KR20190047307A - Dye having ionized hydrogen and its producing method - Google Patents
Dye having ionized hydrogen and its producing method Download PDFInfo
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- A—HUMAN NECESSITIES
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- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A—HUMAN NECESSITIES
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- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
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Abstract
Description
본 발명은 수소를 용존시킴으로써 염색 후 두피와 모발에 대한 부작용을 개선하고 발색 및 색상 지속력을 높일 수 있는 염색제에 대한 것이다.The present invention relates to a dye capable of improving adverse effects on the scalp and hair after dyeing by dissolving hydrogen and enhancing color development and color sustainability.
미용시술 분야에서 화학제품의 사용빈도가 높은 염모제는 인체에 유해한 성분들이 많이 함유되어 있다. 머리 염색약에는 모발의 겉의 층(큐티클)을 열리게 하는 암모니아, 색상발색을 만들어내는 여러 가지의 화학합성을 촉진하는 파라페닐렌디아민(p-Phenylene diamine, PPD) 등의 유해물질이 함유되어 있다.In the field of cosmetic surgery, the hair dye that has a high frequency of use of chemical products contains many harmful components to the human body. Hair dyes contain harmful substances such as ammonia, which opens the outer layer of the hair (cuticle), and p-phenylene diamine (PPD), which promotes various chemical syntheses that produce color development.
미국의 접촉성 피부염학회(The American Dermatitis Society)에서 2006년 올해의 알러지 유발 물질(Allergen of the year)에 뽑힌 성분이기도 하다. 특히 흑색 염모제에 필수적으로 포함되어야 하는 발색제 성분이 ㄴ파라페닐렌디아민(PPD)은 산화제 성분인 과산화수소와 반응하여 생성되는 부산물이 발암성 물질이라고 알려져 있다.The American Dermatitis Society in the United States in 2006, this year's allergy-causing substance (Allergen of the year) is also a component. Particularly, it is known that paraphenylenediamine (PPD), which is a coloring agent component which is to be included in a black dyeing agent, is a carcinogenic substance which is produced by reacting with hydrogen peroxide which is an oxidizing agent component.
미용실에서 사용하는 다수의 염모제에 포함된 염료 중 PPD는 정확한 색상의 표현, 빠른 착색 등의 작용을 하므로 염료에 필수적으로 함유되어 있는 성분인바 PPD의 부작용을 개선하기 위한 조치가 필요로 되어왔다.Among the dyes contained in many hair dyes used in beauty salons, PPD has a function of expressing color accurately and fast coloring, and therefore, it has become necessary to take measures to improve side effects of PPD which is an essential component of dyes.
최근 세포의 에너지를 만들어내는 인체의 엔진, 미토콘드리아의 ATP 생성 기능을 음이온화된 수소수가 도와주는 역할을 할 수 있고, 이를 통해 수소수는 피부의 건강을 유지시켜 주는 성분으로 보고되고 있다.Recently, ATP production of mitochondria, the engine of the human body that produces the energy of the cell, can help the number of anionized hydrogen, and thus the water of water is reported to be a component that maintains skin health.
본 발명자는 수소수가 pH 9-11의 염모제를 중성화함으로써 PPD 등을 비롯한 발색제 성분의 독성을 순화시킬 수 있음에 착안하여 염모제에 수소수를 용존시킴으로써 독성을 완화하고 발색력을 높인 새로운 염색방법을 개발하여 본 발명을 완성하게 되었다.The inventors of the present invention have developed a new dyeing method in which the toxicity of dye components, including PPD, is neutralized by neutralizing the hair dye having a pH of 9 to 11 by dissolving hydrogen peroxide in the hair dye, thereby improving the coloring ability Thereby completing the present invention.
본 발명은 전기분해한 수소를 용존시킨 염색제를 제공하는 것을 목적으로 한다.An object of the present invention is to provide a staining agent in which electrolyzed hydrogen is dissolved.
염모제는 통상 발색제 및 알칼리제를 포함한 제1제와 산화제를 포함한 제2제로 구성된다. The hair dye is usually composed of a first agent containing a coloring agent and an alkaline agent and a second agent containing an oxidizing agent.
본 발명의 염색제는 하기 단계를 거쳐 제조된다:The dye of the present invention is prepared by the following steps:
정제수에 수소가스 발생장치를 이용하여 정제된 물에 수소를 침전시켜 수소수를 생성하는 단계,Precipitating hydrogen in purified water by using a hydrogen gas generator in purified water to produce hydrogen peroxide,
생성된 수소수와 염색 제1제 제조용 원료를 혼합하여 교반한 후 약 20-30℃의 온도에서 유화시키는 단계,Mixing the resultant aqueous hydrogen peroxide with a raw material for preparing a dye preparation agent, stirring the mixture, and emulsifying the mixture at a temperature of about 20 to 30 ° C,
유화된 수소수 함유 염색 제1제에 마그네슘카보네이트를 0.01 내지 0.1 중량비로 첨가한 후 수소가스 발생장치를 이용하여 수소 용존율 2000ppb 이상이 될 때까지 수소가스를 주입하여 수소 함유 염색 제1제를 얻는 단계, 및 A magnesium chloride is added to the emulsified hydrophilic dye-containing dye 1 at a ratio of 0.01 to 0.1 weight ratio, and hydrogen gas is injected until a hydrogen dissolution rate of at least 2000 ppb is reached using a hydrogen gas generator to obtain a hydrogen- Step, and
수소 함유 염색 제1제를 질소를 이용하여 용기에 투입하여 포장하는 단계.The step of charging the hydrogen-containing dyeing agent into the vessel using nitrogen.
상기 수소수 함유 염색 제1제내 수소용존율은 2000ppb 내지 3000ppb 인 것이 바람직하다.It is preferable that the hydrogen dissolution rate in the dye-containing dye containing the hydrogen-containing water is 2000 ppb to 3000 ppb.
상기 염색 제1제 제조용 원료는 통상적으로 사용될 수 있는 발색제, 항산화제, 알칼리제, 점도증진제, 유화제, pH 안정제, 식물유래오일, 향료 및 정제수를 포함할 수 있다.The raw materials for preparing the dye 1 can include commonly used coloring agents, antioxidants, alkalis, viscosity enhancers, emulsifiers, pH stabilizers, plant-derived oils, fragrances and purified water.
본 발명의 제1제와 함께 사용하는 산화제인 제2제는 통상 사용되는 조성의 제2제를 사용할 수 있으나, 가장 바람직하게는 과산화수소를 5 내지 6 중량%로 포함하는 것을 사용한다.The second agent, which is an oxidizing agent used in combination with the first agent of the present invention, may be a second agent of a commonly used composition, but most preferably contains 5 to 6% by weight of hydrogen peroxide.
본 발명의 수소가 용존된 염색제를 사용하면, 제1제에 용존된 수소의 작용으로 염모제의 사용으로 인한 옻 오름이나 알러지가 완화되고 PPD(파라페닐렌 디아민) 등을 비롯한 발색제 성분의 반복적 사용에 의해 유발되는 부작용이 예방되며, 모발에 발색의 촉진 및 착색 후 오래 유지되도록 하는 효과가 있다. When the hydrogen-dissolved dye of the present invention is used, the action of hydrogen dissolved in the first agent reduces poisoning and allergy caused by the use of the hair dye, and the repeated use of the coloring agent component such as PPD (paraphenylenediamine) And it has an effect of promoting color development in hair and keeping it long after coloration.
특히, 손상모일 경우 기존 염모제를 모발에 도포한 후 착색까지의 시간이 오래 걸리고, 착색 후에도 퇴색되거나 탈색이 빠르게 이루어지지만, 수소수를 용존시킨 본 발명의 염모제를 사용하면 음이온화된 수소의 역할로 독성물질이 제거되면서 암모니아 기능에 상승작용을 하므로 착색에 소요되는 시간이 단축되고, 착색 후에도 퇴색이나 탈색 현상이 현저하게 지연될 수 있다. Particularly, in the case of damaged hair, it takes a long time until coloring after applying the existing hair dye to the hair, and even after coloring, it is faded or decolorized rapidly. However, when the hair dye used in the present invention in which water is dissolved is used, it acts as an anionized hydrogen Since toxic substances are removed, they have a synergistic effect on the ammonia function, so that the time required for coloring is shortened, and fading or decolorization phenomenon may be significantly delayed even after coloring.
나아가, 통상적으로 염모제를 재도포하는 경우 앞서 염색한 색상과 겹쳐져 원하는 발색이 어려운데, 본 발명의 염모제를 사용하면, 앞선 염색의 색상제거 활성으로 기존 염색과 새로운 염색간의 얼룩짐이 현저하게 방지되고, 색상의 변경에도 기존 염모제의 잔여 색상이 남지 않아 원하는 발색이 가능하다.Further, when the hair dye is redeposited, it is difficult to achieve the desired color development by overlapping with the previously colored hair. When the hair dye is used, the unevenness between the existing dye and the new dye is remarkably prevented by the color removal activity of the previous dye, The remaining color of the existing hair dye does not remain, so that desired color development is possible.
본 발명에 따르면, 염색 시간이 매우 단축되고 염색 후 모발의 손상이 줄어들 것이 기대되며 재염색시 잔존 염색제의 영향이 줄어든다는 효과가 기대된다.According to the present invention, it is expected that the dyeing time is greatly shortened, the hair damage after dyeing is reduced, and the effect of the residual dye is reduced in re-dyeing.
도1은 염색제 10분 도포 후 발색 정도를 비교한 사진이고,
도2는 염색제 20분 도포 후 발색 정도를 비교한 사진이며,
도3은 염색제 30분 도포 후 발색 정도를 비교한 사진이다.Fig. 1 is a photograph showing the degree of color development after the application of the dye for 10 minutes,
2 is a photograph showing the degree of color development after the application of the dye for 20 minutes,
3 is a photograph comparing the degree of color development after application of the dye for 30 minutes.
이하, 실시예를 통하여 본 발명의 구성 및 효과를 더욱 상세히 설명하고자 한다. 이들 실시예는 오로지 본 발명을 예시하기 위한 것일 뿐, 본 발명의 범위가 이들 실시예에 의해 한정되는 것은 아니다.Hereinafter, the constitution and effects of the present invention will be described in more detail through examples. These examples are only for illustrating the present invention, and the scope of the present invention is not limited by these examples.
실시예1Example 1 : 본 발명의 방법에 따른 염색: Dyeing according to the method of the present invention
하기 표와 같은 성분들의 조합으로 이루어진 채운 통상의 염모제 제1제를 제조하였다. A filled conventional hair dye formulation 1 was prepared by combining the following ingredients.
상기 제1제 혼합 후 마그네슘 카보네이트를 상기 제1제 총 중량에 대해 0.01 중량비로 첨가한 다음, 수소가스발생장치(HYGEN TECH HG-3800S 사용)를 이용하여 수소 용존량을 2000ppb 이상으로 용존시켰다. 이와 같이 수소가 용존된 제1제를 하기 표2 조성의 염색 제2제와 혼합하여 백색의 인조모발에 도포하였다. After mixing the first agent, magnesium carbonate was added in a ratio of 0.01 weight part based on the total weight of the first agent. Then, the amount of dissolved hydrogen was dissolved to not less than 2000 ppb by using a hydrogen gas generator (HYGEN TECH HG-3800S). The first agent in which hydrogen was dissolved was mixed with the dyeing agent 2 of the following Table 2 and applied to white artificial hair.
비교예1: 수소수를 용존시키지 아니한 일반 염모제로의 염색Comparative Example 1: Dyeing with a general dyeing agent which did not dissolve hydrogenated water
수소를 제외하고 표1의 성분과 동일하고 수소 함량은 정제수로 대체된 성분비의 염모제1제를 표2의 제2제와 혼합하여 백색의 인조모발에 도포하였다.Hydrogen content was the same as that of Table 1 except for hydrogen, and 1 part of the hair dye having the component ratio replaced with purified water was mixed with the second part of Table 2 and applied to white artificial hair.
실험예1Experimental Example 1 : 염색 도포 시간별 : Dye application time 발색Color 정도의 비교 Comparison of degree
상기 실시예 1 및 비교예 1의 방법과 같이 염색하되 제1제를 도포한 후 실내 온도 25℃에서 각각 10분, 20분 및 30분 경과 후의 모발의 발색 정도를 사진으로 촬영하였다. The color of the hair after 10 minutes, 20 minutes and 30 minutes at room temperature of 25 ° C was photographed in the same manner as in Example 1 and Comparative Example 1, except that the first agent was applied.
그 결과는 도 1 내지 도3에 나타내었다. The results are shown in Figs.
도 1은 10분 경과 후 실시예와 비교예의 발색 정도를 비교한 사진인데, 본 발명에 따른 수소수를 용존시켜 도포한 경우(실시예) 진하게 발색되었고 일반 염모제로 염색한 경우(비교예) 10분으로는 흰색의 모발이 40% 이상 남아 있었다.FIG. 1 is a photograph showing the degree of color development of Examples and Comparative Examples after 10 minutes. FIG. 1 is a photograph showing the results obtained by dissolving hydrogenated water according to the present invention (Example), dark coloring and dying with a general hair dye (Comparative Example) At least 40% of white hair remained.
도2는 20분 경과 후 실시예와 비교예의 발색 정도를 비교한 사진인데, 실시예에 따른 경우 보다 진하고 선명하게 발색되었고 비교예는 흰색 모발이 20% 정도 남았으며 진하기도 실시예에 비해 흐리게 선명도가 떨어졌다. FIG. 2 is a photograph comparing the color development degree of the example and the comparative example after lapse of 20 minutes. The color was darker and sharper than that according to the example. In the comparative example, about 20% of white hair was left, Fell.
도3은 30분 경과 후 실시예와 비교예의 발색 정도를 비교한 사진인데, 실시예의 경우 상당히 진한 발색 결과가 확인된 반면 비교예의 경우 실시예에 비해 눈에 띄게 발색이 덜 되었음을 확인할 수 있었다.FIG. 3 is a photograph comparing the color development degree of the example and the comparative example after the lapse of 30 minutes. In the case of the example, the color development was confirmed to be considerably dark, but in the comparative example, the color development was noticeably less than that in the example.
본 발명에 따른 수소가 함유된 염색제를 이용하여 염색하면 염색 시술로 손상이 줄어들고 발색 시간이 단축된 염색 시술이 가능하게 되므로 오랫동안 정형적인 염색방법이 주를 이루던 염색 시장에 새로운 염색제가 도입됨으로써 미용 시장의 활성화를 기대할 수 있을 것이다.Since the dyeing using the hydrogen-containing stain agent according to the present invention can reduce the damage by the dyeing procedure and shorten the coloring time, the new stain agent is introduced into the dyeing market, which has been dominated by the stereotyped dyeing method for a long time, It can be expected to activate.
A: 비교예에 따른 결과
B: 실시예에 따른 결과A: Results according to comparative example
B: Results according to the embodiment
Claims (2)
생성된 수소수와 염색 제1제 제조용 원료를 혼합하여 교반한 후 약 20-30℃의 온도에서 유화시키는 단계,
유화된 수소수 함유 염색 제1제에 마그네슘카보네이트를 0.01 내지 0.1 중량비로 첨가한 후 수소가스 발생장치를 이용하여 수소 용존율 2000ppb 이상이 될 때까지 수소가스를 주입하여 수소 함유 염색 제1제를 얻는 단계, 및
수소 함유 염색 제1제를 질소를 이용하여 용기에 투입하여 포장하는 단계로 구성되는 수소 함유 염색제 제조방법.Precipitating hydrogen in purified water by using a hydrogen gas generator in purified water to produce hydrogen peroxide,
Mixing the resultant aqueous hydrogen peroxide with a raw material for preparing a dye preparation agent, stirring the mixture, and emulsifying the mixture at a temperature of about 20 to 30 ° C,
A magnesium chloride is added to the emulsified hydrophilic dye-containing dye 1 at a ratio of 0.01 to 0.1 weight ratio, and hydrogen gas is injected until a hydrogen dissolution rate of at least 2000 ppb is reached using a hydrogen gas generator to obtain a hydrogen- Step, and
And a step of putting the hydrogen-containing dye-forming agent into a vessel using nitrogen and packaging the hydrogen-containing dye-forming agent.
A stain agent having a hydrogen dissolution rate of 2000 ppb to 3000 ppb prepared by the method of claim 1.
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JP5627170B2 (en) * | 2004-09-24 | 2014-11-19 | ザ プロクター アンド ギャンブルカンパニー | High speed hair dyeing method |
KR101669545B1 (en) * | 2016-07-01 | 2016-10-28 | 주식회사 수소나라 | scalp integrated management apparatus using the hydrogen |
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JP5627170B2 (en) * | 2004-09-24 | 2014-11-19 | ザ プロクター アンド ギャンブルカンパニー | High speed hair dyeing method |
KR101669545B1 (en) * | 2016-07-01 | 2016-10-28 | 주식회사 수소나라 | scalp integrated management apparatus using the hydrogen |
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