirring water solution
(min)
Time of stirring water solution
(min)
Sweetness
(%)
Sweetness
(%)
Saltness
(%)
Saltness
(%)
pHpH LL aa bb Hardness
(dyne/cm3)
Hardness
(dyne / cm 3)
1One 22 1414 0.50.5 1313 5.405.40 4.48 4.48 6.22 6.22 35.85 35.85 2.85 2.85 10.41 10.41 3621.65 3621.65 22 1414 22 0.50.5 1515 5.305.30 4.53 4.53 6.40 6.40 35.03 35.03 3.07 3.07 11.67 11.67 3063.90 3063.90 33 22 1414 33 1313 5.405.40 4.66 4.66 6.05 6.05 35.77 35.77 2.75 2.75 33.33 33.33 3451.45 3451.45 44 1414 22 33 1515 5.305.30 4.68 4.68 6.26 6.26 30.62 30.62 4.88 4.88 9.81 9.81 4175.65 4175.65 55 22 1414 1.751.75 1414 5.405.40 4.46 4.46 6.19 6.19 35.07 35.07 2.72 2.72 10.28 10.28 5226.75 5226.75 66 1414 22 1.751.75 1515 5.405.40 4.48 4.48 6.22 6.22 31.32 31.32 5.05 5.05 9.84 9.84 3487.90 3487.90 77 88 88 0.50.5 1414 5.305.30 4.45 4.45 6.22 6.22 31.70 31.70 3.59 3.59 9.58 9.58 5681.65 5681.65 88 88 88 33 1414 5.305.30 4.63 4.63 6.31 6.31 33.45 33.45 3.29 3.29 10.41 10.41 5269.50 5269.50 99 88 88 1.751.75 1414 5.405.40 4.53 4.53 6.29 6.29 34.73 34.73 3.11 3.11 10.76 10.76 4212.70 4212.70 1010 88 88 1.751.75 1414 5.405.40 4.48 4.48 6.33 6.33 34.68 34.68 3.40 3.40 10.73 10.73 4100.80 4100.80

ResponsesResponses ModelModel R-squared1 ) R-squared 1 ) F-valueF-value P-value
Prob > F2)
P-value
Prob> F 2)
Equation of on terms of pseudo componentEquation of terms on pseudo component
Time of stirring water solutionTime of stirring water solution LinearLinear 0.85030.8503 19.88619.886 0.0013** 0.0013 ** 14.1+0.833A+B14.1 + 0.833A + B SweetnessSweetness LinearLinear 0.27770.2777 1.3461.346 0.32010.3201 5.36-0.033A+0B5.36-0.033A + 0B SaltnessSaltness LinearLinear 0.65740.6574 6.7176.717 0.0235* 0.0235 * 4.533+0.015A+0.084B4.533 + 0.015A + 0.084B pHpH LinearLinear 0.45940.4594 2.9742.974 0.11610.1161 6.247+0.068A-0.035B6.247 + 0.068A-0.035B LL LinearLinear 0.50510.5051 3.5723.572 0.08530.0853 33.820-1.619A-0.456B33.820-1.619A-0.456B aa 2FI2FI 0.77750.7775 6.9896.989 0.0220* 0.0220 * 3.471+0.779A+0.236B+0.478AB3.471 + 0.779A + 0.236B + 0.478AB bb 2FI2FI 0.66930.6693 4.0494.049 0.06850.0685 12.682-3.783A+3.648B-6.195AB12.682-3.783A + 3.648B-6.195AB HardnessHardness 2FI2FI 0.12260.1226 0.2790.279 0.83850.8385 4229.195-262.067A+88.2333B+320.487AB4229.195-262.067A + 88.2333B + 320.487AB

A: ginger juice, B: SaltA: ginger juice, B: Salt

1) 0<R2<1, close to 1 means more significant 1) 0 <R 2 <1, close to 1 means more significant

2) * p<0.05, ** p<0.01 2) * p < 0.05, ** p < 0.01

<< 실시예Example 3> 기계적 특성 확인 3> Confirm mechanical properties

상기 실시예 1과 같이 제조된 생강함초캔디의 색은 색도계(Colormeter CR-200, Minolta, Co., Osaka, Japan)를 사용하여 L, a, b를 각 3회 반복하여 측정한 후 평균값으로 나타내었다. 이때 사용한 표준백판의 L값은 93.49, a값은 1.63, b값은 3.13로 보정한 후 측정하였다. 경도(Hardness)는 Texture Analyser (TA, XT Express v 2.1, London, England)를 사용하여 3회 측정 후 평균값을 나타내었다. Lee NJ 등(2006)과 Silva 등(2016)의 연구방법을 응용하여 송곳형 탐침 p/2N을 이용하여 pre-test speed 0.5 mm/sec, test speed 2.0 mm/sec, distance 5.0 mm, trigger force 1.0 g로 실시하였다.The color of the ginger green tea candy prepared as in Example 1 was measured by repeatedly measuring L, a, and b three times using a colorimeter (Colormeter CR-200, Minolta Co., Osaka, Japan) . The L value of the standard white plate used was 93.49, the a value was corrected to 1.63, and the b value was corrected to 3.13. The hardness was measured after three measurements using a Texture Analyzer (TA, XT Express v 2.1, London, England). Using the method of Lee et al. (2006) and Silva et al. (2016), the pre-test speed of 0.5 mm / sec, test speed of 2.0 mm / g.

그 결과, 표 2와 같이 생강함초캔디의 명도 (L, lightness), 적색도(a, redness) 및 황색도(b, yellowness) 값은 각각 30.62~35.85, 2.72~5.05 및 9.58~33.33의 범위를 나타내었고, a와 b는 독립변수가 서로 상호작용하는 2FI 모델이 선택되었으며, L은 선형 모델이 선택되었다. As a result, as shown in Table 2, the lightness, lightness, redness, and yellowness of the ginger green pepper candies were in the range of 30.62 to 35.85, 2.72 to 5.05, and 9.58 to 33.33, respectively , And 2FI model where a and b interacted with each other were selected, and L was selected as a linear model.

a는 생강즙과 소금의 첨가량이 증가할수록 증가하였으며, p-value가 0.0220로 0.5% 이내의 수준에서 유의성이 나타났으며, R2 값은 0.7775로 모델의 적합성이 확인되었다. L은 생강즙과 소금의 첨가량이 증가할수록 감소하였고, b에서는 생강즙의 첨가량이 감소할수록 소금 첨가량이 증가할수록 높은 경향을 보였다. a was increased with the addition of ginger juice and salt, and the p- value was 0.0220, which was significant at the level of 0.5%, and the R 2 value was 0.7775. L decreased with the addition of ginger juice and salt, and b decreased with increasing ginger juice and salt content.

생강첨가 사과잼(Lee SM 2014), 흑삼 농축액 첨가 젤리(Kim 등 2010), 장뇌삼 추출액 첨가 캔디(Kim & Kim 2005)에서도 첨가량이 증가할수록 L가 낮은 것으로 나타났으며, 감국, 산국 및 구절초꽃 추출액 첨가 캔디(Lee 등 2009)연구에서는 추출액의 첨가량이 증가할수록 a는 증가하고 L은 감소하여 본연구와 유사한 것으로 나타났다. In addition, the L was low as the amount of added ginger added apple jam (Lee SM 2014), black ginseng added jelly (Kim et al. 2010) and candied with ginseng extract (Kim & Kim 2005) In the study of additive candy (Lee et al. 2009), a increases and L decreases as the amount of extract added increases.

한편, 생강 저장 안정성의 연구(Jo 등 1997)에서 생강의 갈변은 비효소적 갈색화 반응인 마이야르(Maillard) 반응과 아스코르브산(ascorbic acid) 산화반응이 기인한다고 보고됨에 따라, 본 발명의 생강즙 제조과정 중 이와 같은 갈색화 반응이 기인했을 것이라고 판단되며, 그 외 생강즙과 소금 첨가로 인해 설탕용액의 카라멜화 반응이 촉진되어 a는 증가하고, L는 감소한 것으로 판단된다.Meanwhile, in the study of ginger storage stability (Jo et al., 1997), it was reported that browning of ginger was caused by Maillard reaction and ascorbic acid oxidation reaction, which are non-enzymatic browning reactions, It is concluded that this brownening reaction may be caused during the process, and the caramelization reaction of the sugar solution is promoted by addition of ginger juice and salt, so a is increased and L is decreased.

또한, 생강함초캔디의 경도 범위는 3063.9 ~ 5681.65 dyne/cm3로 확인되었으며 2FI 모델로 결정되었으나, p-value는 0.8385(R2 0.1226)으로 유의적이지 않아 모델의 적합성이 인정되지 않았다. 그러나 소금의 첨가량이 증가할수록 경도에 양의 영향을 주었으나 생강즙은 음의 영향을 주어 소금보다 생강즙에 더 많은 영향을 받는 것으로 나타났다. The hardness range of the ginger green tea candy was 3063.9 ~ 5681.65 dyne / cm 3 and it was determined as 2FI model, but the p-value was 0.8385 (R 2 0.1226). However, as the added amount of salt increased, it affected the hardness, but the ginger juice had a negative effect and was more affected by the ginger juice than the salt.

상기 결과는 감국, 산국 및 구절초꽃 추출액 첨가 캔디(Lee 등 2009)연구에서 추출액의 첨가 캔디연구에서 추출액의 첨가량이 증가할수록 수분함량이 높아 대조군에 비해 유의적으로 경도가 감소한다는 연구결과와 유사한 것으로 사료된다.The results are similar to those of the study that the hardness decreases significantly in the candy study of extract added with candy (Lee et al., 2009) .

<< 실시예Example 4> 관능적 특성 확인 4> Confirm sensory characteristics

상기 실시예 1과 같이 제조된 생강함초캔디의 관능평가는 (주) 일동후디스에서 운영 중인 “후디스맘 아카데미 예비맘 클래스” 수강생 중 임신초기 또는 입덧 중인 임신부를 대상으로 본 실험의 목적과 취지를 설명한 후 참여 희망 임신부 20명을 대상으로 실시하였으며, 실험군 중 반복 실험군을 통해 관능적 감각이 부족한 대상은 연구대상에서 제외하고 총 15명을 panel로 선택하였다. 관능검사 항목은 색(Color), 향(Flavor), 단맛(Sweetness), 짠맛(Saltiness), 매운맛(Hot taste), 전반적 기호도(Overall quality)의 특성으로 구성하였으며, 7점 척도법으로 선호도가 높을수록 높은 점수를 주도록 하였다. The sensory evaluation of the ginger green tea candy prepared in the same manner as in Example 1 was conducted in the "Fudisu Mam Academy Preliminary Mam Class" which is operated by Ildong Foods Co., Ltd., to describe the purpose and purpose of the experiment The subjects who did not have enough sensory sensation were selected as a panel of 15 subjects in the experiment group. Sensory test items consisted of color, flavor, sweetness, saltiness, hot taste, and overall quality. The higher the preference by the 7 point scale method, I gave a high score.

그 결과, 표 4와 같이 색은 3.73~5.32, 향은 4.05~5.05, 단맛 3.67~5.14, 짠맛 3.59~5.09, 매운맛 3.55~5.15 및 전반적인 기호도는 3.32~5.45 사이의 범위로 나타났다. 관능적 특성 모두에서 도 3과 같이 독립변수들 간에 교호 작용하는 2차 모델(quadratic model)이 결정되었다. 또한, 표 5와 같이 R2 값은 색 0.9538, 향 0.9447, 전반적인 기호도 0.8998로 모델의 적합성이 인정되었으며, p-value는 색 0.0089(p<0.01), 향 0.0126(p<0.05), 전반적인 기호도 0.0396(p<0.05)으로 유의적인 결과를 보였으며, 관능검사의 모든 항목에서 생강즙과 소금의 첨가량이 증가할수록 기호도가 증가하다가 일정 시점 이후에는 다시 감소하는 경향을 보였다. As a result, as shown in Table 4, the color was 3.73 to 5.32, the flavor was 4.05 to 5.05, the sweet taste was 3.67 to 5.14, the salty taste was 3.59 to 5.09, the hot taste was 3.55 to 5.15, and the overall preference ranged from 3.32 to 5.45. In both sensory characteristics, a quadratic model of interaction between independent variables was determined as in Fig. As shown in Table 5, the R 2 value of the model was 0.9538, 0.9447, and 0.8998, and the p value was 0.0089 ( p <0.01), 0.0126 ( p <0.05) ( p <0.05). The sensory evaluation showed that the preference of ginger juice and salt increased with the addition of ginger juice and salt.

상기 결과는 흑삼 농축액 첨가 젤리(Kim 등 2010)연구에서 대조군보다 흑삼 농축액 1% 첨가 수준에서 가장 높은 기호도를 보이다가 농도가 증가할수록 감소한다는 연구 결과와 유사한 경향을 보였으나, 본 연구에 비해 매우 낮은 농도에서 기호도가 높게 나타났다. These results were similar to those of the study that the concentration of black ginseng concentrate added jelly (Kim et al. 2010) showed the highest preference at 1% addition of black ginseng concentrate and decreased with increasing concentration. However, Concentration was high in concentration.

Sample No.Sample No. Variable levelsVariable levels ResponsesResponses Ginger juice
(g)
Ginger juice
(g)
water
(g)
water
(g)
Salt
(g)
Salt
(g)
ColorColor FlavorFlavor SweetnessSweetness SaltnessSaltness Hot tasteHot taste Overall qualityOverall quality
1One 22 1414 0.50.5 4.32 4.32 4.45 4.45 4.45 4.45 4.45 4.45 4.65 4.65 4.63 4.63 22 1414 22 0.50.5 3.73 3.73 4.05 4.05 3.86 3.86 3.82 3.82 3.60 3.60 3.32 3.32 33 22 1414 33 4.55 4.55 4.18 4.18 4.09 4.09 3.59 3.59 4.30 4.30 3.79 3.79 44 1414 22 33 4.41 4.41 4.19 4.19 3.67 3.67 3.95 3.95 3.55 3.55 3.32 3.32 55 22 1414 1.751.75 4.57 4.57 4.59 4.59 4.36 4.36 4.09 4.09 4.25 4.25 4.26 4.26 66 1414 22 1.751.75 4.55 4.55 4.67 4.67 4.55 4.55 4.23 4.23 4.00 4.00 4.05 4.05 77 88 88 0.50.5 4.59 4.59 4.50 4.50 4.27 4.27 4.36 4.36 3.90 3.90 4.11 4.11 88 88 88 33 4.86 4.86 4.32 4.32 4.00 4.00 3.82 3.82 3.85 3.85 3.68 3.68 99 88 88 1.751.75 5.27 5.27 5.05 5.05 5.14 5.14 4.95 4.95 5.05 5.05 5.21 5.21 1010 88 88 1.751.75 5.32 5.32 5.05 5.05 5.14 5.14 5.09 5.09 5.15 5.15 5.45 5.45

1) Mean 1) Mean

ResponsesResponses ModelModel R-squared1 ) R-squared 1 ) F-valueF-value P-value
Prob > F2)
P-value
Prob> F 2)
Equation of on terms of pseudo componentEquation of terms on pseudo component
ColorColor QuadraticQuadratic 0.95380.9538 16.530816.5308 0.0089** 0.0089 ** 5.221-0.125A+0.196B+0.113AB-0.588A2-0.419B25.221-0.125A + 0.196B + 0.113AB-0.588A2-0.419B2 FlavorFlavor QuadraticQuadratic 0.94470.9447 13.674713.6747 0.0126* 0.0126 * 4.980-0.054A-0.051B+0.104AB-0.287A2-0.507B24.980-0.054A-0.051B + 0.104AB-0.287A2-0.507B2 SweetnessSweetness QuadraticQuadratic 0.84410.8441 4.33434.3343 0.09020.0902 4.975-0.138A-0.138B+0.041AB-0.359A2-0.677B24.975-0.138A-0.138B + 0.041AB-0.359A2-0.677B2 SaltnessSaltness QuadraticQuadratic 0.84040.8404 4.21354.2135 0.09420.0942 4.814-0.022A-0.212B+0.250AB-0.448A2-0.516B24.814-0.022A-0.212B + 0.250AB-0.448A2-0.516B2 Hot tasteHot taste QuadraticQuadratic 0.69410.6941 1.81571.8157 0.29160.2916 4.778-0.341A-0.075B+0.075AB-0.332A2-0.582B24.778-0.341A-0.075B + 0.075AB-0.332A2-0.582B2 Overall QualityOverall Quality QuadraticQuadratic 0.89980.8998 7.18917.1891 0.0396* 0.0396 * 5.104-0.166A-0.043B-0.039AB-0.720A2-0.983B25.104-0.166A-0.043B-0.039AB-0.720A2-0.983B2

A: ginger juice, B: SaltA: ginger juice, B: Salt

1) 0<R2<1, close to 1 means more significant 1) 0 <R 2 <1, close to 1 means more significant

2) * p<0.05, ** p<0.01 2) * p < 0.05, ** p < 0.01

<< 실시예Example 5> 캔디 품질 최적화 5> Optimize candy quality

품질 최적화는 1950년대 도입되어 최근 Food science와 technology databases에 일반적으로 사용되고 있는 response surface methodolory(Reinheimer 등 2011) 중 중심합성계획법(central composite design)에 따라 확인하였다. Quality optimization was introduced in the 1950s and confirmed by the central composite design of the response surface methodology (Reinheimer et al. 2011), which is currently used in food science and technology databases.

독립변수로는 생강함초캔디의 맛에 가장 영향을 많이 주는 생강즙과 소금을 두 가지를 요인으로 설정하였으며, 종속변수로는 기계적 검사로 캔디의 명도(L, lightness), 적색도(a, redness) 및 황색도(b, yellowness)와 같은 색도, pH, 염도, 경도(Hardness) 및 용해도를 측정하였다. 관능 평가 항목은 색(Color), 향(Flavor), 단맛(Sweetness), 짠맛(Saltiness), 매운맛(Hot taste), 전반적인 기호도(Overall quality)로 설정하였다.Two independent variables were ginger juice and salt, which were the most influential on the taste of ginger green tea candy. Luminosity (L, lightness), redness (a, redness) PH, salinity, hardness, and solubility such as yellow color (b, yellowness) were measured. Sensory evaluation items were set to Color, Flavor, Sweetness, Saltiness, Hot taste, Overall quality.

생강함초캔디의 품질 최적화 분석은 독립변수인 생강즙과 소금의 양을 Design Expert 8 통계 프로그램을 이용하여 선정하고, 지점 예측(point prediction)을 통해 최적점을 확인하였다. 각 실험군의 종속변수(용해도, 당도, 염도 및 pH, 색도, 경도, 관능평가)간의 관계를 확인하기 위해 중첩등고선도와 반응표면등고선도 3D plot을 이용하였고, 수치 최적화는 아래의 계산식과 같이 적합도(desirability)를 구하고 가장 높은 적합도를 나타내는 최적점을 채택하였다(Lee & Joo 2014).The quality optimization analysis of ginger green tea candy was performed by selecting the independent variables ginger juice and salt amount using the Design Expert 8 statistical program and confirming the optimal point by point prediction. In order to confirm the relationship between the dependent variables (solubility, sugar content, salinity and pH, color, hardness, sensory evaluation) of each experimental group, 3D plot of overlap contour and response surface contour lines was used. (Lee & Joo, 2014). In addition, the optimal score for the best fit was adopted.

Figure pat00001
Figure pat00001

생강함초캔디의 제조조건 최적화를 위해 Canonical 모형의 수치 최적화(numerical optimization) 예측 값은 독립변수인 생강즙과 소금의 배합 범위 내에서 유의적인 결과를 나타낸 색, 향, 전반적인 기호도를 최대로 설정하였다. 지점 예측을 통해 최고의 적합도(desirability)를 나타낸 최적점을 선택하여 도출하였으며, 최적점으로 도출된 생강함초캔디는 생강즙 7.75g, 소금 1.77g으로 예측되었고, 이 때 사용된 반응 모형을 이용한 모형 최적화(graphical optimization)와 중첩등고선도는 도 4와 같이 확인되었다.In order to optimize the manufacturing conditions of ginger green tea candy, the numerical optimization predictions of Canonical model were set to maximum color, aroma, and general preference which showed significant results within the range of independent variables ginger juice and salt. The optimum point of the best ginger green tea candy was estimated to be 7.75 g of ginger juice and 1.77 g of ginger juice. graphical optimization and overlapping contour maps were confirmed as shown in FIG.

상기 결과들로부터 생강함초캔디는 캔디 100g 기준으로 생강즙 7.65g과 소금 1.75g의 적은 양으로도 임신부의 입덧을 완화시킬 수 있음이 확인되었다. 현재 시판되고 있는 임신부용 캔디는 신맛 나는 과일캔디로 pH가 낮고 캔디 섭취의 단점 중 장기적인 산의 노출로 치아 에나멜이 부드러워지고, 치아 마모의 위험으로 임신부의 치아를 더욱 손상시킬 수 있으나, 본 발명에 따른 캔디는 치아 손상에도 덜 위해한 임산부용 캔디제품으로 임신부의 입덧과 속편함에도 효과가 있다.From the above results, it was confirmed that ginger green tea candy can alleviate the morning sickness of pregnant woman even with a small amount of 7.65 g of ginger juice and 1.75 g of salt based on 100 g of candy. The currently marketed candy for pregnant women is a sour fruit candy which is low in pH and can be damaged by the long-term acid exposure of soft candy, which may soften the tooth enamel and further damage the pregnant tooth due to risk of tooth wear. The candy according to the present invention is effective for the morning sickness and sequelae of the pregnant woman.

또한, 임신부라는 특수 집단을 대상으로 한 제품개발연구는 아직까지 매우 희소하여 다양한 제품이 개발되고 있지 못함에 따라, 임신부들이 쉽게 섭취할 수 있는 생강함초캔디는 임신부의 특성에 맞게 영양적, 기능적 및 기호도 측면에서도 우수한 제품으로 제공될 수 있다.In addition, research on the development of a product targeting a special group of pregnant women is so rare that various products have not been developed. Therefore, ginger powdery candy, which can be easily ingested by pregnant women, is nutritionally, functionally, It can be provided as an excellent product in terms of preference.

이상으로 본 발명 내용의 특정한 부분을 상세히 기술하였는 바, 당업계의 통상의 지식을 가진 자에게 있어서, 이러한 구체적 기술은 단지 바람직한 실시양태일 뿐이며, 이에 의해 본 발명의 범위가 제한되는 것이 아닌 점은 명백할 것이다. 따라서 본 발명의 실질적인 범위는 첨부된 청구항들과 그것들의 등가물에 의하여 정의된다고 할 것이다.While the present invention has been particularly shown and described with reference to specific embodiments thereof, those skilled in the art will appreciate that such specific embodiments are merely preferred embodiments and that the scope of the present invention is not limited thereby. something to do. It is therefore intended that the scope of the invention be defined by the claims appended hereto and their equivalents.

Claims (7)

생강과 물을 함께 분쇄하여 분쇄물을 준비하는 단계;
상기 분쇄물에서 육질과 생강즙으로 분리하는 단계;
상기 분리된 생강즙을 냉장보관하여 전분을 제거하는 단계;
상기 전분이 제거된 생강즙을 농축하는 단계;
상기 농축된 생강즙에 설탕, 소금, 함초, 물엿 및 물을 혼합하여 가열하는 단계; 및
상기 가열된 혼합물을 성형틀에 넣어 성형하는 단계를 포함하는 생강함초캔디 제조방법.
Grinding ginger and water together to prepare a pulverized product;
Separating the pulverized product into meat and juice;
Storing the separated ginger juice in a refrigerator to remove starch;
Concentrating the ginger juice from which the starch has been removed;
Mixing the concentrated ginger juice with sugar, salt, green tea, millet, and water and heating; And
And molding the heated mixture in a mold.
청구항 1에 있어서, 상기 농축된 생강즙은 1 내지 4% 브릭스(brix)로 농축된 것을 특징으로 하는 생강함초캔디 제조방법.[Claim 2] The method according to claim 1, wherein the concentrated ginger juice is concentrated at 1-4% brix. 청구항 1에 있어서, 상기 생강함초캔디는 캔디 총 100 중량부에 대하여, 생강즙 5 내지 12 중량부, 설탕 50 내지 80 중량부, 소금 0.3 내지 3 중량부, 함초 0.5 내지 1 중량부, 물엿 14 내지 18 중량부 및 물 5 내지 12 중량부를 포함하는 것을 특징으로 하는 생강함초캔디 제조방법.The ginger green tea candy according to claim 1, wherein the ginger green tea candy comprises 5 to 12 parts by weight of ginger juice, 50 to 80 parts by weight of sugar, 0.3 to 3 parts by weight of salt, 0.5 to 1 part by weight of green tea, And 5 to 12 parts by weight of water. 청구항 1에 있어서, 상기 생강함초캔디는 캔디 100g에 대하여, 생강즙 7.65g 및 소금 1.75g을 포함하는 것을 특징으로 하는 생강함초캔디 제조방법.The method according to claim 1, wherein the ginger green tea candy comprises 7.65 g of ginger juice and 1.75 g of salt per 100 g of candy. 청구항 1에 있어서, 상기 농축된 생강즙에 설탕, 소금, 함초, 물엿 및 물을 혼합하여 가열하는 단계는 서서히 가열하여 120 내지 150℃까지 가열하는 것을 특징으로 하는 생강함초캔디 제조방법.The method according to claim 1, wherein the step of mixing and heating the concentrated ginger juice with sugar, salt, green tea, millet, and water is gradually heated to 120 to 150 ° C. 청구항 1 내지 청구항 5 중 어느 한 항의 방법에 따라 제조된 입덧 예방 또는 개선용 생강함초캔디.A ginger green tea candy for preventing or improving morning sickness produced according to the method of any one of claims 1 to 5. 청구항 1 내지 청구항 5 중 어느 한 항의 방법에 따라 제조된 생강함초캔디를 유효성분으로 함유하는 입덧 예방 또는 개선용 식품조성물.A food composition for preventing or improving morning sickness containing ginger powdery candy according to any one of claims 1 to 5 as an active ingredient.
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KR20150114699A (en) * 2014-04-02 2015-10-13 이섭이 manufacturing method of candy
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JPH06113743A (en) * 1992-10-02 1994-04-26 Mikakutou Kk Healthy candy containing raw material of crude medicine in high concentration and its production
KR20030008446A (en) * 2001-07-18 2003-01-29 정영내 morning sickness relief compositions of which chief ingredient is ginger
KR20150096990A (en) 2014-02-17 2015-08-26 신안군 The composition and manufactur methods of candy using Saliocomia herbacea L
KR20150114699A (en) * 2014-04-02 2015-10-13 이섭이 manufacturing method of candy
KR20160060871A (en) * 2014-11-20 2016-05-31 김성춘 Method for Preparing Ginger Tea and Ginger Tea Composition thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20220143999A (en) * 2021-04-16 2022-10-26 금산덕원인삼약초영농조합법인 manufacturing methods of balloon flower hydrolysis concentration

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